Patents Assigned to Henkel Kommanditgesellschaft
  • Patent number: 5840786
    Abstract: The invention relates to a plastisol composition based on bead polymers. The bead polymers preferably have a core/shell structure and an average diameter of 1 to 150 .mu.m. The bead polymers are preferably chlorine-free and are made up at least of a) styrene, .alpha.-methyl styrene and/or p-methyl styrene on the one hand and b) 2 to 20% by weight (based on the copolymer) of olefinically unsaturated carboxylic acids. The plastisol composition according to the invention may be used for the production of coating compositions, sealing compounds and adhesives.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: November 24, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Michael Beck, Lutz Jeromin, Christiane Hoeltgen, Wolfgang Ritter
  • Patent number: 5834275
    Abstract: A process is provided for deodorizing an aqueous culture broth composition by: (a) providing an aqueous culture broth composition containing odorous compounds in spray form; (b) providing a stream of superheated steam; (c) providing a spray zone in vacuo; (d) simultaneously introducing both the aqueous composition of (a) and the superheated steam into the spray zone causing the odorous compounds to be entrained in the superheated steam, thus forming a deodorized aqueous culture broth composition; (e) removing the superheated steam containing the entrained odorous compounds from the spray zone; and (f) discharging the deodorized aqueous culture broth composition from the spray zone. Preferably, the culture broth composition is maintained at a temperature of less than 50.degree. C. in the spray zone to prevent inactivation of temperature-sensitive materials such as enzymes. Pressure in the spray zone may be about 10 to 250 mbar and temperature of the superheated steam can be up to 250.degree. C.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: November 10, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wilfried Raehse, Kathleen Paatz, Werner Pichler, Horst Upadek
  • Patent number: 5830260
    Abstract: The waste gas accumulating in the drying of products containing volatile ingredients is cooled, the condensate obtained is subjected to crossflow membrane filtration and part of the cleaned waste gas is returned to the drying process. The concentrate obtained is put to a material, thermal or other use. The both effective and economic process is suitable for eliminating the aerosols, particularly the organic aerosols, present in the waste gas.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: November 3, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Levent Yueksel, Wilhelm Johannisbauer, Katrin Burmeister, Heike Fleischmann
  • Patent number: 5830483
    Abstract: An oil-in-water emulsion comprising(A) from about 50 to about 99% by weight of water;(B) from about 1 to about 30% by weight of an oil phase; and(C) an emulsifying effective quantity of an emulsifier system consisting essentially of(i) at least one nonionic emulsifier of formula (I):Z.sub.x R.sup.1 (R.sup.2 --CO).sub.y G.sub.z (I)in which Z is a sugar unit selected from the group consisting of pentoses and hexoses, x is a number of 1 to 5, R.sup.1 is a saturated alkyl radical containing 1 to 3 carbon atoms, R.sup.2 is a linear or branched alkyl radical or mono- or polyunsaturated alkenyl radical containing 8 to 22 carbon atoms, y is the number 1 or 2, G is a polyglycerol residue consisting of 2 to 10 glycerol units and z is the number 1 or 2, and(ii) at least one ionic emulsifier selected from the group consisting of cationic and anionic emulsifiers.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: November 3, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Kurt Seidel, Christian Priebe, Detlef Hollenberg
  • Patent number: 5827393
    Abstract: Hot melt adhesives having an "open time" of 10 minutes or longer, preferably more than 1 hour and, more preferably, more than 2 hours for a contact pressure of 5 kg/cm.sup.2 and atmospheric conditions of 25.degree. C./26% relative air humidity are provided. Immediately after the parts to be joined have been pressed together at 18.degree. to 23.degree. C., strengths (initial strengths) of 1 MPa and more and preferably more than 1.5 MPa are obtained. The hot melt adhesive is comprised of 1) a polyester, polyamide, polyethylene/vinyl acetate, or NCO-terminated polyurethane prepolymer which does not crystallize during the open time and 2) a tackifier and/or a plasticizer.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: October 27, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans-Georg Kinzelmann, Regina Biele
  • Patent number: 5827456
    Abstract: A plastic bottle, made of polyethylene (PE), polypropylene (PP), or poly(ethylene terephthalate) (PET), blown with a very thin overall wall thickness within the range 0.1 to 0.3 mm, includes a triangular or polygonal cross-section, the bottle being preferably surrounded by a supporting jacket. The bottle can be blown with a uniform wall thickness and adequate strength without the need for reinforcing ribs via walls formed by pressing them against the surface of a blow mold which has been worked at least in some areas by etching, form-cutting or eroding, having features with heights of 0.05 to 0.15 mm.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: October 27, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rainer Bergner, Hubert Droessler, Peter Kittscher, Siegfried Konkel, Volker Weiss, Paul-Otto Weltgen
  • Patent number: 5824633
