Abstract: A composite wastewater sampler includes a flow-through-chamber having an inlet port and an outlet port with a path between them that gradually increases in depth and width and then decreases in width. It is shaped to cause fluid to: (1) flow from the inlet port; (2) drop to a lower level of flow within the flow-through-chamber; (3) gradually adjust in cross-sectional shape to the outlet port; and (4) flow back into a wastewater pipe. A sampling nozzle extends into the flow-through-chamber adjacent to the inlet port and within the path of the downwardly flowing wastewater so that wastewater exiting the port contacts the nozzle and flows downwardly across it.

Abstract: To sample liquids containing volatile materials, the liquid is pumped through a syringe needle into a container until the container overflows. The needle is removed slowly and the container is automatically closed as the needle is withdrawn, wherein liquid flows upwardly continuously as the needle is withdrawn through an opening. The cap for the container includes a closure having a valve opening extending upwardly and sized to narrowly receive a syringe in a perpendicular valve member opening. The valve member includes a flat member on one end adapted to be gripped by a cam follower for opening and closing of the valve opening in coordination with the movement of the syringe.

Abstract: A variable-orifice fluid restrictor for use with a supercritical extractor or chromatograph includes an inlet line for fluid at a pressure above its critical pressure, an extended tubular probe having an inner and an outer surface and a proximal and a distal end. The proximal end of the probe is disposed toward the inlet line. The distal end of the probe includes an adjustable orifice means adapted for metering the fluid and having first and second orifice members and an adjusting stem having first and second ends. The adjustable orifice means is adjacent to the outer surface of the probe and the orifice means is adjustable with the adjusting stem. The end of the adjusting stem is located at the distal end of the probe and is adapted for moving the first orifice member with respect to the second orifice member to control the adjustable orifice for varying the restriction of fluid passing through the adjustable orifice.

Abstract: To determine the total organic carbon content of a flowing liquid in a continuous process, water and oxidizing agents enter lower ports in a multi-stage column and flow upwardly through residence chambers as they are mixed. Spaced apart along the upper path of the liquid, there are helical reaction grooves relatively shallow and containing at least one helical groove to cause rapid motion of the liquid. An ultraviolet lamp extends downwardly through the center of the column so that the outer confining surface of the helical grooves is the outer surface of the ultraviolet lamp, causing the liquid to move rapidly in intimate contact with the ultraviolet lamp to receive intense radiation. The stages are separate and interchangeable so that selected sizes may interconnect. The residence chambers may have different sizes to permit different lengths of residence time and thus permit tailoring of the reaction to the expected organic carbon content and possible side reactions with other impurities in the water.

Abstract: In order to determine the biological oxygen demand of sewage, a sample of sewage is taken into a reaction vessel in which there is a biological bath which is kept moving turbulently by an agitator. An oxygen probe measure the oxygen consumption per unit time. After each measuring cycle the reaction vessel is rinsed with diluting water and is then ready for another measuring cycle. The reaction vessel penetrates into the sewage to be tested. The sewage sample enters the reaction vessel via an aperture.

Abstract: An automatic variable-orifice fluid restrictor for use with a supercritical extractor having a collection trap or a supercritical chromatograph includes an inlet line for fluid at a pressure above its critical pressure, an extended tubular probe having an inner and an outer surface and a proximal and a distal end. The proximal end of the probe carries an inlet connected to the inlet line and is outside of the trap. The distal end of the probe includes a variable orifice means adapted for metering the fluid. The variable orifice means is adjacent to the outer surface of the probe and is located in the midst of the trap. The variable orifice means is adjusted by an adjusting stem having first and second ends. The first end of the adjusting stem is connected to automatic control means such as a servo at the proximal end of the probe and outside of the trap. The second end of the adjusting stem varies the area of the orifice by moving a first orifice member.

Abstract: To avoid deposits on the restrictor that channels extractant into a collector, a heated capillary tube pressure release restrictor, has a thermally insulated outlet end in a collecting trap substantially colder than the capillary tube. The restrictor is heated between the insulation and the capillary tube by Joulean heating. The solvent in the trap is at a pressure of 5 to 200 psi above atmospheric pressure. The thermal resistance of the insulation is selected to reduce the heat added to the extractant to a minimum and yet cause the temperature of the extractant to be in a range within which it is sufficiently hot so it does not freeze when added to the collection solvent but not so hot as to reduce partitioning of the extract and extractant before the extractant leaves the collection solvent. It has a thermal conductivity no greater than 60 BTU's per hour, per square foot, per inch for a one degree Fahrenheit difference.

Abstract: To draw samples from a source of liquid, a pumping system measures the amount of liquid being pumped by detecting pump cycles and calculating the pumped liquid from this measurement and stored data including conduit size, pressure head and statistical data to correlate detected pump cycles with volume of liquid pumped. Pressure pulses cause by a peristaltic pump are sensed by a piezoelectric film positioned on an inlet conduit connecting the pump to the source of water and, when the liquid reaches a predetermined point determined by the nature of pulses are counted to determine the number of pump cycles.

Abstract: To provide performance particularly in handling supercritical extraction systems, a specially designed pump includes a cam-driven, single-plunger with a cam having a profile that enables the pumping system to avoid destructive reverse torque on the cam, gear train and drive motor after the cam passes top dead center. The fluid volume leaving the pump is determined by measuring only pressure or other parameters related to flow and movement of the plunger. Measurement of the fluid volume leaving the pump is useful for recording or indicating the flow rate while the pump is operating.

