Abstract: A process for preparing a catalyst for the hydrogenation of aromatic or polyaromatic compounds comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
Abstract: A vessel for the downflow of a preferably hydrocarbon liquid, containing solid particles: a bottom comprising a cylindrical upper part (11), a lower part (12) with a decreasing cross section and a varying angle of inclination ? with respect to the vertical axis (Z), and an outlet pipe (9); injections (5) and (6) of recirculated and/or of makeup liquid into the lower and upper parts respectively; injections (5) inclined with respect to the tangent to the wall of the lower part at the injection point by an angle ?1 in the vertical plane (xz) and by an angle ?2 in the horizontal plane (xy); injections (6) are inclined with respect to the wall of the upper part by an angle ?1 in the vertical plane (xz) and by an angle ?2 in the horizontal plane (xy).
Type:
Grant
Filed:
February 5, 2020
Date of Patent:
March 8, 2022
Assignee:
IFP Energies Nouvelles
Inventors:
Benjamin Amblard, Joao Marques, Jean-Francois Le Coz
Abstract: The present invention relates to a process for treating, by reactive distillation, an olefinic feedstock comprising linear olefins containing n carbon atoms, and branched olefins, the branched olefins comprising tertiary branched olefins, for example a mixture of n-butenes and of tertiary branched olefins comprising isobutene, so as to produce an olefinic effluent with a mass content of tertiary branched olefin of less than or equal to 3% by weight and a heavy hydrocarbon effluent, said process comprising the feeding of a reactive distillation section with said olefinic feedstock and with an alcohol feedstock comprising a primary alcohol, said reactive distillation section comprising a column composed at least of an upper reflux zone into which is introduced said alcohol feedstock, comprising, for example, ethanol, an intermediate reaction zone comprising at least 6 reactive doublets, and a lower fractionation zone at the level of which said section is fed with said olefinic feedstock, said reactive distillat
Type:
Grant
Filed:
January 28, 2019
Date of Patent:
March 8, 2022
Assignees:
IFP Energies Nouvelles, Total Research & Technology Feluy
Inventors:
Kirill Drobyshev, Vincent Coupard, Nikolai Nesterenko
Abstract: Stabilization system for a system subjected to external stresses, in particular for a floating support structure, the stabilization system comprising at least three damping devices (1), in form of U-shaped tubes, made up of liquid reserves (2) and a connecting tube (3). At least two of the damping devices are not parallel to one another. The invention further relates to a floating support structure comprising such a stabilization system.
Abstract: The invention relates to a process for the rejuvenation of an at least partially spent catalyst resulting from a hydrotreating process, said at least partially spent catalyst resulting from a fresh catalyst comprising a metal from group VIII, a metal from group VIb, an oxide support, and optionally phosphorus, said at least partially spent catalyst additionally comprising carbon in a content of between 2% and 20% by weight, with respect to the total weight of the at least partially spent catalyst, and sulfur in a content of between 1% and 8% by weight, with respect to the total weight of the at least partially spent catalyst, said process comprising the following stages: a) said spent catalyst is brought into contact with an impregnation solution containing a compound comprising a metal from group VIb, b) a drying stage is carried out at a temperature of less than 200° C.
Abstract: The present invention relates to a device and to a process for the fluidized bed catalytic cracking of a hydrocarbon feedstock, in which: a first feedstock (2) is cracked in a dense fluidized bed reactor (1) in the presence of a catalyst (3) to produce a first effluent; and at least one second feedstock (10) is cracked in a transport fluidized bed reactor (4) in the presence of the catalyst (3) supplied by the dense fluidized bed reactor (1) to produce a second effluent, the second feedstock (10) being a heavier feedstock than the first feedstock (2).
Abstract: The present invention relates to a device and a process for converting aromatic compounds, wherein: methyl-substituted aromatic compounds are extracted from a hydrocarbon feedstock (2) comprising aromatic compounds having at least 8 carbon atoms in an extraction unit (1), to produce at least one effluent enriched in methyl-substituted aromatic compounds (3A, 3B) and an effluent depleted in methyl-substituted aromatic compounds (4); and C2+ alkyl chains of the aromatic compounds of the depleted effluent (4) are converted into methyl groups in a hydrogenolysis unit (5) placed downstream of the extraction unit (1), to produce a hydrogenolysis effluent enriched in methyl-substituted aromatic compounds (7).
