Abstract: The disclosure relates to an adhesive composition for bonding lignocellulosic substrates. The adhesive composition contains a crosslinker and a non-urea diluent where the non-urea diluent is present in an amount from about 0.01 to about 75 weight % based on the total wet weight of the composition and where the crosslinker contains essentially no formaldehyde. Also disclosed is the adhesive further containing. an aqueous mixture of a protein source. The disclosure also relates to a process for making lignocellulosic composites utilizing the disclosed adhesive composition and to the lignocellulosic composites made using the disclosed process.
Type:
Grant
Filed:
October 9, 2008
Date of Patent:
April 3, 2012
Assignee:
Hercules Incorportated
Inventors:
Richard L. Brady, Qu-Ming Gu, Ronald R. Staib
Abstract: This invention relates to a process for preparing polyamine-epihalohydrin resins having reduced levels of residuals. The process comprises (a) charging a membrane separation apparatus with an aqueous composition comprising at least one polyamine-epihalohydrin resin, and (b) separating the aqueous composition into a permeate and a retentate by passing the aqueous composition through the membrane of the membrane separation apparatus. The retentate comprises at least one polyamine-epihalohydrin resin having lower levels of residuals on an equal active component basis than the aqueous composition of (a). The permeate comprises residuals removed from the aqueous composition of (a) and less than 5% by weight of the active component of said at least one polyamine-epihalohydrin resin. The polyamine-epihalohydrin resins having reduced levels of residuals can be used to make wet strength agents, dry strength agents, creping adhesives for paper products, curing agents for wood product adhesives, and other products.
Abstract: An apparatus and method for the subterranean support of underground conduits is disclosed, including a pile driver that is configured to connect to an articulated boom of an excavator or another unit of positioning machinery to insert a section of curved sheet pile beneath a conduit. In one exemplary embodiment, the pile driver has a head portion and a body portion. The head portion of the pile driver is connected to the excavator and the body portion of the pile driver is moveable relative to both the head portion of the pile driver and the excavator to allow the pile driver to properly orient a section of curved sheet pile for insertion into subterranean material beneath an underground conduit.
Abstract: The present invention relates to a personal care composition additive for use on keratin substrates in order to provide long lasting benefits to the keratin substrate such as in conditioning systems, such as 2/1 shampoo's, leave-on and rinse off conditioners, for hair and skin, or for imparting greater water resistance to such personal care compositions as sunscreens or cosmetics.
Type:
Application
Filed:
June 24, 2011
Publication date:
December 29, 2011
Applicant:
Hercules Incorporated
Inventors:
Paquita ERAZO-MAJEWICZ, Gijsbert Kroon, Thi Hong Lan Le-Pham, Tuttu Maria Nuutinen
Abstract: The present invention is related to the use of a non-cellulosic cationically modified polysaccharide in cleaning compositions and more particularly to a surfactant based cleansing composition comprising, a surfactant, a non-cellulosic cationically modified polysaccharide and a solvent for use in personal care composition, household care composition or an institutional care composition.
Type:
Grant
Filed:
October 9, 2009
Date of Patent:
December 13, 2011
Assignee:
Hercules Incorporated
Inventors:
Piet Brand, Richard G. Brown, Anita N. Chan, Paquita Erazo-Majewicz, Jashawant J. Modi
Abstract: Compositions and methods for the removal of resin from wood chips processed in a Kraft pulping process are disclosed. The method is particularly useful for removing triterpene and triterpenoid resin.
Abstract: Size press compositions and methods for producing sized paper products, including liner board, are disclosed. The size press compositions contain at least one non-reactive cationic surface sizing agent, at least one reactive sizing agent, at least one promoter resin, at least one binder, and water. The at least one non-reactive cationic surface sizing agent may be a polymer in the form of a dispersion, an emulsion or a latex with a positive zeta potential below about pH 6. The at least one reactive sizing agent may be a dispersion, an emulsion or a latex including an alkyl ketene dimer or an alkyl succinic anhydride. The at least one promoter resin may be a polyaminoamide-epichlorohydrin resin or poly (dimethyldiallylammonium chloride).
Abstract: The present invention relates to processes for enhancing a refiner's production rate and/or reducing the specific energy consumption for a freeness target through the use of lubricant(s) or carrier(s)/frictionizer(s), respectively.
Type:
Grant
Filed:
April 1, 2010
Date of Patent:
July 19, 2011
Assignee:
Hercules Incorporated
Inventors:
Eric Oswaldo Fernandez, Mark Edward Laurint
Abstract: Pigmented coated paper is prepared by adding a water-soluble hydroxyalkylcellulose (HAC) with an alkyl moiety of 1 to 4 carbons, or water soluble alkylhydroxyalkylcellulose (AHAC) with an alkyl hydrophobe of 1 to 24 carbons to a pigmented wet coating formulation in an amount equal to or greater than 0.15 parts HAC or AHAC based on pigment content of the coating and applying the pigmented wet coating formulation to a moving paper web via roller metering size press, wherein the use of HAC or AHAC in the pigmented coating significantly reduce misting of the coating during application as compared to the control condition with no HAC or AHAC added.
Abstract: The present invention relates to aqueous formulations useful in useful in personal care, oral care, household and institutional applications which contain polymers comprised of water soluble synthetic backbone with covalently connected hydrophobic ends can deliver ‘salt-like’ rheology to surfactant formulations containing surfactant concentrations at which thickening by salt is not effective.
Abstract: The embodiments of the process of the present invention relate to the preparation of alkyl ketene dimers (AKD), where the process combines at least one polyamine with a fatty acid chloride in a molar ratio of less than one mole of polyamine to one mole of fatty acid chloride thereby forming an alkyl ketene dimer/amine salt that is subsequently separated into an organic dimer layer and an aqueous salt layer.
