Patents Assigned to Heraeus Precious Metals North America Conshohocken LLC
  • Patent number: 11289238
    Abstract: A solvent-free electroconductive composition may be used to make electroconductive lines on a surface of a substrate or electroconductive plugs within via holes of a substrate. The solvent-free electroconductive composition is generally made of about 40 to about 95 wt % of a conductive component, about 4 to about 30 wt % of a polymer or oligomer comprising a reactive functional group, up to about 20 wt % of a monomeric diluent comprising a reactive functional group, and up to about 3 wt % of a curing agent. In some instances, the solvent-free electroconductive composition further includes up to about 3 wt % of a lubricating compound. Substrates made using solvent-free electroconductive compositions may be used in printed circuit boards, integrated circuits, solar cells, capacitors, resistors, thermistors, varistors, resonators, transducers, inductors, and multilayer ferrite beads.
    Type: Grant
    Filed: December 4, 2019
    Date of Patent: March 29, 2022
    Assignee: HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC
    Inventor: Seigi Suh
  • Patent number: 11088104
    Abstract: A process for forming an electric heater comprising the steps: (a) providing a heater element and a power supply, (b) applying a layer of a copper paste onto the heater element and/or the power supply and drying the applied layer of copper paste, (c1) applying a solder agent onto the dried copper paste and appropriately arranging the heater element and the power supply such that the heater element and the power supply contact each other by means of the dried copper paste and the solder agent or (c2) appropriately arranging the heater element and the power supply such that the heater element and the power supply contact each other by means of the dried copper paste, and applying a solder agent next to the dried copper paste or (c3) if in step (b) the copper paste has been applied only onto the heater element and then dried, applying a solder agent onto the power supply and appropriately arranging the heater element and the power supply such that the heater element and the power supply contact each other by me
    Type: Grant
    Filed: October 22, 2019
    Date of Patent: August 10, 2021
    Assignee: HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC
    Inventors: Ryan Persons, Sebastian Fritzsche, Steffan Käss, Tanja Dickel
  • Patent number: 10287442
    Abstract: Electrically conductive polymeric compositions adapted for use in forming electronic devices are disclosed. The compositions are thermally curable at temperatures less than about 250° C. Compositions are provided which may be solvent-free and so can be used in processing or manufacturing operations without solvent recovery concerns. Core-shell conductive particles provide the conductivity of the compositions and devices contemplated herein.
    Type: Grant
    Filed: December 13, 2012
    Date of Patent: May 14, 2019
    Assignee: HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC
    Inventors: Hong Jiang, Aziz S. Shaikh
  • Patent number: 10224438
    Abstract: The invention provides an electroconductive paste comprising metallic particles, an inorganic reaction system, and an organic vehicle. The inorganic reaction system includes a lead-tellurium-magnesium composition of Formula (II): Pba—Teb—(Mgw—Cax—Sry—Baz)-Md-Oe, wherein 0<a, b, or d?1, 0?w, x, y, z?1, w+x+y+z=c, at least one of w, x, y and z is greater than zero, the sum of a, b, c and d is 1, 0<c?0.2, 0?d?0.5, a:b is between about 10:90 and about 90:10, (a+c+d):b is between about 10:90 and about 90:10, M is one or more elements, and e is a number sufficient to balance the Pb, Te, Mg—Ca—Sr—Ba and M components.
    Type: Grant
    Filed: March 10, 2017
    Date of Patent: March 5, 2019
    Assignee: HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN, LLC
    Inventors: Cuiwen Guo, Li Yan, Lei Wang
  • Patent number: 10217876
    Abstract: The invention relates to a passivated emitter rear solar cell, comprising a silicon substrate having a front and back surface, a rear passivation layer on the back surface of the silicon substrate having a plurality of open holes formed therein, an aluminum back contact layer formed in the open holes of the rear passivation layer, and at least one backside soldering tab on the back surface of the silicon substrate. The backside soldering tab is formed from an electroconductive paste composition comprising conductive metallic particles, at least one lead-free glass frit, and an organic vehicle comprising at least one silicone oil.
    Type: Grant
    Filed: March 24, 2017
    Date of Patent: February 26, 2019
    Assignee: HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC
    Inventors: Devidas Raskar, Yi Yang, Lixin Song, Guang Zhai
  • Patent number: 10115836
    Abstract: An inorganic reaction system comprising a lead-bismuth-tellurium-silicate composition of Formula (I): Pba—Bib—Tec—Sig-Md-Oe, wherein 0<a, b, c, d, or g?1, 0?d, e?1, and the sum of a, b, c, d and g is 1, 0<a?0.05, 0.2<b?0.95, 0<c?0.5, 0<d?0.2, 0<g?0.5, a:b is between about 0.1:99.9 to about 5:95, b:c is between about 50:50 to 99:1, a:c is between about 1:99 to about 10:90, b:g is between about 50:50 to about 98:2, M is one or more elements, and e is a number sufficient to balance the Pb, Bi, Te, Si, and M components.
