Patents Assigned to Kemira Oyj
  • Publication number: 20230287629
    Abstract: A method for monitoring hydrophobic particles contained in a pulp suspension, includes obtaining a sample from a pulp suspension or a filtrate of the pulp suspension. A fluorescent dye is added to the sample to stain particles in the sample. The sample is fractionated to obtain at least a first fraction and a second fraction, wherein the second fraction is a fiber fraction. The method includes for the obtained fractions, fluorescence emitted by the particles in the fractions, calculating an integral of the fluorescence measured for the fractions excluding the fiber fraction, and correlating the calculated integral of the fluorescence to the amount of acetone soluble material in the pulp suspension, and optionally measuring light scattering signal of the particles in at least first and second fractions.
    Type: Application
    Filed: May 18, 2023
    Publication date: September 14, 2023
    Applicant: KEMIRA OYJ
    Inventors: Marjatta PIIRONEN, Iiris JOENSUU, Lari VÄHÄSALO
  • Patent number: 11753580
    Abstract: An inverse emulsion composition comprising: one or more hydrophobic liquids having a boiling point at least about 100° C.; up to about 38% by weight of one or more acrylamide-(co)polymers; one or more emulsifier surfactants; and one or more inverting surfactants; wherein, when the composition is inverted in an aqueous solution, it provides an inverted solution having a filter ratio using a 1.2 micron filter (FR1.2) of about 1.5 or less.
    Type: Grant
    Filed: April 17, 2019
    Date of Patent: September 12, 2023
    Assignee: KEMIRA OYJ
    Inventors: Logan Jackson, Thomas J. Lynch, Ronald Robinson, Frances Fournier, Hong Yang, Sukhjit Aujla, Do Hoon Kim, Dennis Arun Alexis
  • Patent number: 11738292
    Abstract: Terpolymers and use thereof are provided comprising one or more nonionic monomers, one or more anionic monomers and one or more cationic monomers, These terpolymers and compositions containing may be used as flocculants, for example, for treating tailings, such as oil sands tailings, to facilitate solid-liquid separation, for example, in order to efficiently recycle water and/or to reduce the volume of tailings which may be transferred to a tailings pond and/or to a dedicated disposal area.
    Type: Grant
    Filed: September 4, 2018
    Date of Patent: August 29, 2023
    Assignee: KEMIRA OYJ
    Inventors: Tom Fenderson, Igal Maasen, Erica Pin, Miguel Pelaez
  • Patent number: 11697772
    Abstract: Hydrotropic composition comprising at least one surface active cationic component, which is selected from a group of cholinium, guadinium or tetramethylguadinium, preferably cholinium, and a straight or branched carboxylate anion having at least six carbon atoms; and its uses, for treating of oil sands or the like, for treating tailings from separation of bitumen, asphaltenes or the like.
    Type: Grant
    Filed: March 31, 2021
    Date of Patent: July 11, 2023
    Assignee: KEMIRA OYJ
    Inventors: Alistair King, Evangelos Sklavounos, Tiina Laaksonen, Antti Rantamaki, Susanne Wiedmer, Lasse Kyllonen, Suvi-Katriina Ruokonen
  • Patent number: 11692312
    Abstract: A method for monitoring hydrophobic particles contained in a pulp suspension, includes obtaining a sample from a pulp suspension or a filtrate of the pulp suspension. A fluorescent dye is added to the sample to stain particles in the sample. The sample is fractionated to obtain at least a first fraction and a second fraction, wherein the second fraction is a fiber fraction. The method includes for the obtained fractions, fluorescence emitted by the particles in the fractions, calculating an integral of the fluorescence measured for the fractions excluding the fiber fraction, and correlating the calculated integral of the fluorescence to the amount of acetone soluble material in the pulp suspension, and optionally measuring light scattering signal of the particles in at least first and second fractions.
