Patents Assigned to JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
  • Publication number: 20240052532
    Abstract: A low-thermal-shrinkage polyester industrial yarn and preparation method thereof are provided. The low-thermal-shrinkage polyester industrial yarn is prepared by spinning and winding a modified polyester after solid-state polycondensation to increase viscosity. The preparation method of the modified polyester includes: after uniformly mixing terephthalic acid, ethylene glycol, 2,5-pyridinedicarboxylic acid and copper chloride, successively performing an esterification reaction and a polycondensation reaction to obtain the modified polyester. The polyester segments of the prepared low-thermal-shrinkage polyester industrial yarn comprises a terephthalic acid segment, an ethylene glycol segment and a 2,5-pyridinedicarboxylic acid segment, and 2,5-pyridinedicarboxylic acid segments of different polyester segments are coordinated by Cu2+. The molar ratio of the terephthalic acid segment to the 2,5-pyridinedicarboxylic acid segment is 1:(0.03-0.05).
    Type: Application
    Filed: August 25, 2021
    Publication date: February 15, 2024
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Rui CHEN, Lili WANG, Shanshui WANG, Damao YANG, Ye ZHANG, Xiaohua SUN, Fangming TANG, Tong WANG
  • Publication number: 20240052529
    Abstract: A high-strength thermal-stability polyester industrial yarn is prepared by spinning, winding and coordination treatment of a modified polyester after a solid-state polycondensation; wherein the method of coordination treatment comprises: soaking the wound fiber in an aqueous solution of a coordination agent, and the concentration of the aqueous solution of the coordination agent is 0.1-0.2 mol/L; wherein the condition of coordination treatment is 48-72 hours at 80-100° C., and the concentration of the aqueous solution of the coordination agent is 0.1-0.2 mol/L; wherein the polyester segments of the prepared high-strength thermal-stability polyester industrial yarn comprises a terephthalic acid segment, an ethylene glycol segment and a 2,6-pyridinedicarboxylic acid segment, and 2,6-pyridinedicarboxylic acid segments of different polyester segments are coordinated by Fe3+, the molar ratio of the terephthalic acid segment to the 2,6-pyridinedicarboxylic acid segment is 1:(0.03-0.05).
    Type: Application
    Filed: August 25, 2021
    Publication date: February 15, 2024
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Shanshui WANG, Fangming TANG, Lili WANG, Yiwei SHAO, Yanli ZHAO, Xiaoyu WANG, Chaoming YANG
  • Publication number: 20230392300
    Abstract: A high-strength creep-resistant polyester industrial yarn and preparation method thereof are provided. The high-strength creep-resistant polyester industrial yarn is prepared by spinning, winding and coordination treatment of a modified polyester after solid-state polycondensation to increase viscosity. The condition of coordination treatment is 60-72 hours at 80-100° C. The coordination agent is AgNO3, FeCl2, CuCl2, or NiCl2. The polyester segments of the prepared high-strength creep-resistant polyester industrial yarn includes a terephthalic acid segment, an ethylene glycol segment and a 2-(4-pyridine) terephthalic acid segment, and 2-(4-pyridine) terephthalic acid segments of different polyester segments are coordinated by metal ions (Ag+, Fe2+, Cu2+ or Ni2). The molar ratio of the terephthalic acid segment to the 2-(4-pyridine) terephthalic acid segment is 1:(0.03-0.05). The N atom on the pyridine of the 2-(4-pyridine) terephthalic acid segment is involved in coordination.