    Type: Grant
    Filed: January 8, 2015
    Date of Patent: October 30, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Lei Wang, Cuiwen Guo, Raymond M. Cosimano, Li Yan, Brenton Yancey
  • Patent number: 10074456
    Abstract: A dielectric glass composition suitable for use in an electronic device which comprises a sufficient amount of silicon dioxide to impart durability to the glass composition when subject to a humid environment, and one or more alkali metal oxides, wherein (i) the total content of the alkali metal oxides is at least about 10 wt % and no more than about 35 wt %, based upon 100% total weight of the glass composition, (ii) the median particle size (d50) of the glass composition is no more than about 5 ?m, and (iii) the glass composition has a coefficient of thermal expansion of at least about 10 ppm/K and no more than about 25 ppm/K, is provided.
    Type: Grant
    Filed: May 29, 2015
    Date of Patent: September 11, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Matthew Sgriccia, Mark Challingsworth, Samson Shahbazi, Ryan Persons, Steven Grabey
  • Patent number: 10049781
    Abstract: The invention provides an electroconductive paste comprising metallic particles and an organic vehicle comprising an aldehyde resin and a solvent. The invention also provides an electroconductive paste comprising metallic particles comprising at least two types of metallic particles selected from the group consisting of a first metallic particle having an average particle size d50 of at least about 1 ?m and no more than about 4 ?m, a second metallic particle having a d50 of at least about 8 ?m and no more than about 11.5 ?m, and a third metallic particle having d50 of at least about 5 ?m and no more than about 8 ?m, and an organic vehicle. The invention further provides an article comprising a glass substrate comprising a transparent conductive oxide coating and a conductive electrode formed by applying aforementioned conductive paste on said glass substrate, and a method of producing such an article.
    Type: Grant
    Filed: January 22, 2014
    Date of Patent: August 14, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Virginia C. Garcia, Matthew Sgriccia, Mark Challingsworth
  • Patent number: 10039180
    Abstract: A dielectric tape suitable for use in an electronic device is provided. A dielectric slip composition comprises an organic vehicle and a dielectric glass composition comprising at least about 20 wt % and no more than about 50 wt % silicon dioxide, based upon 100% total weight of the glass composition, at least about 10 wt % and no more than about 50 wt % alkali metal oxides, based upon 100% total weight of the glass composition, and at least about 1 wt % and no more than about 10 wt % of at least one transition metal oxide. A method of forming an electronic device is also provided. The method includes the steps of applying at least one dielectric tape to at least one non-planar surface of a substrate, and subjecting the at least one dielectric tape to one or more thermal treatment steps to form a dielectric layer.
    Type: Grant
    Filed: April 5, 2016
    Date of Patent: July 31, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Samson Shahbazi, Steven Grabey, Mark Challingsworth, Ryan Persons
  • Patent number: 10038109
    Abstract: Solar cell conductor formulations made are from two silver powders having different particle size distributions, an aluminum powder, and two frit glass compositions having softening points in the range of 250-700° C. and whose softening points differ by at least 10° C.
    Type: Grant
    Filed: September 5, 2012
    Date of Patent: July 31, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Shahram Seyedmohammadi, Himal Khatri, Srinivasan Sridharan, Aziz S. Shaikh
  • Patent number: 10014418
    Abstract: The present invention relates to an inorganic reaction system used in the manufacture of electroconductive pastes. The inorganic reaction system comprises a lead containing matrix forming composition and a tellurium oxide additive. Preferably the lead containing matrix forming composition is between 5-95 wt. % of the inorganic reaction system, and the tellurium oxide additive is between 5-95 wt. % of the inorganic reaction system. The lead containing matrix forming composition may be a glass frit, and may comprise lead oxide. Another aspect of the present invention relates to an electroconductive paste composition that comprises metallic particles, an inorganic reaction system as previously disclosed, and an organic vehicle. Another aspect of the present invention relates to an organic vehicle that comprises one or more of a binder, a surfactant, a solvent, and a thixatropic agent.
    Type: Grant
    Filed: September 7, 2016
    Date of Patent: July 3, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Lei Wang, Matthias Hörteis, Weiming Zhang
  • Patent number: 9892816
    Abstract: An electroconductive hole plug paste comprising about 60-80 wt % of platinum particles, about 10-20 wt % of Al2O3, and about 10-20 wt % of organic vehicle, based upon 100% total weight of the paste, wherein the organic vehicle includes at least one viscosity-modifying component in an amount sufficient to provide the electroconductive hole plug paste with a viscosity of about 800-1,500 kcPs, is provided. A ceramic substrate assembly for an implantable medical device having the electroconductive hole plug paste of the invention, and a method of forming the same, are also provided.
    Type: Grant
    Filed: May 5, 2014
    Date of Patent: February 13, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Samson Shahbazi, Steven Grabey, Mark Challingsworth
  • Publication number: 20170352773
    Abstract: A conductive paste for forming a solar cell electrode, including: a conductive powder containing silver as a main component; glass frit; and an organic vehicle, wherein the glass frit contains tellurium glass frit having tellurium oxide as a network-forming component. The conductive paste of the present invention makes it possible to form a solar cell electrode having a low dependence on firing temperature without causing problems due to fire-through into the substrate, and to thereby obtain a solar cell having good solar cell characteristics.
