Patents Assigned to King Industries
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Patent number: 5275749Abstract: The invention relates to the lubricating compositions containing an N-acyl-N-alkoxyalkyl aspartate ester, optionally, in further combination with an anti-wear agent. The compositions exhibit corrosion inhibition and anti-wear properties, coupled with improved demulsibility.Type: GrantFiled: November 6, 1992Date of Patent: January 4, 1994Assignee: King Industries, Inc.Inventors: Robert L. Kugel, Werner J. Blank
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Patent number: 5187019Abstract: Amino resins, e.g., urea-formaldehyde and melamine-formaldehyde thermosetting resins, are cured with a latent catalyst which is a thermally-decomposable adduct of an aromatic sulfonic acid (e.g., p-toluene sulfonic acid) and a bicyclic oxazolidines (e.g., 1-aza-3,7-dioxa-5-ethylbicyclo (3.3.0) octane. The coating compositions can contain other conventional co-reactants, such as polyols, polyacids, alkyd resins, polyester resins, epoxies, acrylics and the like. Coatings containing the amino resin, co-reactant, and latent catalyst have an acceptable viscosity stability, cure rapidly at temperatures lower than some other latent catalysts, and produce films with no wrinkles.Type: GrantFiled: September 6, 1991Date of Patent: February 16, 1993Assignee: King Industries, Inc.Inventors: Leonard J. Calbo, Robert D. Coughlin
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Patent number: 5169564Abstract: A composition which is thermooxidatively stable is provided which comprises a normally thermooxidatively unstable organic compound and effective amount of a thermooxidative stabilizing composition comprising an oil soluble sulfonate of a metal selected from barium, calcium, magnesium, zinc or a mixture of any of the foregoing; an effective amount of at least one primary antioxidant; optionally an effective amount of a secondary antioxidant; and optionally a carrier for the thermooxidative stabilizing composition. A thermooxidative stabilizing composition and a method for stabilizing a normally unstable organic compound comprising the addition of an effective amount of the thermooxidative stabilizing composition are provided as well.Type: GrantFiled: April 21, 1989Date of Patent: December 8, 1992Assignee: King Industries, Inc.Inventors: Lawrence V. Gallacher, Alfen J. Gustavsen, Robert L. Kugel
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Patent number: 5133900Abstract: A composition which is thermooxidatively stable is provided which comprises a normally thermooxidatively unstable organic compound and effective amount of a thermooxidative stabilizing composition comprising an oil soluble sulfonate of a metal selected from barium, calcium, magnesium, zinc or a mixture of any of the foregoing; an effective amount of a stabilizer comprising an alkali or alkaline earth metal or zinc soap of an alkyl or alkenyl succinic acid, a partial ester thereof or a mixture of the foregoing; an effective amount of at least one primary antioxidant; optionally an effective amount of a secondary antioxidant; and optionally a carrier for the thermooxidative stabilizing composition. A thermooxidative stabilizing composition and a method for stabilizing a normally unstable organic compound comprising the addition of an effective amount of the thermooxidative stabilizing composition are provided as well.Type: GrantFiled: April 21, 1989Date of Patent: July 28, 1992Assignee: King Industries, Inc.Inventors: Lawrence V. Gallacher, Alfen J. Gustavsen, Robert L. Kugel
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Patent number: 5134205Abstract: This invention relates to certain polyamine hydroxyalkyl carbamate monomers, polymers and copolymers thereof and blends of the same with crosslinking film making agents and films thereof deposited on substrates.Type: GrantFiled: March 28, 1989Date of Patent: July 28, 1992Assignee: King IndustriesInventor: Werner J. Blank
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Patent number: 5102961Abstract: The present invention is directed to a polymeric isocyanate modified epoxy blocked sulfonic acid ester as a catalyst for the crosslinking of polymers having hydroxyl, carboxyl, and amide functional groups with a crosslinking agent and resin compositions containing the same. More particularly, the present invention is directed to a polymeric isocyanate modified epoxy blocked sulfonic acid ester with a molecular weight of about 1000 preferably prepared from a sulfonic acid, an epoxy resin and a mono- or di-isocyanate and resin compositions containing the polymeric isocyanate modified epoxy blocked sulfonic acid ester catalyst. The catalyst when used in the crosslinking or curing of hydroxyl, carboxyl or amide containing polymers with an acid catalyzed amino-formaldehyde crosslinking agent, such as hexamethoxymethylmelamine ("HMMA"), produced polymeric film coatings which have superior hardness, impact resistance, adhesion, improved blister resistance, salt spray characteristics and flexibility.Type: GrantFiled: January 5, 1989Date of Patent: April 7, 1992Assignee: King IndustriesInventor: Werner J. Blank
