Patents Assigned to JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
  • Patent number: 11142850
    Abstract: A type of easy-to-dye porous modified polyester fibers and preparing method thereof are disclosed. The preparing method is using the modified polyester melt through a porous spinneret with FDY process; wherein the modified polyester is a product of an esterification and successive polycondensation reactions of an evenly mixed terephthalic acid, ethylene glycol, main chain silicated diol, 2,2,3,4,5,5-hexamethyl-3,4-hexanediol, and metal oxide doped Sb2O3 powder; wherein the main chain silicated diol is selected from the group consisting of dimethylsiloxane diol, dimethyldiphenyldisiloxane glycol and tetramethyldisiloxane diol. The structural formula of 2,2,3,4,5,5-hexamethyl-3,4-hexanediol is as follows: The dye uptake and the K/S value of the prepared easy-to-dye porous modified polyester fiber are high. This invention features a method with ease of application and a product with good dyeing performance and good quality.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: October 12, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Xiaohua Sun, Aiqi Kang, Lili Wang
  • Publication number: 20210309799
    Abstract: A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following: The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.
    Type: Application
    Filed: October 29, 2019
    Publication date: October 7, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lili WANG, Xiaoyu WANG, Fangming TANG
  • Publication number: 20210284792
    Abstract: A type of degradable polyester fiber and preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with the fully drawn yarn (FDY) technique, and the modified polyester is composed of the terephthalic acid segments, the ethylene glycol segments, the 2,5,6,6-tetramethyl-2,5-heptanediol segments and the fluorinated dicarboxylic acid segments, wherein the fluorinated dicarboxylic acid is one selected from 2,2-difluoro-1,3-malonic acid, 2,2-difluoro-1,4-succinic acid, 2,2-difluoro-1,5-glutaric acid and 2,2,3,3-tetrafluoro-1,4-succinic acid. Moreover, the modified polyester is dispersed with the doped ZrO2 powder. The obtain fiber has an intrinsic viscosity drop of 23-28% when stored at 25° C. and R.H. 65% for 60 months. The method herein is of low cost and easy technologies, whereas the obtained fiber has a rapid natural degradation rate and a wide application prospect.
    Type: Application
    Filed: October 29, 2019
    Publication date: September 16, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Yuanhua ZHANG, Zhujun DING, Lili WANG
  • Patent number: 11091587
    Abstract: A type of wool-like polyester filament and preparing method thereof are disclosed. The preparing method is manufacturing filament from a modified polyester through a POY process and a successive DTY processes, wherein the modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, 1,4-butanediol, fluorinated dicarboxylic acid, tert-butyl branched hexanediol and 2,5,6,6-tetramethyl-2,5-heptanediol. The obtained fiber has a dye uptake of 90.32-93.27% and a K/S value of 22.15-23.42 when dyed at 100° C., and has an intrinsic viscosity drop of 17-20% when stored at 25° C. and R.H. 65% for 60 months. This invention features a method with ease of application and a product with good dyeing and degradation performance.
    Type: Grant
    Filed: October 28, 2019
    Date of Patent: August 17, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Shanshui Wang, Lili Wang, Jiangen Shen
  • Publication number: 20210246577
    Abstract: A type of easy-to-dye porous modified polyester fibers and preparing method thereof are disclosed. The preparing method is using the modified polyester melt through a porous spinneret with FDY process; wherein the modified polyester is a product of an esterification and successive polycondensation reactions of an evenly mixed terephthalic acid, ethylene glycol, main chain silicated diol, 2,2,3,4,5,5-hexamethyl-3,4-hexanediol, and metal oxide doped Sb2O3 powder; wherein the main chain silicated diol is selected from the group consisting of dimethylsiloxane diol, dimethyldiphenyldisiloxane glycol and tetramethyldisiloxane diol. The structural formula of 2,2,3,4,5,5-hexamethyl-3,4-hexanediol is as follows: The dye uptake and the K/S value of the prepared easy-to-dye porous modified polyester fiber are high. This invention features a method with ease of application and a product with good dyeing performance and good quality.