    Abstract: Heterogenous surfactant granules consisting of an inner core containinga) alkyl sulfates corresponding to formula (I):R.sup.1 O--SO.sub.3 X (I)in which R.sup.1 is an alkyl radical containing 16 to 18 carbon atoms and X is an alkali metal or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium, andb1) alkyl sulfates corresponding to formula (II):R.sup.2 O--SO.sub.3 X (II)in which R.sup.2 is an alkyl radical containing 12 to 14 carbon atoms and X is as defined above, orb2) alkyl ether sulfates corresponding to formula (III):R.sup.3 O(CH.sub.2 CH.sub.2).sub.n SO.sub.3 X (III)in which R.sup.3 is an alkyl radical containing 16 to 18 carbon atoms, n is a number of 1 to 3 and X is as defined above,and a coating over the inner core consisting of alkyl sulfates corresponding to formula (II), with the provisos that the ratio by weight of component a) to component b) in the inner core is 100:0 to 30:70, and the ratio by weight of the inner core to the coating is 99.5:0.5 to 90:10.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: October 20, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ditmar Kischkel, Karl Schmid, Andreas Syldath, Thomas Krohnen
  • Patent number: 5819505
    Abstract: Continuous anti-adherent treatment process for a surface-tacking thermofusible adhesive, characterized in that a carrier belt (1) is continuously displaced in translation, the upper surface thereof being cooled by its lower face, said surface being covered by a layer (3) of an anti-adherent protection product, the thermofusible adhesive (4) to be treated being deposited on the protection product layer. The assembly (7) comprising of the adhesive (4) and the layer (3) of protection product is folded back on itself so as to release a composite material (8) consisting of a double thickness (4, 4') of thermofusible adhesive sandwiched between two layers (9, 9') of anti-adherent protection product (3) and the composite material is cut into fragments.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: October 13, 1998
    Assignees: Henkel France, Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Jean Fayolle, Daniel Grandin, Heinrich Niethen, Michel Pierron, Jean-Louis Prevot
  • Patent number: 5821360
    Abstract: A process for producing polycarboxylic acids or their salts from polysaccharides is provided. Solid particulate polysaccharides having at least one primary alcohol group in the polysaccharides are oxidized with nitrogen dioxide in a fluid bed. The fluidizing gas contains nitrogen dioxide and the process is operated at a pressure of from 0.5 to 12 bars and a temperature between the boiling point of nitrogen dioxide and 160.degree. C. At least two moles of nitrogen dioxide for the equivalent of the primary alcohol groups reacted over the entire reaction are provided.
    Type: Grant
    Filed: July 31, 1996
    Date of Patent: October 13, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Konrad Engelskirchen, Herbert Fischer, Werner Juettner, Hans-Wilhelm Verholt, Thomas Moeller
  • Patent number: 5817254
    Abstract: An aqueous emulsion concentrate comprising:A) a water-insoluble oil component;B) at least one hydrophilic nonionic emulsifier;C) at least one lipophilic co-emulsifier; andD) from about 50 to about 70% by weight of water, based on the weight of the concentrate;wherein components A), B) and C) are present in a ratio by weight of A:B:C of 1:(0.31-1.5):(0.31-1.5); and wherein the emulsion concentrate is flowable and pumpable at 20.degree. C.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: October 6, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Armin Wadle, Achim Ansmann, Guido Baumoeller, Holger Tesmann
  • Patent number: 5814597
    Abstract: The invention relates to a solid material (primary drying product) containing alkali metal silicate with a modulus (molar ratio of SiO.sub.2 to M.sub.2 O, M=alkali metal) of 0.8 to 4 in homogeneous admixture with other inorganic and/or organic useful materials and/or auxiliaries, which has been dried from a finely sprayed aqueous preparation of mixtures of the alkali metal silicates and the inorganic and/or organic useful materials and/or auxiliaries by means of a hot gas stream. The solid material according to the invention is characterized in that, as a primary drying product in homogeneous admixture with the alkali metal silicate, it contains at least 10% by weight of water-soluble inorganic and/or organic salts, has apparent densities of at least 150 g/l, possesses a microporous absorbent internal structure and has been dried with superheated steam as the hot gas stream.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: September 29, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wilfried Raehse, Johann F. Fues, Kathleen Paatz, Wilhelm Beck, Wolfgang Hlavacek
  • Patent number: 5811386
    Abstract: A surface active mixture comprising: (A) from about 1 to about 50% by weight of an anionic surfactant having one or two lipophilic groups and having from 1 to 22 carbon atoms and a polar group selected from the group consisting of carboxylate, sulfate and sulfonate groups; (B) from about 0.5 to about 15% by weight of an alkyl glycoside of the formula R(G).sub.x, wherein R is a linear saturated alkyl radical having from 8 to 22 carbon atoms and (G).sub.x is a glycoside or oligoglycoside unit with a degree of oligomerization x of 1 to 10; (C) from about 0.1 to about 7% by weight of a nitrogen-containing copolymer having a molecular weight of from about 15,000 to about 1,500,000 wherein said copolymer is comprised of: (i) from about 99.5 to about 45 mole-% of units derived from vinyl pyrrolidone, (ii) from at 0.5 to about 50 mole-% of units derived from a monomer corresponding to formula (I):CH.sub.2 .dbd.CHR.sup.1 --COOR.sup.2 --NR.sup.3 R.sup.4 (I)R.sup.1 is hydrogen or methyl, R.sup.2 is a C.sub.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: September 22, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Reinhard Mueller, Kurt Seidel, Detlef Hollenberg, Manuela Ehlert
  • Patent number: 5811560
    Abstract: The invention pertains to a method for preparing 8-alpha,12-oxido-13,14,15,16, -tetranorlabdane by cyclizing a mixture of hydroxy-olefins (I)-(III. See the specification for their formulae. The cyclization is carried out in the presence of 10 to 100 wt. % acid, relative to the mixture of compounds (I) to (III).
