Patents Assigned to Idemitsu Petrochemical Company Limited
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Patent number: 4919911Abstract: The present invention provides a method of recovering a lithium chloride, which comprises reacting a dihalogenated aromatic compound and an alkali metal sulfide and/or alkali metal hydrogen sulfide in a polar solvent under the pressure of lithium chloride, separating a solvent insoluble component from the resultant reaction mixture to obtain a solution, and calcinating a residue obtained by removing volatile substances from the resultant solution, as well as a method of recovering a lithium chloride, which comprises reacting a dihalogenated aromatic compound and an alkali metal sulfide and/or alkali metal hydrogen sulfide in a polar solvent under the pressure of lithium chloride, separating the granular polymer ingredient from the resultant reaction mixture subjecting the liquid suspension obtained by said separation to solid-liquid separation and calcinating the residue obtained by removing volatile substances from the resultant solution component.Type: GrantFiled: December 16, 1988Date of Patent: April 24, 1990Assignee: Idemitsu Petrochemical Company LimitedInventors: Daigo Shirota, Masao Omori, Hiroyasu Yamato, Norio Ogata
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Patent number: 4910294Abstract: Disclosed is a process for producing stably a polyarylene sulfide of high purity and high molecular weight by contacting a dihalogeno aromatic compound with an alkali metal sulfide in a polar solvent which comprises, as a first stage, reacting a dihalogeno aromatic compound with an alkali metal sulfide in a polar solvent in the presence of a lithium compound and in the presence of substantially no water at 200.degree.-270.degree. C. with concentration of remaining alkali metal sulfide being 5.5 g/l-polar solvent or less in terms of sulfur; then adding water in an amount of 1.0-10 mols per 1 mol of said alkali metal sulfide; and, thereafter, as a second stage, carrying out the reaction at 220.degree.-280.degree. C. Preferred dihalogeno aromatic compound is p-dichlorobenzene, preferred alkali metal sulfide is sodium sulfide and/or lithium sulfide and preferred lithium compound is lithium chloride and/or lithium sulfide.Type: GrantFiled: June 20, 1988Date of Patent: March 20, 1990Assignee: Idemitsu Petrochemical Company LimitedInventors: Norio Ogata, Hiroyasu Yamato
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Patent number: 4906429Abstract: This invention provides a process for producing a blown film of butene-1 polymer excellent in elasticity, elastic recovery, impact strength and the like which includes extruding a butene-1 polymer having a melt index of 0.3-10 g/10 min in a tubular form from extrusion die at an extrusion temperature of 120.degree.-250.degree. C. and then inflation molding the tubular film under the conditions that frost line height is 38-100 cm, stretch ratio in machine direction is 5 or more and ratio of stretch ratio in machine direction/stretch ratio in transverse direction is 2.5 or more.Type: GrantFiled: May 27, 1988Date of Patent: March 6, 1990Assignees: Idemitsu Petrochemical Company Limited, Neste OyInventors: Takashi Yamawaki, Takeshi Yamada
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Patent number: 4869924Abstract: This invention provides a method for synthesis of diamond by contacting a substrate with a mixed gas of carbon source gas and hydrogen gas activated by irradiation with microwave to produce plasma, thereby to deposit diamond on the surface of the substrate wherein microwave is introduced from a plurality of directions to the substrate and an apparatus for synthesis of diamond which comprises at least one microwave oscillator which oscillates microwave, a plurality of waveguides for introducing from a plurality of directions the microwave oscillated from said microwave oscillator to a substrate for deposition of diamond, and a reaction chamber which is connected to said waveguides and in which diamond is deposited by generation of plasma thereby to form a diamond thin film on the surface of said substrate.Type: GrantFiled: August 31, 1988Date of Patent: September 26, 1989Assignee: Idemitsu Petrochemical Company limitedInventor: Toshimichi Ito
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Patent number: 4842951Abstract: A resin laminate is disclosed, which comprises a gas permeation-resistant resin layer having laminated on each side thereof a polyolefin based resin layer, wherein said polyolefin based resin layer contains an inorganic filler in an amount of 30 to 80% by weight based on the total weight of the resin composition. The resin laminate may be provided with a thermoplastic resin layer containing no inorganic filler on the outersurface thereof. The resin laminate has a minimized oxygen gas permeability and has a low calorific value and is useful as a packaging material.Type: GrantFiled: December 24, 1987Date of Patent: June 27, 1989Assignee: Idemitsu Petrochemical Company LimitedInventors: Toyokazu Yamada, Masao Miyama, Hideo Sugimura, Takeshi Shinohara
