Patents Assigned to Infineum International Ltd.
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Patent number: 10640724Abstract: An additive package is disclosed for preparing an automotive crankcase lubricating oil composition for an internal combustion engine. The additive package is made by admixing: (i) 50 mass % or less of an oil of lubricating viscosity; (ii) 50 mass % or less of at least one overbased metal detergent, preferably at least one overbased metal hydroxybenzoate detergent; (iii) 50 mass % or less of an oil-soluble block or graft co-polymer of at least one polymeric block A which is derived from a hydroxycarboxylic acid and at least one polyalkylene block B which is a residue of a polyalkylene glycol, and (iv) optionally, at least one further additive selected from a dispersant, an antioxidant and/or an antiwear agent. The additive package includes less than 2.00 mass % preferably less than 1.50 mass %, of a friction modifier which is a monoester of a C5 to C30 carboxylic acid and which is free of nitrogen. Component (ii) is preferably an overbased metal hydroxybenzoate detergent.Type: GrantFiled: June 2, 2017Date of Patent: May 5, 2020Assignee: INFINEUM INTERNATIONAL LTD.Inventors: Anthony J. Strong, Philip J. Woodward
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Highly borated dispersant concentrates for lubricating oil compositions and methods for forming same
Patent number: 10487286Abstract: A process for producing a borated polyalkenyl succinimide dispersant composition in which the boron is incorporated primarily as cyclic metaboric acid moieties and the equivalents of boron incorporated per equivalent of nitrogen in the succinimide carrier is greater than 2; in which process a slurry of orthoboric acid is added to a polyalkenyl succinimide to form a reaction mixture, which reaction mixture is then heated under conditions (at a temperature and pressure and for a time) sufficient to remove from the reaction mixture from about 0.8 to about 1.2 moles of water of reaction per mole of boric acid charged.Type: GrantFiled: May 23, 2016Date of Patent: November 26, 2019Assignee: INFINEUM INTERNATIONAL LTD.Inventors: Marc W. Meads, Jacob Emert, Jun Hua -
Patent number: 10472584Abstract: A lubricant additive concentrate having a kinematic viscosity of from about 40 to about 300 cSt at 100° C., containing a dispersant-detergent colloid complex, including a polybutenyl succinimide dispersant that is the reaction product of a polyamine and polybutenyl succinic anhydride (PIBSA) derived from polybutene having a number average molecular weight (Mn) of from about 1300 to about 2500 and a terminal vinylidene content of at least about 65%, and succinic and/or maleic anhydride via an ene maleation process, the PIBSA having a succinic anhydride (SA) functionality (F) of greater than 1.7 and less than about 2.5; and a detergent colloid including overbased detergent having a total base number (TBN) of from about 370 to about 1000 mg KOH/g derived from one or more surfactants selected from (i) sulfonate; (ii) phenate; and (iii) carboxylate surfactant; in which the mass ratio of the dispersant to the overbased detergent colloid in the concentrate is from about 0.5 to about 5.Type: GrantFiled: July 30, 2015Date of Patent: November 12, 2019Assignee: INFINEUM INTERNATIONAL LTD.Inventors: Jacob Emert, Sonia Oberoi, Gang Hu, Peter J. Hobin, Gareth B. L. Strange, Alessandra Catani, Claire L. Fitter, James R. Millington
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Patent number: 8105991Abstract: An overbased metal sulphonate detergent having incorporated therein at least one friction modifier including at least one amine group.Type: GrantFiled: October 1, 2008Date of Patent: January 31, 2012Assignee: Infineum International Ltd.Inventors: Peter J. Dowding, Christopher J. Adams
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Patent number: 7597725Abstract: An additive composition for a fuel oil composition and that is free of polycyclic carboxylic acids and of acid derivatives thereof comprises an additive that comprises one or more monocarboxylic acids, each having from 10 to 24 carbon atoms, or acid derivatives thereof, optionally in combination with one or both of an anti-oxidant additive and an anti-static additive.Type: GrantFiled: September 30, 2003Date of Patent: October 6, 2009Assignee: Infineum International Ltd.Inventors: Rinaldo Caprotti, Carlo S. Fava, Graham Jackson, Iain More
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Patent number: 7520906Abstract: A fuel oil containing a conductivity improving additive comprising the combination of: (a) a polymethacrylate, polyacrylate or polyfumarate polymer not prepared from a quaternary ammonium monomer and having a number average molecular weight of about 1,000 to 10,000,000 and either (b) a conductivity improver comprising (i) an olefin polysulfone and (ii) a polymeric polyamine reaction product of epichlorohydrin and an aliphatic primary monoamine or an N-aliphatic hydrocarbyl alkylene diamine, or the sulfonic acid salt of the polymeric polyamine reaction product or (c) a conductivity improver comprising a hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer, wherein the copolymer has an alkylvinyl monomer unit to cationic vinyl monomer unit ratio of from about 1:1 to about 10:1, the copolymer having a number average molecular weight of from about 800 to about 1,000,000.Type: GrantFiled: June 30, 2004Date of Patent: April 21, 2009Assignee: Infineum International Ltd.Inventor: Fiona K. Gormley
