Patents Assigned to Kemira Oyj
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Patent number: 12215463Abstract: The present invention provides a process for producing paper or board, comprising slushing a stock of dried fibres in a slushing system comprising a pulper, and/or feeding a stock of never-dried fibres in a fiber line of an integrated paper mill; deflaking and/or refining the stock in a deflaker and/or a refiner, optionally diluting the deflaked and/or refined stock, directing the deflaked and/or refined stock to a headbox, forming a web, and drying the web, wherein a polymeric paper making additive is added to one or more of the stocks of dried fibres and never-dried fibres before deflaking and/or refining of the stock. The present invention further provides paper and board with improved properties.Type: GrantFiled: May 22, 2019Date of Patent: February 4, 2025Assignee: Kemira OyjInventors: Diego Salas, Jinho Lee, Jan-Luiken Hemmes
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Patent number: 12202756Abstract: In a water treatment system, a pretreatment chemical is added to water stream in a pretreatment process including a coagulation, flocculation and separation to reduce amount of dissolved and/or particulate matter in the water stream. Hydrophobic conditions in the water stream are monitored upstream or downstream from adding the pretreatment chemicals. Dosing of the pretreatment chemical to the water stream is controlled based on the monitored hydrophobic conditions. Thereby a membrane fouling in subsequent membrane filtration stage can be minimized.Type: GrantFiled: December 4, 2023Date of Patent: January 21, 2025Assignee: KEMIRA OYJInventors: Mehrdad Hesampour, Roderick Abinet, Marjatta Piironen, Eija Korte, Iiris Joensuu
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Patent number: 12174612Abstract: Estimating or predicting runnability or end product quality risk level for a pulp or papermaking process is disclosed. The method includes measuring hydrophobicity values of samples originating from a same aqueous process stream. A hydrophobicity measurement signal is produced of measured hydrophobicity values as a function of time. A risk level is calculated for the process. At least one mathematical index is calculated based on the hydrophobicity measurement signal, and optionally based on the amount of particles in the sample, other property of the aqueous stream and/or production data. The mathematical index and optionally the amount of the particles, other property, and/or production data is used as a risk indicator input in the calculation. Based on the risk level calculated for the pulp or papermaking process, the runnability and/or end product quality risk level for the pulp or papermaking process is indicated.Type: GrantFiled: June 17, 2020Date of Patent: December 24, 2024Assignee: Kemira OyjInventors: Iiris Joensuu, Marjatta Piironen
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Patent number: 12172913Abstract: A method for removing biologically recalcitrant soluble organic compounds from wastewater simultaneously in an activated sludge process comprising an aeration tank and a solid-liquid separation unit, in which method at least one Al and/or Fe based inorganic metal coagulant is added to the wastewater in the activated sludge process and/or prior to conveying wastewater to an activated sludge process.Type: GrantFiled: June 10, 2020Date of Patent: December 24, 2024Assignee: Kemira OyjInventors: Göran Bäckman, Sakari Halttunen, Pascal Morin, Marina Shestakova
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Patent number: 12163289Abstract: A coating structure for a sheet-like substrate is disclosed including cellulosic fibres and a sheet-like product. The structure includes at least one pre-coat layer and a top coat layer, where the pre-coat layer(s) and the top coat layer include 10-90 weight-% of a styrene (meth)acrylate copolymer which is polymerised in the presence of a stabiliser, and which has a glass transition temperature Tg?20° C., preferably ?15° C., more preferably ?13° C. Furthermore, the pre-coat layer(s) includes a polysaccharide, such as starch, and the top coat layer includes 5-60 weight-% of at least one water-soluble coating binder, which is selected from polysaccharides and polyvinyl alcohols, as well as at most 5.0 weight-% of a cross-linker, which reacts with —OH or —COOH groups.Type: GrantFiled: June 19, 2019Date of Patent: December 10, 2024Assignee: Kemira OyjInventors: Tarja Turkki, Sami Puttonen, Helena Peuranen, Mari Ojanen, Erland Hermansson, Anneli Lepo
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Patent number: 12114659Abstract: The invention relates to a method for controlling of a biofilm, for removing a formed biofilm and/or for controlling a growth of microorganisms, preferably bacteria, in an aqueous environment of an industrial manufacturing process comprising cellulosic fibre material. In the method a composition comprising a compound selected from a group consisting of 3-[(4-methylphenyl)sulphonyl]-2-propenenitrile and 4-amino-N-2-thiazolyl-benzenesulphonamide is administered to the aqueous environment of the process.Type: GrantFiled: July 26, 2022Date of Patent: October 15, 2024Assignees: Kemira Oyj, University of CopenhagenInventors: Jaakko Simell, Marko Kolari, Michael Givskov, Tim Tolker-Nielsen, Morten Levin Rybtke, Jens Bo Andersen
