Abstract: A gas-barrier resin (A) having an oxygen permeability coefficient of 1.0×10?14 (cm3·cm/cm2·s·Pa) or less; and a copolymer (B) containing monomer structural units represented by the formula (1), the formula (2), and the formula (3): where: R1 represents a hydrogen atom or a methyl group; R2 represents a hydrocarbon group having 1 to 20 carbon atoms that may be substituted with a halogen atom, a hydroxy group, an alkoxy group, or an amino group; 1, m, and n represent numerical values representing molar proportions of the respective monomer structural units, and n may represent 0; and p represents an integer of from 1 to 4, wherein a ratio of a mass of the copolymer (B) to a total mass of the gas-barrier resin (A) and the copolymer (B) is from 1 mass % to 40 mass %.
Type:
Application
Filed:
July 17, 2018
Publication date:
May 20, 2021
Applicants:
SHOWA DENKO K.K., JAPAN POLYETHYLENE CORPORATION
Abstract: The metallocene compound represented by the following general formula (1): (the numerals and signs in the general formula (1) are as described in the description).
Abstract: The metallocene compound represented by the following general formula (1): (the numerals and signs in the general formula (1) are as described in the description).
Abstract: A catalyst configured to be handled more easily than conventional catalysts and configured to copolymerize an ?-olefin and a (meth)acrylic acid ester with high activity. The objects are achieved by polymerization using an olefin polymerization catalyst which contains a metal complex obtained by reacting a ligand having a specific structure and a transition metal compound containing a transition metal selected from nickel or palladium having a specific structure.
Type:
Application
Filed:
March 18, 2019
Publication date:
April 29, 2021
Applicants:
Japan Polyethylene Corporation, Japan Polypropylene Corporation
Inventors:
Yohei KONISHI, Hiromasa TANAHASHI, Hisashi OHTAKI, Naomasa SATO
Abstract: The present invention relates to a polar group-containing olefin copolymer (A?) which is produced through polymerization using a transition metal catalyst, which has a weight-average molecular weight falling within a specific range and which contains a polar group-containing monomer within a specific range; a multinary polar olefin copolymer (A?) indispensably containing a polar monomer component that has a norbornene skeleton and a carboxyl group or an acid anhydride group and having three or more types of monomer units; and a resin composition (C) containing a specific amount of a polar group-containing olefin copolymer (A) and a specific amount of an olefin resin (B).
Type:
Grant
Filed:
October 1, 2018
Date of Patent:
April 13, 2021
Assignees:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: Provided is a multi-component, polar group-containing olefin copolymer balanced between transparency, rigidity and toughness. The multi-component, polar group-containing olefin copolymer is a multi-component, polar group-containing olefin copolymer comprising: at least one structural unit (A) selected from the group consisting of a structural unit derived from ethylene and a structural unit derived from an ?-olefin which contains 3 to 20 carbon atoms, at least one structural unit (B) composed of a polar group-containing olefin monomer, and a structural unit (C) derived from a non-polar cyclic olefin.
Type:
Application
Filed:
December 17, 2018
Publication date:
March 4, 2021
Applicants:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: The present invention relates to a method for producing a copolymer of ethylene and an allyl monomer that is represented by formula (1) and has a polar group, or a copolymer of ethylene, the allyl monomer that is represented by formula (1) and has a polar group, and another monomer. This production method is characterized by using a metal complex, which is represented by general formula (C1), as a polymerization catalyst and by having a silane compound, which is represented by general formula (2) and has a silicon-hydrogen bond, coexist with the metal complex. (In the formulae, the symbols are as defined in the description.) According to the present invention, a copolymer of an allyl monomer that has a polar group is able to be produced with high catalytic activity, said copolymer being capable of having various applications.
Type:
Application
Filed:
January 29, 2019
Publication date:
February 25, 2021
Applicants:
THE UNIVERSITY OF TOKYO, SHOWA DENKO K.K., JAPAN POLYETHYLENE CORPORATION
Abstract: The metallocene compound represented by the following general formula (1): (the numerals and signs in the general formula (1) are as described in the description).
Abstract: The present invention pertains to a method for producing a copolymer of ethylene and an allyl monomer having a polar group represented by general formula (1), or a copolymer of ethylene, an allyl monomer having a polar group represented by general formula (1), and other monomers, wherein the copolymer is produced in the presence of a boron compound having a boron-hydrogen bond or a boron-carbon bond (for example, a compound represented by general formula (2)) by using a metal complex represented by general formula (C1) as a polymerization catalyst (the symbols in the formulas are as described in the description). According to the present invention, a copolymer of ethylene and an allyl monomer can be efficiently produced with high catalytic activity, wherein the copolymer has a polar group and can be used in various applications.
Type:
Application
Filed:
March 7, 2019
Publication date:
February 11, 2021
Applicants:
The University of Tokyo, SHOWA DENKO K. K., Japan Polyethylene Corporation
Abstract: An object of the present invention is to provide a multi-component polar olefin copolymer which has sufficiently improved solvent solubility without impairing mechanical properties and the like.
Type:
Application
Filed:
March 28, 2018
Publication date:
December 10, 2020
Applicants:
Japan Polyethylene Corporation, Japan Polypropylene Corporation
Abstract: The present invention relates to a polyethylene resin composition for lamination having excellent adhesiveness to a substrate or the like, and preferably also excellent in easy-opening properties such as easy piercing properties, and more specifically, relates to a polyethylene resin composition (C) for lamination containing an ethylene/propylene copolymer (A) having the following properties (a-1) to (a-4). (a-1) A constituent unit derived from ethylene is contained 80 to 98 mol % as a main component, a constituent unit derived from propylene is contained 2 to 20 mol % as an essential sub-component, and a constituent unit derived from a third ?-olefin other than ethylene and propylene may be contained 5 mol % or less as a sub-component. (a-2) MFR 0.1 to 100 g/10 min. (a-3) Density is 0.88 to 0.94 g/cm3. (a-4) Total of vinyl and vinylidene is 0.35 or more.
