Patents Assigned to Kumiai Chemical Industry Co., Ltd.
  • Patent number: 4163661
    Abstract: Trifluoromethylphenoxy phenoxy crotonic acid derivatives of the formula ##STR1## wherein X represents hydrogen or halogen atom, and R represents an alkyl, haloalkyl, alkenyl haloalkenyl or alkynyl group are disclosed. These compounds disclose herbicidal activity.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: August 7, 1979
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Kazuo Jikihara, Shigekazu Itoh, Shuichi Takayama, Koichi Sato, Ichiro Kimura, Isao Chiyomaru
  • Patent number: 4123554
    Abstract: The present invention relates to a compound having the following general formula (I): ##STR1## wherein X stands for a halogen atom or a methyl radical; and R stands for an alkyl or alkoxy radical containing 3 to 6 carbon atoms provided that R represents an alkyl radical containing 3 to 6 carbon atoms when X is a methyl radical, a process for the production thereof, an agricultural composition containing the said compound as an effective component, and a method for preventing and healing the diseases of the plant and in soil using the said compound.
    Type: Grant
    Filed: November 11, 1976
    Date of Patent: October 31, 1978
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Seigo Kawada, Yoshitaka Suda, Shigeru Tsuchiya, Nobuya Ohta, Norimichi Muramatsu, Kazuo Nishio
  • Patent number: 4105693
    Abstract: 2-Alkylbenzanilide is produced by reacting an alkyl 2-alkylbenzoate having the formula ##STR1## wherein X represents a lower alkyl group and R represents a lower alkyl group with an aniline having the formula ##STR2## wherein Y represents hydrogen atom, an alkoxy, alkenyloxy, alkynyloxy, benzyloxy or halobenzyloxy group in the presence of an alcoholate in a solvent which is hardly azeotropically distilled with the by-product of alcohol.
    Type: Grant
    Filed: April 22, 1976
    Date of Patent: August 8, 1978
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Isao Chiyomaru, Seigo Kawada, Kiyoshi Takita
  • Patent number: 4101670
    Abstract: A composition useful as herbicides, germicides, and acaricides without showing toxicity to men and beasts as well as to fish and shellfishes containing as the active ingredient the compound represented by the general formula ##STR1## wherein R represents a lower alkyl group; R' represents a group shown by the formula ##STR2## (WHEREIN Y represents a halogen atom, an alkyl group, an alkoxy group, a nitro group, a methylthio group, or a trifluoromethyl group and n is an integer of 0 to 3); X represents an oxygen atom or a sulfur atom; and m is an integer of 3 to 6.
    Type: Grant
    Filed: August 16, 1976
    Date of Patent: July 18, 1978
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Kunihiko Fujimori, Kuniaki Shimizu, Haruki Ogawa
  • Patent number: 4089964
    Abstract: Method of controlling fungal diseases in plants and Compositions effective therefor are shown. The method comprises the steps of applying an effective amount of a substituted derivative of 1,1,-dichloroalkene-1 of the general formulaR--X--(CH.sub.2).sub.n --CH.dbd.CCl.sub.2In this generalized formula R is an alkyl group having 1 to 12 carbon atoms, a phenyl group, a di-chloro-phenyl group, a methyl-phenyl group, a nitro-phenyl group, a benzyl group, a chloro-benzyl group, a di-chloro-benzyl group, a methyl-benzyl group, a phenethyl group or a benzothiazolyl group; X is sulfur, a sulfinyl group or a sulfonyl group; and n is an integer of 3,5, and 7.
    Type: Grant
    Filed: March 28, 1977
    Date of Patent: May 16, 1978
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Hironari Sugiyama, Isao Chiyomaru, Itsuki Okuda, Hisaaki Yamamoto, Hideo Ito
  • Patent number: 4089884
    Abstract: A novel class of compounds, tris(triorganosilylalkyl) phosphites, represented by the general formula [R.sub.3 Si(CH.sub.2).sub.n O].sub.3 P where R is a monovalent hydrocarbon group and n is 1, 2 or 3. These novel compounds may be synthesized by dehydrochlorination reaction between a triorganosilyl-substituted alkanol and phosphorus trichloride in the presence of a tertiary amine. They have useful values as agricultural chemicals because of their biological activities and also as intermediate compounds in the preparation of certain medicines and chemicals.
    Type: Grant
    Filed: July 12, 1977
    Date of Patent: May 16, 1978
    Assignees: Shin-Etsu Chemical Co., Kumiai Chemical Industry Co., Ltd.
    Inventors: Toshio Shinohara, Masatoshi Arai, Kenichi Kojima
  • Patent number: 4071534
    Abstract: A process for producing a mono- or di-alkali metal salt or alkaline earth metal salt of L-ascorbic acid-2-sulfate which comprises reacting L-ascorbic acid in which the 5 and 6 positions are protected by a ketone or aldehyde, with dimethyl formamide-sulfur trioxide complex, which is produced by a reaction of dimethyl formamide with chlorosulfonic acid and a dehydrohalogenating agent such as pyridine, triethylamine, dimethyl aniline, which is a tertiary amine so as to produce a sulfate, and neutralizing the product with an alkali metal hydroxide or an alkaline earth metal hydroxide, and removing said protecting aldehyde or ketone at 5- and 6-positions.
    Type: Grant
    Filed: August 3, 1976
    Date of Patent: January 31, 1978
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Eiichi Hayashi, Kiyoshi Takita, Hironari Sugiyama, