Patents Assigned to Huntington Alloys Corporation
  • Patent number: 11814704
    Abstract: An alloy includes a composition, in weight percent, of aluminum from about 1.3% to about 1.8%, cobalt from about 1.5% to about 4.0%, chromium from about 18.0% to about 22.0%, iron from about 4.0% to about 10.0%, molybdenum from about 1.0% to about 3.0%, niobium from about 1.0% to about 2.5%, titanium from about 1.3% to about 1.8%, tungsten from about 0.8% to about 1.2%, carbon from about 0.01% to about 0.08%, and balance nickel and incidental impurities. The alloy has a stress rupture life at 700° C. and 393.7 MPa (57.1 ksi) of at least 300 hours and a room temperature percent elongation of at least 15% after aging at 700° C. for 1,000 hours.
    Type: Grant
    Filed: January 13, 2022
    Date of Patent: November 14, 2023
    Assignee: HUNTINGTON ALLOYS CORPORATION
    Inventors: Brian A. Baker, John J. Debarbadillo
  • Publication number: 20230212716
    Abstract: Nickel-base precipitation hardenable alloys with enhanced hydrogen embrittlement resistance and desired yield strength have critical ranges of titanium and iron, among other elements. One of the nickel-base precipitation hardenable alloys has a composition, in wt.%, of Cr from about 18.0% to about 23.0%, Fe from about 7.0% to about 12.0%, Mo from about 6.5% to about 9.5%, Nb from about 3.2% to about 5.2%, Ti from about 0.3% to about 1.3%, Al up to about 0.4%, with a balance of Ni and incidental impurities. This alloy has a yield strength (0.2% offset) greater than or equal to 120 ksi (827 MPa), a plastic strain ratio greater than or equal to 0.35, and a plastic strain to failure greater than or equal to 9.0%.
    Type: Application
    Filed: December 30, 2022
    Publication date: July 6, 2023
    Applicant: Huntington Alloys Corporation
    Inventors: Brian DeForce, Brian A. Baker, Edward Francis Damm, III
  • Publication number: 20220220582
    Abstract: An alloy includes a composition, in weight percent, of aluminum from about 1.3% to about 1.8%, cobalt from about 1.5% to about 4.0%, chromium from about 18.0% to about 22.0%, iron from about 4.0% to about 10.0%, molybdenum from about 1.0% to about 3.0%, niobium from about 1.0% to about 2.5%, titanium from about 1.3% to about 1.8%, tungsten from about 0.8% to about 1.2%, carbon from about 0.01% to about 0.08%, and balance nickel and incidental impurities. The alloy has a stress rupture life at 700° C. and 393.7 MPa (57.1 ksi) of at least 300 hours and a room temperature percent elongation of at least 15% after aging at 700° C. for 1,000 hours.
    Type: Application
    Filed: January 13, 2022
    Publication date: July 14, 2022
    Applicant: Huntington Alloys Corporation
    Inventors: Brian A. Baker, John J. Debarbadillo
  • Patent number: 10260129
    Abstract: A high temperature, high strength Ni—Co—Cr alloy is provided. The alloy includes, in weight percent (wt. %): 23.5 to 25.5% Cr, 15.0 to 22.0% Co, 1.1 to 2.0% Al, 1.0 to 1.8% Ti, 0.95 to 2.2% Nb, less than 1.0% Mo, less than 1.0% Mn, up to 0.24% Si, less than 3.0% Fe, less than 0.3% Ta, less than 0.3% W, 0.005 to 0.08% C, 0.01 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, and a balance of Ni plus trace impurities.