    Type: Application
    Filed: October 29, 2019
    Publication date: August 12, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Xiaohua SUN, Aiqi KANG, Lili WANG
  • Publication number: 20210246579
    Abstract: A type of easy-to-dye degradable polyester FDY and preparing method thereof are disclosed. The method for preparing an easy-to-dye degradable polyester FDY is to prepare a modified polyester FDY from a modified polyester melt with FDY process; wherein the material is a modified polyester; wherein the modified polyester has a molecular chain structure composed of terephthalic acid segments, ethylene glycol segments, 2,2,3,4,5,5-hexamethyl-3,4-hexanediol segments and tert-butyl branched heptanediol segments; wherein the modified polyester is dispersed by solid heteropolyacid powder calcined at a 400˜700° C. temperature. The preparing method has a simple process, modifying the polyester through solid heteropolyacid, tert-butyl branched heptanediol and 2,2,3,4,5,5-hexamethyl-3,4-hexanediol, which increases the hydrolysis rate of the polyester, improves the dyeing performance and prepares products with excellent mechanical properties.
    Type: Application
    Filed: October 28, 2019
    Publication date: August 12, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei FAN, Fangming TANG, Shanshui WANG
  • Publication number: 20210230776
    Abstract: A type of high-modulus-low-shrinkage activated PET industrial yarn and preparing method thereof are disclosed. The preparing method is to manufacture filament from a modified polyester, which is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol and tert-butyl branched heptanediol, through a series of processes composed of viscosity enhancing by solid state polycondensation, melting, metering, extruding, cooling, oiling, stretching, heat setting, relaxation heat-treating, oiling with activation oil, winding and pre-activation treatment. The relaxation heat-treating indicates passing the modified polyester yarns through a space with a certain temperature within 200-220° C. under a proper relaxation state; and the proper relaxation state means a 3.0-5.0% of overfeed for the winding.
    Type: Application
    Filed: October 28, 2019
    Publication date: July 29, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Fangming TANG, Shanshui WANG, Damao YANG
  • Patent number: 11053387
    Abstract: A one-step spun composite DTY and preparation method thereof are provided. The bi-profiled fiber is manufactured with two types of modified polyester of different viscosities through the steps of melting, melt metering, composite extruding, cooling, oiling, drawing, heat setting and winding. Wherein those two modified polyesters have a molecular structure including terephthalic acid segments, ethylene glycol segments and branched diol segments, and the branched diol has a structural formula of here R1 and R2 are separately selected from the linear alkylene with 1-3 carbon atoms, R3 from the alkyl with 1-5 carbon atoms, and R4 from the alkyl with 2-5 carbon atoms. The obtained one-step spun composite DTY has an elastic shrinkage rate of no less than 35%. The method presented in this invention is involved in a simple and reasonable technological process for wide application range.
    Type: Grant
    Filed: July 27, 2018
    Date of Patent: July 6, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Guanfan Jin, Ming Chen, Huailin Ren, Yongfeng Wang, Xiangming Wang
  • Patent number: 11035056
    Abstract: A method for improving the quality of a polyester industrial yarn is provided. First, in the cooling process of preparing a polyester industrial yarn prepared by polyester spinning, the longitudinal height is kept unchanged, and the cross-sectional area of the slow cooling chamber is enlarged. The chamber maintains the surface temperature of the spinneret by means of heat preservation, and then uses an oil agent containing 67.30-85.58 wt % crown ether in the oiling process of polyester industrial yarn prepared by polyester spinning. Enlarging the cross-sectional area of the slow-cooling chamber refers to the cross section of the slow cooling chamber is changed from a circular shape to a rectangular shape while keeping the spinneret connected to the slow cooling chamber unchanged. The cleaning cycle of the spinneret is prolonged by 35-45%, the full package rate of polyester industrial yarn is larger than 99%.
    Type: Grant
    Filed: July 27, 2018
    Date of Patent: June 15, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Damao Yang, Ye Zhang, Fangming Tang, Huirong Zhao
  • Patent number: 10982044
    Abstract: A low-shrinkage polyester industrial yarn and a preparation method thereof are provided. The preparation method includes the following steps: subjecting the modified polyester to polycondensation, melting, measuring, extruding, cooling, oiling, stretching, heat setting and winding, wherein the content of the crown ether in the oil agent is 67.30-85.58 wt %. The material of the prepared low shrinkage polyester industrial yarn is a modified polyester, the molecular chain of the modified polyester includes a terephthalic acid segment, an ethylene glycol segment, and a branched diol segment, and the structural formula of the branched diol is as follows: Wherein R1 and R2 are each independently selected from a linear alkylene group having 1-3 carbon atoms, R3 is selected from an alkyl group having 1-5 carbon atoms, and R4 is selected from an alkyl group consisting of 2-5 carbon atoms.