    Type: Grant
    Filed: May 5, 1997
    Date of Patent: September 22, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Andreas Bomhard, Thomas Markert
  • Patent number: 5811594
    Abstract: Methyl-end-capped alkyl and/or alkenyl polyglycol ethers; a process for their production by methylation of products of the addition of ethylene oxide and propylene oxide to primary alcohols; to formulations containing these substances; and to the use of the substances for the production of surface-active formulations.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: September 22, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl Schmid, Joaquim Bigorra Llosas
  • Patent number: 5807529
    Abstract: A process for producing silicate or silicate-containing builder granules having an apparent density of at least 600 g/l by compacting silicate materials having an apparent density of less than 500 g/l, a molar ratio of SiO.sub.2 to Na.sub.2 O of 1.3 to 4, and a water content of up to 15% by weight, wherein the silicate materials are X-ray amorphous and are present in the form of a fine particle solid having a flake structure.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: September 15, 1998
    Assignee: Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Hans-Friedrich Kruse, Beatrix Kottwitz, Volker Bauer, Berthold Schreck, Joerg Poethkow, Wolfgang Breuer
  • Patent number: 5807502
    Abstract: An aqueous fatty alcohol dispersion containing:(a) 5% to 40% by weight of a Cl.sub.10 -C.sub.28 fatty alcohol;(b) 0.5% to 5% by weight of anionic interfacially active compounds;(c) 0.5% to 5% by weight of nonionic interfacially active compounds comprising the reaction products of ethylene oxide with alkane-1,2-diols containing 6 to 18 carbon atoms, and(d) the balance, water. The dispersion is useful as an antifoam agent.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: September 15, 1998
    Assignee: Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Horst-Werner Wollenweber, Rainer Hoefer, Heinz-Guenther Schulte
  • Patent number: 5806680
    Abstract: A process for filling a non-self-supporting pack with cylindrical, pellet-like products by introducing into a pack closely surrounding at least one multiple-row layer of the products in such a manner that the products are arranged beside and above one another in linear contact with one another at their cylindrical surfaces and are arranged closely adjacent one another in the pack so that they fit exactly into the pack, are self-supporting, and disperse a pressure applied externally to the pack through the cylindrical surfaces of the products. The pack is brought into a transportation position wherein the products are in an upright position. A pack unit of the products is also disclosed.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: September 15, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Barthel, Werner Kuenzel, Hubert Droessler, Monika Schmitt, Klaus Meyer, Stefan Huchler
  • Patent number: 5802815
    Abstract: A process for filling and self-sealing containers with molten materials is provided. The process comprises filling a container with a molten material and covering the surface of the molten material which is still at elevated temperature after filling with an insert consisting of a plastic film and a plastic disk. The plastic film faces the molten material and is larger than the plastic disk. The diameter of the plastic disk is slightly smaller than the internal diameter of said container.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: September 8, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Christoph Lohr, Krebs Michael, Robert Magunia
  • Patent number: 5804672
    Abstract: A mixture of an adduct of an epoxy resin and a novolak with an acrylate polymer, a modified bisphenol A or a polyol in conjunction with a polyisocyanate or a polyol of an OH-terminated polyurethane or polyester gives a heat-sealing adhesive combining high heat resistance and good hydrolysis stability with relatively high bond strengths. Accordingly, the composition is suitable above all as a base material and cover film for printed circuits.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: September 8, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Gerd Bolte, Gunter Henke, Ulrike Bruninghaus
  • Patent number: 5799829
    Abstract: The invention includes an adhesive-filled tube comprising a membrane-sealed mouth and a cannula, with a bore extending over is longitudinal axis, inseparably fixed to the mouth, and a closure cap releasably fixed to the cannula with a needle-like spike which is guided for displacement in the bore of the cannula, and which is held fixed by its head elements, the latter being thicker than its needle element, in a starting position in a recess of the closure cap provided with an access opening to the cannula with the opportunity for axial displacement into an opening position piercing the membrane. In particular, the danger of adhesive issuing from the cannula after the membrane has been pierced is reduced. To this end, a closure element is formed on the spike between the head element and the needle element bearing sealingly against the cannula outlet opening in the membrane-piercing opening position of the spike.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: September 1, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rolf Lier, Herbert Densky