Abstract: A dry strength composition for manufacture of paper, board or the like is disclosed. The dry strength composition includes, as a mixture, at least one anionically derivatized polysaccharide, and cationic starch having an amylopectin content ?80 weight-%. The anionically derivatized polysaccharide and the cationic starch provide the composition with a charge density in a range of 0.1-1.5 meq/g, when measured at pH 2.8, and ?0.1-?3 meq/g, preferably ?0.3-?2.5 meq/g, more preferably ?0.5-?2.0 meq/g, when measured as an aqueous solution, at pH 7.0. Further disclosed are a use of the composition and a method for manufacturing paper, board or the like.
Type:
Grant
Filed:
January 18, 2019
Date of Patent:
August 30, 2022
Assignee:
Kemira Oyj
Inventors:
Matti Hietaniemi, Asko Karppi, Jonas Konn
Abstract: Provided for example is a system and method for real-time monitoring or controlling wastewater or sludge dewatering or thickening processes. The system and method can also enable operators to remotely monitor their own system off-site.
Type:
Grant
Filed:
December 10, 2015
Date of Patent:
August 23, 2022
Assignee:
KEMIRA OYJ
Inventors:
Roderick Abinet, Greg Land, David Soper, Tafadzwa Mariga
Abstract: A method for manufacturing a multi-layered paperboard is disclosed, which includes at least two fibrous layers, in which method at least one layer of the multi-layered paperboard is treated by applying an aqueous solution of a first strength component in dissolved form including anionic strength polymer and/or amphoteric strength polymer composition on a surface of layer, and an aqueous solution of a cationic second strength component in dissolved form is added to a fibre stock from which at least one of the fibrous layers joined together is formed.
Abstract: The present embodiments generally relate to the treatment of produced water comprising one or more water soluble polymers, wherein such treatment comprises: adding to the produced water at least one iron complex; and degrading at least a portion of the one or more water soluble polymers. This treatment may result in a reduction of the viscosity of said produced water and/or the degradation of the water soluble polymers which are contained therein.
Type:
Grant
Filed:
March 6, 2018
Date of Patent:
June 21, 2022
Assignee:
KEMIRA OYJ
Inventors:
Iris Porat, Miguel Pelaez, Mehrdad Hesampour, Yuping Luo, William Morris, Luciana Bava
Abstract: A method is disclosed for monitoring deposit formation in an aqueous process. The method includes providing a feed flow of aqueous liquid onto a receiving surface of a monitoring cell. At least part of the receiving surface is illuminated with a light source. Visual data is collected at a multitude of positions across the receiving surface, and the collected visual data is analysed. A quantitative scaling and/or fouling indication is computed for the receiving surface. The monitoring cell has an inlet for the aqueous feed flow and an outlet for a reject flow from the monitoring cell. The receiving surface includes a selective barrier membrane. The feed flow is directed to the receiving surface at an elevated pressure to produce a permeate part that passes through the selective barrier membrane, and a concentrate part that forms the reject flow.
Abstract: Well treatment fluids, and methods for treating wellbores or fracturing subterranean formations, which include acrylamide polymer or copolymer crosslinked with one or more crosslinkers and one or more iron-containing compounds are provided.
Type:
Grant
Filed:
December 30, 2014
Date of Patent:
May 24, 2022
Assignee:
KEMIRA OYJ
Inventors:
Jiang Li, Roopa Tellakula, Scott Rosencrance
Abstract: A method for manufacturing paper or board is disclosed and further disclosed is an internal sizing system for providing improved retention of hydrophobic internal sizing agents. The internal sizing system includes a hydrophobic internal sizing agent as a first component selected from a group consisting of alkenyl succinic anhydride (ASA), alkyl ketene dimer (AKD), rosin sizes and any combination thereof, and a water-soluble polymer product including amphoteric polyacrylamide as a second component, which amphoteric polyacrylamide has neutral or cationic net charge at pH 7, a weight-average molecular weight of 700,000-18,000,000 g/mol and a total ionicity of 4-28 mol-%, where the first component and the second component are provided as separate components or as a combination of the first component and the second component.
