Abstract: A process and apparatus for gasification of organic materials (typically incorporated in domestic and industrial wastes, including auto shredder residues) to produce useful synthesis gas (with a major content CO and H.sub.2) with effectively non-toxic ash residue by means of at least one continuously operated burner, preferably stoichiometrically balanced (1:2 for natural gas/oxygen) at least at startup and shut down (optionally with some excess of oxygen, usually under steady-state conditions, such as at a ratio of 1:4 or higher, especially if the charge has well over 18% water content), directed into a primary single stage reaction zone (through an opening in common with the effluent product gas discharged therefrom such as to assure intimate contact therebetween), which zone contains a tumbling charge in a rotating barrel-shaped horizontal reactor thus heated to from about 650.degree. to about 800.degree. C.

Abstract: Method of continuously casting steel slabs and the like wherein a layer of melting powder is maintained at the top portion of the casting mold with sufficient thickness so as to provide an increased thermal insulation to the liquid layers of steel and slag, whereby the formation of a solidified slag rim in the mold is eliminated and the surface quality of the steel products is considerably improved. The melting powder addition according to the invention also reduces the number of break-outs and consequently considerably increases the availability and productivity of the caster.

Abstract: A method and apparatus for gasifying organic materials in a gasification reactor and vitrifying residual ash in a melting furnace comprising introducing a charge containing organic materials into said reactor, heating the charge sufficiently to thermally decompose and gasify the organic materials resulting in evolved gases, by means of at least one high temperature burner gas stream by combustion of a fuel with an oxygen-containing gas, to produce said synthesis gas and residual ash, introducing said residual ash from said reactor into a separate melting furnace, vitrifying said residual ash in said melting furnace by combustion of a fuel with an oxygen-containing gas, removing said vitrified ash as a solid frit product, and introducing the combustion gas from said furnace into said reactor.

Abstract: Methods and systems are provided for controlling the pneumatic transport of friable particulate solid material through a transport pipe by means of a carrier gas circulating in a loop comprising the transport pipe and a carrier gas recycle conduit. A value of kinetic energy of the carrier gas is determined at a location proximal to a point of introduction of the material into the transport pipe. This value is compared with a kinetic energy set point to produce a first control signal which controls venting of carrier gas from the loop. A value of flow rate of the carrier gas in the loop is determined and compared with a comparison signal based on the first control signal to produce a second control signal. The second control signal is used to control the flow rate of the carrier gas through the carrier gas loop.

Abstract: In method and apparatus for producing iron and steel from iron cores largely composed of iron oxides, wherein a direct reduction process is used to produce a solid particulate intermediate product, generally known as sponge Iron or Direct Reduced Iron (DRI); pneumatically conveying large iron-bearing particles, such as pelletized iron ore or particularly DRI, in a closed transport pipe, eg. from the reduction reactor of the direct reduction process to the metallurgical furnaces where liquid iron or steel are produced, for example electric arc furnaces, induction furnaces, basic oxygen furnaces, etc. or to a briquetting press to form DRI briquettes, or simply to a silo or storage bin, or in general to a subsequent processing step for said DRI. When the carrier gas is recirculated for reuse, surprisingly air can be a preferred source of such gas, especially for reactive hot DRI.

Abstract: A process and apparatus for gasification of organic materials (typically incorporated in domestic and industrial wastes, including auto shredder residues) to produce useful synthesis gas (primarily CO & H.sub.2) with effectively non-toxic ash residue by means of a preferably stoichiometric burner directed into a single stage reactor containing a tumbling charge thus heated to 650.degree. to 800.degree. C. (below the incipient fusion temperature of the charge) resulting in thermally cracking and gasifying the organic materials in the charge and reacting the complex hydrocarbons and gas evolved with the CO.sub.2 and H.sub.2 O generated by the burner by combustion of a fuel and oxygen-containing gas at a high flame temperature, typically 2500.degree. to 3000.degree. C.

