Patents Assigned to Kemira
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Patent number: 12338579Abstract: The invention relates to a composition and method for manufacture of paper, board, tissue or the like. The composition comprises an amphoteric polymer component, which has a weight average molecular weight of at least 600 000 g/mol, preferably at least 1 000 000 g/mol, more preferably at least 2 000 000 g/mol, and at least one synthetic cationic polymer component, which is a copolymer of a polyamidoamine and has a weight average molecular weight ?550 000 g/mol, preferably ?500 000 g/mol, more preferably ?400 000 g/mol and dispersity index more than 15, preferably more than 20, more preferably more than 25.Type: GrantFiled: March 4, 2021Date of Patent: June 24, 2025Assignee: Kemira OyjInventors: Kimmo Strengell, Asko Karppi
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Patent number: 12332612Abstract: The invention provides a way to monitor a process (1). The invention utilizes explanation values. A ML model of the process is created. The ML model utilizes measurements from the process as inputs to the ML model and forms model outputs. The inputs are classified to groups in the. The explanation values are calculated for each input indicating contribution of the input to the model output/s, and a sum of the explanation values for each group are calculated. The calculated sums are monitored, each sum indicating status of the group in question.Type: GrantFiled: October 13, 2020Date of Patent: June 17, 2025Assignee: KEMIRA OYJInventors: Iiris Joensuu, Marjatta Piironen, Torsten Haverinen-Nielsen, Vesa-Matti Tikkala
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Patent number: 12332174Abstract: In a starch concentration measurement, a liquid sample is conducted from a liquid sample such as pulp suspension or filtrate of a paper, board or tissue process. An iodine solution is added to the sample, and a light absorbance or transmittance of the sample is measured at a wavelength longer than about 650 nm, for example longer than about 700 nm. The measured absorbance or transmittance of the sample is converted into the starch concentration of the sample by a predefined correlation between a starch concentration and a light absorbance or transmittance.Type: GrantFiled: March 24, 2017Date of Patent: June 17, 2025Assignee: KEMIRA OYJInventors: Lari Vähäsalo, Marjatta Piironen, Iiris Joensuu
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Patent number: 12320071Abstract: The invention relates to a composition for use in a manufacture of paper, board or the like. The composition comprises a mixture of cationic starch having amylopectin content of at least 85%, and an amphoteric polymeric structure comprising structural units originating from non-ionic monomers, preferably (meth)acrylamide, anionic groups and cationic groups, the polymeric structure comprising cationic groups at least 0.2 mol-%.Type: GrantFiled: December 18, 2020Date of Patent: June 3, 2025Assignee: Kemira OyjInventors: Matti Hietaniemi, Asko Karppi
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Patent number: 12297597Abstract: The present invention relates to a microfibrillated cellulose composition comprising microfibrillated cellulose originating from agricultural biomass, comprising: ?30 wt % cellulose, 1-15 wt % pectin, 8-25 wt % hemicellulose, 0-12 wt %, lignin, 0-15 wt % ash, and 0-8 wt % protein, based on dry solids content of said microfibrillated cellulose; and a biocide composition comprising at least two biocidal components, wherein the at least two biocidal components are selected from the groups of biocidal components consisting of: Group I: compounds with activated halogen atoms, Group II: heterocyclic N—S compounds, Group III: aldehydes, and Group IV: surface active biocidal compounds selected from the group consisting of quaternary ammonium compounds, long-chain alkylamines, guanidines and biguanidines, and any combination thereof, and the at least two biocidal components are selected from at least two different groups.Type: GrantFiled: July 19, 2019Date of Patent: May 13, 2025Assignee: KEMIRA OYJInventors: Kaisa Karisalmi, Jaakko Ekman, Marko Kolari, Satu Ikavalko, Boris Dossman
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Patent number: 12281032Abstract: The present invention relates to a method of evaluating and optionally selecting a suitable chemistry for removal of microplastics in a liquid matrix, said method comprising using at least one coagulant and/or flocculant and measuring fluorescence intensity and light scattering intensity of any particles in a sample volume of clarified liquid matrix by an optical measurement.Type: GrantFiled: February 18, 2020Date of Patent: April 22, 2025Assignee: KEMIRA OYJInventors: Outi Gronfors, Mehrdad Hesampour, Katriina Rajala, Lenita Lindberg
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Patent number: 12215463Abstract: The present invention provides a process for producing paper or board, comprising slushing a stock of dried fibres in a slushing system comprising a pulper, and/or feeding a stock of never-dried fibres in a fiber line of an integrated paper mill; deflaking and/or refining the stock in a deflaker and/or a refiner, optionally diluting the deflaked and/or refined stock, directing the deflaked and/or refined stock to a headbox, forming a web, and drying the web, wherein a polymeric paper making additive is added to one or more of the stocks of dried fibres and never-dried fibres before deflaking and/or refining of the stock. The present invention further provides paper and board with improved properties.Type: GrantFiled: May 22, 2019Date of Patent: February 4, 2025Assignee: Kemira OyjInventors: Diego Salas, Jinho Lee, Jan-Luiken Hemmes