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Patent number: 7101830Abstract: A gas engine lubricating oil composition having a boron content of more than 95 ppm, the gas engine lubricating oil composition comprising: a major amount of a lubricating oil having a viscosity index of 80 to 120, and including at least 90 mass percent of saturates and 0.03 mass percent or less of sulphur; and at least one metal detergent. The gas engine lubricating oil composition exhibits improved oxidation and reduced deposit formation.Type: GrantFiled: March 3, 2003Date of Patent: September 5, 2006Assignee: Infineum International Ltd.Inventors: Yolanda Owen, Laurent Chambard
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Patent number: 7067599Abstract: A copolymer comprising units derivable from (A) one or more olefins of defined chain length; and (B) one or more ethylenically unsaturated compounds different from (A). The copolymers are useful as cold flow improvers in fuel oils.Type: GrantFiled: December 2, 1999Date of Patent: June 27, 2006Assignee: Infineum International Ltd.Inventors: Robert Dryden Tack, Brid Dilworth, Dennis George Peiffer
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Patent number: 6869919Abstract: Soot induced kinematic viscosity increase of lubricating oil compositions for diesel engines equipped with EGR systems can be ameliorated by selection of viscosity modifier, lubricating oil flow improvers, detergents and/or dispersants.Type: GrantFiled: September 10, 2002Date of Patent: March 22, 2005Assignee: Infineum International Ltd.Inventors: Andrew J. D. Ritchie, Jai G. Bansal, Jacob Emert, Glen P. Fetterman, Antonio Gutierrez, Matthew D. Irving, Christopher J. Locke, Michael T. Minotti
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Patent number: 6855674Abstract: Low molecular weight oxazine ring-containing Mannich base condensates of hydroxy aromatic compounds, aldehyde; and amine. Such compounds are useful as soot dispersants in lubricating oils when used alone, or in combination with high molecular weight dispersants.Type: GrantFiled: December 2, 2002Date of Patent: February 15, 2005Assignee: Infineum International Ltd.Inventor: Antonio Gutierrez
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Patent number: 6852679Abstract: A lubricating oil composition having less than 0.2 wt. % sulfur, less than 50 ppm chlorine, less than 50 ppm phosphorus, a NOACK volatility of 15 wt. % or less comprising an organo-molybdenum compound, an overbased calcium or magnesium salicylate, a dispersant and a supplemental antioxidant.Type: GrantFiled: February 20, 2002Date of Patent: February 8, 2005Assignee: Infineum International Ltd.Inventors: Rolfe J. Hartley, Malcolm Waddoups, Ricardo A. Bloch, Roger W. Glyde, Robert Robson
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Patent number: 6821307Abstract: An improved fuel oil composition comprises fuel oil and specific acylated polyalkylene polyamine.Type: GrantFiled: December 18, 2002Date of Patent: November 23, 2004Assignee: Infineum International Ltd.Inventors: Rinaldo Caprotti, Christophe Ledeore
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Patent number: 6790913Abstract: Additive compositions comprising: (i) at least one oil-soluble hydrogenated block diene polymer, comprising at least one crystallizable block, obtainable by end-to-end polymerization of a linear diene, and at least one non-crystallizable block, the non-crystallizable block being obtainable by 1,2-configuration polymerization of a linear diene, by polymerization of a branched diene, or by a mixture of such polymerizations, (ii) at least one ethylene-unsaturated ester compound; and (iii) at least one comb polymer. The additive compositions are used to improve cold flow characteristics in fuel oils. The additive compositions are particularly effective in fuel oils having a 90-20% boiling temperature range, as measured in accordance with ASTM D-86, of more than 115° C., preferably more than 120° C., more preferably more than 130° C., and most preferably more than 140° C., and a final boiling point of more than 370° C., preferably more than 380° C.Type: GrantFiled: October 7, 2002Date of Patent: September 14, 2004Assignee: Infineum International Ltd.Inventors: Vincent J. P. R. Deneker, Paul Harffey
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Patent number: 6787509Abstract: A gas engine lubricating oil composition that is substantially free from dispersant. The gas engine lubricating oil composition has a TBN in the range of 3.5 to 20. The gas engine lubricating oil composition comprises an oil of lubricating viscosity and at least one metal detergent.Type: GrantFiled: September 9, 2002Date of Patent: September 7, 2004Assignee: Infineum International Ltd.Inventors: Laurent Chambard, Yolanda Owen