    Type: Grant
    Filed: August 1, 2018
    Date of Patent: April 16, 2019
    Assignee: Huntington Alloys Corporation
    Inventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
  • Patent number: 10253382
    Abstract: A high strength corrosion resistant tubing comprises about 35 to about 55% Ni, about 12 to about 25% Cr, about 0.5 to about 5% Mo, up to about 3% Cu, about 2.1 to about 4.5% Nb, about 0.5 to about 3% Ti, about 0.05 to about 1.0% Al, about 0.005 to about 0.04% C, balance Fe plus incidental impurities and deoxidizers. The composition also satisfies the equation: (Nb?7.75 C)/(Al+Ti)=about 0.5 to about 9. A process for manufacturing the tubing includes: extruding the alloy to form a tubing; cold working the extruded tubing; annealing the cold worked tubing; and applying at least one age hardening step to the annealed tubing. Another process includes extruding the alloy at a temperature of about 2050° F. or less; annealing the extruded tubing; and applying at least one age hardening step to the annealed tubing.
    Type: Grant
    Filed: June 11, 2012
    Date of Patent: April 9, 2019
    Assignee: Huntington Alloys Corporation
    Inventor: Sarwan K. Mannan
  • Publication number: 20180340242
    Abstract: A high temperature, high strength Ni—Co—Cr alloy is provided. The alloy includes, in weight percent (wt. %): 23.5 to 25.5% Cr, 15.0 to 22.0% Co, 1.1 to 2.0% Al, 1.0 to 1.8% Ti, 0.95 to 2.2% Nb, less than 1.0% Mo, less than 1.0% Mn, up to 0.24% Si, less than 3.0% Fe, less than 0.3% Ta, less than 0.3% W, 0.005 to 0.08% C, 0.01 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, and a balance of Ni plus trace impurities.
    Type: Application
    Filed: August 1, 2018
    Publication date: November 29, 2018
    Applicant: Huntington Alloys Corporation
    Inventors: Brian A. BAKER, Gaylord D. Smith, Ronald D. Gollihue
  • Patent number: 10112254
    Abstract: A method of producing a nickel alloy clad steel pipe including: providing a hollow cylinder of nickel alloy cladding material and a hollow cylinder of steel, placing the hollow cylinder of the nickel alloy cladding material concentrically inside the hollow cylinder of steel or the hollow cylinder of the steel concentrically inside the hollow cylinder of nickel alloy cladding material to form a composite billet, heating the composite billet to 1121-1260° C., and extruding the composite billet, wherein the nickel alloy cladding material comprises 6.0-12.0 wt. % molybdenum, 19.0-27.0 wt. % chromium, 1.0 wt. % maximum tungsten, 0.6 wt. % maximum aluminum, 0.6 wt. % maximum titanium, 0.001-0.05 wt. % carbon, 0.001-0.035 wt. % nitrogen, 0.001-0.3 wt. % silicon, 1.0 wt. % maximum niobium, 2.5 wt. % maximum iron, 0.5 wt. % maximum manganese, 0.015 wt. % maximum phosphorous, 0.015 wt. % maximum sulfur, 1.0 wt. % maximum cobalt, and the balance nickel and may have a solidus temperature greater than 1312° C.
    Type: Grant
    Filed: August 18, 2015
    Date of Patent: October 30, 2018
    Assignee: Huntington Alloys Corporation
    Inventors: Bhaven Chakravarti, Brian A. Baker, Debajyoti Maitra
  • Patent number: 10100392
    Abstract: A high strength, corrosion resistant alloy suitable for use in oil and gas environments includes, in weight percent: 0-15% Fe, 18-24% Cr, 3-9% Mo, 0.05-3.0% Cu, 4.0-6.5% Nb, 0.5-2.2% Ti, 0.05-1.0% Al, 0.005-0.040% C, balance Ni plus incidental impurities and deoxidizers. A ratio of Nb/(Ti+Al) is equal to 2.5-7.5.
    Type: Grant
    Filed: April 29, 2015
    Date of Patent: October 16, 2018
    Assignee: Huntington Alloys Corporation
    Inventor: Sarwan Kumar Mannan
  • Patent number: 10041153
    Abstract: A high temperature, high strength Ni—Co—Cr alloy possessing essentially fissure-free weldability for long-life service at 538° C. to 816° C. contains in % by weight about: 23.5 to 25.5% Cr, 15-22% Co, 1.1 to 2.0% Al, 1.0 to 1.8 % Ti, 0.95 to 2.2% Nb, less than 1.0% Mo, less than 1.0% Mn, less than 0.3% Si, less than 3% Fe, less than 0.3% Ta, less than 0.3% W, 0.005 to 0.08% C, 0.01 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, 0.005% to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities. The strength and stability is assured at 760° C. when the Al/Ti ratio is constrained to between 0.95 and 1.25. Further, the sum of Al+Ti is constrained to between 2.25 and 3.0. The upper limits for Nb and Si are defined by the relationship: (% Nb+0.95)+3.32(% Si)<3.16.