Type:
Grant
Filed:
October 31, 2018
Date of Patent:
May 24, 2022
Assignee:
Kemira Oyj
Inventors:
Timo Valkealaakso, Simo-Pekka Vanninen, Asko Karppi
Abstract: A sample of an aqueous stream is conducted to an optical measurement device. A hydrophobic dye is added. The sample is fractionated into fractions according to particle size or mass. The fluorescence intensity values and light scattering intensity values for the fractions are measured. The fluorescence intensity values of the fractions are added together thus obtaining a sum of the fluorescence intensity values. The light scattering intensity values of the fractions are added together, thus obtaining a sum of the light scattering intensity values. A hydrophobicity density of the particles in the sample, is calculated by dividing the sum of the fluorescence intensity values with the sum of the light scattering intensity values, and the concentration of hydrophobic contaminants in the aqueous stream is monitored and controlled based on the calculated hydrophobicity density of the particles in the sample.
Type:
Application
Filed:
December 20, 2019
Publication date:
May 12, 2022
Applicant:
KEMIRA OYJ
Inventors:
Iiris JOENSUU, Marjatta PIIRONEN, Andy BERGERON, Travis BJERKETVEDT
Abstract: Provided herein are liquid polymer (LP) compositions comprising an acrylamide (co)polymer, as well as methods for preparing inverted polymer solutions by inverting these LP compositions in an aqueous fluid. The resulting inverted polymer solutions can have a concentration of acrylamide (co)polymer of from about 50 to about 15,000 ppm, and a filter ratio of 1.5 or less at 15 psi using a 1.2 ?m filter. Also provided are methods of using these inverted polymer solutions in dewatering, clarification, flocculation and/or thickening applications, and the like.
Type:
Grant
Filed:
December 7, 2016
Date of Patent:
April 12, 2022
Assignees:
KEMIRA OYJ, CHEVRON U.S.A. INC.
Inventors:
Logan Jackson, Thomas J. Lynch, Ronald Robinson, Frances Fournier, Hong Yang, Sukhjit Aujla, Do Hoon Kim, Dennis Arun Alexis, Varadarajan Dwarakanath, David Espinosa, Taimur Malik
Abstract: Methods for fracturing a subterranean formation penetrated by a well bore are provided, the method comprising the step of injecting a well treatment fluid into the well bore at a pressure and flow rate sufficient to fracture the subterranean formation, wherein the well treatment fluid comprises one or more iron-containing compounds and one or more booster compounds. The methods can be used to reduce viscosity and to facilitate the decomposition of acrylamide-containing polymers.
Abstract: The invention relates to a polymer having a main chain which is obtained by free radical emulsion polymerisation of a monomer mixture, which comprises at least one optionally substituted styrene, at least one C1-C4 alkyl (meth) acrylate and at least one ethylenically unsaturated monomer. The monomer mixture is polymerised in a reaction mixture comprising a natural and/or synthetic polymeric stabilator. According to the invention the polymer main chain further comprises a reaction product of silica sol and an unsaturated organosilicon compound. The invention relates also to methods of making such polymer.
Abstract: The invention relates to an arrangement for continuous production of polymer including a polymerisation reactor. The reactor includes a first pulley and a second pulley arranged at a distance from each other, which distance, defining a longitudinal first direction, and a flexible endless belt having a first edge section and a second edge section, which belt, is arranged to travel over the first pulley and the second pulley as a flat belt. The reactor further includes a supporting structure, which is arranged to support the flexible endless belt between the first pulley and the second pulley, whereby the supporting structure is arranged to form the flexible endless belt into a trough section by deviating the first edge section and the second edge section of the flexible endless belt away from the first direction. The trough section has a width-to-height ratio <1.2.
Abstract: Disclosed is a method for controlling a biofilm, removing a formed biofilm and/or controlling a growth of microorganisms, preferably bacteria, in an aqueous environment of an industrial manufacturing process including a cellulosic fibre material.
Type:
Application
Filed:
August 28, 2018
Publication date:
February 24, 2022
Applicant:
Kemira Oyj
Inventors:
Jaakko Simell, Marko Kolari, Jonas Konn
Abstract: A strength additive system for manufacturing paper, board, tissue or the like includes preferably as separate components, a cationic strength agent, such as a cationic polymer with aldehyde functional groups, and an anionic copolymer obtained by polymerization of a reaction mixture including (meth)acrylamide and anionic monomers, the standard viscosity of the obtained copolymer being in a range of 1.5-5.0 mPas. A method for manufacturing of a paper, board, tissue or the like is further disclosed.