Abstract: In this invention, a process for producing fermentable sugars derivable from biomass that contains polysaccharide, such as cellulose, which has been made increasingly accessible as a substrate for enzymatic degradation or other methods of depolymerization. The process of the present invention increases accessibility of polysaccharides, typically present in biomass and produces polysaccharides with increased accessibility. The polysaccharides with increased accessibility may be subsequently saccharified to yield fermentable sugars. These fermentable sugars are subsequently able to be fermented to produce various target chemicals, such as alcohols, aldehydes, ketones or acids.
Type:
Application
Filed:
November 2, 2010
Publication date:
June 2, 2011
Applicant:
Hercules Incorporated
Inventors:
Herbert T. Conners, Patrick J. Cowan, John C. Gast, Robert P. O'Flynn O'Brien
Abstract: The invention provides for a retainer for stabilizing a threaded member. The retainer may include a base portion having an opening and an outer perimeter lying in a first plane, the opening having a plurality of elongated sections each extending toward the outer perimeter so as to define in the base portion one or more arms. Each of the aims may have a head section having at least one groove, the head sections being located in a second plane which is parallel to and spaced apart from the first plane. The elongated sections may be symmetrically arranged about an axis. The grooves may be arranged to define at least a portion of a helix. The outer perimeter of the retainer may be circular.
Abstract: Polyamidoamine (PAE) resins are prepared from polyamidoamine made with excess amine, which are reacted with a specifically defined amount of difunctional crosslinker. The amount of difunctional crosslinker used is based on the polyamidoamine amine number and reduced specific viscosity (RSV). The PAE resin is prepared by first synthesizing a polyamidoamine from a polyamine and a polycarboxylic acid or polycarboxylic acid derivative, wherein the polyamine is present in a molar excess, said molar excess being from about 1.02 to 2.00, then reacting the polyamidoamine with difunctional crosslinker, wherein the weight % of difunctional crosslinker to polyamidoamine solids is no more than about 0.308(amine number/RSV)—9.18 or 385(amine number/RSV)—5.20, wherein the amine number is expressed as the milliequivalents of amine per gram of polyamidoamine solids and the RSV is the reduced specific viscosity measured at 2% concentration in 1M NH4Cl expressed in deciliters per gram.
Abstract: This invention relates to a process for preparing polyamine-epihalohydrin resins having reduced levels of residuals. The process comprises (a) charging a membrane separation apparatus with an aqueous composition comprising at least one polyamine-epihalohydrin resin, and (b) separating the aqueous composition into a permeate and a retentate by passing the aqueous composition through the membrane of the membrane separation apparatus. The retentate comprises at least one polyamine-epihalohydrin resin having lower levels of residuals on an equal active component basis than the aqueous composition of (a). The permeate comprises residuals removed from the aqueous composition of (a) and less than 5% by weight of the active component of said at least one polyamine-epihalohydrin resin. The polyamine-epihalohydrin resins having reduced levels of residuals can be used to make wet strength agents, dry strength agents, creping adhesives for paper products, curing agents for wood product adhesives, and other products.
Abstract: A water-borne coating composition containing an ether derivative of raw cotton linters (RCL), a latex polymer, and water in which the ether derivative RCL provides improved rheological properties when compared to analogous cellulose ether compounds produced from more refined cellulose sources while not substantially degrading the coating composition's aesthetic qualities.
Abstract: Several Michael addition adducts of vinylamines with ?,?. -unsaturated alkyl carbonyl compounds including amides, esters and acids, particularly acrylamide are presented. Additionally, a process for producing these Michael addition adducts is described. These adducts are generally useful in the manufacture of paper and are particularly useful as dry strength additives to make paperboard products using a papermaking machine.
Abstract: An oil-in-water emulsion useful as a defoamer for pulp and paper mill applications is described. The defoamer has an oil blend (of a triglyceride oil or a mixture of triglyceride oils and silicone), a stabilizing agent (to make the oil blend stable in the emulsion), hydrophobic silica particles, surfactants, dispersants, and other components. The emulsion is usable directly at low concentrations to control foam.
Type:
Grant
Filed:
December 8, 2005
Date of Patent:
February 22, 2011
Assignee:
Hercules Incorporated
Inventors:
Huai N. Cheng, Eric O. Fernandez, John M. Sheepy
Abstract: A defoamer made from a composition that has at least one triglyceride oil or triglyceride oil mixture, at least one silicone, at least one silicone-triglyceride stabilizing agent, hydrophobic silica particles, optionally one or more surfactants and/or dispersants, and optionally one or more thickeners, and optionally one or more biocides. The defoamers described herein have utility in controlling foam in industrial applications. Typically, the defoamer can be used to control foam in pulp and paper applications.
Type:
Grant
Filed:
December 8, 2005
Date of Patent:
February 1, 2011
Assignee:
Hercules Incorporated
Inventors:
Huai N. Cheng, Eric Oswaldo Fernandez, John M. Sheepy
Abstract: An apparatus and method for the subterranean support of underground conduits is disclosed, including a pile driver that is configured to connect to an articulated boom of an excavator or another unit of positioning machinery to insert a section of curved sheet pile beneath a conduit. In one exemplary embodiment, the pile driver has a head portion and a body portion. The head portion of the pile driver is connected to the excavator and the body portion of the pile driver is moveable relative to both the head portion of the pile driver and the excavator to allow the pile driver to properly orient a section of curved sheet pile for insertion into subterranean material beneath an underground conduit.