Abstract: In a method of producing iron and steel, from iron ores largely composed of iron oxides, wherein a direct reduction process is used to produce a solid particulate intermediate product, generally known as sponge iron or Direct Reduced Iron (DRI); pneumatically conveying the DRI in a closed pipe from the reduction reactor of the direct reduction process to the metallurgical furnaces where liquid iron or steel are produced, for example electric arc furnaces, induction furnaces, basic oxygen furnaces, etc. or to a briquetting press to form DRI briquettes, or simply to a silo or storage bin, or in general to a subsequent processing step for said DRI. When the carrier gas is recirculated for reuse, surprisingly air is preferred as the source of such gas, especially for reactive hot DRI. This method has a superior efficiency and productivity and reduces the overall energy consumption relative to currently used DRI steelmaking plants.

Abstract: A method and apparatus for feeding iron-bearing particles into a metallurgical furnace such as an electric arc furnace, comprising a vessel for containing a bath of molten iron, having a wall extending above the bath of molten iron, a preferably screw type feeder mounted on the exterior of the vessel, a feeding port in the vessel wall shaped to permit passage of the feeder into the interior of the bath of vessel and located at such a height from the molten iron so that no molten materials will spill out from the furnace through the port during the normal operation and maneuvering of the furnace; and actuating means for extending the screw type feeder from a retracted position out of the vessel to an extended position into the vessel.

Abstract: Process control method for regulating the percentage reduction of sponge metal produced in a moving bed vertical reduction reactor by means of sampling at a single level in the reactor (preferably centrally located) for determining the concentration ratio of a reducing gas species and its oxidized product (such as the CO/CO.sub.

Abstract: At least a percentage of iron ore pellets and the like for use in a direct reduction process for the production of sponge iron are coated with a thin porous coating of Portland cement to counteract tendency to aggregate. This is accomplished by method and apparatus that mixes water and cement powder at the point of delivery in a manner such that no pumps are subjected to a wet cement slurry. The slurry is mixed and maintained in suspension by air agitation in a bin and then flowed through a bin discharge pipe and sprayed therefrom onto a passing layer of pellets in a controlled manner by regulated air injection into the discharage pipe.

Abstract: Magnetic valve and methods related thereto for regulating the physically unobstructed flow of ferromagnetic particulate solid materials through a conduit by means of an electromagnetic and/or permanent magnetic device for establishing and controlling a magnetic field, which is caused to selectively pass along a magnetic circuit which comprises said particulate materials in said conduit to be regulated and wherein said magnetic field is deviated from said conduit or deactivated to allow the flow of said material.

Abstract: A process for the gaseous reduction of iron ore to sponge in a vertical shaft, moving bed reactor wherein a hot gaseous mixture of hydrogen and carbon monoxide generated by the internal steam reformation of gaseous hydrocarbon(s), preferably methane or natural gas, is used to reduce the ore without the need for any external catalytic reformer. A reducing gas recycle loop is established to which hydrocarbon and reclaimed waste hot water are fed in the proper proportions as the reducing gas make-up source with the sponge iron produced in the reduction reactor being used to catalyze hydrocarbon reformation, and with the carbon content of the recycled gas being maintained low by removing carbon dioxide therefrom.

Abstract: A method and apparatus for the gaseous reduction of particulate iron ores, wherein the ore or is fed to a vertical moving bed direct reduction reactor, reduced therein, and discharged as hot sponge iron. The ore is charged to the top portion of the reduction zone of the furnace wherein the bed of particles which descend by gravity is reduced by a hot reducing gas largely composed by carbon monoxide and hydrogen. The hot reducing gas is divided in two portions, a first portion which flows upwardly through the reduction zone to reduce the ores therein, and a second portion which flows downwardly through a lower discharge zone to maintain the bed at a suitable temperature level. Finally, the product sponge iron is discharged from the bottom portion of the discharge zone of the furnace and conveyed, for example, to be melted in an electric arc furnace or to be briquetted in a briquetting machine coupled to the reduction reactor.