Abstract: A catalyst for olefin polymerization that contains a metal complex represented by general formula (C1) and a method for producing polyethylene, a copolymer of ethylene and an olefin having a polar group represented by general formula (1), or a copolymer of ethylene, an olefin having a polar group represented by general formula (1) and another monomer, using the aforementioned metal complex as a polymerization catalyst, wherein the symbols in formula (C1) and formula (1) are as defined in the specification.
Type:
Application
Filed:
November 7, 2018
Publication date:
November 5, 2020
Applicants:
THE UNIVERSITY OF TOKYO, SHOWA DENKO K. K., JAPAN POLYETHYLENE CORPORATION
Abstract: An object of the present invention is to provide a novel production method of ethylene-based ionomer having excellent mechanical properties and heat resistance which exhibits remarkably excellent breaking elongation, breaking stress, and strain hardening, and has a high melting point. The present invention relates to a production method of an ethylene-based ionomer including a heating conversion step of heating a specific ethylene/unsaturated carboxylic acid ester copolymer and converting the ester group in the copolymer into a metal-containing carboxylate containing a metal ion of Group 1, 2, or 12 of the periodic table.
Type:
Grant
Filed:
October 15, 2015
Date of Patent:
July 21, 2020
Assignees:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: An object of the present invention is to provide a polyethylene-based resin composition excellent in the moldability and at the same time, excellent in the balance between impact strength and stiffness as well as in the transparency, and a molded product and a film, which are obtained by the molding of the polyethylene-based resin composition. The polyethylene-based resin composition of the present invention comprises from 41 to 99 wt % of (A) an ethylene-based polymer satisfying specific conditions and from 1 to 59 wt % of (B) an ethylene-based polymer satisfying specific conditions, wherein MFR of the composition as a whole is from 0.05 to 50 g/10 min and the density is from 0.910 to 0.960 g/cm3.
Abstract: Provided is a process of effectively producing an ethylene/unsaturated carboxylic acid copolymer having excellent mechanical and thermal properties. A process for producing an ethylene/unsaturated carboxylic acid copolymer comprises: producing an ethylene/unsaturated carboxylic acid ester copolymer from ethylene and unsaturated carboxylic acid ester using a late-transition-metal complex catalyst; and heating the ethylene/unsaturated carboxylic acid ester copolymer at a temperature capable of converting the ester group into a carboxylic acid group, thereby converting into the ethylene/unsaturated carboxylic acid copolymer.
Type:
Grant
Filed:
January 11, 2018
Date of Patent:
February 4, 2020
Assignees:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: An object of the present invention is to provide a polyethylene-based resin composition excellent in the moldability and at the same time, excellent in the balance between impact strength and stiffness as well as in the transparency, and a molded product and a film, which are obtained by the molding of the polyethylene-based resin composition. The polyethylene-based resin composition of the present invention comprises from 41 to 99 wt % of (A) an ethylene-based polymer satisfying specific conditions and from 1 to 59 wt % of (B) an ethylene-based polymer satisfying specific conditions, wherein MFR of the composition as a whole is from 0.05 to 50 g/10 min and the density is from 0.910 to 0.960 g/cm3.
Abstract: An object of the present invention is to provide a polyethylene for injection molding, which has an excellent balance between moldability and durability, and a molded article such as an injection-molded plastic fuel tank that has an excellent balance among injection moldability, durability, and impact resistance. The invention relates to a polyethylene for injection molding, the polyethylene comprising at least two types of specific polyethylenes, wherein the density, the high load melt flow rate, and the relationship between the weight ratio and the density of the polyethylene satisfy specific characteristics.
Abstract: The present invention relates to a method for producing a copolymer of ethylene and a polar group-containing olefin using as a catalyst a metal complex of group 10 elements having a structure represented by formula (C4) and (C5) (in the formula, “Men” represents a menthyl group and “Me” represents a methyl group). The method of the present invention makes it possible to produce a polar group-containing olefin polymer available for various applications, as being a high molecular weight body, which has been difficult to produce, and to produce the polymer in a molecular weight range such that the polymer has good moldability.
Type:
Grant
Filed:
September 15, 2015
Date of Patent:
September 17, 2019
Assignees:
THE UNIVERSITY OF TOKYO, SHOWA DENKO K.K., JAPAN POLYETHYLENE CORPORATION
Abstract: A polyethylene for a pipe and a joint of the present invention satisfies the following characteristics (1) to (5): Characteristic (1): a melt flow rate at a temperature of 190° C. and a load of 21.6 kg (HLMFR) is 5 to 20 g/10 minutes, Characteristic (2): a density (D) is 0.954 to 0.960 g/cm3, Characteristic (3): a ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) (Mw/Mn) measured by gel permeation chromatography (GPC) is 15 to 27, Characteristic (4): a rupture time at 80° C. and 5 MPa by a full notch creep test (FNCT) is 150 hours or more, and Characteristic (5): a Charpy impact strength (CIS) measured at ?20° C. is 8.5 kJ/m2 or more.
Abstract: An object of the invention is to provide an ethylene-based polymer excellent in moldability and durability, and also excellent in the balance of stiffness and durability, and to provide a molded product of hollow plastic using the ethylene-based polymer. The ethylene-based polymer according to the invention is an ethylene-based polymer having specific characteristics and manufactured by a homopolymerization of ethylene or a copolymerization of ethylene and ?-olefin using a chromium catalyst.