    Type: Grant
    Filed: April 8, 2009
    Date of Patent: August 7, 2018
    Assignee: Huntington Alloys Corporation
    Inventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
  • Patent number: 9017490
    Abstract: A high strength, corrosion resistant alloy suitable for use in oil and gas environments includes, in weight %: 0-12% Fe, 18-24% Cr, 3-6.2% Mo, 0.05-3.0% Cu, 4.0-6.5% Nb, 1.1-2.2% Ti, 0.05-0.4% 0.05-0.2% Al, 0.005-0.040% C, balance Ni plus incidental impurities and deoxidizers. A ratio of Nb/(Ti+Al) is equal to 2.5-7.5 to provide a desired volume fraction of ?? and ?? phases. The alloy has a minimum yield strength of 145 ksi.
    Type: Grant
    Filed: November 18, 2008
    Date of Patent: April 28, 2015
    Assignee: Huntington Alloys Corporation
    Inventor: Sarwan Kumar Mannan
  • Publication number: 20130327447
    Abstract: A high strength corrosion resistant tubing comprises about 35 to about 55% Ni, about 12 to about 25% Cr, about 0.5 to about 5% Mo, up to about 3% Cu, about 2.1 to about 4.5% Nb, about 0.5 to about 3% Ti, about 0.05 to about 1.0% Al, about 0.005 to about 0.04% C, balance Fe plus incidental impurities and deoxidizers. The composition also satisfies the equation: (Nb?7.75 C)/(Al+Ti)=about 0.5 to about 9. A process for manufacturing the tubing includes: extruding the alloy to form a tubing; cold working the extruded tubing; annealing the cold worked tubing; and applying at least one age hardening step to the annealed tubing. Another process includes extruding the alloy at a temperature of about 2050° F. or less; annealing the extruded tubing; and applying at least one age hardening step to the annealed tubing.
    Type: Application
    Filed: June 11, 2012
    Publication date: December 12, 2013
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventor: Sarwan K. Mannan
  • Patent number: 8603389
    Abstract: A Ni—Cr—Fe alloy in the form of a weld deposit, a welding electrode and flux and a method of welding utilizing the Ni—Cr—Fe alloy. The alloy comprises in % by weight: 27-31 Cr, 6-11 Fe, 0.01-0.04 C, 1.5-4 Mn, 1-3 Nb, up to 3 Ta, 1-3 (Nb+Ta), 0.01-0.50 Ti, 0.0003-0.02 Zr, 0.0005-0.004 B, <0.50 Si, 0.50 max Al, <0.50 Cu, <1.0 W, <1.0 Mo, <0.12 Co, <0.015 S, <0.015 P, 0.01 max Mg, balance Ni plus incidental additions and impurities. The welding method includes welding using a short arc wherein the distance from the electrode tip to the weld deposit is maintained at less than 0.125 inch.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: December 10, 2013
    Assignee: Huntington Alloys Corporation
    Inventor: Samuel D. Kiser
  • Patent number: 8568901
    Abstract: An alloy for use as a welding overlay for boiler tubes in a low NOx coal-fired boiler comprising in % by weight: 36 to 43% Cr, 0.2 to 5.0% Fe, 0-2.0% Nb, 0-1% Mo, 0.3 to 1% Ti, 0.5 to 2% Al, 0.005 to 0.05% C, 0.005 to 0.020% (Mg+Ca), 0-1% Mn, 0-0.5% Si, less than 0.01% S, balance substantially Ni and trace additions and impurities. The alloy provides exceptional coal ash corrosion resistance in low partial pressures of oxygen. The alloy also increases in hardness and in thermal conductivity at service temperature over time. The increased hardness improves erosion resistance of the tubes while the increased thermal conductivity improves the thermal efficiency of the boiler and its power generation capabilities.
