Abstract: This invention relates to two-piece child resistant closures which utilize a ratchet feature to screw on the closure and, more specifically, to a two-piece child resistant closure wherein a particular ratchet configuration and placement of the elements thereof provides negligible reverse torque during undepressed counter-clockwise rotation of the outer closure member. Negligible reverse torque is defined as the torque caused by frictional contact of the outer and inner cap members when the undepressed closure is turned in the removal direction is insufficient to cause the undesired or accidental removal of the closure from the container.

Abstract: A colloidal sulfur particle opacifying extender scatters light across the visible spectrum to result in an overall colorless appearance. A process for opacifying and extending a matrix which can be a water-borne emulsion or a coating, using the colloidal sulfur particles, and opacified and extended water-borne emulsions and coatings including the colloidal sulfur particles are also provided.

Abstract: A process for the treatment of refinery oily sludges to produce an oily fraction that is reprocessed in the refinery into (i) salable products and (ii) a solid residue meeting environmental regulatory agency requirements for disposal in non-hazardous solid waste landfills. The process includes mixing the refinery oily sludge with a particulate filter aid and preferably a single solvent selected from refinery intermediate and product streams and contacting this mixture with plate filters in a closed filter vessel. A cake residue forms on the filter plates and a filtrate mixture of oil, water and solvent is produced. The filtrate is separated into an oily fraction and a water fraction. The oily fraction is rerouted to refinery operating units for processing into salable products. The water fraction is routed to a refinery water treatment system. When filter cake residue has built to a predetermined level, charge to the filter vessel is discontinued.

Abstract: A colloidal sulfur particle opacifying extender scatters light across the visible spectrum to result in an overall colorless appearance. A process for opacifying and extending a matrix which can be a water-borne emulsion or a coating, using the colloidal sulfur particles, and opacified and extended water-borne emulsions and coatings including the colloidal sulfur particles are also provided.

Abstract: A method of increasing the hydrophobicity of solid materials. The inventive method comprises the steps of: (a) metal ion activating the surface of a solid substrate material to provide reactive metal sites on the surface and (b) chemically bonding a surfactant to the surface at the reactive metal sites. Titanium dioxide pigments and other particulate property modifiers treated in accordance with the inventive method are more readily dispersed in polymer compositions.

Abstract: A process for co-producing hydrogen peroxide and another useful product, namely either an oxalate ester or a carbonate ester product, is provided The process comprises reacting a saturated monohydric alcohol with carbon monoxide and a quinone to form an oxalate ester or a carbonate ester product and hydroquinone. The hydroquinone is then reacted with oxygen to form hydrogen peroxide and a quinone.

Abstract: An improved method for preparing a rutile titanium dioxide pigment of uniform particle size wherein the pigment is formed by reaction of a mixture of an oxidizing gas and a titanium halide in the vapor phase at elevated temperatures in the presence of a metal ion containing compound. The improvement comprises introducing the metal ion containing compound into a vapor phase oxidation reactor containing the reacting mixture in at least two separate and discrete increments. The first increment is introduced into the reactor at a point prior to reaction of said mixture having occurred while the second increment is introduced into the reactor at a point wherein at least 20 weight percent of the total titanium halide reactant has been converted to the desired titanium dioxide pigment.

Abstract: The present invention provides a pigmentary titanium composite having good durability and excellent optical properties. The inventive composite consists essentially of: a particulate titanium dioxide base; a hydrous zirconium oxide layer deposited on the titanium dioxide base; and a hydrous alumina layer deposited on the hydrous zirconium oxide layer. The alumina layer consists essentially of boehmite alumina and/or pseudoboehmite alumina.The present invention also provides a method for preparing the inventive pigmentary composite. The inventive method comprises the steps of: (a) preparing an aqueous slurry comprising water and a particulate titanium dioxide base; (b) depositing a layer of a hydrous zirconium oxide precipitate on the titanium dioxide base; and (c) depositing a layer of a hydrous alumina precipitate on the layer of hydrous zirconium oxide. The hydrous alumina precipitate consists essentially of boehmite alumina and/or pseudoboehmite alumina.

Abstract: A process for making colored pigments based on zircon is described whereby a mixture of zirconium halide, silicon halide and a metal halide chromophore are oxidized at a temperature in the range of from about 600.degree. to about 1400.degree. C. This combustion process may be conducted in much less time than prior art procedures which calcine zirconium oxide, silicon oxide and a chromophore. Additionally, the resultant particles are sufficiently small to enable the pigment to be used immediately without need for a subsequent grinding or pulverization step, as typically required by the prior art.

Abstract: A capsule mixing device which comprises a motor suitable for powering a vibrating mixing arm with vibrating device connected to the motor having at one end thereof an arm for holding a capsule in place during mixing, and card actuator suitable for activating and controlling the motor at a predetermined speed for a predetermined length of time whereby materials contained within the capsule are mixed to a predetermined desired state by action of the vibrating device on the arm.