    Type: Application
    Filed: August 24, 2021
    Publication date: December 7, 2023
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Fangming TANG, Shanshui WANG, Lili WANG, Ye ZHANG, Cunhong WEI, Yumei ZHANG, Yanli ZHAO
  • Patent number: 11788212
    Abstract: A type of semi-dull polyester drawn yarns and preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with FDY technique, wherein the modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, main chain silicated diol, fluorinated dicarboxylic acid, matting agent and doped Bi2O3, in which the main chain silicated diol could be dimethylsiloxane diol, dimethyldiphenyldisiloxane glycol or tetramethyldisiloxane diol, and in which the fluorinated dicarboxylic acids could be 2,2-difluoro-1,3-malonic acid, 2,2-difluoro-1,4-succinic acid, 2,2-difluoro-1,5-glutaric acid or 2,2,3,3-tetrafluoro-1,4-succinic acid. The obtained fiber has a dye uptake of 87.5-91.8% when dyed at 120° C., and has an intrinsic viscosity drop of 18-26% when stored at 25° C. and R.H. 65% for 60 months.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: October 17, 2023
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lili Wang, Zangzang Niu, Chaoming Yang
  • Patent number: 11702768
    Abstract: A preparation method of self-crimping elastic combined filament yarns for knitting is disclosed, wherein the combined filament yarns are extruded from the same spinneret; a first fiber-forming polymer melt is divided into two ways, one is directly extruded after distribution; and the other is extruded after distribution by side-by-side composite spinning together with a second fiber-forming polymer melt; the first fiber-forming polymer and the second fiber-forming polymer are compatible or partially compatible; on the same spinneret, a ratio of the number of spinneret holes m for direct extrusion to the number of spinneret holes n for extrusion after distribution by side-by-side composite spinning is 1:(5-10); the self-crimping elastic combined filament yarns for knitting are prepared according to specific spinning processes, wherein the combined filament yarn mainly comprises a first fiber-forming polymer monofilament and a first/second fiber-forming polymer side-by-side composite monofilament; wherein the m
    Type: Grant
    Filed: June 10, 2020
    Date of Patent: July 18, 2023
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Fangming Tang, Shanshui Wang, Lixin Yin, Lili Wang
  • Patent number: 11686018
    Abstract: A degradable polyester fiber and its preparation method are disclosed. The preparation method is to cool a PET melt dispersing with doped ZrO2 powder by ring-blowing after extruded from a trilobal spinneret hole on a spinneret, and manufacture a fully drawn yarn (FDY) according to an FDY process with the PET melt, then the degradable polyester fiber is prepared after a relaxation heat treatment. The trilobal spinneret hole on the spinneret has three leaves with unequal lengths and angles, and all the trilobal spinneret holes are distributed in concentric circles, with a center line of the leaf opposite to the smallest angle in each trilobal spinneret hole passing through the center of the circle, and pointing away from the center of the circle. The process is simple, and the obtain fiber has good performances in degradation and elasticity.
    Type: Grant
    Filed: June 11, 2020
    Date of Patent: June 27, 2023
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Shanshui Wang, Hongwei Fan, Fangming Tang, Lili Wang
  • Patent number: 11639562
    Abstract: A thermal-moisture comfortable polyester FDY for summer use and a preparation method thereof are provided. The FDY is made of matting agents dispersed polyester via the steps of spinning melt metering, extruding via the compositional spinneret, cooling, oiling, drawing, heat setting and winding. The woven fabrics manufactured with the FDY possess a wicking height and an evaporation rate of larger than or equal to 135 mm and 0.22 g/h, respectively. The compositional spinneret is simultaneously provided with cruciform orifices and circular orifices, and the length ratio of cruciform orifice to circular orifice is equal to the product of their equivalent diameter ratio and a coefficient K, here equivalent diameter is the ratio of orifice cross-section area to its circumference and K ranges from 0.97 to 1.03, and the oiling involves the oiling agent containing 67.30-85.58 wt % of crown ether.