Type:
Application
Filed:
December 13, 2019
Publication date:
March 3, 2022
Applicant:
IFP Energies nouvelles
Inventors:
Vincent COUPARD, Alexandre PAGOT, Vanessa VINCENT-GENOD
Abstract: The present invention relates to the field of the conversion of hydrocarbons and more particularly to that of catalytic reforming. A subject matter of the invention is a process employing at least two reaction zones, two reduction zones and one regeneration zone, and in which the effluents from the reduction zones are recycled, at least in part, at the top of each reaction zone.
Abstract: Between 40% and 75% by weight of a first bitumen base B1 an asphalt obtained by a solvent deasphalting of a first vacuum residue R1 resulting from the distillation of an effluent hydroconverted by a process for the ebullated bed hydroconversion of a heavy hydrocarbon feedstock, and Between 25% and 60% by weight of a second bitumen base B2 and/or of a flux F, F at least one heavy aromatic cut with a hydrogen content of greater than 8.5% by weight, B2, R1 or a second vacuum residue R2 resulting from a distillation of a crude oil or a mixture of R1 and R2.
Abstract: The invention concerns a method for rejuvenating an at least partially used catalyst originating from a hydroprocessing and/or hydrocracking process, the at least partially used catalyst being derived from a fresh catalyst comprising at least one group VIII metal (in particular, Co), at least one group VIB metal (in particular, Mo), an oxide support, and optionally phosphorus, the method comprising the steps: a) regenerating the at least partially used catalyst in a gas stream containing oxygen at a temperature between 300° C. and 550° C. so as to obtain a regenerated catalyst, b) then placing the regenerated catalyst in contact with phosphoric acid and an organic acid, each having acidity constant pKa greater than 1.5, c) performing a drying step at a temperature less than 200° C. without subsequently calcining it, so as to obtain a rejuvenated catalyst.
Abstract: The invention relates to a process for treating an alcoholic feedstock, comprising: a) a stage of preheating of said alcoholic feedstock to a temperature of between 70° C. and 200° C.; b) a stage of pretreatment on an acidic solid, operating at a temperature of between 70° C. and 200° C., to produce a pretreated alcoholic feedstock; c) a stage of partial vaporization to produce a vaporized stream and a liquid stream; and d) a stage of purification of the liquid stream resulting from stage c), to give a stream rich in water, a stream rich in monoalcohol and a stream rich in impurities.
Type:
Application
Filed:
November 27, 2019
Publication date:
March 3, 2022
Applicants:
TOTAL RESEARCH & TECHNOLOGY FELUY, IFP Energies Nouvelles
Inventors:
Nicolas ARIBERT, Ludovic CHAHEN, Arnaud LANOUE, Vincent COUPARD, Nikolai NESTERENKO
Abstract: A process for preparing a selective hydrogenation catalyst comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
Abstract: The present invention is based on the use of a two-step hydrocracking process for the production of naphtha, comprising a step of hydrogenation placed downstream of the second hydrocracking step, the hydrogenation step treating the effluent resulting from the second hydrocracking step in the presence of a specific hydrogenation catalyst. Furthermore, the hydrogenation step and the second hydrocracking step are performed under specific operating conditions and in particular under quite specific temperature conditions.
Type:
Application
Filed:
January 2, 2020
Publication date:
March 3, 2022
Applicant:
IFP Energies Nouvelles
Inventors:
Emmanuelle GUILLON, Anne-Claire DUBREUIL, Antoine DAUDIN
Abstract: The invention relates to a process for synthesizing 5-hydroxymethylfurfural from a fructose-containing feedstock in the presence of at least one aprotic polar solvent and at least one dehydration catalyst, in which process the maximum instantaneous fructose concentration 5.0 wt %.
Abstract: The present invention concerns a method for cleaning a reactor (4) for treating a lignocellulosic biomass (P), said method comprising the following steps: a) draining the reactor of the reaction mixture containing the biomass, b) filling the reactor with a basic aqueous solution (EB), c) draining the reactor, d) injecting steam (V) into the reactor, e) filling the reactor with an aqueous solution (E), f) draining the reactor.
