Abstract: A process and system for producing reducing gases are disclosed, wherein volatile components derived from coal are transformed into reducing gases suitable for utilization as synthesis gas, as a reducing agent for the direct reduction of iron ores and/or as a clean fuel.

Abstract: A method and an integrated steel plant wherein, instead of using coke oven gases, converter gases and blast furnace top gases available as fuel for power generation or other heating purposes, these gases are more efficiently utilized as chemical agents for direct reduction of iron ores producing DRI. DRI is charged to blast furnaces increasing production of crude steel without increasing the capacities of the coke oven plant and blast furnaces and without changes in the quality of the crude steel, or, if production rate is maintained, the fossil fuels specific consumption is significantly reduced. Utilisation of primary fossil energy according to the invention also reduces the specific CO2 emissions per ton of crude steel. The specific CO2 emission in conventional integrated mills is about 1.6 tons of CO2 per ton of crude steel.

Abstract: The invention relates to a method and system for destroying liquid toxic materials for example polychlorinated biphenyls, and producing a reducing gas. In a preferred embodiment, harmful intermediates are not generated when the toxic materials are destroyed due to the reducing atmosphere produced by partial combustion with a molecular-oxygen-containing gas and steam. Liquid materials containing high concentrations of PCB's are mixed with non-toxic hydrocarbons for sustaining an autothermic reaction. The efficiency of the PCB's destruction process exceeds the required environmental regulations and produces a useful reducing gas which can be utilized as a synthesis gas in chemical processes or as a fuel for heat and/or power production.

Abstract: So as to provide a container that is inexpensive to manufacture and that promotes a uniform flow of particulate bulk materials therethrough, a vessel is suggested comprising at least two wall segments having a generally downwardly converging wall defining a vertical axis for the vessel, a first upper segment being vertically arranged above a second lower segment, each one of the wall segments having an upper edge and a lower edge, the perimeter of the upper edge of the second lower wall segment being larger than the perimeter of the lower edge of the first upper wall segment the lower edge of the first upper wall segment and the upper edge of the second lower wall segment being positioned proximate to each other and cooperating to provide an enlargement of the cross-sectional area of the volume occupied by the particulate solid material.

Abstract: A method and an integrated steel plant wherein, instead of using coke oven gases, converter gases and blast furnace top gases available as fuel for power generation or other heating purposes, these gases are more efficiently utilized as chemical agents for direct reduction of iron ores producing DRI.

Abstract: So as to provide a container that is inexpensive to manufacture and that promotes a uniform flow of particulate bulk materials therethrough, a vessel (10) is suggested comprising at least two wall segments (12, 14) having a generally downwardly converging wall defining a vertical axis for said vessel, a first upper segment (12) being vertically arranged above a second lower segment (14), each one of said wall segments having an upper edge and a lower edge, the perimeter of the upper edge of said second lower wall segment (14) being larger than the perimeter of the lower edge of said first upper wall segment (12); said lower edge of said first upper wall segment (12) and said upper edge of said second lower wall segment (14) being positioned proximate to each other and cooperating to provide an enlargement (34) of the cross-sectional area of the volume occupied by said particulate solid material; and the lower edge of said first upper segment (12) defining a plane forming an angle with respect to the vertical

Abstract: A method and apparatus for the production of prereduced iron ore, DRI, sponge iron or the like by the gaseous reduction of iron-oxide containing particles in a reduction system which comprises a preheating device for the iron ore particles. The preheating device preserves the strength of the iron ore particles through the reduction system by preheating the particles with non-reducing (or preferably oxidizing) gas, whereby the DRI or like material produced is stronger than if it were processed in a reduction reactor without said preheating device. The invention thereby avoids sticking and fines production problems which some iron ores cause in the reduction reactor. The preheating device also produces other advantages in the reduction system as, for example, that the reducing gas reaches a higher degree of oxidation in the reduction reactor whereby the productivity of the reduction system increases as a result of the decreased amount of reducing gas as well as the decreased residence time required.