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Patent number: 12202756Abstract: In a water treatment system, a pretreatment chemical is added to water stream in a pretreatment process including a coagulation, flocculation and separation to reduce amount of dissolved and/or particulate matter in the water stream. Hydrophobic conditions in the water stream are monitored upstream or downstream from adding the pretreatment chemicals. Dosing of the pretreatment chemical to the water stream is controlled based on the monitored hydrophobic conditions. Thereby a membrane fouling in subsequent membrane filtration stage can be minimized.Type: GrantFiled: December 4, 2023Date of Patent: January 21, 2025Assignee: KEMIRA OYJInventors: Mehrdad Hesampour, Roderick Abinet, Marjatta Piironen, Eija Korte, Iiris Joensuu
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Patent number: 12174612Abstract: Estimating or predicting runnability or end product quality risk level for a pulp or papermaking process is disclosed. The method includes measuring hydrophobicity values of samples originating from a same aqueous process stream. A hydrophobicity measurement signal is produced of measured hydrophobicity values as a function of time. A risk level is calculated for the process. At least one mathematical index is calculated based on the hydrophobicity measurement signal, and optionally based on the amount of particles in the sample, other property of the aqueous stream and/or production data. The mathematical index and optionally the amount of the particles, other property, and/or production data is used as a risk indicator input in the calculation. Based on the risk level calculated for the pulp or papermaking process, the runnability and/or end product quality risk level for the pulp or papermaking process is indicated.Type: GrantFiled: June 17, 2020Date of Patent: December 24, 2024Assignee: Kemira OyjInventors: Iiris Joensuu, Marjatta Piironen
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Patent number: 12172913Abstract: A method for removing biologically recalcitrant soluble organic compounds from wastewater simultaneously in an activated sludge process comprising an aeration tank and a solid-liquid separation unit, in which method at least one Al and/or Fe based inorganic metal coagulant is added to the wastewater in the activated sludge process and/or prior to conveying wastewater to an activated sludge process.Type: GrantFiled: June 10, 2020Date of Patent: December 24, 2024Assignee: Kemira OyjInventors: Göran Bäckman, Sakari Halttunen, Pascal Morin, Marina Shestakova
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Patent number: 12163289Abstract: A coating structure for a sheet-like substrate is disclosed including cellulosic fibres and a sheet-like product. The structure includes at least one pre-coat layer and a top coat layer, where the pre-coat layer(s) and the top coat layer include 10-90 weight-% of a styrene (meth)acrylate copolymer which is polymerised in the presence of a stabiliser, and which has a glass transition temperature Tg?20° C., preferably ?15° C., more preferably ?13° C. Furthermore, the pre-coat layer(s) includes a polysaccharide, such as starch, and the top coat layer includes 5-60 weight-% of at least one water-soluble coating binder, which is selected from polysaccharides and polyvinyl alcohols, as well as at most 5.0 weight-% of a cross-linker, which reacts with —OH or —COOH groups.Type: GrantFiled: June 19, 2019Date of Patent: December 10, 2024Assignee: Kemira OyjInventors: Tarja Turkki, Sami Puttonen, Helena Peuranen, Mari Ojanen, Erland Hermansson, Anneli Lepo
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Patent number: 12114659Abstract: The invention relates to a method for controlling of a biofilm, for removing a formed biofilm and/or for controlling a growth of microorganisms, preferably bacteria, in an aqueous environment of an industrial manufacturing process comprising cellulosic fibre material. In the method a composition comprising a compound selected from a group consisting of 3-[(4-methylphenyl)sulphonyl]-2-propenenitrile and 4-amino-N-2-thiazolyl-benzenesulphonamide is administered to the aqueous environment of the process.Type: GrantFiled: July 26, 2022Date of Patent: October 15, 2024Assignees: Kemira Oyj, University of CopenhagenInventors: Jaakko Simell, Marko Kolari, Michael Givskov, Tim Tolker-Nielsen, Morten Levin Rybtke, Jens Bo Andersen
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Patent number: 12116294Abstract: A treatment system for removing dissolved organic compounds from wastewater, which comprises a water-soluble cationic polymer, and wood-based organic material having an average particle size <10 mm. The invention relates also use of said treatment system for COD removal in the treatment of wastewaters, and a method for removing dissolved organic compounds from wastewater.Type: GrantFiled: June 12, 2020Date of Patent: October 15, 2024Assignee: Kemira OyjInventors: Sakari Halttunen, Matias Penttinen, Jonni Ahlgren, Susann Härkönen, Marina Shestakova
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Patent number: 12071399Abstract: The present invention relates to a process for the preparation of arylsulfonylpro-penenitriles. The reaction starting from arylsulfonyl halides is catalyzed by a cat-alyst compound comprising a transition metal. The process is scalable, environ-mentally benign and provides the product in good yield.Type: GrantFiled: November 4, 2019Date of Patent: August 27, 2024Assignee: Kemira OyjInventors: Jaakko Hiltunen, Petteri Suominen, Ivan Ogibalov, Ain Uustare