    Type: Grant
    Filed: July 27, 2018
    Date of Patent: May 2, 2023
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Shanshui Wang, Lili Wang, Lixin Yin
  • Patent number: 11629436
    Abstract: A lightweight heat-preserving fiber and a preparation method thereof are provided, wherein the fiber is prepared by measuring, composite spinneret's extruding, cooling, oiling, drawing, heat setting and winding a polyester melt. The composite spinneret has a hollow spinning hole and a circular spinning hole. The ratio of the micropore length of hollow spinning hole to circular spinning hole equals to the ratio of the equivalent diameter of hollow spinning hole to circular spinning hole multiplies the coefficient K, and the equivalent diameter is the ratio of the cross-sectional area to the circumference of the cross-section, the coefficient K ranges from 0.97 to 1.03. The oil agent contains a crown ether, and the content of the crown ether ranges from 67.30 to 85.58 wt %. The thermal conductivity of a knitted fabric having a basis weight of 100 g/m2 prepared by lightweight heat-preserving fiber is no larger than 0.150 W/m·K.
    Type: Grant
    Filed: July 27, 2018
    Date of Patent: April 18, 2023
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Shanshui Wang, Lixin Yin, Lili Wang
  • Publication number: 20230040916
    Abstract: A recycled polyester filament and preparation method therefor are disclosed. In the process of preparing a fiber from a recycled polyester according to the FDY process, the ring-blowing is used for cooling, and the distribution of spinneret holes on the spinneret is controlled to meet certain conditions, then the recycled polyester filament is obtained by relaxation heat treatment after a fully drawn yarn is produced. The spinneret holes are C-shaped spinneret holes and circular spinneret holes, the cross-section of the C-shaped spinneret hole is composed of an outer arc, an inner arc, and two line segments, and two endpoints of the outer arc are A and B respectively; wherein the certain conditions include: all the spinneret holes are distributed in concentric circles, and the C-shaped spinneret holes are located on the outermost circle, rotating at different angles and randomly distributed.
    Type: Application
    Filed: June 12, 2020
    Publication date: February 9, 2023
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei FAN, Shanshui WANG, Lili WANG, Fangming TANG
  • Publication number: 20230030865
    Abstract: A degradable polyester fiber and its preparation method are disclosed. The preparation method is to cool a PET melt dispersing with doped ZrO2 powder by ring-blowing after extruded from a trilobal spinneret hole on a spinneret, and manufacture a fully drawn yarn (FDY) according to an FDY process with the PET melt, then the degradable polyester fiber is prepared after a relaxation heat treatment. The trilobal spinneret hole on the spinneret has three leaves with unequal lengths and angles, and all the trilobal spinneret holes are distributed in concentric circles, with a center line of the leaf opposite to the smallest angle in each trilobal spinneret hole passing through the center of the circle, and pointing away from the center of the circle. The process is simple, and the obtain fiber has good performances in degradation and elasticity.
    Type: Application
    Filed: June 11, 2020
    Publication date: February 2, 2023
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Shanshui WANG, Hongwei FAN, Fangming TANG, Lili WANG
  • Publication number: 20230026102
    Abstract: A preparation method of self-crimping elastic combined filament yarns for knitting is disclosed, wherein the combined filament yarns are extruded from the same spinneret; a first fiber-forming polymer melt is divided into two ways, one is directly extruded after distribution; and the other is extruded after distribution by side-by-side composite spinning together with a second fiber-forming polymer melt; the first fiber-forming polymer and the second fiber-forming polymer are compatible or partially compatible; on the same spinneret, a ratio of the number of spinneret holes m for direct extrusion to the number of spinneret holes n for extrusion after distribution by side-by-side composite spinning is 1:(5-10); the self-crimping elastic combined filament yarns for knitting are prepared according to specific spinning processes, wherein the combined filament yarn mainly comprises a first fiber-forming polymer monofilament and a first/second fiber-forming polymer side-by-side composite monofilament; wherein the m
    Type: Application
    Filed: June 10, 2020
    Publication date: January 26, 2023
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei FAN, Fangming TANG, Shanshui WANG, Lixin YIN, Lili WANG
  • Publication number: 20230026569
    Abstract: A type of side-by-side self-crimping elastic fiber and preparation method thereof are disclosed. The preparation method includes distributing compatible or partially compatible first fiber-forming polymer melts and second fiber-forming polymer melts, then the fiber is extruded from first spinneret holes and second spinneret holes on the same spinneret. The first fiber-forming polymer melts and the second fiber-forming polymer melts flow into the first spinneret holes through first and second distribution holes, and flow into the second spinneret holes through third and fourth distribution holes, wherein the four distribution holes are cylindrical holes of equal height, the ratio of the diameter of the first distribution holes to the diameter of the second distribution holes is (1.10-1.20):1, and the ratio of the diameter of the third distribution holes to the diameter of the fourth distribution holes is 1:(1.10-1.20).