Abstract: The present invention relates to a method and apparatus for separating undesired toxic metals, such as Zn, Pb and Cd, from iron-containing materials by: sintering a mixture of such materials (typically including EAF dust and mill scale) with carbonaceous particles to form sturdy sinter lumps; preheating such lumps in a non-reducing atmosphere, if needed, to achieve an elevated temperature generally above the vaporization temperature of the undesired metals, but below the sticking temperature of iron-containing lumps (which is typically below the vaporization temperatures of such undesired metals in their oxide form), feeding the lumps at such elevated temperature into a reduction reactor; flowing hot reducing gas through lumps to volatilize undesired reduced metals and carry the volatilized metals out of reduction reactor leaving the iron-containing lumps largely stripped of the undesired metals and ready for discharge and safe and/or useful disposal or re-use, and finally cooling the off gas from the reactor

Abstract: Method and apparatus for pneumatically transporting solid and abrasive particulate materials at high temperature, by means of a carrier gas through a plurality of co-axial straight pipes. The pipes are maintained under constant tension by applying a force across at least one expansion joint coupling said pipes in order to maintain said pipes straight against the forces acting on said pipes which tend to cause bending and deformation thereof, as for example: thermal elongation, the weight of the solids conveyed through said pipes, the friction forces between said pipes and its supporting frame, and the pressure of the carrier gas inside said pipes. The constant tensioning force may be applied for example, by means of hydraulic cylinders in combination with a telescopic water-cooled sleeve.

Abstract: Methods and apparatus for the reduction into metallic iron of iron-oxides-containing particles having a broad range of sizes. Particles, typically within a broad range of sizes of about 0.1 mm to about 50 mm, are reduced by contact with a hot reducing gas, preferably from a horizontal gas distributor which defines the bottom of the reduction zone by supplying a uniform upflow of gas mainly composed of hydrogen (and/or carbon monoxide) within a temperature range of 650° C. to 1050° C. and at a velocity of about 0.5-0.7 m/s to fluidize at least some of the particles of a size of about 1.0 mm or less (when present).

Abstract: A method and apparatus for increasing the productivity of an existing direct reduction iron (DRI) plant without increasing its reformer capacity existing in the plant. This object is achieved by not only recycling some effluent gas of the reduction reactor to the gas reformer (with natural gas or the like added with an oxidant as make up gas), but also recycling an additional portion of the effluent gas with added natural gas and an oxygen containing stream directly to the reducing gas stream exiting the reformer prior to or as part of its introduction to the reduction reactor, thereby providing additional reducing agents and increasing the reducing capacity of the plant. The oxygen containing stream is preferably added to the recycled reducing gas without preheating. Any excess or purged effluent gas is as usual burned as fuel.

Abstract: The present invention describes a method and apparatus for the reduction into metallic iron of iron-oxides-containing particles having a broad range of sizes. Particles, preferably within a broad range of sizes smaller than about 3.2 mm, are reduced by contact with a hot reducing gas, preferably mainly composed of hydrogen and within a temperature range of 700 to 750.degree. C. The reducing gas flows through a descending moving bed of coarser particles and forms an ascending fluidized bed of fines, all in a single reduction reactor, where the particles charged to the reactor are fed into the lower portion of the fluidized bed and the reduced fines are withdrawn from the reactor from the upper portion of the fluidized bed.

Abstract: A coiling system for thin steel strip which avoids problems of thin steel strip winding on its pinch rolls and assures that the strip is guided towards the predetermined coiling roll, thus decreasing operational delays and increasing productivity of a thin gage hot rolling steel strip mill. The system comprises a flap guide positionable in at least two positions, a first position contacting a pinch roll during the initial threading period of each strip to be coiled, and a second normal operating position without contact with said pinch roll when the strip is being wound in said predetermined coiler. The flap guide may also be used in multiple coiler rolls systems and may be adapted for automatic operation.