    Type: Grant
    Filed: July 2, 2018
    Date of Patent: July 4, 2023
    Assignee: KEMIRA OYJ
    Inventors: Marjatta Piironen, Iiris Joensuu, Lari Vähäsalo
  • Patent number: 11673982
    Abstract: A method of producing a surface sizing composition, the method comprising: providing a metal salt having at least 3 valence electrons, wherein the metal salt is selected from the group of aluminium sulfate, aluminium chloride, aluminium nitrate, polyaluminium sulfate (PAS), polyaluminium chloride (PAC), and polyaluminium chloride sulfate (PACS), polyaluminium formiate, polyaluminium nitrate, and any combination thereof; providing an aqueous polymer dispersion, wherein the aqueous polymer dispersion is an aqueous polymer dispersion (A) and an aqueous prepolymer composition (B), wherein the aqueous polymer dispersion (A) is obtainable by free radical emulsion copolymerizing a first ethylenically unsaturated monomer blend, and wherein the aqueous prepolymer composition (B) is obtainable by free radical emulsion copolymerizing in a polymerization solvent comprising C1-6-carboxylic acid and C1-6-carboxylic acid anhydride, a second ethylenically unsaturated monomer blend; and mixing the metal salt and the aqueous p
    Type: Grant
    Filed: December 21, 2021
    Date of Patent: June 13, 2023
    Assignee: KEMIRA OYJ
    Inventors: Anneli Lepo, Tarja Turkki, Elsi Turunen
  • Patent number: 11655593
    Abstract: A method for manufacturing a multi-layered fibrous web is disclosed, which includes at least two fibrous layers, where each layer is formed from one or more fibre stocks. The fibrous layers are combined prior to subjecting the multilayered fibrous web to wet-pressing and drying. At least one layer of the multi-layered fibrous web is formed from a fibre stock including at least 50 weight-% of a chemi-thermomechanical pulp (CTMP), a hardwood kraft pulp and/or a recycled fibre material calculated from a thick stock applied to a particular layer approach system. A first strength component and a second strength component are added to the fibre stock. The first strength component includes a cationic strength agent and the second strength component includes a synthetic amphoteric polymer composition having a net charge from ?3 to +1 meq/g (dry), at a pH of 7.
    Type: Grant
    Filed: July 10, 2019
    Date of Patent: May 23, 2023
    Assignee: Kemira Oyj
    Inventors: Matti Hietaniemi, Asko Karppi, Jukka Rautiainen
  • Patent number: 11643782
    Abstract: Disclosed is a method for controlling a biofilm removing a formed biofilm and/or controlling a growth of microorganisms, preferably bacteria, in an aqueous environment of an industrial manufacturing process including a cellulosic fibre material.
    Type: Grant
    Filed: August 28, 2018
    Date of Patent: May 9, 2023
    Assignee: Kemira Oyj
    Inventors: Jaakko Simell, Marko Kolari, Jonas Konn
  • Patent number: 11629459
    Abstract: A method is disclosed for treating aqueous feed by dissolved gas flotation. The aqueous feed originates from industrial processing of fibrous material, where the aqueous feed includes an aqueous phase and solid particulate material suspended in the aqueous phase. The method includes bringing a flocculant in contact with the aqueous feed, flocculating suspended solid particulate material into flocs and contacting formed flocs with gas bubbles and inducing their flotation in a flotation basin. The flocculant includes a polymer composition having a charge density of at the most 1.7 meq/g dry and the polymer composition includes a cationic synthetic first polymer having a charge density at least 1.0 meq/g dry at pH 2.8, and at least one second polymer obtained by polymerization of (meth)acrylamide, the second polymer being polymerized in presence of the cationic first polymer, where the first polymer has a higher charge density than the second polymer.
    Type: Grant
    Filed: December 14, 2018
    Date of Patent: April 18, 2023
    Assignee: Kemira Oyj
    Inventors: Matti Hietaniemi, Jyri Välimäki, Joonas Likander, Rosa Carceller
  • Patent number: 11612898
    Abstract: The present embodiments generally relate to a technology for improving Cu/Mo grade by the addition of cationic polymers as selective depressants for acid insoluble matters, e.g., silicates and/or clays, in the flotation circuit. Various types of cationic polymers are demonstrated to be effective depressants including polyamine, polyDADMAC, and cationic polyacrylamide. Also disclosed are processes for enriching a desired mineral from an ore comprising the desired mineral and gangue, wherein the process comprises carrying out a flotation process in the presence of one or more cationic polymer depressants.
