Patents Assigned to Kraton Polymers U.S. LLC
  • Patent number: 9304231
    Abstract: The present invention is directed to a composition for a gel useful in fiber optic cable which has the normal consistency of a grease but which, if desired, will become a rubbery coherent gel upon heating; a method of making the heat-fusible gel, and a method of making a spliceable fiber optic cable, and a fiber optic cable. In the broadest sense, a heat-fusible oil gel composition for fiber optic cable is disclosed, comprising: from 50 to 80 wt. % of a grease-like gel based on a hydrocarbon oil containing from 2 to 10 wt. % of an S-EB or S-EP diblock polymer, or a mixture of these diblock copolymers, and from 20 to 50 wt. % of a grease-like gel based on a polar oil containing from 5 to 25 wt. % of an S-EB-S or S-EP-S triblock copolymer, or a mixture of these triblock copolymers.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: April 5, 2016
    Assignee: Kraton Polymers U.S. LLC
    Inventor: Lydia Salazar
  • Publication number: 20160060437
    Abstract: In order to provide a rubber composition having high transparency, toughness and heat-resisting property, the present invention can provide a composition comprising a neodymium-catalyzed isoprene rubber (IR) component; and a rubber polymer (RB) component selected from the group consisting of BR, 1,2-polybutadiene rubber, and SBR, wherein the amount of IR is from about 5 to 95 mass parts with the proviso that the total amount of IR and RB is 100 mass parts, wherein the composition is substantially free of silica, wherein the composition has haze of less than about 20%, and wherein the composition has Type A Durometer hardness (0 sec) of about 30 or more.
    Type: Application
    Filed: August 24, 2015
    Publication date: March 3, 2016
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Fumio NAITO, Yoshikatsu Nakazawa, Norio Masuko, Arwin van der Waal
  • Patent number: 9249335
    Abstract: The invention relates to unique applications for the novel high melt flow, low viscosity, selectively hydrogenated styrene-butadiene-styrene (hSBS) or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene (hSBSS) block copolymers, wherein the melt flow rate of said block copolymer is at least 100 g/10 min at 230° C. under 2.16 kg mass according to ASTM D1238. These block copolymers are novel and have the highest melt flow rate of any styrenic block copolymer also possessing high strength and elasticity. It has applications that prior to the present invention were not normally possible due to the normal low melt flow rate of styrenic block copolymers. The present invention also encompasses various fields of use such as a fiberglass hSBS or hSBSS reinforced mat, low viscosity hSBS or hSBSS coatings for industrial uses, hot melt adhesives prepared from hSBS or hSBSS blended with polyalpha-olefins, and elastic film, fiber, and nonwoven constructions using hSBS or hSBSS.
    Type: Grant
    Filed: August 27, 2014
    Date of Patent: February 2, 2016
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Troy E. Wiegand, Kathryn Janelle Wright
  • Patent number: 9243163
    Abstract: The invention relates to unique applications for the novel high melt flow, low viscosity, selectively hydrogenated styrene-butadiene-styrene (hSBS) or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene (hSBSS) block copolymers, wherein the melt flow rate of said block copolymer is at least 100 g/10 min at 230° C. under 2.16 kg mass according to ASTM D1238. These block copolymers are novel and have the highest melt flow rate of any styrenic block copolymer also possessing high strength and elasticity. It has applications that prior to the present invention were not normally possible due to the normal low melt flow rate of styrenic block copolymers. The present invention also encompasses various fields of use such as a fiberglass hSBS or hSBSS reinforced mat, low viscosity hSBS or hSBSS coatings for industrial uses, hot melt adhesives prepared from hSBS or hSBSS blended with polyalpha-olefins, and elastic film, fiber, and nonwoven constructions using hSBS or hSBSS.
    Type: Grant
    Filed: August 27, 2014
    Date of Patent: January 26, 2016
    Assignee: Kraton Polymers U.S. LLC
    Inventor: Lydia Ann Salazar
  • Patent number: 9238770
    Abstract: The present invention relates to a synthetic cement that comprises a low viscosity monofunctional monomer, a dicyclopentadienyl moiety having a pendant free radical reactive species, 1,3-butyleneglycol dimethacrylate, unsaturated styrenic block copolymer, and a peroxide curing agent. Additionally it may include weighting agents depending on the circumstances of the well, as is well known to those skilled in the art. Other additional components such as oil based mud, suspending agents, Portland cement, acrylates and methacrylates, retardant curing additives, and clays may optionally be incorporated into the synthetic cement. The synthetic cement is activated by heat, for example, and can be crafted to set within a certain time frame, for example in 4 hours, so that it pumpable for as long as need be, and then be set to seal the well in the manner desired.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: January 19, 2016
    Assignee: Kraton Polymers U.S. LLC
    Inventor: Erin Murphy
  • Publication number: 20160009907
    Abstract: In order to provide a rubber composition having high transparency and toughness, the present invention can provide a crosslinked rubber composition, being substantially free of silica, comprising a first olefin polymer having refractive index of between 1.500 to 1.525 at 23 degree C.; and a second olefin polymer which is different from the first olefin polymer, wherein the composition has haze of 20% or less on 2 mm thick sheet, measured according to JIS K7136, and wherein the composition has Type A Durometer hardness (0 sec) of 35 or more, measured according to JIS K6253.
