Patents Assigned to Kemira
  • Patent number: 10883226
    Abstract: The present invention relates to a method of producing microfibrillated cellu-lose (MFC) comprising (i) providing cellulosic material, (ii) drying the cellulosic material so that specific surface area (SSA), when measured with BET-method, is at most 10 m2/g, and (iii) subjecting the dried cellulosic material to mechanical treatment. The present invention additionally relates to microfibril-lated cellulose produced with the method of the present invention.
    Type: Grant
    Filed: December 22, 2016
    Date of Patent: January 5, 2021
    Assignee: Kemira Oyj
    Inventors: Kari Vanhatalo, Tom Lundin, Marcus Lillandt
  • Publication number: 20200399828
    Abstract: A method is disclosed for treating aqueous feed by dissolved gas flotation. The aqueous feed originates from industrial processing of fibrous material, where the aqueous feed includes an aqueous phase and solid particulate material suspended in the aqueous phase. The method includes bringing a flocculant in contact with the aqueous feed, flocculating suspended solid particulate material into flocs and contacting formed flocs with gas bubbles and inducing their flotation in a flotation basin. The flocculant includes a polymer composition having a charge density of at the most 1.7 meq/g dry and the polymer composition includes a cationic synthetic first polymer having a charge density at least 1.0 meq/g dry at pH 2.8, and at least one second polymer obtained by polymerization of (meth)acrylamide, the second polymer being polymerized in presence of the cationic first polymer, where the first polymer has a higher charge density than the second polymer.
    Type: Application
    Filed: December 14, 2018
    Publication date: December 24, 2020
    Applicant: Kemira Oyj
    Inventors: Matti Hietaniemi, Jyri Välimäki, Joonas Likander, Rosa Carceller
  • Patent number: 10858782
    Abstract: A method is disclosed for dewatering of sludge from a pulp, paper or board making process, such as deinking sludge, including obtaining of an aqueous sludge including an aqueous phase and a fibre material suspended in the aqueous phase. The sludge is subjected to a pre-thickening step, where a first part of the aqueous phase is removed from the sludge and to a pressing step, where a second part of the aqueous phase is removed from the sludge, thereby obtaining a dry pressed sludge. Before or at the pre-thickening step a polymer composition having a charge density of at the most 1.7 meq/g, preferably at most 1.5 meq/g, more preferably at most 1.1 meq/g, is added to the sludge.
    Type: Grant
    Filed: December 15, 2017
    Date of Patent: December 8, 2020
    Assignee: Kemira Oyj
    Inventors: Matti Hietaniemi, Rosa Carceller, Asko Karppi, Joonas Likander, Jyri Välimäki
  • Patent number: 10862152
    Abstract: The invention relates to a microbial fuel cell arrangement comprising a cell reactor. The cell reactor comprises a membrane, which has an active surface and a support surface, as well as a pore size of ?10 nm and/or a divalent ion rejection of ?50%; an anode and a cathode, which are connected with each other through an external electrical circuit; an influent inlet for liquid medium arranged at the active surface side of the membrane and at least one permeate outlet arranged at the support surface side of the membrane; an influent line connected to the influent inlet; a concentrate outlet, arranged at the active surface side of the membrane and connected to a concentrate line; and pressurisation means for creating pressure difference between the active surface side and support surface side of the membrane. The invention relates also to a method for operating a microbial fuel cell.
    Type: Grant
    Filed: December 29, 2016
    Date of Patent: December 8, 2020
    Assignee: Kemira Oyj
    Inventors: Sakari Halttunen, Jussi Ruotsalainen, Hannele Havansi, Mehrdad Hesampour
  • Publication number: 20200377673
    Abstract: A method for producing an aqueous copolymer solution, which comprises dissolving a copolymer of (meth)acrylamide and at least 1 mol-% cationic monomers, calculated from total amount of monomers in the dissolving water having calcium hardness of at least mg/l, expressed as Ca2+, and adding acid comprising monoprotic organic acid and/or mineral acid to the dissolving water and/or the aqueous solution of the copolymer in an amount sufficient to provide the aqueous solution of the copolymer with a pH of equal to or less than 4.5. The invention also relates to uses of the obtained polymer solutions in manufacturing of paper, board or the like or in treatment of sludge or water.