    Type: Application
    Filed: August 24, 2017
    Publication date: December 7, 2017
    Applicants: SHOEI CHEMICAL INC., HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC
    Inventors: Masami NAKAMURA, Naoto SHINDO, Tadashi KANASAKU
  • Patent number: 9824790
    Abstract: Paste compositions, methods of making a paste composition, photovoltaic cells, and methods of making a photovoltaic cell contact are disclosed. The paste composition can include a conductive metal component such as aluminum, phosphate glass, phosphorus compounds such as alky! phosphate, and a vehicle. The contact can be formed on a passivation layer on a silicon wafer by applying the paste on the passivation layer and firing the paste. During firing, the metal component can fire through the passivation layer, thereby electrically contacting the silicon substrate.
    Type: Grant
    Filed: August 16, 2012
    Date of Patent: November 21, 2017
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Dongshe Zhang, Aziz S. Shaikh, Srinivasan Sridharan, Himal Khatri, Hong Jiang, George E. Graddy, Jr.
  • Patent number: 9799421
    Abstract: The invention provides an electroconductive paste comprising 50-90 wt. % of copper particle, 0.5-10 wt. % of a glass frit, 0.1-5% wt. % of adhesion promoter, which is at least one selected member from the group consisting of cuprous oxide, titanium oxide, zirconium oxide, boron resinate, zirconium resinate, amorphous boron, lithium phosphate, bismuth oxide, aluminum oxide, and zinc oxide, and 5-20 wt. % of an organic vehicle. An article comprising an aluminum nitride substrate and electroconductive paste of the invention is also provided. A method of forming an electroconductive circuit comprising is also provided.
    Type: Grant
    Filed: May 28, 2014
    Date of Patent: October 24, 2017
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Virginia C. Garcia, Matthew Sgriccia, Mark Challingsworth
  • Patent number: 9773579
    Abstract: Electrically conductive polymeric compositions curable at temperatures below 250° C. are disclosed. The compositions are particularly well suited for forming electrodes used in association with certain solar cells.
    Type: Grant
    Filed: September 28, 2011
    Date of Patent: September 26, 2017
    Assignee: HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC
    Inventors: Hong Jiang, Aziz S. Shaikh
  • Patent number: 9722102
    Abstract: In general, the invention relates to electro-conductive pastes comprising a glass which comprises molybdenum and lead as a constituent of a solar cell paste, and the use of such in the preparation of photovoltaic solar cells. More specifically, the invention relates to electroconductive pastes, precursors, processes for preparation of solar cells, solar cells and solar modules. The invention relates to an electro-conductive paste at least comprising as paste constituents: a) metallic particles; b) a glass; c) an organic vehicle; and d) an additive; wherein the glass comprises the following: i) Pb in the range from about 1 to about 94 wt. %; ii) Mo in the range from about 2 to about 30 wt. %; iii) O in the range from about 1 to about 50 wt. %; with the wt. % in each case being based on the total weight of the glass.
    Type: Grant
    Filed: January 9, 2015
    Date of Patent: August 1, 2017
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Devidas Raskar, Xiao Chao Song, Chi Long Chen
  • Patent number: 9680036
    Abstract: A method of reducing bow and/or improving the electrical performance of an aluminum back contacted silicon solar cell includes applying to a silicon wafer substrate a paste including aluminum and an organometallic compound, and firing the substrate. The organometallic compound is a C1 to C30 organometallic compound of a metal selected from the group consisting of Ag, Al, Ba, Bi, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Nd, Ni, Sb, Si, Sn, Sr, Ta, V, Zn, Zr. A paste is formed having an exothermic reaction peak at a temperature of at least 300° C. to less than 660° C.
    Type: Grant
    Filed: January 3, 2012
    Date of Patent: June 13, 2017
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Nazarali Merchant, Aziz S. Shaikh, Chandrashekhar S. Khadilkar, Srinivasan Sridharan, Hong Jiang
  • Publication number: 20170092788
    Abstract: The invention relates to an electroconductive paste composition comprising conductive metallic particles comprising silver, at least one glass frit, and an organic vehicle comprising at least about 0.5 wt % and no more than about 50 wt % of at least one poly-siloxane compound, based upon 100% total weight of the organic vehicle.
    Type: Application
    Filed: August 2, 2016
    Publication date: March 30, 2017
    Applicant: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Lixin SONG, Yi ZHANG
  • Patent number: 9275772
    Abstract: An electroconductive paste composition, particularly for solar cells, contains silver particles, glass particles, an organic vehicle, and at least one additive. The additive may be tantalum pentoxide or fine, electrically conductive, metal particles, such as gold and/or platinum group metals. When used to form an electrical contact on a solar cell, such a paste provides for enhanced adhesion of the contact to the cell and improved electron transmission.
    Type: Grant
    Filed: May 15, 2012
    Date of Patent: March 1, 2016
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventor: Weiming Zhang