Patents Assigned to Kawasaki Kasei Chemicals Ltd.
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Patent number: 6264819Abstract: It is an object of the present invention to produce a cooking liquor containing polysulfide sulfur at a high concentration from white liquor in a pulp production process with a high selectivity at a low electric power with very little production of thiosulfate ions as by-product. The present invention provides a method for producing polysulfides, which comprises introducing a solution containing sulfide ions into an anode compartment of an electrolytic cell comprising the anode compartment provided with a porous anode, a cathode compartment provided with a cathode and a diaphragm partitioning the anode compartment and the cathode compartment, for electrolytic oxidation to obtain polysulfide ions, wherein at least the surface of said anode is made of nickel, and the porous anode has a physically continuous three-dimensional network structure.Type: GrantFiled: January 28, 2000Date of Patent: July 24, 2001Assignees: Asahi Glass Company Ltd., Kawasaki Kasei Chemicals Ltd., Nippon Paper Industries Co., Ltd.Inventors: Tatsuya Andoh, Junji Tanaka, Tetsuji Shimohira
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Patent number: 6106589Abstract: An agent for treating metal ions in an aqueous solution, which comprises an anthrahydroquinone compound and a metal supported on a carbonaceous carrier.Type: GrantFiled: August 12, 1997Date of Patent: August 22, 2000Assignees: Kawasaki Kasei Chemicals Ltd., N.E. Chemcat CorporationInventors: Suehide Hirata, Koji Kusabe, Hiroshi Nakamura, Kikuo Fujiwara
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Patent number: 5972197Abstract: A method for producing polysulfides, which comprises introducing a solution containing sulfide ions into an anode compartment of an electrolytic cell comprising the anode compartment provided with a porous anode, of which at least the surface is made of carbon, a cathode compartment provided with a cathode, and a diaphragm partitioning the anode compartment and the cathode compartment, and carrying out electrolytic oxidation to obtain polysulfide ions.Type: GrantFiled: December 23, 1997Date of Patent: October 26, 1999Assignees: Asahi Glass Company Ltd., Kawasaki Kasei Chemicals Ltd.Inventors: Tatsuya Andoh, Tetsuji Shimohira, Eiji Endoh
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Patent number: 5834608Abstract: Copper phthalocyanine is prepared by heating and reacting phthalic acid or a derivative thereof, urea or a derivative thereof and copper or a copper compound in the presence of molybdenum or a molybdenum compound as a catalyst and sulfur.Type: GrantFiled: May 30, 1996Date of Patent: November 10, 1998Assignee: Kawasaki Kasei Chemicals Ltd.Inventor: Kazuhiro Maruyama
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Patent number: 5750743Abstract: A method for preparing a solution of an alkali salt of anthrahydroquinone, which comprises reacting a solution of an alkali salt of 1,4-dihydro-9,10-dihydroxyanthracene with anthraquinone in the presence of an alkali.Type: GrantFiled: December 12, 1996Date of Patent: May 12, 1998Assignee: Kawasaki Kasei Chemicals Ltd.Inventor: Hiroyuki Suganuma
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Patent number: 5702615Abstract: A method for the treatment of waste water, which comprises treating waste water containing at least a sulfide-type malodorous substance, in the presence of a transition metal compound and hydrogen peroxide or a hydrogen peroxide-forming compound, wherein at least an iron family element compound and a vanadium family element compound are used as the transition metal compound.Type: GrantFiled: June 24, 1996Date of Patent: December 30, 1997Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Shigeaki Numata, Souichi Shibuya
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Patent number: 5496939Abstract: A method for producing copper phthalocyanine, which comprises heating and reacting phthalic acid or a phthalic acid derivative, urea or a urea derivative, and a copper compound, using molybdenum or a molybdenum compound as a catalyst, in the presence or absence of an inert organic solvent, wherein at least one compound selected from the group consisting of an aromatic dithiol compound of the following formula (I), a saturated aliphatic dithiol compound of the following formula (II), and their precursors, or at least one compound selected from the group consisting of a ruthenium compound and an osmium compound, is added to the reaction system: ##STR1##C.sub.m H.sub.2m-x R.sub.x (SH).sub.2 (II)wherein ring A in the formula (I) is a 6-membered single carbon ring or polycyclic condensed carbon ring aromatic compound, R for R.sub.n in the formula (I) or for R.sub.Type: GrantFiled: March 8, 1995Date of Patent: March 5, 1996Assignee: Kawasaki Kasei Chemicals Ltd.Inventor: Kazuhiro Maruyama