    Type: Application
    Filed: May 15, 2018
    Publication date: December 3, 2020
    Applicant: Kemira Oyj
    Inventors: Asko Karppi, Matti Hietaniemi
  • Patent number: 10844542
    Abstract: The present invention relates to a method for providing a pretreated filler composition for use in paper and board manufacturing including the steps of: a) providing a filler comprising precipitated calcium carbonate, said filler being in the form of a slurry comprising no additives; b) providing at least one polymer selected from polyvinylamine or polyacrylic amide, said polymer having a charge density of an absolute value of at most 4 meq/g determined at pH 7; c) combining said at least one polymer of step b) with the filler of step a); d) providing a slurry of nanofibrillar cellulose; e) combining said nanofibrillar cellulose slurry with the formed combination of step c) and forming a pretreated filler composition comprising aggregates. Further it also relates to a pretreated filler composition prepared therefrom, and its use in stocks, paper and paper board.
    Type: Grant
    Filed: December 17, 2014
    Date of Patent: November 24, 2020
    Assignees: KEMIRA OYJ, UPM-KYMMENE CORPORATION, STORA ENSO OYJ
    Inventors: Matti Hietaniemi, Mikko Virtanen, Katariina Torvinen, Terhi Saari, Erkki Hellen
  • Publication number: 20200361805
    Abstract: A method for dewatering of biological sludge is disclosed. The method includes addition of a flocculant to a biological sludge, which includes an aqueous phase and a suspended solid organic material, flocculating and dewatering the sludge. The flocculant includes a polymer composition, which includes a cationic crosslinked first polymer, which is selected from crosslinked polyamines, and a cationic second polymer, which is a polymer obtained by polymerization of (meth)acrylamide and cationic monomers, the second cationic polymer being polymerized in presence of the cationic first polymer.
    Type: Application
    Filed: December 14, 2018
    Publication date: November 19, 2020
    Applicant: Kemira Oyj
    Inventors: Joonas Likander, Rosa Carceller
  • Publication number: 20200354248
    Abstract: A composition for stabilizing iron compounds in an aqueous environment, includes a polycarboxylic acid or its salt(s), at least one monomeric or polymeric phosphonate including at least one phosphonic acid group, or its salt(s), at least one corrosion inhibitor including amino groups, and 1-15 weight-% of polycitric acid or a copolymer of citric acid with polyols or glycerol, calculated as an active ingredient from a total weight of constituents in the composition, as dry.
    Type: Application
    Filed: February 27, 2018
    Publication date: November 12, 2020
    Applicant: Kemira Oyj
    Inventors: Fengyang LI, Yan XU
  • Publication number: 20200347552
    Abstract: The invention relates to a method for producing paper, board or the like. The method comprises obtaining a thick stock comprising cellulose fibres, forming a fibrous web and drying of drying the fibrous web. A strength agent system, which comprises at least one synthetic or natural polymer, or their mixture, and microfibrillated parenchymal cellulose material originating from non-wood sources, is added to the thick stock. The invention relates also to paper or board produced by the method.
    Type: Application
    Filed: July 16, 2020
    Publication date: November 5, 2020
    Applicant: Kemira Oyj
    Inventors: KAISA KARISALMI, Tom Lundin, Mikko Virtanen, Antti Laukkanen, Jason McKee
  • Patent number: 10822462
    Abstract: The present disclosure relates to a novel aqueous composition of a structurally modified, water soluble polymer suitable for papermaking and to a method for manufacturing it. The method includes cleaving a backbone of the acrylamide polymer by a degradation agent and cross-linking the acrylamide polymer subjected to cleaving by using a polyfunctional cross-linking agent.