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Patent number: 5023367Abstract: This invention relates to a linear, low-molecular-weight polyester-based polyol having terminal primary hydroxyl groups, low viscosity, high solids content and having the structural formula: ##STR1## where n is 1 or 2 and at least 70% by weight is n=1, and m=2-10, said polyol being substantially free of cyclohexane dimethanol.Type: GrantFiled: May 22, 1989Date of Patent: June 11, 1991Assignee: King Industries, Inc.Inventors: Leonard J. Calbo, Jr., Lawrence V. Gallacher
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Patent number: 5023016Abstract: A concentrate composition is disclosed which comprises (a) a blend of (i) a metal sulfonate and (ii) an alkali or alkaline earth metal or zinc salt of a carboxylic acid and (b) a carrier. The composition is useful as a rust- and corrosion-inhibitor in a petroleum or synthetic base medium and is capable of maintaining metal sulfonate content at temperatures greater than 150.degree. C., e.g., 200.degree. C., for 20 hours.Type: GrantFiled: November 22, 1989Date of Patent: June 11, 1991Assignee: King Industries, Inc.Inventors: Lawrence V. Gallacher, Alfen J. Gustavsen, Robert L. Kugel
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Patent number: 4943656Abstract: This invention relates to novel processes for the production of enhanced yields of polyalkylaromatic polysulfonic acids. More particularly, the invention pertains to processes for sulfonating polyalkylaromatic compounds employing sulfuric acid treatment and recovering the polyalkylaromatic polysulfonic acid produced thereby after formation of a three phase system by the addition of controlled amounts of water, causing the polysulfonic acid to accumulate in the bottom layer, with which it is readily separated.Type: GrantFiled: July 19, 1984Date of Patent: July 24, 1990Assignee: King Industries, Inc.Inventors: Lawrence V. Gallacher, Harry N. Condos
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Patent number: 4922002Abstract: This invention relates to certain linear, low-molecular-weight polyester-based polyols having at least two hydroxyl groups, low viscosity, high solids content and having the structural formula: ##STR1## wherein R is a moiety derived from a saturated aliphatic polyhydric alcohol; n is 1 or 2, and at least about 50% by weight, of n is n=1; p is 0 to 4 inclusive and m is 2 to 10 inclusive; said polyol being substantially free of any unreacted polyhydric alcohol.Type: GrantFiled: May 22, 1989Date of Patent: May 1, 1990Assignee: King Industries, Inc.Inventors: Leonard J. Calbo, Jr., Lawrence V. Gallacher
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Patent number: 4910243Abstract: Dinonylnaphthalene sulfonic acid, derivatives thereof and mixtures of any of them, are effective as dispersants for nonaqueous fluid compositions containing finely divided solid particles when added in an effective amount less than that necessary to act as a catalyst for any organic binder resin comprising an aminoplast and coreactants in the composition or in formulations made from the composition.Type: GrantFiled: December 23, 1987Date of Patent: March 20, 1990Assignee: King Industries, Inc.Inventors: Rudolph Berndlmaier, Richard J. Shain
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Patent number: 4902821Abstract: This invention relates to a linear, low-molecular-weight polyester-based polyol having terminal primary hydroxyl groups, low viscosity, high solids content and having the structural formula: ##STR1## where n is 1 or 2 and at least 70% by weight is n=1, and m=2-10, said polyol being substantially free of cyclohexane dimethanol.Type: GrantFiled: December 27, 1982Date of Patent: February 20, 1990Assignee: King Industries, Inc.Inventors: Leonard J. Calbo, Jr., Lawrence V. Gallacher
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Patent number: 4900358Abstract: Compositions comprising alkanolamine salts of alkylaromatic sulfonic acids, a half acid ester of an alkyl- or alkenylsuccinic acid and a liquid medium comprising predominantly water, and, optionally, sufficient excess alkanolamine to maintain true solubility in all proportions with water provide thin, continuous, clear protective coatings for metallic substrates normally susceptible to corrosion.Type: GrantFiled: March 30, 1988Date of Patent: February 13, 1990Assignee: King Industries, Inc.Inventor: Lawrence V. Gallacher