    Type: Application
    Filed: June 11, 2020
    Publication date: January 26, 2023
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei FAN, Lili WANG, Fangming TANG, Aiqi KANG, Shanshui WANG
  • Publication number: 20220356604
    Abstract: A preparation method of fibers for medical antibacterial fabric includes cooling an antibacterial polyester melt by ring-blowing after extruded from a trilobal spinneret hole on a spinneret, and manufacturing a fully drawn yarn (FDY), then performing a relaxation heat treatment to obtain the fiber. The shapes and sizes of three leaves from different trilobal spinneret holes are the same; wherein all the trilobal spinneret holes are distributed in concentric circles, and the direction of the shortest leaf in each trilobal spinneret hole is randomly distributed. The prepared fiber has a three-dimensional crimp shape and includes antibacterial polyester monofilaments with trilobal cross-section. The fiber has mechanical performance indices as a crimp shrinkage of 26-29%, a crimp stability of 78-82%, a shrinkage elongation of 55-62%, a crimp elastic recovery rate of 70-75%, a breaking strength of 2.4-2.6 cN/dtex, an elongation at break of 55.0±5.0%, and a monofilament fineness of 1.00-1.50 dtex.
    Type: Application
    Filed: June 12, 2020
    Publication date: November 10, 2022
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lixin YIN, Cunhong WEI, Chengqian ZHU, Libo JIANG
  • Patent number: 11352719
    Abstract: A type of polyester yarn for an industrial sewing thread and preparing method thereof are provided. The preparing method is composed of a viscosity enhancing by a solid state polycondensation and a melt spinning for a modified polyester, and the modified polyester is a product of esterification and polycondensation of evenly mixed terephthalic acid, ethylene glycol, tert-butyl branched dicarboxylic acid, trimethylsilyl branched diol and a doped Sb2O3 powder, wherein the tert-butyl branched dicarboxylic acid is selected from the group consisting of 5-tert-butyl-1,3-benzoic acid, 2-tert-butyl-1,6-hexanedioic acid, 3-tert-butyl-1,6-hexanedioic acid and 2,5-di-tert-butyl-1,6-hexanedioic acid. Moreover, the modified polyester is dispersed with a doped ZrO2 powder. An obtained fiber has an intrinsic viscosity drop of 23-28% when stored at 25° C. and R.H. 65% for 60 months.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: June 7, 2022
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Shanshui Wang, Lili Wang
  • Patent number: 11248087
    Abstract: A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following: The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: February 15, 2022
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lili Wang, Xiaoyu Wang, Fangming Tang
  • Publication number: 20210355609
    Abstract: A type of polyester yarn for an industrial sewing thread and preparing method thereof are provided. The preparing method is composed of a viscosity enhancing by a solid state polycondensation and a melt spinning for a modified polyester, and the modified polyester is a product of esterification and polycondensation of evenly mixed terephthalic acid, ethylene glycol, tert-butyl branched dicarboxylic acid, trimethylsilyl branched diol and a doped Sb2O3 powder, wherein the tert-butyl branched dicarboxylic acid is selected from the group consisting of 5-tert-butyl-1,3-benzoic acid, 2-tert-butyl-1,6-hexanedioic acid, 3-tert-butyl-1,6-hexanedioic acid and 2,5-di-tert-butyl-1,6-hexanedioic acid. Moreover, the modified polyester is dispersed with a doped ZrO2 powder. An obtained fiber has an intrinsic viscosity drop of 23-28% when stored at 25° C. and R.H. 65% for 60 months.