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Patent number: 12072279Abstract: A method to determine vapor phase corrosion load in paper and board manufacturing system is disclosed. The method allows optimizing oxidative biocide content in aqueous solutions, suspensions and slurries in the paper and board manufacturing system. The method is based on determination of redox values (rH) of the system during determined time period. A correlation between rH values exceeding a predetermined rH threshold values and corrosion load provides an estimate of increased or decreased corrosion load and allows timely changes to biocide dosage.Type: GrantFiled: November 27, 2019Date of Patent: August 27, 2024Assignee: Kemira OyjInventors: Marko Kolari, Iiris Joensuu
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Patent number: 12043559Abstract: The invention concerns an online method and system for monitoring properties of an aqueous stream of an industrial process. The method comprises providing an initial aqueous stream originating from said process, the aqueous stream containing solid matter exhibiting a first settling behavior; adding modifying agent to the initial aqueous stream at an addition rate sufficient to provide a modified aqueous stream containing solid matter exhibiting a second settling behavior different from the first settling behavior; conducting a sample of the initial aqueous stream or modified aqueous stream, any combination stream comprising the modified aqueous stream or any substream of the modified aqueous stream batchwise from a sampling point to a settling vessel having a volume; and measuring the settling behavior of the solid matter in the sample locally in the settling vessel as a function of time.Type: GrantFiled: July 19, 2011Date of Patent: July 23, 2024Assignee: KEMIRA OYJInventors: Iiris Joensuu, Marjatta Piironen, Eija Saari, Jukka-Pekka Sirviö, Seppo Tuomivaara
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Patent number: 12044607Abstract: A sample of an aqueous stream is conducted to an optical measurement device. A hydrophobic dye is added. The sample is fractionated into fractions according to particle size or mass. Fluorescence intensity values and light scattering intensity values for the fractions are measured. Fluorescence intensity values of the fractions are added together thus obtaining a sum of the fluorescence intensity values. Light scattering intensity values of the fractions are added together, thus obtaining a sum of the light scattering intensity values. A hydro-phobicity density of the particles in the sample, is calculated by dividing the sum of the fluorescence intensity values with the sum of the light scattering intensity values. A concentration of hydrophobic contaminants in the aqueous stream is monitored and controlled based on the calculated hydrophobicity density of the particles in the sample.Type: GrantFiled: December 20, 2019Date of Patent: July 23, 2024Assignee: KEMIRA OYJInventors: Iiris Joensuu, Marjatta Piironen, Andy Bergeron, Travis Bjerketvedt
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Patent number: 12031274Abstract: A method for preparation of a starch-promoted alkyl ketene dimer (AKD) sizing emulsion is provided. The inventive method comprises adding a sizing promoter comprising high-charge cationic starch and polyaluminum chloride (PAC) to a stabilized AKD emulsion and further wherein addition of said sizing promoter comprising high-charge cationic starch and PAC is effected at ambient temperature, after emulsification, stabilization, and homogenization of said stabilized AKD emulsion; and prior to addition of the starch-promoted AKD sizing emulsion to papermaking furnish, pulp, or fiber stock.Type: GrantFiled: December 30, 2021Date of Patent: July 9, 2024Assignee: Kemira OyjInventors: Jennifer Riser, Kirsi Terava, Timo Valkealaakso, Jaakko Hiltunen
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Patent number: 11976418Abstract: The present invention provides a novel method and composition for enhancing the efficiency of starch adsorption (i.e., starch trapping) from starch-containing furnishes comprising high content of recycled fibers for use in paper making processes such as pulp, paper, or board production. A novel polymer coagulation system is disclosed in which two quick inversion cationic emulsion polymers (starch trapping polymers A and B) are co-mixed at optimal blend ratios to meet specific recycled fiber and process water requirements for different recycled fiber plants and added to furnishes prior to formation of paper or board in a paper machine. Co-mixed solutions of starch trapping polymers A and B provide synergistic enhancements in (i) starch trapping efficiency and (ii) starch retention in the produced paper or board over equivalent dosage levels of singly administered polymer A, polymer B, or conventional starch trapping products, without over-flocculation or formation of stickies.Type: GrantFiled: October 12, 2021Date of Patent: May 7, 2024Assignee: KEMIRA OYJInventors: Yuping Luo, Jennifer Riser
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Patent number: 11959018Abstract: Liquid polymer and inverse emulsion compositions comprising: one or more hydrophobic liquids having a boiling point at least about 100° C.; one or more acrylamide-(co)polymers; one or more emulsifier surfactants; one or more inverting surfactants; and one or more poly(alkyl)acrylate compounds. When the composition is inverted in an aqueous solution, it provides an inverted solution having a filter ratio using a 1.2 micron filter (FR1.2) of about 1.5 or less.Type: GrantFiled: June 29, 2018Date of Patent: April 16, 2024Assignee: KEMIRA OYJInventors: Hong Yang, Frances Troy