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Patent number: 4895674Abstract: A concentrate composition is disclosed which comprises (a) a blend of (i) a metal sulfonate and (ii) an alkali or alkaline earth metal or zinc salt of a carboxylic acid and (b) a carrier. The composition is useful as a rust- and corrosion-inhibitor in a petroleum or synthetic base medium and is capable of maintaining metal sulfonate content at temperatures greater than 150.degree. C., e.g., 200.degree. C., for 20 hours.Type: GrantFiled: March 16, 1987Date of Patent: January 23, 1990Assignee: King Industries, Inc.Inventors: Lawrence V. Gallacher, Alfen J. Gustavsen, Robert L. Kugel
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Patent number: 4888441Abstract: This invention relates to certain linear, low-molecular-weight polyester-based polyols having at least two hydroxyl groups, low viscosity, high solids content and having the structural formula: ##STR1## wherein R is a moiety derived from a saturated aliphatic polyhydric alcohol; n is 1 or 2, and at least about 50% by weight, of n is n=1; p is 0 to 4 inclusive and m is 2 to 10 inclusive; said polyol being substantially free of any unreacted polyhydric alcohol.Type: GrantFiled: December 21, 1984Date of Patent: December 19, 1989Assignee: King Industries, Inc.Inventors: Leonard J. Calbo, Jr., Lawrence V. Gallacher
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Patent number: 4820830Abstract: This invention relates to certain polyamine hydroxyalkyl carbamate monomers, polymers and copolymers thereof and blends of the same with crosslinking film making agents and films thereof deposited on substrates.Type: GrantFiled: March 2, 1987Date of Patent: April 11, 1989Assignee: King Industries, Inc.Inventor: Werner J. Blank
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Patent number: 4662532Abstract: An object and bulk material holding container having a floor attached to corner units for supporting upright walls. The corner units have enclosed pockets for receiving lower ends of the posts joined to the walls. Cooperating notch and tabs on the posts and corner units function in conjunction with the lower ends of the posts to hold the walls in generally upright positions. Foldable gates extend adjacent posts. The gates can be folded down onto the top of the floor along with the walls to place the container in a collapsed storable condition. In one form the floor has laterally movable extensions that are locked in selected positions to change the width of the floor.Type: GrantFiled: November 4, 1985Date of Patent: May 5, 1987Assignee: Steel King Industries, Inc.Inventors: Fredric E. Anderson, Garry M. Grzesiak, Gary J. Rosenberg
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Patent number: 4255395Abstract: Improved solvent-extractants for the selective recovery of metal values from acidic aqueous media comprise solutions of 5-alkylbenzotriazoles in water-immiscible organic solvents. Extraction efficiency is enhanced by addition to the solvent-extractant of alkyl aromatic sulfonic acids, alkyl phosphoric acids or carboxylic acids. Especially important applications for the improved solvent-extractants are in the recovery of copper (II) from cobalt (II), copper (II) from nickel (II), copper (II) from iron (III), copper (II) from zinc (II), nickel (II) from cobalt (II), nickel (II) from zinc (II), nickel (II) from iron (III), iron (III) from magnesium (II), and cobalt (II) from zinc (II).Type: GrantFiled: August 30, 1979Date of Patent: March 10, 1981Assignee: King Industries, Inc.Inventors: Lawrence V. Gallacher, Rachelle M. Rydzik
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Patent number: 4251665Abstract: Amino resins, e.g., urea-formaldehyde and melamine-formaldehyde thermosetting resin systems, are cured with thermally-decomposable adducts of aromatic sulfonic acids and oxa-azacyclopentanes. The resin products cured with these adducts provide surface coatings having superior water resistance properties. The cured compositions can include other conventional ingredients capable of co-reacting with the amino resins, such as polyols, polyacids, alkyd resins, polyester resins, epoxies, acrylics and the like, to provide compositions curable to products having a wide range of properties.Type: GrantFiled: October 5, 1979Date of Patent: February 17, 1981Assignee: King Industries, Inc.Inventor: Leonard J. Calbo
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Patent number: 4200729Abstract: Amino resins, e.g., urea-formaldehyde and melamine-formaldehyde thermosetting resin systems, are cured with thermally-decomposable adducts of aromatic sulfonic acids and oxa-azacyclopentanes. The resin products cured with these adducts provide surface coatings having superior water resistance properties. The cured compositions can include other conventional ingredients capable of co-reacting with the amino resins, such as polyols, polyacids, alkyd resins, polyester resins, epoxies, acrylics and the like, to provide compositions curable to products having a wide range of properties.Type: GrantFiled: May 22, 1978Date of Patent: April 29, 1980Assignee: King Industries, IncInventor: Leonard J. Calbo