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Patent number: 6784143Abstract: The use, in a minor amount, of a detergent composition comprising one or more metal detergents which comprises metal salts of organic acids, wherein the detergent composition comprises more than 50 mole %, based on the moles of the metal salts of organic acids in the detergent composition, of: (I) a metal salt of an aromatic carboxylic acid, or (II) a metal salt of a phenol, or (III) both a metal salt of an aromatic carboxylic acid and a metal salt of a phenol, in a lubricating oil composition for improving the oxidation resistance of the lubricating oil composition, wherein the amount of phosphorus and sulfur in the oil composition is less than 0.09 mass % and at most 0.5 mass % respectively, based on the mass of the oil composition. It has also been found that a detergent composition comprising more than 50 mole % of a metal salt of an aromatic carboxylic acid improves the reduction in wear in an engine.Type: GrantFiled: May 9, 2002Date of Patent: August 31, 2004Assignee: Infineum International Ltd.Inventors: Christopher J. Locke, Mark G. Stevens, Peter Wrench, Stephen Arrowsmith, Rebecca C. Castle, Jane R. Galsworthy
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Patent number: 6750183Abstract: Lubricating oil compositions providing superior soot dispersing characteristics, which contain a combination of a high molecular weight dispersant and a soot dispersant comprising a linked aromatic oligomer.Type: GrantFiled: December 22, 2000Date of Patent: June 15, 2004Assignee: Infineum International Ltd.Inventors: Antonio Gutierrez, Ricardo A. Bloch, Nancy Z. Diggs, Fredrick W. Girschick, David J. Martella, Mark G. Stevens, Jacob Emert
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Patent number: 6743757Abstract: A dispersant that is a reaction product of a polyalkenyl-substituted mono- or dicarboxylic acid, anhydride or ester; and a polyamine, wherein the reaction product has from greater than about 1.3 to less than about 1.7 mono- or di-carboxylic acid producing moieties per polyalkenyl moiety, and the polyalkenyl moiety has a number average molecular weight of at least about 1800, and a molecular weight distribution (Mw/Mn) of from about 1.5 to about 2.0.Type: GrantFiled: December 6, 2001Date of Patent: June 1, 2004Assignee: Infineum International Ltd.Inventors: Ian A. W. Bell, Jacob Emert, Raymond Fellows, Antonio Gutierrez, Robert Robson
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Patent number: 6734148Abstract: A boron-containing dispersant composition containing one or more dispersants that are the reaction product of a polyalkenyl-substituted mono- or dicarboxylic acid, anhydride or ester; and a polyamine, in which at least one of the dispersants has a polyalkenyl moiety with a number average molecular weight of at least about 1800, and from greater than about 1.3 to about 1.7 mono- or di-carboxylic acid producing moieties per polyalkenyl moiety; and in which a ratio of wt. % of boron to wt. % of nitrogen (B/N) for the dispersant composition is from about 0.05 to about 0.24.Type: GrantFiled: December 6, 2001Date of Patent: May 11, 2004Assignee: Infineum International Ltd.Inventors: Ian A. W. Bell, Jacob Emert, Raymond Fellows, Antonio Gutierrez, Robert Robson
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Patent number: 6723685Abstract: A lubricating oil composition comprising a) an oil of lubricating viscosity having a viscosity index of at least 95; b) at least one calcium detergent; c) at least one oil soluble molybdenum compound; d) at least one organic ashless nitrogen-free friction modifier; and e) at least one metal dihydrocarbyldithiophosphate compound, the composition having a Noack volatility of about 15 wt. % or less, from 0.05 to 0.6 wt. % calcium from the calcium detergent, molybdenum in an amount of at least 10 ppm from the molybdenum compound, and phosphorus from the metal dihydrocarbyldithiophosphate compound in an amount up to about 0.1 wt. %.Type: GrantFiled: April 5, 2002Date of Patent: April 20, 2004Assignee: Infineum International Ltd.Inventors: Rolfe J. Hartley, Malcolm Waddoups
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Patent number: 6719814Abstract: The invention provides a lubricity additive in the form of an ester of an acid and an alcohol, wherein the acid is an aromatic mono-, di- or polyhydric, mono-, di- or polycarboxylic acid or mixture thereof, which may be alkylated and/or alkoxylated and wherein the alkyl and/or alkoxy groups, if any, are independently selected from groups having from 1 to 30 carbon atoms, characterised in that (a) the alcohol is glycerol, and (b) the mole percent of acid groups in the lubricity additive is less than 10%, based on the total of acid and ester groups. The invention also provides a process for preparing the lubricity additive, and a middle distillate fuel oil having a sulphur concentration of 0.2% by weight or less, and a minor portion of the lubricity additive.Type: GrantFiled: November 4, 1999Date of Patent: April 13, 2004Assignee: Infineum International LTDInventor: Jian Lin