    Type: Grant
    Filed: July 27, 2018
    Date of Patent: April 20, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Yiwei Shao, Lixin Yin, Fangming Tang
  • Patent number: 10968538
    Abstract: A type of fully dull polyester drawn yarns and a preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with the fully drawn yarn (FDY) technique, and the modified polyester is a product of an esterification and successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, 2,5,6,6-tetramethyl-2,5-heptanediol, a fluorinated dicarboxylic acid, a matting agent, a calcined multiphase solid acid base powder and a doped Bi2O3 powder. The obtained fiber has an intrinsic viscosity drop of 18-26% when stored at 25° C. and R.H. 65% for 60 months. The method of improving the degradation performance of polyester fiber through the incorporation of 2,5,6,6-tetramethyl-2,5-heptanediol, the fluorinated dicarboxylic acid, the doped Bi2O3 powder and the calcined multiphase solid acid base powder is easy to operate.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: April 6, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD
    Inventors: Lixin Yin, Feng Chen, Xiaohua Sun
  • Patent number: 10961641
    Abstract: A type of feather-like polyester fiber and a preparing method thereof are disclosed. The preparing method is to manufacture filament from a modified polyester through a POY process with a four-fold flat spinneret and a successive DTY processes, wherein said modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, main-chain silicated diol and fluorinated dicarboxylic acid, and the spinneret is the one set with four-fold flat shaped orifices. The obtained fiber has a dye uptake of 89.6-93.7% when dyed at 130° C., and has an intrinsic viscosity drop of 13-20% when stored at 25° C. and R.H. 65% for 60 months. This invention is simple to apply and features a product with good dyeing and degradation performance.
    Type: Grant
    Filed: October 28, 2019
    Date of Patent: March 30, 2021
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Lili Wang, Jiangen Shen
  • Publication number: 20210087716
    Abstract: A type of fully dull polyester drawn yarns and a preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with the fully drawn yarn (FDY) technique, and the modified polyester is a product of an esterification and successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, 2,5,6,6-tetramethyl-2,5-heptanediol, a fluorinated dicarboxylic acid, a matting agent, a calcined multiphase solid acid base powder and a doped Bi2O3 powder. The obtained fiber has an intrinsic viscosity drop of 18-26% when stored at 25° C. and R.H. 65% for 60 months. The method of improving the degradation performance of polyester fiber through the incorporation of 2,5,6,6-tetramethyl-2,5-heptanediol, the fluorinated dicarboxylic acid, the doped Bi2O3 powder and the calcined multiphase solid acid base powder is easy to operate.
    Type: Application
    Filed: October 29, 2019
    Publication date: March 25, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lixin YIN, Feng CHEN, Xiaohua SUN
  • Publication number: 20210054534
    Abstract: A thermal-moisture comfortable polyester FDY for summer use and a preparation method thereof are provided. The FDY is made of matting agents dispersed polyester via the steps of spinning melt metering, extruding via the compositional spinneret, cooling, oiling, drawing, heat setting and winding. The woven fabrics manufactured with the FDY possess a wicking height and an evaporation rate of larger than or equal to 135 mm and 0.22 g/h, respectively. The compositional spinneret is simultaneously provided with cruciform orifices and circular orifices, and the length ratio of cruciform orifice to circular orifice is equal to the product of their equivalent diameter ratio and a coefficient K, here equivalent diameter is the ratio of orifice cross-section area to its circumference and K ranges from 0.97 to 1.03, and the oiling involves the oiling agent containing 67.30-85.58 wt % of crown ether.
    Type: Application
    Filed: July 27, 2018
    Publication date: February 25, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei FAN, Shanshui WANG, Lili WANG, Lixin YIN
  • Publication number: 20210054535
    Abstract: A type of feather-like polyester fiber and a preparing method thereof are disclosed. The preparing method is to manufacture filament from a modified polyester through a POY process with a four-fold flat spinneret and a successive DTY processes, wherein said modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, main-chain silicated diol and fluorinated dicarboxylic acid, and the spinneret is the one set with four-fold flat shaped orifices. The obtained fiber has a dye uptake of 89.6-93.7% when dyed at 130° C., and has an intrinsic viscosity drop of 13-20% when stored at 25° C. and R.H. 65% for 60 months. This invention is simple to apply and features a product with good dyeing and degradation performance.
    Type: Application
    Filed: October 28, 2019
    Publication date: February 25, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei FAN, Lili WANG, Jiangen SHEN
  • Publication number: 20210017673
    Abstract: A type of semi-dull polyester drawn yarns and preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with FDY technique, wherein the modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, main chain silicated diol, fluorinated dicarboxylic acid, matting agent and doped Bi2O3, in which the main chain silicated diol could be dimethylsiloxane diol, dimethyldiphenyldisiloxane glycol or tetramethyldisiloxane diol, and in which the fluorinated dicarboxylic acids could be 2,2-difluoro-1,3-malonic acid, 2,2-difluoro-1,4-succinic acid, 2,2-difluoro-1,5-glutaric acid or 2,2,3,3-tetrafluoro-1,4-succinic acid. The obtained fiber has a dye uptake of 87.5-91.8% when dyed at 120° C., and has an intrinsic viscosity drop of 18-26% when stored at 25° C. and R.H. 65% for 60 months.