Type:
Application
Filed:
December 13, 2019
Publication date:
February 24, 2022
Applicants:
IFP Energies nouvelles, INSTITUT NATIONAL DE RECHERCHE POUR L'AGRICULTURE, L'ALIMENTATION ET L'ENVIRONNEMENT, AGRO INDUSTRIES RECHERCHE ET DEVELOPPEMENT
Abstract: The invention relates to a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut, hydrogen and a rejuvenated catalyst are brought into contact, said hydrodesulfurization process being carried out at a temperature of between 200° C. and 400° C., a total pressure of between 1 and 3 MPa, an hourly space velocity, defined as being the flow rate by volume of feedstock relative to the volume of catalyst, of between 1 and 10 h?1 and a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l, said rejuvenated catalyst resulting from a hydrotreating process and comprises at least one metal from group VIII, at least one metal from group VIb, an oxide support and at least one organic compound containing oxygen and/or nitrogen and/or sulfur.
Abstract: The present invention relates to a hydrogenolysis process wherein a hydrocarbon-based feedstock comprising aromatic compounds having at least 8 carbon atoms is treated by means of a hydrogen feed and in the presence of a catalyst, in order to convert C2+ alkyl chains of said aromatic compounds into methyl groups and to produce a hydrogenolysis effluent enriched in methyl-substituted aromatic compounds, wherein the catalyst comprises a support, comprising at least one refractory oxide, and an active phase comprising nickel and molybdenum, wherein: the nickel content being between 0.1 and 25% by weight relative to the total weight of the catalyst; the molybdenum content being between 0.1 and 20% by weight relative to the total weight of the catalyst; and the catalyst comprising a molar ratio of molybdenum to nickel of between 0.2 and 0.9. The present invention also relates to said catalyst and to the process for preparing said catalyst.
Type:
Application
Filed:
December 13, 2019
Publication date:
February 24, 2022
Applicant:
IFP Energies nouvelles
Inventors:
Vincent COUPARD, Anne-Claire DUBREUIL, Alexandre JOUVE, Denis UZIO
Abstract: The present invention relates to a process for producing butadiene from ethanol, in two reaction steps, comprising a step a) of converting ethanol into acetaldehyde and a step b) of conversion into butadiene, said step b) simultaneously implementing a reaction step and a regeneration step in (n+n/2) fixed-bed reactors, n being equal to 2 or a multiple thereof, comprising a catalyst, said regeneration step comprising four successive regeneration phases, said step b) also implementing a regeneration loop for the inert gas and at least one regeneration loop for the gas streams comprising oxygen.
Type:
Application
Filed:
December 13, 2019
Publication date:
February 24, 2022
Applicants:
IFP Energies nouvelles, COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
Abstract: The present invention relates to a process for producing butadiene from ethanol, in two reaction steps, comprising a step a) of converting ethanol into acetaldehyde and a step b) of conversion into butadiene, said step b) simultaneously implementing a reaction step and a regeneration step in (n+n/2) fixed-bed reactors, n being equal to 4 or a multiple thereof, comprising a catalyst, said regeneration step comprising four successive regeneration phases, said step b) also implementing three regeneration loops.
Type:
Application
Filed:
December 13, 2019
Publication date:
February 17, 2022
Applicants:
IFP Energies nouvelles, COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
Abstract: Apparatus and process for converting aromatic compounds, comprising/using: a fractionating train (4-7) suitable for extracting at least one benzene-comprising fraction (22), one toluene-comprising fraction (23) and one fraction (24) comprising xylenes and ethylbenzene from the feedstock (2); a xylene separating unit (10) suitable for treating the fraction comprising xylenes and ethylbenzene and producing a para-xylene-comprising extract (39) and a raffinate (40) comprising ortho-xylene, meta-xylene and ethylbenzene; an isomerizing unit (11) for treating the raffinate and producing a para-xylene-enriched isomerizate (42), which is sent to the fractionating train; and an alkylating reaction section (13) for treating at least part of the benzene-comprising fraction with an ethylene source (30) and producing an alkylation effluent (31) comprising ethylbenzene, which is sent to the isomerizing unit.