    Type: Application
    Filed: October 29, 2018
    Publication date: November 18, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei FAN, Shanshui WANG, Lili WANG
  • Patent number: 11174576
    Abstract: A type of easy-to-dye degradable polyester FDY and preparing method thereof are disclosed. The method for preparing an easy-to-dye degradable polyester FDY is to prepare a modified polyester FDY from a modified polyester melt with FDY process; wherein the material is a modified polyester; wherein the modified polyester has a molecular chain structure composed of terephthalic acid segments, ethylene glycol segments, 2,2,3,4,5,5-hexamethyl-3,4-hexanediol segments and tert-butyl branched heptanediol segments; wherein the modified polyester is dispersed by solid heteropolyacid powder calcined at a 400˜700° C. temperature. The preparing method has a simple process, modifying the polyester through solid heteropolyacid, tert-butyl branched heptanediol and 2,2,3,4,5,5-hexamethyl-3,4-hexanediol, which increases the hydrolysis rate of the polyester, improves the dyeing performance and prepares products with excellent mechanical properties.
    Type: Grant
    Filed: October 28, 2019
    Date of Patent: November 16, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Fangming Tang, Shanshui Wang
  • Patent number: 11174345
    Abstract: A type of degradable polyester fiber and preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with the fully drawn yarn (FDY) technique, and the modified polyester is composed of the terephthalic acid segments, the ethylene glycol segments, the 2,5,6,6-tetramethyl-2,5-heptanediol segments and the fluorinated dicarboxylic acid segments, wherein the fluorinated dicarboxylic acid is one selected from 2,2-difluoro-1,3-malonic acid, 2,2-difluoro-1,4-succinic acid, 2,2-difluoro-1,5-glutaric acid and 2,2,3,3-tetrafluoro-1,4-succinic acid. Moreover, the modified polyester is dispersed with the doped ZrO2 powder. The obtain fiber has an intrinsic viscosity drop of 23-28% when stored at 25° C. and R.H. 65% for 60 months. The method herein is of low cost and easy technologies, whereas the obtained fiber has a rapid natural degradation rate and a wide application prospect.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: November 16, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Yuanhua Zhang, Zhujun Ding, Lili Wang
  • Patent number: 11174575
    Abstract: A type of high-modulus-low-shrinkage activated PET industrial yarn and preparing method thereof are disclosed. The preparing method is to manufacture filament from a modified polyester, which is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol and tert-butyl branched heptanediol, through a series of processes composed of viscosity enhancing by solid state polycondensation, melting, metering, extruding, cooling, oiling, stretching, heat setting, relaxation heat-treating, oiling with activation oil, winding and pre-activation treatment. The relaxation heat-treating indicates passing the modified polyester yarns through a space with a certain temperature within 200-220° C. under a proper relaxation state; and the proper relaxation state means a 3.0-5.0% of overfeed for the winding.
    Type: Grant
    Filed: October 28, 2019
    Date of Patent: November 16, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Fangming Tang, Shanshui Wang, Damao Yang
  • Patent number: 11174346
    Abstract: A flame-retardant polyester fiber obtained by spinning flame-retardant polyester and irradiating with ultraviolet light and having a limiting oxygen index value of greater than 30. Flame retardant 2-carboxyethylphenylphosphinic acid to improve the flame retardant properties of polyester, the use of polyester containing unsaturated double bond in UV irradiation, the double bond opens to form a crosslinking point, the formation of a certain amount of the network structure improves the heat-resistant temperature of the poly-fiber and improves the anti-dripping performance of the polyester fiber.
    Type: Grant
    Filed: October 25, 2016
    Date of Patent: November 16, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lili Wang, Lixin Yin, Qianhan Liu, Feng Li