    Type: Grant
    Filed: August 30, 2017
    Date of Patent: March 28, 2023
    Assignee: KEMIRA OYJ
    Inventors: Marcelo Moreira Costa, Xihui Yin, Sergio Cabo
  • Patent number: 11598051
    Abstract: A method includes forming an aqueous fibre suspension including cellulosic fibres from one or more raw material flows, and applying at least one chemical and/or physical control measure to the aqueous fibre suspension or at least one of its raw material flows for control of microbial activity in the aqueous fibre suspension or the raw material flow before an inlet of an intermediate residence entity. In this manner a starting ORP value for the aqueous fibre suspension is obtained. The aqueous fibre suspension is in the intermediate residence entity at least a minimum delay time. A final ORP value is measured for the aqueous fibre suspension after an outlet of the intermediate residence entity before the formation of the fibrous web. An ORP difference value between the starting ORP and final ORP values is calculated. Finally, the aqueous fibre suspension is formed into a fibrous web and dried.
    Type: Grant
    Filed: June 19, 2018
    Date of Patent: March 7, 2023
    Assignee: Kemira Oyj
    Inventors: Jaakko Ekman, Marko Kolari, Juhana Ahola
  • Patent number: 11560323
    Abstract: The present embodiments generally relate to the use of one or more polymers, e.g., one or more dry acid polymers and/or one or more dry acid polymers with salt, as flocculants, generally for treating tailings, e.g., oil sands tailings, in need of solid-liquid separation, e.g., in order to efficiently recycle water and/or to reduce the volume of tailings which may be transferred to a tailings pond and/or a dedicated disposal area.
    Type: Grant
    Filed: April 14, 2021
    Date of Patent: January 24, 2023
    Assignee: KEMIRA OYJ
    Inventors: Duane C. Wilson, Thomas Fenderson, Igal Maasen, Sukhjit Aujla
  • Publication number: 20230019003
    Abstract: Emulsions, treatment fluids and methods for treating subterranean formations are provided, wherein the emulsions comprise water, a water-immiscible liquid, one or more polymers, and an inverting surfactant composition comprising one or more surfactants selected from the group consisting of ethoxylated alcohol compounds, ethoxylated fatty acid compounds, and alkyl polyethyleneglycol ether carboxylic acid compounds, and salts or esters thereof. The emulsions are particularly suitable for use in brine.
    Type: Application
    Filed: July 20, 2020
    Publication date: January 19, 2023
    Applicant: Kemira OYJ
    Inventors: Roopa TELLAKULA, Louis ROSATI, Ronald ROBINSON, Samuel HANSON
  • Patent number: 11536658
    Abstract: The present invention provides a method for determining concentration of polyelectrolyte or phosphonate in a sample comprising polyelectrolyte or phosphonate in low concentrations. The method comprises admixing the sample with a reagent comprising a lanthanid(lll) ion; admixing the sample with silica; allowing the polyelectrolyte or phosphonate in the sample to interact with the reagent comprising the lanthanide(lll) ion and the silica; exciting the sample and detecting a sample signal deriving from the lanthanide(lll) ion by time-resolved fluorescence measurement; and determining the concentration of the polyelectrolyte or phosphonate in the sample by using the detected sample signal.
    Type: Grant
    Filed: September 27, 2019
    Date of Patent: December 27, 2022
    Assignee: Kemira Oyj
    Inventors: Salla Puupponen, Sari Krapu
  • Patent number: 11535985
    Abstract: A method for manufacture of paper or board, in which method an inverted solution of cationic polymer is added to the fiber suspension for providing retention enhancement without over-flocculating fiber stock and destruction sheet formation and/or improving drainage and enhancing or at least maintaining strength of paper or board, An inverted solution has a bulk viscosity of 50-150 mPas at 0.2 weight-% cationic polymer concentration and inverted solution comprises cationic polymer obtained by reverse phase emulsion polymerization of a monomer blend comprising non-ionic monomers, 15-50 mol-% cationic monomers, an optionally at most 50 ppm of a crosslinking agent, and a chain transfer agent, and the obtained reverse phase emulsion of cationic polymer is inverted into an aqueous solution.