Abstract: Method and apparatus for the production of prereduced iron ore, Direct Reduced Iron (DRI), or the like, in an ironmaking plant wherein the reducing gas utilized in the chemical reduction of iron oxides is generated from natural gas within the reduction reactor system by reforming the hydrocarbons with such oxidants as water and oxygen inside the reduction reactor which under steady state conditions contains metallic iron which acts as a reformation catalyst. The amount of carbon in the DRI can be reliably controlled by modifying the relative amounts of water, carbon dioxide and oxygen in the composition of the reducing gas fed to the reduction reactor. The amount of carbon in the DRI is controlled by the amount of water in the reducing gas fed to the reduction reactor while the addition of oxygen provides the energy necessary for such DRI carburization.

Abstract: A method and apparatus for producing DRI, prereduced materials, or the like, utilized in the steelmaking industry, where hydrogen contained in the gas stream purged from the reduction reactor is separated (preferably by means of a PSA system) and recycled to said reduction reactor. The productivity of the reduction plant is increased by using the separated hydrogen as a chemical reductant in the reactor, instead of using it as fuel. This is particularly useful in upgrading existing DRI production plants.

Abstract: A method and apparatus for producing direct reduced iron using a melter-gasifier and two reduction reactors. In the first reduction reactor, iron ore is prereduced using a reducing gas from a melter-gasifier. This prereduced iron ore is fed into the melter-gasifier to produce pig iron. A secondary reducing gas comprising hydrogen and carbon monoxide is withdrawn from the first reduction reactor and is reacted with water to produce carbon dioxide which is subsequently removed to produce a tertiary reducing gas that is used in the second reduction reactor to produce direct reduced iron from iron ore.

Abstract: Method and apparatus for the production of prereduced iron ore, Direct Reduced Iron (DRI), or the like, in an ironmaking plant wherein the reducing gas utilized in the chemical reduction of iron oxides is generated from natural gas within the reduction reactor system by reforming the hydrocarbons with such oxidants as water and oxygen inside the reduction reactor which under steady state conditions contains metallic iron which acts as a reformation catalyst. The amount of carbon in the DRI can be reliably controlled by modifyng the relative amounts of water, carbon dioxide and oxygen in the composition of the reducing gas fed to the reduction reactor. The amount of carbon in the DRI is controlled by the amount of water in the reducing gas fed to the reduction reactor while the addition of oxygen provides the energy necessary for such DRI carburization.

Abstract: A process and apparatus for gasification of organic materials (typically incorporated in domestic and industrial wastes, including auto shredder residues) to produce useful synthesis gas (primarily CO & H.sub.2) with effectively non-toxic ash residue by means of a preferably stoichiometric burner directed into a single stage reactor containing a tumbling charge thus heated to 650.degree. to 800.degree. C. (below the incipient fusion temperature of the charge) resulting in thermally cracking and gasifying the organic materials in the charge and reacting the complex hydrocarbons and gas evolved with the CO.sub.2 and H.sub.2 O generated by the burner by combustion of a fuel and oxygen-containing gas at a high flame temperature, typically 2500.degree. to 3000.degree. C.

Abstract: Refractory materials (typically refractory bricks) having the exposed working surface treated to form a silica sand glazed surface for their utilization in iron ore reduction reactors, for example of the moving bed type, fluidized bed type, rotary kilns, or the like, and method and apparatus for treating refractory bricks before installation as well as for treating refractory linings already installed in existing iron ore reduction plants, which produce direct reduced iron (DRI), prereduced iron ores, or the like. Some operational problems, involving adherence and buildup of aggregates from small metallic iron particles on the refractory lining of said reduction reactor, are minimized with a corresponding decrease in operating costs and an increase in the availability of the DRI producing plant.

Abstract: A method and apparatus for producing direct reduced iron using a melter-gasifier and two reduction reactors. In the first reduction reactor, iron ore is prereduced using a reducing gas from a melter-gasifier. This prereduced iron ore is fed into the melter-gasifier to produce pig iron. A secondary reducing gas comprising hydrogen and carbon monoxide is withdrawn from the first reduction reactor and is reacted with water to produce carbon dioxide which is subsequently removed to produce a tertiary reducing gas that is used in the second reduction reactor to produce direct reduced iron from iron ore.