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Patent number: 12116294Abstract: A treatment system for removing dissolved organic compounds from wastewater, which comprises a water-soluble cationic polymer, and wood-based organic material having an average particle size <10 mm. The invention relates also use of said treatment system for COD removal in the treatment of wastewaters, and a method for removing dissolved organic compounds from wastewater.Type: GrantFiled: June 12, 2020Date of Patent: October 15, 2024Assignee: Kemira OyjInventors: Sakari Halttunen, Matias Penttinen, Jonni Ahlgren, Susann Härkönen, Marina Shestakova
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Patent number: 12072279Abstract: A method to determine vapor phase corrosion load in paper and board manufacturing system is disclosed. The method allows optimizing oxidative biocide content in aqueous solutions, suspensions and slurries in the paper and board manufacturing system. The method is based on determination of redox values (rH) of the system during determined time period. A correlation between rH values exceeding a predetermined rH threshold values and corrosion load provides an estimate of increased or decreased corrosion load and allows timely changes to biocide dosage.Type: GrantFiled: November 27, 2019Date of Patent: August 27, 2024Assignee: Kemira OyjInventors: Marko Kolari, Iiris Joensuu
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Patent number: 12071399Abstract: The present invention relates to a process for the preparation of arylsulfonylpro-penenitriles. The reaction starting from arylsulfonyl halides is catalyzed by a cat-alyst compound comprising a transition metal. The process is scalable, environ-mentally benign and provides the product in good yield.Type: GrantFiled: November 4, 2019Date of Patent: August 27, 2024Assignee: Kemira OyjInventors: Jaakko Hiltunen, Petteri Suominen, Ivan Ogibalov, Ain Uustare
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Patent number: 12044607Abstract: A sample of an aqueous stream is conducted to an optical measurement device. A hydrophobic dye is added. The sample is fractionated into fractions according to particle size or mass. Fluorescence intensity values and light scattering intensity values for the fractions are measured. Fluorescence intensity values of the fractions are added together thus obtaining a sum of the fluorescence intensity values. Light scattering intensity values of the fractions are added together, thus obtaining a sum of the light scattering intensity values. A hydro-phobicity density of the particles in the sample, is calculated by dividing the sum of the fluorescence intensity values with the sum of the light scattering intensity values. A concentration of hydrophobic contaminants in the aqueous stream is monitored and controlled based on the calculated hydrophobicity density of the particles in the sample.Type: GrantFiled: December 20, 2019Date of Patent: July 23, 2024Assignee: KEMIRA OYJInventors: Iiris Joensuu, Marjatta Piironen, Andy Bergeron, Travis Bjerketvedt
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Patent number: 12043559Abstract: The invention concerns an online method and system for monitoring properties of an aqueous stream of an industrial process. The method comprises providing an initial aqueous stream originating from said process, the aqueous stream containing solid matter exhibiting a first settling behavior; adding modifying agent to the initial aqueous stream at an addition rate sufficient to provide a modified aqueous stream containing solid matter exhibiting a second settling behavior different from the first settling behavior; conducting a sample of the initial aqueous stream or modified aqueous stream, any combination stream comprising the modified aqueous stream or any substream of the modified aqueous stream batchwise from a sampling point to a settling vessel having a volume; and measuring the settling behavior of the solid matter in the sample locally in the settling vessel as a function of time.Type: GrantFiled: July 19, 2011Date of Patent: July 23, 2024Assignee: KEMIRA OYJInventors: Iiris Joensuu, Marjatta Piironen, Eija Saari, Jukka-Pekka Sirviö, Seppo Tuomivaara
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Patent number: 12031274Abstract: A method for preparation of a starch-promoted alkyl ketene dimer (AKD) sizing emulsion is provided. The inventive method comprises adding a sizing promoter comprising high-charge cationic starch and polyaluminum chloride (PAC) to a stabilized AKD emulsion and further wherein addition of said sizing promoter comprising high-charge cationic starch and PAC is effected at ambient temperature, after emulsification, stabilization, and homogenization of said stabilized AKD emulsion; and prior to addition of the starch-promoted AKD sizing emulsion to papermaking furnish, pulp, or fiber stock.Type: GrantFiled: December 30, 2021Date of Patent: July 9, 2024Assignee: Kemira OyjInventors: Jennifer Riser, Kirsi Terava, Timo Valkealaakso, Jaakko Hiltunen
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Patent number: 11976418Abstract: The present invention provides a novel method and composition for enhancing the efficiency of starch adsorption (i.e., starch trapping) from starch-containing furnishes comprising high content of recycled fibers for use in paper making processes such as pulp, paper, or board production. A novel polymer coagulation system is disclosed in which two quick inversion cationic emulsion polymers (starch trapping polymers A and B) are co-mixed at optimal blend ratios to meet specific recycled fiber and process water requirements for different recycled fiber plants and added to furnishes prior to formation of paper or board in a paper machine. Co-mixed solutions of starch trapping polymers A and B provide synergistic enhancements in (i) starch trapping efficiency and (ii) starch retention in the produced paper or board over equivalent dosage levels of singly administered polymer A, polymer B, or conventional starch trapping products, without over-flocculation or formation of stickies.Type: GrantFiled: October 12, 2021Date of Patent: May 7, 2024Assignee: KEMIRA OYJInventors: Yuping Luo, Jennifer Riser