    Type: Grant
    Filed: June 30, 2020
    Date of Patent: December 27, 2022
    Assignee: Kemira Oyj
    Inventors: Yuping Luo, Jennifer Riser, Zheng Dang, Junhua Chen, Ronald Robinson, Andrew Pencek, Barbara Lukasik
  • Patent number: 11535539
    Abstract: A method for treating a wastewater or a wastewater sludge includes adding performic acid to the wastewater and/or the waster sludge as an odor controlling agent and/or corrosion controlling agent.
    Type: Grant
    Filed: November 17, 2017
    Date of Patent: December 27, 2022
    Assignee: Kemira Oyj
    Inventors: James Currie Allen, Tafadzwa Mariga
  • Patent number: 11530514
    Abstract: A method for manufacturing a fibrous web, such as web of paper, board, tissue or the like is disclosed. The method includes obtaining at least one fibre suspension of lignocellulosic and/or cellulosic fibres and feeding the fibre suspension into an intermediate residence entity. The fibre suspension including bacterial endospores, is discharged out of the intermediate residence entity via an outlet after a residence time of at least 2 hours in the intermediate residence entity and after a time delay the fibre suspension is formed into a fibrous web. Bacterial endospores are sensitized by adding a germinant surfactant including a primary or secondary ammonium head group and a linear unsubstituted C12-alkyl tail, to the fibre suspension at an addition point located at a lower part of the intermediate residence entity or after the outlet of the intermediate residence entity, but before the formation of the fibrous web.
    Type: Grant
    Filed: November 8, 2018
    Date of Patent: December 20, 2022
    Assignee: Kemira Oyj
    Inventors: Juhana Ahola, Marko Kolari
  • Patent number: 11525022
    Abstract: A method for dewatering of biological sludge is disclosed. The method includes addition of a flocculant to a biological sludge, which includes an aqueous phase and a suspended solid organic material, flocculating and dewatering the sludge. The flocculant includes a polymer composition, which includes a cationic crosslinked first polymer, which is selected from crosslinked polyamines, and a cationic second polymer, which is a polymer obtained by polymerization of (meth)acrylamide and cationic monomers, the second cationic polymer being polymerized in presence of the cationic first polymer.
    Type: Grant
    Filed: December 14, 2018
    Date of Patent: December 13, 2022
    Assignee: Kemira Oyj
    Inventors: Joonas Likander, Rosa Carceller
  • Patent number: 11525218
    Abstract: A barrier coating composition is disclosed including 30-70 weight-% of a styrene (meth)acrylate copolymer, polymerised in the presence of a stabiliser, and the styrene (meth)acrylate copolymer having a glass transition temperature Tg?20° C., preferably ?10° C., 30-70 weight-% of a polyvinyl alcohol, and at most 5.0 weight-% of a cross-linker, reacting with —OH or —COOH groups. Further disclosed is a sheet-like product coated with the coating composition.
    Type: Grant
    Filed: June 14, 2018
    Date of Patent: December 13, 2022
    Assignee: Kemira Oyj
    Inventors: Helena Peuranen, Sami Puttonen, Tarja Turkki, Mari Ojanen, Erland Hermansson
  • Patent number: 11518695
    Abstract: A method for producing an aqueous copolymer solution, which comprises dissolving a copolymer of (meth)acrylamide and at least 1 mol-% cationic monomers, calculated from total amount of monomers in the dissolving water having calcium hardness of at least mg/l, expressed as Ca2+, and adding acid comprising monoprotic organic acid and/or mineral acid to the dissolving water and/or the aqueous solution of the copolymer in an amount sufficient to provide the aqueous solution of the copolymer with a pH of equal to or less than 4.5. The invention also relates to uses of the obtained polymer solutions in manufacturing of paper, board or the like or in treatment of sludge or water.
    Type: Grant
    Filed: May 15, 2018
    Date of Patent: December 6, 2022
    Assignee: Kemira Oyj
    Inventors: Asko Karppi, Matti Hietaniemi