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Patent number: 5474593Abstract: An agent for treating metal ions in an aqueous solution, comprising a solid porous carrier and, supported thereon, an organic reagent (hereinafter referred to as a "redox reagent") which is capable of converting metal ions (inclusive of metal complex ions) contained in an aqueous solution to zero valent metal or monovalent metal ions by a redox reaction and which is capable of carrying out oxidation-reduction reversibly.Type: GrantFiled: September 8, 1994Date of Patent: December 12, 1995Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Tatsuya Sakurai, Hiroshi Fujimura, Koji Kusabe, Keishiro Hata
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Patent number: 5225578Abstract: A 2-(1-alkylaminoalkyl)-3-hydroxy-1,4-naphthoquinone of the formula: ##STR1## wherein R.sup.1 is an alkyl group or a cycloalkyl group, and R.sup.2 is an alkyl group having at least 2 carbon atoms.Type: GrantFiled: February 18, 1992Date of Patent: July 6, 1993Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Hiroyuki Suganuma, Hiroshi Fujimura
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Patent number: 5153314Abstract: A process for producing a copper phthalocyanine compound, which comprises heating and reacting phthalic acid or a phthalic acid derivative, urea or a urea derivative and cuprous chloride in the presence of a catalyst in an inert organic solvent, wherein the cuprous chloride is used in an amount of from 95 to 99% of the stoichiometric amount relative to the phthalic acid or the phthalic acid derivative.Type: GrantFiled: October 31, 1990Date of Patent: October 6, 1992Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Tomio Segawa, Kazuhiro Maruyama, Tadashi Ninomiya, Motokazu Suyama
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Patent number: 5153339Abstract: Naphthoquinone having a purity of higher than 95% is separated from an aqueous slurry of naphthoquinone and phthalic acid prepared by contacting, with an aqueous medium, a reaction mixture gas containing naphthoquinone and phthalic anhydride formed by a catalytic vapor phase oxidation of naphthalene. An extraction of naphthoquinone is carried out with a chain or cyclic saturated hydrocarbon at 60.degree. to 110.degree. C. under the condition adjusting pH to 1.2 to 5 and substantially dissolving phthalic acid in the aqueous phase and leaving resinous materials as a bottom.Type: GrantFiled: June 25, 1982Date of Patent: October 6, 1992Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Ryo Matsuura, Tatsuyoshi Komatsu, Kenji Usui, Toru Sato
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Patent number: 4980489Abstract: A 2-(1-alkylaminoalkyl)-3-hydroxy-1,4-naphthoquinone of the formula: ##STR1## wherein R.sup.1 is an alkyl group or a cycloalkyl group, and R.sup.2 is an alkyl group having at least 2 carbon atoms.The compounds are used in the preparation of a 2-(1-alkenyl)-3-hydroxy-1,4-naphthoquinone having insecticidal and fungicidal activity and a 2-alkyl-3-acyloxy-1,4-naphthoquinone having insecticidal and fungicidal activity and a 2-alkyl-3-acyloxy-1,4-naphthoquinone having miticidal activity.Type: GrantFiled: February 15, 1989Date of Patent: December 25, 1990Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Hiroyuki Suganuma, Hiroshi Fujimura
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Patent number: 4906747Abstract: In a process for producing a metal phthalocyanine and/or its derivative by heating phthalic anhydride and/or its derivative, urea and a metal compound in an organic solvent in the presence of a catalyst, or by heating phthalodinitrile and a metal or a metal compound in an organic solvent, the improvement wherein the reaction for the production of the metal phthalocyanine and/or its derivative is conducted by an addition of cyanuric acid and/or its derivative.Type: GrantFiled: December 15, 1988Date of Patent: March 6, 1990Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Tomio Segawa, Kazuhiro Maruyama, Tadashi Ninomiya, Motokazu Suyama
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Patent number: 4840932Abstract: A process for producing 1,4-naphthoquinone by oxidizing naphthalene with molecular oxygen in a vapor phase in the presence of a catalyst. The catalyst is made of a mixture of a carrier and fusible catalytic components including vanadium oxide and alkali metal sulfate and pyrosulfate, and has a molded configuration having one or more through-holes.Type: GrantFiled: March 16, 1988Date of Patent: June 20, 1989Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Ryo Matsuura, Shigeyuki Yoshimura, Yasuo Asanuma, Katsuaki Nasu, Haruo Yoshizumi, Kazumi Tsujimoto, Toshiyuki Kimura