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Patent number: 11959018Abstract: Liquid polymer and inverse emulsion compositions comprising: one or more hydrophobic liquids having a boiling point at least about 100° C.; one or more acrylamide-(co)polymers; one or more emulsifier surfactants; one or more inverting surfactants; and one or more poly(alkyl)acrylate compounds. When the composition is inverted in an aqueous solution, it provides an inverted solution having a filter ratio using a 1.2 micron filter (FR1.2) of about 1.5 or less.Type: GrantFiled: June 29, 2018Date of Patent: April 16, 2024Assignee: KEMIRA OYJInventors: Hong Yang, Frances Troy
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Publication number: 20240092668Abstract: In a water treatment system, a pretreatment chemical is added to water stream in a pretreatment process including a coagulation, flocculation and separation to reduce amount of dissolved and/or particulate matter in the water stream. Hydrophobic conditions in the water stream are monitored upstream or downstream from adding the pretreatment chemicals. Dosing of the pretreatment chemical to the water stream is controlled based on the monitored hydrophobic conditions. Thereby a membrane fouling in subsequent membrane filtration stage can be minimized.Type: ApplicationFiled: December 4, 2023Publication date: March 21, 2024Applicant: KEMIRA OYJInventors: Mehrdad HESAMPOUR, Roderick ABINET, Marjatta PIIRONEN, Eija KORTE, Iiris JOENSUU
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Patent number: 11932707Abstract: The present invention relates to a method and an arrangement for dissolving starch. Specifically, the present invention relates to a method for dissolving starch by introducing mechanical force to at least partially gelatinized aqueous starch.Type: GrantFiled: February 6, 2020Date of Patent: March 19, 2024Assignee: Kemira OyjInventors: Asko Karppi, Perttu Heiska, Mika Suvanto, Matti Hietaniemi
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Patent number: 11925914Abstract: Systems for producing performic acid and methods for producing performic acid. The systems may include two or more reactor units, two or more servient programmable logic controllers, a control panel, and a master programmable logic controller. The system may modify the production of performic acid in at least one of the two or more reactor units upon and/or after the occurrence of a disruptive event in order to maintain a desired level of performic acid production and/or a desired level of disinfection.Type: GrantFiled: March 9, 2021Date of Patent: March 12, 2024Assignee: KEMIRA OYJInventors: Patricia Aubeuf-Prieur, Iris Porat, Marco Stammegna, Sampsa Greus
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Patent number: 11897984Abstract: Tagging agents, including fluorescent monomers, which may be polymerized. Anti-scalant polymer compositions that include a copolymer of a tagging agent and an anti-scalant monomer. Methods for synthesizing tagging agents, anti-scalant polymer compositions, and detecting an anti-scalant polymer composition.Type: GrantFiled: December 4, 2020Date of Patent: February 13, 2024Assignee: KEMIRA OYJInventors: Vesa Nuutinen, Erkki Johannes Metsälä, Reijo Aksela, Vesa Vuori, Mehrdad Hesampour
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Patent number: 11891499Abstract: The present invention relates to a granular microfibrillated cellulose product comprising a microfibrillated cellulose originating from agricultural biomass, said microfibrillated cellulose product comprising ?75 wt % of cellulose, preferably ?70 wt %, based on dry solids content of said product, wherein said granular microfibrillated cellulose product has a bulk density of 500-1200 kg/m3; a flowability of 5-60 ml/s, measured by a Copley scientific powder flowability tester having a stainless steel cylinder with orifice 16 or funnel with orifice 15; and a water content of at most 60 wt %, based on total microfibrillated cellulose product. The present invention further relates to its manufacture and use in and manufacture of paper and paperboard products.Type: GrantFiled: July 19, 2019Date of Patent: February 6, 2024Assignee: KEMIRA OYJInventors: Juhana Ahola, Kaisa Karisalmi, Christos Rampotas, Perttu Heiska, Mika Suvanto
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Patent number: 11879095Abstract: The present embodiments generally relate to methods and compositions comprising one or more polymers which gradually increase in charge, thereby providing for an increase in viscosity in an aqueous solution or aqueous composition, such as when present in a desired aqueous environment. Use of such compositions and methods comprising one or more polymers which gradually increase in charge, thereby providing for an increase in viscosity in an aqueous solution or aqueous composition during enhanced oil recovery may result in an increase in oil production relative to methods and/or compositions which do not comprise one or more polymers which gradually increase in charge, thereby providing for an increase in viscosity in an aqueous solution or aqueous composition.Type: GrantFiled: September 17, 2019Date of Patent: January 23, 2024Assignee: KEMIRA OYJInventors: Leena Nurmi, Sirkku Hanski, Susanna Toivonen, Louis Rosati