    Type: Application
    Filed: October 29, 2019
    Publication date: January 21, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Lili WANG, Zangzang NIU, Chaoming YANG
  • Publication number: 20210009755
    Abstract: A type of wool-like polyester filament and preparing method thereof are disclosed. The preparing method is manufacturing filament from a modified polyester through a POY process and a successive DTY processes, wherein the modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, 1,4-butanediol, fluorinated dicarboxylic acid, tert-butyl branched hexanediol and 2,5,6,6-tetramethyl-2,5-heptanediol. The obtained fiber has a dye uptake of 90.32-93.27% and a K/S value of 22.15-23.42 when dyed at 100° C., and has an intrinsic viscosity drop of 17-20% when stored at 25° C. and R.H. 65% for 60 months. This invention features a method with ease of application and a product with good dyeing and degradation performance.
    Type: Application
    Filed: October 28, 2019
    Publication date: January 14, 2021
    Applicant: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Shanshui WANG, Lili WANG, Jiangen SHEN
  • Patent number: 10822451
    Abstract: A bi-profiled fiber and preparing method thereof are provided. The bi-profiled fiber is manufactured through the steps of spinning melt metering, extruding via the composite spinneret, cooling, oiling, drawing, heat setting and winding, finally containing both double-cross monofilaments and circular monofilaments simultaneously. The bi-profiled fiber is made of the modified polyester, and the modified polyester is dispersed by matte agent and is composed of terephthalic acid segments, ethylene glycol segments and branched diol segments, and the branched diol segment has a structural formula of where R1 and R2 are separately selected from the linear alkylene with 1-3 carbon atoms, R3 from the alkyl with 1-5 carbon atoms, and R4 from the alkyl with 2-5 carbon atoms. The matte agents is a mixture of amorphous titanium dioxide and amorphous silicon dioxide, or a mixture of calcium carbonate and amorphous silicon dioxide.
    Type: Grant
    Filed: July 27, 2018
    Date of Patent: November 3, 2020
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Fangming Tang, Lixin Yin, Shanshui Wang
  • Patent number: 10815333
    Abstract: A high-modulus low-shrinkage polyester industrial yarn obtained by subjecting a polyester to dissolution, washing and solid state polycondensation followed by spinning. The high-modulus low-shrinkage polyester industrial yarn has a dry heat shrinkage rate of 2.0±0.25% under test conditions of 177° C.×10 min×0.05 cN/dtex. The average value of the crystal volume Vc of the high-modulus low-shrinkage polyester industrial yarn is larger than 230 nm3. The high-modulus low-shrinkage polyester industrial yarn has a fiber modulus of ?100 cN/dtex. The polycondensation catalyst consists of magnesium ethylene glycol and antimony ethylene glycol, which has a small thermal degradation coefficient.
    Type: Grant
    Filed: June 12, 2016
    Date of Patent: October 27, 2020
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Wengang Li, Yanfang Wang, Lili Wang, Damao Yang, Fangming Tang, Lixin Yin, Guangkun Song
  • Patent number: 10801132
    Abstract: A high uniformity coloured polyester industrial yarn and preparation method. The raw material of the high-uniformity coloured polyester industrial yard is the modified polyester composed of terephthalic acid segment, an ethylene glycol segment and a branched diol. The high-uniformity coloured polyester industrial yarn is prepared by esterification reaction of terephthalic acid with a branched diol using concentrated sulfuric acid as catalyst to obtain terephthalic acid glycol ester. Terephthalic acid and ethylene glycol are formulated to carry out esterification reaction to obtain ethylene terephthalate. Finally, stir and mix the two materials and carry out the polycondensation reaction in the low vacuum stage and the high vacuum stage under the action of the catalyst and the stabilizer to obtain modified polyester. Measure the modified polyester and add black masterbatch.
    Type: Grant
    Filed: June 26, 2017
    Date of Patent: October 13, 2020
    Assignee: JIANGSU HENGLI CHEMICAL FIBRE CO., LTD.
    Inventors: Hongwei Fan, Lili Wang, Xiaobing Fan, Damao Yang, Guangkun Song, Huirong Zhao, Shanshui Wang