Abstract: The present invention relates to a surface sizing composition comprising a metal salt, wherein the metal has at least 3 valence electrons, and an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend comprising (a) 0 to 75% by weight of at least one optionally substituted styrene, (b) 15 to 100% by weight of at least one C1-C4-alkyl (meth)acrylate, and (c) 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, wherein the sum (a)+(b)+(c) is 100%, in the presence of a water-soluble redox system comprising a first free radical initiator for the free radical emulsion copolymerization and an aqueous prepolymer composition (B) obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend comprising (i) 5 to 50%
Type:
Grant
Filed:
March 29, 2018
Date of Patent:
February 8, 2022
Assignee:
Kemira Oyj
Inventors:
Anneli Lepo, Tarja Turkki, Elsi Turunen
Abstract: The present embodiments generally relate to methods for the treatment of tailings, e.g., oil sands tailings, including methods comprising the use of one or more flocculants, one or more coagulants and one or more oxidants to treat said tailings and/or to improve the performance of said one or more flocculants.
Abstract: A coating structure for a sheet-like substrate, which includes lignocellulosic fibres is disclosed. The structure includes at least one pre-coat layer including at least 70 weight-% of a first styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser, having a glass transition temperature Tg ?20° C. preferably ?10° C., ?30 weight-% of inorganic platy mineral particles and 0.01-2 weight-% of at least one first thickener. The coating structure further includes a top coat layer including at least 50 weight-% of a second styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser having a glass transition temperature Tg ?20° C. preferably ?10° C., ?30 weight-% of inorganic mineral particles, 0.01-5 weight-% of at least one second thickener and 0.5-30 weight-% of an antiblocking agent. Further disclosed is a sheet-like product coated with the coating structure.
Abstract: The present invention relates to a process for in situ the preparation of mixtures of chelating agents by catalyzed reactions of diethanolamine derivatives with maleic acid and then with 2-halocarboxylic acid, to mixtures of chelating agents and methods using such chelating agents.
Type:
Grant
Filed:
June 27, 2018
Date of Patent:
January 18, 2022
Assignee:
Kemira Oyj
Inventors:
Reijo Aksela, Jonas Konn, Anna-Maija Perander, Anna Haarala, Riitta Ilmoniemi, Hanna Hoffren
Abstract: A method is disclosed for monitoring and controlling treatment of a waste water stream. The method includes measuring UV absorbance of a waste water influent and/or waste water effluent, measuring turbidity of the waste water influent and/or waste water effluent, and determining the concentration of dissolved organics in the waste water influent and/or waste water effluent based on the measured UV absorbance. The method includes controlling the dosing of at least one coagulant to the waste water influent based on the measured UV absorbance and/or the determined concentration of the dissolved organics, and optionally based on the measured turbidity, and optionally controlling the dosing of at least one flocculant to the waste water influent based on the measured turbidity.
Type:
Application
Filed:
November 14, 2019
Publication date:
January 13, 2022
Applicant:
Kemira Oyj
Inventors:
Marjatta PIIRONEN, Sakari HALTTUNEN, Iiris JOENSUU, Anne MÄKI
Abstract: A method is disclosed for increasing strength properties, preferably burst strength and SCT strength, of a paper or board product. The paper or board product is manufactured from a fibrous web produced by a multilayer headbox, where an aqueous layer is formed between at least a first and a second fibre layer formed from fibrous stock suspension(s), and where feed water for the aqueous layer includes at least one cationic polymer. The method of the invention includes adding an anionic additive selected from a group comprising anionic synthetic organic polymers, anionic polysaccharides, and any of their combinations to the feed water before formation of the aqueous layer.
Type:
Grant
Filed:
June 13, 2018
Date of Patent:
January 4, 2022
Assignee:
Kemira Oyj
Inventors:
Mikko Virtanen, Kimmo Strengell, Juan Cecchini, Matti Hietaniemi