Abstract: A liquid sample storage device which utilizes a liner-holder with a liner which may be disposed of after use, thereby eliminating contamination problems associated with reusable bottles. The liner-holder is a hollow, wedge shaped container with an upwardly extending neck section and vents on the top and bottom, as well as a plurality of vents on each of its sides, to allow adequate displacement of air from within the container as the liner fills with the liquid sample. Two embodiments utilize a liner-holder which may be opened into two sections along a vertical hinge to provide access to the interior for proper positioning and later removal of the liner. The liner is positioned within the liner-holder, secured at the neck, and then suspended within the liner-holder by snap-locks or a support hook to facilitate the input of the sample into the liner.

Abstract: To determine the total organic carbon content of a flowing liquid in a continuous process, water and oxidizing agents enter lower ports in a continuous column and flow upwardly along a helical path with air gaps as they are mixed. The helical reaction path is formed by a helical glass cylinder between an ultraviolet lamp and outer wall of a continuous glass tube to cause rapid motion of the liquid. An ultraviolet lamp extends downwardly through the center of the column so that the outer confining surface of the helical path is the outer surface of the ultraviolet lamp, causing the liquid to move rapidly in intimate contact with the ultraviolet lamp to receive intense radiation. An air gap permits escape of air and reduces bubble size to reduce plug flow.

Abstract: A hydrogen sulfide analyzer that continuously samples waste water from a waste stream or reservoir and measures the concentration of purgeable H.sub.2 S present (H.sub.2 SP) This information, when combined with the volume of water present, provides a control quality signal that regulates the feed rate of the destructor chemical into the waste stream. This results in chemical savings for the user. A second result is the reduction in odor complaints and the corrosion problems associated with H.sub.2 S emissions. The analyzer measures only the purgeable H.sub.2 S contained in the liquid sample. The analyzer violently agitates the sample containing dissolved H.sub.2 S in solution to simulate actual conditions at points of agitation in the waste water stream. It also provides nearly optimal partial pressure conditions for the H.sub.2 S to exit the solution as a free gas. Any H.sub.

Abstract: A multiple chamber sample holding cartridge is used with a supercritical fluid extractor that causes membranes dividing the cartridge into chambers to rupture upon the pressurization of the sample cartridge, thereby allowing the intermixing of materials contained in the chambers. The neutral oil and loss determination of soybean and other oilseed oils by supercritical fluid extraction is efficient with this two-chambered sample cartridge.

Abstract: The rollers of a peristaltic pump are supported to prevent said rollers from compressing said tube more than the thickness of the walls of the tube. A tube holder rotates along with the roller assembly of the peristaltic pump and keeps the tube in line with the rollers.

Abstract: To collect analyte from a supercritical fluid extractor, the collector lifts vials into place by a biasing device that guides the file up to the restrictor where it is sealed. The vial can be moved back down from the collecting mechanism even if frost forms on the vial while the restrictor remains stationary. This vial is held in place by a guide that contains the seal for sealing the vial when it is raised in place.

Abstract: A liquid level monitor using a pressure actuated sensor to replace the open bubble tube. Air flows down the supply tube as in the bubbler, but rather than being released into the water, the air enters a chamber that has one movable wall, such as a diaphragm, that is acted on from the inside by pressurized air and from the outside by the hydrostatic head of the water. When the water pressure exceeds the chamber air pressure, the movable wall is pressed against an air outlet and does not allow air in the chamber to escape through the air outlet. One embodiment uses a diaphragm disposed over the air outlet; however, the concept may be extended to several other movable members, such as a piston with low actuation force. When the air chamber pressure exceeds the water pressure, the movable member moves away from the air outlet, releasing air and causing the chamber pressure to drop down to the water pressure.

Abstract: To measure flow rates, the cross-sectional shape of the flow path is changed by inserting a multiple position gate into the flow path and altering the position of the gate to maintain the head of liquid constant with a reduced flow cross section. The position of the multiple position gate is correlated with the depth as measured with a bubbler to provide an indication of flow rate. To purge the bubbler line, a purge tank is located near the bubbler line. At timed periods or as manually initiated the controller causes an increase in pressure in accumulator portion of the purge tank. When a predetermined pressure is reached, a purge valve in the purge tank opens, rapidly allowing a burst of air at a substantial pressure and velocity to flow through the bubbler line to remove any material adhering to the bubbler outlet port.

Abstract: A method and apparatus for water sampling utilizing on-site solid phase extraction that permits high sample flow rates and eliminates the requirement for sample storage. Samples are collected at a relatively high flow rate and then temporarily stored under pressure before passing through a solid phase extraction device at a slower rate commensurate with the flow rate tolerance of the device. Each sample quantity is also automatically measured, eliminating the requirement for sample storage and subsequent manual quantity measurement and/or transportation to a laboratory.

Abstract: To inject sample into a capillary tube of an electrophoresis apparatus, a vacuum tank is connected to one end of the tube while the other end is in sample to impart a pressure difference across the tube. The pressure in the pressure chamber is sensed, integrated and used to determine and control the amount of sample drawn and to correct peak data.

Abstract: A liquid sample storage device which utilizes a liner-holder with a liner which may be disposed of after use, thereby eliminating contamination problems associated with reusable bottles. The liner-holder is a hollow, wedge shaped container with an upwardly extending neck section and vents on the top and bottom, as well as a plurality of vents on each of its sides, to allow adequate displacement of air from within the container as the liner fills with the liquid sample. Two embodiments utilize a liner-holder which may be opened into two sections along a vertical hinge to provide access to the interior for proper positioning and later removal of the liner. The liner is positioned within the liner-holder, secured at the neck, and then suspended within the liner-holder by snap-locks or a support hook to facilitate the input of the sample into the liner.