Abstract: The invention relates to compounds of the formula (I) ##STR1## in which R=(subst.) alkyl or (subst.) cycloalkyl, which are suitable as intermediates for preparing herbicidal sulfonylureas. According to the invention, the compounds (I) are prepared by(a) diazotizing a compound of the formula (II) ##STR2## in the presence of an acid H.sup.+ X.sup.-, where X.sup.- is an equivalent of an anion, to give the novel compounds (diazonium salts) of the formula (III) ##STR3## (b) reacting the compound of the formula (III) in the presence of iodide ions to give the compound (IV) and ##STR4## (c) reacting the compound of the formula (IV) with an isocyanate of the formula (V)R--N.dbd.C.dbd.O (V)in which R is as defined in formula (I), to give the compound of the formula (I).
Abstract: The invention is directed to a simple process for the preparation of the product 2-carboxy-5-nitrobenzenesulfonic acid (=4-nitro-2-sulfo-benzoic acid) or a salt thereof. The product can be prepared by the oxidation reaction of 2-methyl-5-nitrobenzenesulfonic acid with metal hypochlorites in the presence of metal bases from the group consisting of hydroxides and carbonates, essentially with the exclusion of heavy metal salts.
Abstract: Compounds of formula I, N-oxides or salts, thereof ##STR1## in which q is 0, 1 or 2A is CH and D is N.sup.+ R.times.1/n Q.sup.n- or A is N and D is N.sup.+ R.times.1/n Q.sup.n- or A is CH or N and D is Nor A is N.sup.+ R.times.1/n Q.sup.n- and D is N, R is CR.sup.6 R.sup.7 D.sup.a R.sup.8,Q.sup.n- is an inorganic or organic anion, n being 1, 2, 3 or 4;X is NH, O or S(O).sub.q, (q is 0, 1 or 2); and the R groups have various meanings as defined in the claims are useful pesticidal, especially insecticidal activity.
Type:
Grant
Filed:
May 18, 1999
Date of Patent:
August 22, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Harald Jakobi, Matthias Eckhardt, Wolfgang Schaper, Ralf Braun, Gerhard Krautstrunk, Oswald Ort, Ulrich Sanft, Maria-Theresia Thonessen, Werner Bonin
Abstract: The disclosure relates to the production and the use, by genetic engineering, of plasmids and bacterial strains containing, on a short, precisely characterizable DNA segment, the gene tfdA or a gene almost identical to tfdA.The novel plasmids and microorganisms are suitable for the production of 2,4-D (2,4-dichlorophenoxyacetic acid)-monooxygenase, and as starting materials for the transfer, by genetic engineering of the 2,4-D-degrading property of this enzyme to various organisms.
Type:
Grant
Filed:
June 7, 1995
Date of Patent:
August 8, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Wolfgang R. Streber, Kenneth N. Timmis, Meinhart H. Zenk
Abstract: Compounds of the formula (I) and salts thereof ##STR1## where R.sup.1 to R.sup.5, A, Z, X, X', n and m are as defined in claim 1 are suitable as herbicides and plant growth regulators.
Type:
Grant
Filed:
February 6, 1997
Date of Patent:
June 6, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Wolfgang Giencke, Lothar Willms, Klaus Bauer, Hermann Bieringer, Christopher Rosinger
Abstract: Compounds of the formula (I) and their salts ##STR1## in which R.sup.1 to R.sup.6, Y.sup.1, to Y.sup.2, Y.sup.3, m and n are as defined in claim 1 are suitable as herbicides and plant growth regulators. They can be prepared analogously to known processes using intermediates of the formula (V) (cf. claim 6).
Type:
Grant
Filed:
February 25, 1997
Date of Patent:
May 30, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Klaus Lorenz, Klemens Minn, Lothar Willms, Klaus Bauer, Hermann Bieringer, Christopher Rosinger
Abstract: A combination of DNA sequences is described which, in transgenic plant cells and plants, results in the formation of a modified starch which differs from starch synthesized naturally in the cells, especially in respect of its degree of branching and its phosphate content. A process for the production of genetically modified plants which are modified in respect of the physical and chemical properties of the synthesized starch due to the expression of artificially introduced DNA sequences, the plants obtainable by this process, and the modified starch obtainable from these plants, are also described.
Abstract: Transformed plants resistant to phenmedipham, which are resistant by having been transformed with a purified and isolated carbamate hydrolase gene. The carbamate hydrolase enzyme produced thereby is responsible for the cleavage of the carbamate bond between the benzene rings of phenmedipham. The invention includes the transformed plants, progeny thereof, transformed plant cells, and method of producing the transformed plants and transformed plant cells, which are resistant to phenmedipham. The invention further includes plasmids comprising the carbamate hydrolase gene capable of inactivating phenmedipham.
Type:
Grant
Filed:
October 10, 1997
Date of Patent:
May 9, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Hans-Dieter Pohlenz, Werner Boidol, Wolfgang Streber
Abstract: The invention relates to new substituted pyrazol derivatives of general formula (I) in which: R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the meanings given in the description, agents with herbicidal action containing at least one compound of formula (I), and their use as herbicides.
Type:
Grant
Filed:
July 7, 1999
Date of Patent:
May 2, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Jens Geisler, Helga Franke, Uwe Hartfiel, Michael Ganzer, Jurgen Bohner, Richard Rees
Abstract: Plasmids containing DNA sequences which when inserted into the genome of a plant modify the carbohydrate or protein concentration and the carbohydrate or protein composition, and plant cells and plants that contain these plasmids.DNA sequences located in plasmids reduce ADP-glucose-pyrophosphorylase activity in the plant and thereby the starch concentration, while at the same time increase the mono- and oligosaccharide concentration. Other DNA sequences in plasmids reduce or increase the protein concentration. Plants that contain these plasmids are suitable inter alia for the extraction of sugar or as protein-enriched food or fodder.