    Type: Grant
    Filed: September 15, 2016
    Date of Patent: November 3, 2020
    Assignee: Kemira Oyj
    Inventors: Yuping Luo, Roopa Tellakula, Scott Rosencrance
  • Patent number: 10800869
    Abstract: A polymer composition includes a first host polymer, which is a copolymer of (meth)acrylamide and at least one cationic first monomer, and a second polymer, which is a copolymer of (meth)acrylamide and at least one cationic second monomer. The second polymer is polymerised in presence of the first host polymer, and the first host polymer has a higher cationicity than the second polymer, the difference in cationicity of the first host polymer and the second polymer being at least 3 mol-%, at least 5 mol-%, more preferably at least 7 mol-%. The polymer composition has a standard viscosity of >2.0 mPas, measured at 0.1 weight-% solids content in an aqueous NaCl solution (1 M), at 25° C., using Brookfield VII T viscometer with UL adapter. The invention relates also to uses of said polymer composition.
    Type: Grant
    Filed: December 15, 2017
    Date of Patent: October 13, 2020
    Assignee: Kemira Oyj
    Inventors: Matti Hietaniemi, Rosa Carceller, Asko Karppi, Joonas Likander
  • Patent number: 10787768
    Abstract: A method for manufacture of paper, board or the like, comprising the step of dissolving a composition into aqueous solution, whereby an aqueous treatment solution is obtained for adding the obtained treatment solution to the pulp. The composition comprising a copolymer of acrylamide and at least one cationic monomer, the copolymer comprising cationic monomers at least 15 mol-%, calculated from total amount of monomers, and an ionic crosslinker agent comprising at least two carboxyl groups, wherein the equivalent ratio of carboxyl groups:cationic monomer is between 1:20 and 1:0.5.
    Type: Grant
    Filed: September 4, 2017
    Date of Patent: September 29, 2020
    Assignee: Kemira Oyj
    Inventors: Matti Hietaniemi, Jaakko Ekman, Asko Karppi, Kimmo Strengell
  • Publication number: 20200299903
    Abstract: A method is disclosed for predicting the microbial status of a paper or board making process and/or quality of the dry board or paper obtained from the process for controlling microbial status of a paper or board making process or quality of the dry board or paper obtained from the process. Surface level and duration of time in at least one storage tower or pulper are monitored and correlated with respective predetermined values for the tower or pulper in order to predict the risk of microbial activity.
    Type: Application
    Filed: December 7, 2018
    Publication date: September 24, 2020
    Applicant: Kemira Oyj
    Inventors: Marko Kolari, Marjatta PIIRONEN, Iiris JOENSUU
  • Patent number: 10781556
    Abstract: The invention relates to an aqueous dry strength composition suitable for use in manufacture of paper, board or the like. The composition includes a mixture of a synthetic polymer component, which is a copolymer of acrylamide and at least one anionic monomer, and a cationic starch component. The polymer component has an anionicity of 1-60 mol-%. The synthetic polymer component and cationic starch component provide the composition with a charge density in the range of 0.05-1 meq/g, when measured at pH 2.8, and 0.2-?3 meq/g, when measured at pH 7.0. The invention also relates to a method for making of paper, board or the like, where the dry strength composition is diluted with water, and the solution of the dry strength composition is added to the fibre stock before or after the addition of a cationic strength agent.
    Type: Grant
    Filed: September 26, 2017
    Date of Patent: September 22, 2020
    Assignee: Kemira Oyj
    Inventors: Matti Hietaniemi, Asko Karppi, Mikko Virtanen
  • Patent number: 10781555
    Abstract: The present invention relates to a sizing agent composition comprising starch, lignosulfonate and poly(alkyl acrylate), poly(alkyl (meth)acrylate), a mixture of poly(alkyl acrylate) and poly(alkyl methacrylate) or a copolymer of alkyl acrylate and alkyl (meth)acrylate. The present invention further relates to a method for preparing the sizing agent composition, and use of the sizing agent composition for sizing paper, paper products or board.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: September 22, 2020
    Assignee: Kemira Oyj
    Inventors: Anneli Lepo, Elsi Turunen, Tarja Turkki
  • Publication number: 20200291581
    Abstract: A method for manufacturing paper or board is disclosed and further disclosed is an internal sizing system for providing improved retention of hydrophobic internal sizing agents. The internal sizing system includes a hydrophobic internal sizing agent as a first component selected from a group consisting of alkenyl succinic anhydride (ASA), alkyl ketene dimer (AKD), rosin sizes and any combination thereof, and a water-soluble polymer product including amphoteric polyacrylamide as a second component, which amphoteric polyacrylamide has neutral or cationic net charge at pH 7, a weight-average molecular weight of 700,000-18,000,000 g/mol and a total ionicity of 4-28 mol-%, where the first component and the second component are provided as separate components or as a combination of the first component and the second component.