    Type: Application
    Filed: January 27, 2014
    Publication date: January 14, 2016
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Fumio NAITO, Yoshikatsu Nakazawa
  • Publication number: 20150375199
    Abstract: A rotary enthalpy exchange wheel having a rotatable wheel with air passageways extending from a front side to a back side for passing air streams therethrough. The wheel has a rigid substrate which is coated or laminated with a desiccant composition having a sulfonated block copolymer. The sulfonated block copolymer has at least one end block A and at least one interior block B, wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate ester functional groups based on the number of monomer units.
    Type: Application
    Filed: June 26, 2014
    Publication date: December 31, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Kuitian Tan, Steven Huynh
  • Patent number: 9216405
    Abstract: A rotary enthalpy exchange wheel having a rotatable wheel with air passageways extending from a front side to a back side for passing air streams therethrough. The wheel has a rigid substrate which is coated or laminated with a desiccant composition having a sulfonated block copolymer. The sulfonated block copolymer has at least one end block A and at least one interior block B, wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate ester functional groups based on the number of monomer units.
    Type: Grant
    Filed: June 26, 2014
    Date of Patent: December 22, 2015
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Kuitian Tan, Steven Huynh
  • Patent number: 9182560
    Abstract: A curable polymeric composition is herein disclosed. According to one embodiment, a curable polymeric composition comprises a thermoplastic block copolymer containing at least two polymer blocks A separated by at least one polymer block B. Each polymer block A is primarily a poly(monovinyl aromatic hydrocarbon) block, and polymer block B includes hydrogenated conjugated didne. The solid curable polymeric composition further comprises a curable functional compound compatible with polymer block A. The solid curable polymeric composition optionally comprises an initiator, a plasticizer, an antioxidant; a tackifyer and an aromatic resin.
    Type: Grant
    Filed: February 18, 2011
    Date of Patent: November 10, 2015
    Assignee: KRATON POLYMERS U.S. LLC
    Inventors: Martine Jeanne Dupont, Duco Bodt
  • Publication number: 20150290637
    Abstract: A functionalized block copolymer polymerized using vinylbenzylamino derivative monomers for use in such applications as anionic exchange membranes.
    Type: Application
    Filed: June 9, 2015
    Publication date: October 15, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Carl L. Willis, Adrie A. van der Huizen
  • Publication number: 20150284606
    Abstract: A block copolymer comprising: at least one monoalkenyl arene monomer polymer block (A) and copolymer block (B) containing myrcene, said copolymer block B also including: a) at least one conjugated diene monomer having a lower molecular weight than myrcene, or b) at least one monoalkenyl arene monomer, or c) a mixture of a) and b). The polymer block A may be a copolymer block. When the polymer block A is a copolymer block, both block A and the copolymer myrcene block copolymer B can have a random, tapered or a controlled distribution configuration of comonomers. The block copolymer can be selectively or exhaustively hydrogenated. The block copolymer may be used in making adhesives and vibration damping compositions.
    Type: Application
    Filed: April 2, 2014
    Publication date: October 8, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Marianne STOL, Martine DUPONT
  • Publication number: 20150284605
    Abstract: The invention relates to a novel block copolymer comprising at least one polymeric monoalkenyl arene block and at least one polymeric myrcene block having a low and stable viscosity and having good adhesive properties when used in an adhesive composition or as a damping material. An adhesive composition is also described, preferably containing an SMS triblock optionally mixed with an SM diblock. The adhesive composition comprises: 1) a block copolymer having at least one polymeric monoalkenyl arene block and at least one polymeric myrcene block; 2) a tackifier; 3) optional plasticizer; and 4) optionally a stabilizer. Compared with adhesive compositions comprising SIS block copolymers, those comprising SMS block copolymers have lower and more stable viscosity.
    Type: Application
    Filed: April 2, 2014
    Publication date: October 8, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Martine DUPONT, Marianne STOL
  • Patent number: 9115296
    Abstract: The present invention is directed to bituminous emulsions comprising bitumen, water, one or more emulsifiers systems and a diblock copolymer including one block of a monovinylaromatic hydrocarbon and one block of a conjugated diene, wherein the conjugated diene has a peak molecular weight from 30,000 to 78,000 and a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block. A block copolymer comprising at least two blocks of monovinylaromatic hydrocarbon and at least one block of conjugated diene, the block copolymer selected from linear triblock copolymers having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, multiarm coupled block copolymers having a peak molecular weight that is 1.5 to 9.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: August 25, 2015
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Robert Q. Kluttz, Keith E. Stephens, Willem C. Vonk, Jan Korenstra
  • Publication number: 20150219796
    Abstract: The present invention is directed to a composition for a gel useful in fiber optic cable which has the normal consistency of a grease but which, if desired, will become a rubbery coherent gel upon heating; a method of making the heat-fusible gel, and a method of making a spliceable fiber optic cable, and a fiber optic cable. In the broadest sense, a heat-fusible oil gel composition for fiber optic cable is disclosed, comprising: from 50 to 80 wt. % of a grease-like gel based on a hydrocarbon oil containing from 2 to 10 wt. % of an S-EB or S-EP diblock polymer, or a mixture of these diblock copolymers, and from 20 to 50 wt. % of a grease-like gel based on a polar oil containing from 5 to 25 wt. % of an S-EB-S or S-EP-S triblock copolymer, or a mixture of these triblock copolymers.