Abstract: The present invention relates to a process for preparing 4-substituted cis-cyclohexylamines of high cis-selectivity by reductive amination of cyclohexanones which are substituted in position 4 by an organic radical.
Type:
Grant
Filed:
March 17, 1999
Date of Patent:
April 4, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Dieter Bernd Reuschling, Adolf Heinz Linkies
Abstract: The invention relates to new substituted pyrazol derivatives of general formula (I) in which: R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the meanings given in the description, agents with herbicidal action containing at least one compound of formula (I), and their use as herbicides.
Type:
Grant
Filed:
September 4, 1998
Date of Patent:
February 22, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Jens Geisler, Helga Franke, Uwe Hartfiel, Michael Ganzer, Jurgen Bohner, Richard Rees
Abstract: There are described DNA sequences, which lead to the formation of polyfructans (levans), plasmids containing theses DNA sequences, as well as a process using these plasmids for preparing transgenic plants with polyfructan (levan) expression.
Type:
Grant
Filed:
October 3, 1997
Date of Patent:
February 22, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Manuela Rober, Gebhard Geier, Klaus Geider
Abstract: Described are processes for producing plants whose flowering behavior is modified in comparison to wildtype plants, in particular for producing plants with early flower formation and flowering to an increased extent, and the plants resulting from that process. Further, the use of DNA molecules encoding sucrose carriers for modifying plant flowering behavior is described.
Abstract: The invention relates to a method of controlling harmful plants in rice crops, which comprises applying one or more compounds of the formula (I) or salts thereof whereR.sup.1 is an acyl radical from the group CO--R.sup.2, CS--R.sup.2, CO--OR.sup.3, CS--OR.sup.3, CO--SR.sup.4, CS--SR.sup.4, CO--NR.sup.5 R.sup.6 and CS--NR.sup.5 R.sup.6, and R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 and also X, Y and Z are as defined in the formula (I) of claim 1,to the area under cultivation, which contains the harmful plants and rice plants or their seeds, in an effective amount of from 0.0001 to 0.5 kg of a.i./ha.The compounds (I) are known per se. The invention also provides novel salts of the compounds (I).
Type:
Grant
Filed:
May 21, 1998
Date of Patent:
January 25, 2000
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Gerhard Schnabel, Lothar Willms, Klaus Bauer
Abstract: DNA sequences are described which on the codogenic strand code plant debranching enzymes, whose transcripts formed in transgenic plants code new proteins with the enzymatic activity of debranching enzymes which in transgenic plants reduce the degree of branching of amylopectin starch and DNA sequences which on the codogenic strand code plant debranching enzymes, whose transcripts formed in transgenic plants prevent the synthesis of proteins with the enzymatic activity of debranching enzymes, which in the transgenic plants increases the degree of branching of amylopectin starch, as well as plasmids on which these DNA sequences are localized, which can be introduced into plant cells and plants. Also described is a process for the production of plants changed by genetic engineering whose amylopectin starch is modified, and the modified starch obtainable from these plants.
Type:
Grant
Filed:
April 18, 1996
Date of Patent:
December 14, 1999
Assignee:
Hoechst Schering AgrEvo GmbH
Inventors:
Jens Kossmann, Michael Emmermann, Ivar Virgin
Abstract: Herbicidal compositions comprisingA) at least one compound from the group of the substituted phenylsulfonylureas of the formula I and their agriculturally acceptable salts ##STR1## in which R.sup.1 is (C.sub.1 -C.sub.8)alkyl, (C.sub.3 -C.sub.4)alkenyl, (C.sub.3 -C.sub.4)alkynyl or (C.sub.1 -C.sub.4)alkyl which is mono- to tetrasubstituted by radicals selected from the group consisting of halogen and (C.sub.1 -C.sub.2)alkoxy,andB) at least one herbicidally active compound from the group of compounds composed ofBa) herbicides which act selectively against grasses in cereals and/or maize,Bb) herbicides which act selectively against dicots in cereals and/or maize,Bc) herbicides which act selectively against grasses and dicots in cereals and/or maize andBd) herbicides which act non-selectively against grass weeds and broad-leaved weeds in non-crop areas and/or selectively against grass weeds and broad-leaved weeds in transgenic crops.
Abstract: DNA molecules are described which code for a plastid 2-oxoglutarate/malate translocator, particularly from Spinacia oleracea, as well as bacteria, fungi, transgenic plant cells and transgenic plants containing such DNA molecules.
Type:
Grant
Filed:
December 12, 1996
Date of Patent:
November 9, 1999
Assignee:
Hoechst Schering Agrevo GmbH
Inventors:
Ulf-Ingo Flugge, Andreas Weber, Karsten Fischer
Abstract: There are described DNA sequences, that contain the coding region of an oligosaccharide transporter, whose introduction in a plant genome modifies the formation and transfer of storage materials in transgenic plants, plasmids, bacteria and plants containing these DNA sequences, a process for the preparation and transformation of yeast strains, that makes possible the identification of the DNA sequences of the plant oligosaccharide transporter of the invention, as well as the use of DNA sequences of the invention.
Abstract: This invention relates to DNA sequences and plasmids containing these sequences which can be integrated into a plant genome and which modify the activity of the sucrose-phosphate-synthase (sps) of the plant. The invention relates further to derivatives of the DNA sequences of the invention that are obtained by exchange of single bases or by deletion or insertion of base sequences and which code for proteins with comparable activity to sucrose-phosphate-synthase. Methods for transforming plant cells and regenerating plants from the cells which exhibit modified sucrose-phosphate-synthase activity are also described.