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Patent number: 4832855Abstract: The present invention provides an immersion oil for microscopy, especially suitably a fluorescence microscopy which is superior in properties required for immersion oil for microscopy. This immersion oil comprises a phthalic acid dialkyl ester and a chlorinated paraffin.Type: GrantFiled: December 22, 1987Date of Patent: May 23, 1989Assignee: Idemitsu Petrochemical Company LimitedInventor: Toshiaki Tanaka
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Patent number: 4814520Abstract: Disclosed is a process for producing 2,2-bis(4'-hydroxyphenyl)propanes represented by the following general formula (2): ##STR1## (wherein R.sup.2 represents hydrogen atom or a hologen atom and the four R.sup.2 may be identical or different, R.sup.3 and R.sup.4 which may be identical or different represent hydrogen atom, an alkyl group, an aryl group, an aralkyl group, a cycloalkyl group, an alkoxy group or a halogen atom, p and q which may be identical or different represent integers of 1-4, a is 2 or 3 and b is 2 when a is 2 and is 1 when a is 3), characterized by reacting at least one phenol represented by the following formula (1): ##STR2## (wherein R.sup.1 has the same meaning as R.sup.3 and R.sup.4 and n is an integer of 1-4) with an unsaturated carbon compound represented by the general formula: C.sub.3 R.sub.4.sup.2 (wherein R.sup.2 has the same meaning as in the formula (2) and the four R.sup.2 may be identical or different) in the presence of hydrochloric acid.Type: GrantFiled: September 1, 1987Date of Patent: March 21, 1989Assignee: Idemitsu Petrochemical Company LimitedInventor: Takashi Nakagawa
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Patent number: 4784812Abstract: Disclosed are a ceramics binder comprising an organic binding agent and adamantane and/or trimethylenenorbornane as a binding auxiliary, and a method for producing a ceramics article comprising mixing a ceramics raw material powder with a ceramics binder comprising an organic binding agent and adamantane and/or trimethylenenorbornane as a binding auxiliary, molding the resulting mixture by an injection molding method or an extrusion molding method to obtain a molded article, and sintering the molded article. When the ceramics binder is used in a dough for injection molding, the time required for eliminating the ceramics binder can be shortened and the content of the ceramics binder which remains in the molded articles after eliminating treatment can be reduced to a negligibly low level.Type: GrantFiled: June 16, 1986Date of Patent: November 15, 1988Assignee: Idemitsu Petrochemical Company LimitedInventors: Katsuyoshi Saitoh, Tsunenori Sakai
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Patent number: 4783573Abstract: A process for preparing a linear .alpha.-olefin having from 4 to 20 carbon atoms is disclosed which comprises polymerizing ethylene or gas containing ethylene in the presence of a catalyst consisting of a zirconium halide, an organoaluminium compound and a Lewis base, and adding a catalyst deactivating agent to the resulting reaction mixture, wherein said Lewis base is at least one member selected from the group consisting of thioethers, alkyl disulfides, thiophenes, thiourea, sulfides, phosphines and primary amines.Use of the catalyst enables preparation of linear .alpha.-olefins of a high purity and reduction in the amount of by-produced wax.Type: GrantFiled: December 24, 1986Date of Patent: November 8, 1988Assignee: Idemitsu Petrochemical Company LimitedInventors: Yasushi Shiraki, Shinichi Kawano, Kunio Takeuchi
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Patent number: 4732924Abstract: Disclosed is a method for producing a vinyl aromatic resin composition containing a rubber in a disposed state which comprises from 60 to 90% by weight of a copolymer of a vinyl aromatic monomer with an unsaturated dicarboxylic anhydride in which the content of the vinyl aromatic monomer as a monomer unit is from 70 to 98 mol % and the content of the unsaturated dicarboxylic anhydride as a monomer unit is from 2 to 30 mol %, from 10 to 35% by weight of a graft copolymer and from 0 to 9% by weight of a diene based rubber, by copolymerizing the vinyl aromatic monomer with the unsaturated dicarboxylic anhydride in the presence of the diene based rubber, wherein said method comprises.Type: GrantFiled: July 1, 1986Date of Patent: March 22, 1988Assignee: Idemitsu Petrochemical Company LimitedInventors: Eiichi Terada, Hiroshi Kurokawa, Shigemi Kawazoe