    Type: Application
    Filed: October 31, 2018
    Publication date: September 17, 2020
    Applicant: Kemira Oyj
    Inventors: Timo Valkealaakso, Simo-Pekka Vanninen, Asko Karppi
  • Patent number: 10773977
    Abstract: A method for treating tailings substrate from mining or oil sands separation process, the tailings substrate comprising an aqueous phase with suspended solid particulate material. In the method, a flocculating agent is added to the tailings substrate, flocs are allowed to form and the formed flocs are separated from the aqueous phase. The flocculating agent comprises a degraded polyacrylamide comprising at least anionic units and having a process water viscosity reduced by 25-99%, preferably 50-99%, compared to a substantially similar polyacrylamide that has not been degraded by a degradation agent, measured at a shear rate 1 s?1 as a 0.4-0.8 weight-% solution of polymer in process water.
    Type: Grant
    Filed: June 1, 2018
    Date of Patent: September 15, 2020
    Assignee: KEMIRA OYJ
    Inventors: Thomas Fenderson, Miguel Pelaez, Igal Maasen, Yuping Luo
  • Patent number: 10767315
    Abstract: Drainage and press dewatering system for manufacture of paper, board or the like, comprising (a) amphoteric polyacrylamide, which is a copolymer obtained by polymerizing (meth)acrylamide and 1-80 mol-% of cationic monomers and/or 0.1-70 mol-% of anionic monomers, the polyacrylamide having an intrinsic viscosity in the range of 6-38 dl/g, (b) inorganic microparticles of siliceous material, such as colloidal silica or bentonite, and (c) a high-charged cationic coagulant having a charge density over 5 meq/g and preferably over 6 meq/g determined at pH 6 and selected from aluminium based coagulants, organic polymers and mixtures thereof.
    Type: Grant
    Filed: March 22, 2017
    Date of Patent: September 8, 2020
    Assignee: Kemira Oyj
    Inventors: Matti Hietaniemi, Asko Karppi
  • Patent number: 10767312
    Abstract: The invention relates to a method for producing paper, board or the like. The method comprises obtaining a thick stock comprising cellulose fibres, forming a fibrous web and drying of drying the fibrous web. A strength agent system, which comprises at least one synthetic or natural polymer, or their mixture, and microfibrillated parenchymal cellulose material originating from non-wood sources, is added to the thick stock. The invention relates also to paper or board produced by the method.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: September 8, 2020
    Assignee: Kemira Oyj
    Inventors: Kaisa Karisalmi, Tom Lundin, Mikko Virtanen, Antti Laukkanen, Jason McKee
  • Patent number: 10767317
    Abstract: The invention relates to a method and treatment system for making of paper or surface ply of a multi-ply board from a fibre suspension, where at least 90 weight-% of fibres originate from chemical pulping process, chemi-thereto mechanical pulping process and/or office waste deinking pulping process. The fibre suspension further comprises inorganic mineral particles and cationic starch. A cationic copolymer of acrylamide and cationic monomers is incorporated to the fibre suspension and it is allowed to interact by flocculation with at least some of the said components of the fibre suspension. An anionic copolymer of acrylamide and more than 30 mol-% of anionic monomers is added to the fibre suspension, and fibre suspension is formed into a fibre web and drying the web to a dryness of at least 80%. An aqueous surface composition comprising polymeric binder is applied on the surface of the web.
    Type: Grant
    Filed: May 19, 2017
    Date of Patent: September 8, 2020
    Assignee: KEMIRA OYJ
    Inventors: Josep Lluis Bisbal, Daniel Nuno da Rita Santos, Matti Hietaniemi