    Type: Application
    Filed: February 4, 2014
    Publication date: August 6, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventor: Lydia Salazar
  • Publication number: 20150191637
    Abstract: The present invention provides methods and systems for a hot melt pressure sensitive adhesive and thermoset that comprises from about 5 to about 50 wt. % of a block copolymer, from about 0 to about 75 wt. % of a tackifying resin, from about 0 to about 45 wt. % of an oil, and from about 0 to about 3 wt. % of an antioxidant.
    Type: Application
    Filed: December 30, 2014
    Publication date: July 9, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventor: Jason Drew Gillen
  • Patent number: 9061254
    Abstract: A functionalized block copolymer polymerized using vinylbenzylamino derivative monomers for use in such applications as anionic exchange membranes.
    Type: Grant
    Filed: July 16, 2014
    Date of Patent: June 23, 2015
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Carl L. Willis, Adrie A. van der Huizen
  • Publication number: 20150148467
    Abstract: The present invention comprises a laser sintering powder composition comprising: greater than 30 to 90 wt. % of a hydrogenated styrene-butadiene/styrene-styrene (S(EB/S)S) block copolymer or a hydrogenated styrene-butadiene-styrene (SEBS) block copolymer, or a mixture thereof; 10 to less than 70 wt. % of a C3 to C8 polyolefin, or a mixture of two or more polyolefins, 0 to 20 wt. % mineral oil, 0.2 to 1 wt. % of one or more antioxidants, 0 to 5 wt. % colorant, 0 to 20 wt. % surface modifying agent, wherein the total of the above ingredients is 100 wt. %, and optionally 0 to 5 parts by weight of a powder flow agent, based on 100 weight parts of the laser sintering powder composition. The composition has a melt flow rate of at least 20 grams/10 min. at 190° C./2.16 kg mass. The invention also comprises laser sintered articles and methods for making the same.
    Type: Application
    Filed: November 24, 2014
    Publication date: May 28, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Marcus GREGER, Freddy Vervoort
  • Publication number: 20150148488
    Abstract: The present invention provides for a thermoplastic composition that includes from about 40 to about 95 wt. % of a polyamide, and from about 5 to about 30 wt. % of at least one functionalized, selectively hydrogenated block copolymer, including at least one polymer block A, the A block being at least predominantly a polymerized alkenyl arene block, and at least one selectively hydrogenated polymer block B, the B block prior to hydrogenation being at least predominantly a polymerized conjugated diene block to which grafted thereto on the average an effective amount of monomer acids or their derivatives, including maleic acid, succinic acid, itaconic acid, fumaric acid, and acrylic acid. The composition optionally includes from about 5 to about 50 wt. % of a selectively hydrogenated block copolymer.
    Type: Application
    Filed: November 25, 2013
    Publication date: May 28, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Marcus GREGER, Hendrik DE GROOT
  • Publication number: 20150125682
    Abstract: A fuse molded modeling three dimensional article having areas of dissimilar or different hardness is described, wherein one of said areas is hard and is plastic, metal, glass, wood, concrete, rock, or mixtures thereof, and another of said areas is a less hard area comprising a controlled distribution hydrogenated styrenic block copolymer composition. Although the metal, glass, wood, concrete, and rock are not fuse moldable material, the plastic and the controlled distribution hydrogenated styrenic block copolymer composition are. Thus the scope of the invention is meant to include articles where only one area or layer of the article is fuse molded, or wherein both the hard area/layer and the soft area/layer is formed via a fuse molded technique.
    Type: Application
    Filed: November 1, 2013
    Publication date: May 7, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventor: Marcus GREGER
  • Publication number: 20150104663
    Abstract: The invention concerns an olefinically unsaturated radial styrenic block copolymer having the general formula A-B—Y—(B-A)n wherein each A is independently a polymer block composed of at least 90 mol. % of an alkenyl aromatic hydrocarbon, each B is independently a polymer block composed of at least 90 mol. % of one or more conjugated dienes, Y is the remnant of a coupling agent, and n is an integer from 2 to 5. The invention is also an improved vulcanizer-free latex comprising water and the olefinically unsaturated radial styrenic block copolymer. Moreover, the invention concerns a process for preparing articles by coagulation dipping from the improved latex and dipped goods made from such latex.
    Type: Application
    Filed: October 9, 2014
    Publication date: April 16, 2015
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Wouter DE JONG, Maarten TROMP