Abstract: The present invention provides a novel process for producing hydrogen peroxide. The inventive process utilizes an aqueous liquid reaction medium, a gaseous reactant stream comprising oxygen gas and hydrogen gas, and a catalyst bed comprising a catalyst which is effective for catalyzing the production of hydrogen peroxide from hydrogen and oxygen. The inventive process preferably comprises the step of conducting the gaseous reactant stream and the liquid reaction medium through the fixed catalyst bed in a manner such that a pulse-flow regime is established in the catalyst bed.

Abstract: A method and apparatus for automatically attaching end plates to the ends of a railroad tie. A web of material automatically is fed to a plate assembly position. A portion of the web of material is formed into an end plate at the plate assembly position. The formed end plate is removed from the web of material. The formed end plate then automatically is connected to one end of the railroad tie. The system also senses the size of the end of the railroad tie and the end plate formed at the plate assembly position automatically is sized to be about the same size as the sensed size of the end of the railroad tie.

Abstract: A rail-tie fastening assembly for connecting a rail having a rail flange to a tie comprising a rail seat assembly and a rail anchor. The rail seat assembly is connectable to the tie and includes an anchor slot and a seat hook assembly. The seat hook assembly is adapted to extend a distance over an upper surface of the rail flange. The rail anchor includes an anchor hook assembly adapted to extend over on the upper surface of the rail flange in an assembled position of the rail anchor to the rail seat assembly. The rail anchor is insertable through the anchor slot in the rail seat assembly to the assembled position. The seat hook assembly is spaced a distance from the upper surface of the rail in the assembled position of the rail anchor to the rail seat assembly. The anchor hook assembly engages one side of the rail flange and the seat hook assembly engages the opposite side of the rail flange to restrain lateral movement.

Abstract: The present invention provides improved devices for the production of electrical energy from mixtures of oxygen (i.e., pure oxygen, air, or a similar source of free oxygen) and fuel (i.e., hydrogen and/or a hydrogen-yielding fuel). The devices generally comprise: a first electrode means for receiving electrons; a second electrode means for supplying electrons; and an electrolytic diffusion means, positioned between the two electrode means, for conducting ions from one electrode means to the other electrode means and for conducting oxygen and fuel, oxygen and hydrogen, or oxygen and a combination of fuel and hydrogen from one electrode means to the other electrode means (FIG. 1). At least one of the electrode means is permeable. Additionally, the first electrode means comprises a catalytic material which is a highly active catalyst for the formation of H.sub.2 O.sub.2 from H.sub.2 and O.sub.2.

Abstract: A rail-tie fastening assembly for connecting a rail having a rail flange to a tie comprising a rail seat assembly and a rail anchor. Th rail seat assembly is connectable to the tie and includes an anchor slot and a seat hook assembly. The seat hook assembly is adapted to extend a distance over an upper surface of the rail flange. The rail anchor includes an anchor hook assembly adapted to extend over on the upper surface of the rail flange in an assembled position of the rail anchor to the rail seat assembly. The rail anchor is insertable through the anchor slot in the rail seat assembly to the assembled position. The seat hook assembly is spaced a distance from the upper surface of the rail in the assembled position of the rail anchor to the rail seat assembly. The anchor hook assembly engages one side of the rail flange and the seat hook assembly engages the opposite side of the rail flange to restrain lateral movement.

Abstract: A method and apparatus for removing soot from an exhaust gas stream wherein the exhaust gas stream is contacted with water to provide a substantially water saturated exhaust gas stream, particles and droplets in the water saturated gas stream then are electrically charged to produce a gas stream containing electrically charged particles and droplets, and an electric field is established for electrostatically attracting and de-entraining soot and soot containing water droplets from the gas stream containing electrically charged particles and droplets to provide a substantially soot free exhaust gas stream. The present invention includes a precipitator wherein the insulators are positioned in low dew point relatively clean locations and, in one embodiment, includes the use of the exhaust gas stream to maintain the temperature level of the insulators above dew point.

Abstract: A process for co-producing hydrogen peroxide and another useful product, namely either an oxalate ester or a carbonate ester product, is provided. The process comprises reacting a saturated monohydric alcohol with carbon monoxide and a quinone to form an oxalate ester or a carbonate ester product and hydroquinone. The hydroquinone is then reacted with oxygen to form hydrogen peroxide and a quinone. The quinone from the second reaction can be recycled to the alcohol-carbon monoxide first reaction.

Abstract: The present invention is directed to articles of manufacture comprising solid compacts, formed at elevated pressures, from homogenous, finely divided powders of spray dried water soluble inorganic compounds. The solid compacts are characterized by their readily water dissolvable, substantially nondusting and dense nature.