Abstract: A method is disclosed for the gaseous reduction of iron ore to sponge iron at a given degree of carburization and yet at a temperature suitable for hot briquetting or for direct feed to a melter or to a refining furnace. The desired percentage of carburization and the preferred elevated temperature are achieved by using a hot blend of recycled reducing gas and essentially uncracked natural gas or methane to carburize and to decrease the temperature of the sponge iron in the modifying zone of the reactor.

Abstract: Start-up method for an iron ore direct reduction process, where in the steady-state process the reducing gases are produced by steam reformation of natural gas catalyzed within the reducing zone of the reduction vessel by the reduced ore present therein. During established steady-state operation, a process gas stream is circulated in a reducing gas loop comprising the reduction vessel, a gas heater, and units to remove H.sub.2 O and CO from the gas circulating in said loop. Natural gas and water are fed directly to the reducing gas loop as make-up reactants for the reformation. At plant start-up there is a complete absence of metallic iron to catalyze the reformation reaction at any temperature, and a complete absence of H.sub.2 or CO so no effective reduction is possible to produce the needed metallic iron. In a multi-stage start-up, the reduction vessel is first charged with iron ore and pressurized by introducing natural gas to said loop. Simultaneously, the temperature is raised to the range of 400.

Abstract: Graphite consumable electrode for electric arc furnaces and the like, which comprises a plurality of essentially similar graphite sections and coupled one to the other by means of threaded connections, wherein each section is provided with cooling conduits formed into it, through which a cooling fluid flows fed only through the upper portion of the electrode from a distributing header with the lower tip portion of the electrode being automatically isolated from the cooling fluid flow.

Abstract: A method and apparatus for the direct gaseous reduction of iron ore to sponge iron at an elevated temperature suitable for hot briquetting, wherein a hot reducing gas is circulated upwardly through a descending body of iron ore and a make-up reducing gas stream is added to the circulating gas stream. A sponge iron product having a predetermined desired degree of carburization in the range 0.5% to 4% is obtained by adding a controlled flow of natural gas or other methane-containing gas to said make-up gas stream or to said circulating gas stream.

Abstract: A method for the gaseous reduction of particulate iron ore to sponge iron product in a vertical shaft reactor having a reduction zone in the upper portion thereof, a cooling zone in the lower portion thereof and an intermediate zone between the reduction and cooling zones. In order to reduce the tendency of the hot sponge iron to sinter and agglomerate, and stick to the walls of the reactor, and to give a more uniform product, a cool gas stream is introduced into the intermediate zone and caused to flow downwardly along the wall of the intermediate zone to cool the peripheral portion of the body of reduced ore flowing from the reduction zone through the intermediate zone.

Abstract: Improved process and apparatus for the reduction of iron oxides employing a solid reducing agent. Particulate iron oxides are mixed with particles of the reducing agent and are subjected to high temperatures within a vessel made of refractory material which is externally heated in a furnace. The problem and drawbacks that have been found in the past, such as the fracture and high costs of the refractory vessels, are solved by means of the present invention which comprises laying a sheet made of tinplate or of other suitable material, between the vessel and solids to prevent them from sticking to the vessel because of the high temperature, thus providing an economic and advantageous process. In one of its embodiments, this process is particularly suitable for the production of high purity iron, that is with a low content of gangue and carbon. This high purity iron, once converted to powder with adequate particle size, has a number of diverse applications in industry.

Abstract: A method is disclosed for the gaseous reduction of iron ore to sponge iron at a given degree of carburization and yet at a temperature suitable for hot briquetting or for direct feed to a melter or to a refining furnace. The desired percentage of carburization and the preferred elevated temperature are achieved by using a hot blend of recycled reducing gas and essentially uncracked natural gas or methane to carburize and to decrease the temperature of the sponge iron in the cooling zone of the reactor.