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Patent number: 4795604Abstract: A method for molding 1,4,4a,9a-tetrahydroanthraquinone by cooling and solidifying a melt of 1,4,4a,9a-tetrahydroanthraquinone, which comprises contacting the melt with a cooling surface of a temperature of from about 50.degree. to about 80.degree. C. for solidification, and peeling off the solidified product.Type: GrantFiled: June 10, 1987Date of Patent: January 3, 1989Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Katsumi Matsuzaki, Kenji Usui, Seishi Ikemoto
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Patent number: 4561935Abstract: A process for removing an anthraquinone type scale comprises condensing a steam evaporated from a black liquor obtained by separating pulp from a digested mixture of lignocelluloses containing an anthraquinone type digesting assistant; and contacting a heated aqueous solution of a base in the presence or absence of a reducing agent or an alkali resistant surfactant with a wall of a condenser of an evaporator on which said anthraquinone type scale is adhered.Type: GrantFiled: July 18, 1984Date of Patent: December 31, 1985Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Kazuaki Sakai, Tuneyasu Sato, Kazuhiko Chiba
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Patent number: 4536337Abstract: A process for preparing a quinone, which comprises reacting a polynuclear aromatic hydrocarbon and a ceric salt in an aqueous acid solution in the presence of an organic solvent selected from the group consisting of chlorobenzene and an alkylbenzene represented by the general formula: ##STR1## where each of R.sub.1, R.sub.2 and R.sub.3 is an alkyl group and the total carbon number of the alkyl groups is from 3 to 6.Type: GrantFiled: April 4, 1984Date of Patent: August 20, 1985Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Tatsuyoshi Komatsu, Shigeaki Numata, Toshihiko Sumino, Katsumi Matsuzaki, Masao Narita, Katsuhiko Hioki
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Patent number: 4530745Abstract: A method for electrolyzing cerous sulfate in the electrolytic oxidation of cerous sulfate to ceric sulfate in an aqueous sulfuric acid solution, characterized in that the concentration of the cerous sulfate in the electrolyte to be supplied to the electrolytic cell is maintained, by the presence of ceric sulfate, at a level of at least the saturated concentration of cerous sulfate in the aqueous sulfuric acid solution (exclusive of the cerous sulfate and ceric sulfate) at the initial sulfuric acid concentration and at the temperature of electrolysis, and at most the saturated concentration of cerous sulfate in the presence of the ceric sulfate in the aqueous sulfuric acid solution at the initial sulfuric acid concentration and at the temperature of electrolysis, and the concentration of the ceric sulfate in the electrolyte is maintained at a level of at most the saturated concentration of ceric sulfate in the aqueous sulfuric acid solution at the initial sulfuric acid concentration and at the temperature of eType: GrantFiled: June 13, 1984Date of Patent: July 23, 1985Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Tatsuyoshi Komatsu, Shigeaki Numata, Katsuhiko Hioki, Toshihiko Sumino
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Patent number: 4481073Abstract: A process for removing an anthraquinone type scale comprises condensing a steam evaporated from a black liquor obtained by separating pulp from a digested mixture of lignocelluloses containing an anthraquinone type digesting assistant; and contacting a heated aqueous solution of a base in the presence or absence of a reducing agent or an alkali resistant surfactant with a wall of a condenser of an evaporator on which said anthraquinone type scale is adhered.Type: GrantFiled: November 19, 1981Date of Patent: November 6, 1984Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Kazuaki Sakai, Tuneyasu Sato, Kazuhiko Chiba
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Patent number: 4467112Abstract: p-n-Alkylbenzoic acids having high purity without containing isomers are important as intermediates for liquid crystals. The p-n-alkylbenzoic acid is produced by reacting a p-formylbenzoic acid or its ester with a ketone having the formula ##STR1## wherein R represents a C.sub.1 -C.sub.18 n-alkyl or n-alkenyl group in the presence of a basic catalyst to obtain an unsaturated ketone compound having the formula ##STR2## wherein R is defined above and X represents hydrogen atom or a C.sub.1 -C.sub.Type: GrantFiled: January 16, 1980Date of Patent: August 21, 1984Assignee: Kawasaki Kasei Chemicals Ltd.Inventors: Ryo Matsuura, Kazuya Nagaoka, Kouji Kusabe, Shuichi Nakatani