    Type: Grant
    Filed: November 19, 2007
    Date of Patent: October 29, 2013
    Assignee: Huntington Alloys Corporation
    Inventors: Samuel D. Kiser, Brian A. Baker
  • Publication number: 20130206274
    Abstract: A method of roll-forming sheet or plate into a round hollow, welding the round hollow with a welding alloy that matches the alloy of the round hollow to form a welded pipe, annealing the welded pipe at a minimum of 1950° F. to provide a carbide-free microstructure, ultrasonic inspecting to assure sound welds, and cold-working the annealed and inspected pipe via drawing or pilgering to the desired tensile strength. The compositional range alloys suitable for use in the method of the present invention in weight % is: 25.0-65.0% Ni, 15.0-30.0% Cr, 0-18.0% Mo, 2.5-48.0% Fe, 0-5.0% Cu, 0-5.0% Mn, 0-5.0% Nb, 0-2.0 Ti, 0-5.0% W, 0-1.0% Si, and 0.005-0.1% C. The process has been most preferably optimized for an alloy range consisting of 32.0-46% Ni, 19.5-28.0% Cr, 18.0-40.0% Fe, 3.0-8.0% Mo, 1.0-3.0% Cu, 0.6-1.2% Ti, 0.5-2.0% Mn, 0.1-0.5% Si, 0.01-0.08% C. The present invention also includes the pipe made thereby.
    Type: Application
    Filed: July 19, 2011
    Publication date: August 15, 2013
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventors: Gaylord D. Smith, Ronald D. Gollihue, Brian A. Baker, Lewis E. Shoemaker
  • Patent number: 8187725
    Abstract: A nickel, chromium, iron alloy and method for use in producing weld deposits and weldments formed therefrom. The alloy comprises, in weight percent, about 28.5 to 31.0% chromium; about 0 to 16% iron; less than about 1.0% manganese; about 2.1 to 4.0% niobium plus tantalum; 1.0 to 6.5% molybdenum; less than 0.50% silicon; 0.01 to 0.35% titanium; 0 to 0.25% aluminum; less than 1.0% copper; less than 1.0% tungsten; less than 0.5% cobalt; less than about 0.10% zirconium; less than about 0.01% sulfur; less than 0.01% boron; less than 0.03% carbon; less than about 0.02% phosphorous; 0.002 to 0.015% magnesium plus calcium; and balance nickel and incidental impurities. The method includes the steps of forming a welding electrode from the above alloy composition and melting the electrode to form a weld deposit. A preferred weldment may be in the form of a tubesheet of a nuclear reactor.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: May 29, 2012
    Assignees: Huntington Alloys Corporation, Areva NP Inc.
    Inventors: Samuel D. Kiser, Brian A. Baker, David E. Waskey
  • Patent number: 8133334
    Abstract: A Ni—Fe—Cr alloy having high strength, ductility and corrosion resistance especially for use in deep-drilled, corrosive oil and gas well environments, as well as for marine environments. The alloy comprises in weight %: 35-55% Ni, 12-25% Cr, 0.5-5% Mo, up to 3% Cu, 2.1-4.5% Nb, 0.5-3% Ti, up to 0.7% Al, 0.005-0.04% C, balance Fe plus incidental impurities and deoxidizers. The alloy must also satisfy the ratio of (Nb?7.75 C)/(Al+Ti)=0.5-9 in order to obtain the desired high strength by the formation of ?? and ?? phases. The alloy has a minimum of 1% by weight ?? phase dispersed in its matrix for strength purposes and a total weight percent of ??+?? phases being between 10 and 30.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: March 13, 2012
    Assignee: Huntington Alloys Corporation
    Inventors: Sarwan K. Mannan, Brett Clark Puckett
  • Publication number: 20110011500
    Abstract: A Ni—Fe—Cr—Mo alloy containing a small amount of Cu and correlated percentages of Nb, Ti and Al to develop a unique microstructure to produce 145 ksi minimum yield strength. The unique microstructure is obtained by special annealing and age hardening conditions, by virtue of which the alloy has an attractive combination of yield strength, impact strength, ductility, corrosion resistance, thermal stability and formability, and is especially suited for corrosive oil well applications that contain gaseous mixtures of carbon dioxide and hydrogen sulfide. The alloy comprises in weight percent the following: 0-15% Fe, 18-24% Cr, 3-9% Mo, 0.05 3.0% Cu, 3.6-6.5% Nb, 0.5-2.2% Ti, 0.05-1.0% Al, 0.005-0.040% C, balance Ni plus incidental impurities and a ratio of Nb/(Al+Ti) in the range of 2.5-7.5. To facilitate formability, the composition range of the alloy is balanced to be Laves phase free.
    Type: Application
    Filed: November 18, 2008
    Publication date: January 20, 2011
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventor: Sarwan Kumar Mannan
  • Patent number: 7815848
    Abstract: A corrosion resistant alloy is provided which includes, in percent by weight: (a) 16 to 24% Ni; (b) 18 to 26% Cr; (c) 1.5 to 3.5% Mo; (d) 0.5 to 1.5% Si; (e) 0.001 to 1.5% Nb; (f) 0.0005 to 0.5% Zr; (g) 0.01 to 0.6% N; (h) 0.001 to 0.2% Al; (j) less than 0.2% Ti; and (k) less than 1% Mn, trace impurities, and the balance Fe. Articles, such as flexible automotive exhaust couplings, including the present alloys are also provided.
    Type: Grant
    Filed: April 23, 2007
    Date of Patent: October 19, 2010
    Assignee: Huntington Alloys Corporation
    Inventors: James Roy Crum, Nathan Charles Eisinger, Stephen Mark Gosnay, Gaylord Darrell Smith
  • Publication number: 20100136368
    Abstract: A nickel, chromium, iron alloy and method for use in producing weld deposits and weldments formed therefrom. The alloy comprises, in weight percent, about 28.5 to 31.0% chromium; about 0 to 16% iron, preferably 7.0 to 10.5% iron, less than about 1.0% manganese, preferably 0.05 to 0.35% manganese; about 2.1 to 4.0% niobium plus tantalum, preferably 2.1 to 3.5% niobium plus tantalum, and more preferably 2.2 to 2.8% niobium plus tantalum; 0 to 7.0% molybdenum, preferably 1.0 to 6.5%, and more preferably 3.0 to 5.0% molybdenum; less than 0.50% silicon, preferably 0.05 to 0.30% silicon; 0.01 to 0.35% titanium; 0 to 0.25% aluminum; less than 1.0% copper; less than 1.0% tungsten; less than 0.5% cobalt; less than about 0.10% zirconium; less than about 0.01% sulfur; less than 0.01% boron, preferably less than 0.0015% boron, and more preferably less than 0.001% boron; less than 0.03% carbon; less than about 0.02% phosphorous; 0.002 to 0.015% magnesium plus calcium; and balance nickel and incidental impurities.
    Type: Application
    Filed: July 19, 2007
    Publication date: June 3, 2010
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventors: Samuel D. Kiser, Brian A. Baker, David E. Waskey
  • Publication number: 20090321405
    Abstract: A nickel (Ni), chromium (Cr), cobalt (Co), iron (Fe), molybdenum (Mo), manganese (Mn), aluminum (Al), titanium (Ti), niobium (Nb), silicon (Si) welding alloy, articles made therefrom for use in producing weldments and methods for producing these weldments. The welding alloy contains in % by weight about: 23.5 to 25.5% Cr, 15 to 22% Co, up to 3% Fe, up to 1% Mo, up to 1% Mn, 1.1 to 2.0% Al, 0.8 to 1.8% Ti, 0.8 to 2.2% Nb, 0.05 to 0.28% Si, up to 0.3% Ta, up to 0.3% W, 0.005 to 0.08% C, 0.001 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, up to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities.
    Type: Application
    Filed: June 22, 2009
    Publication date: December 31, 2009
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue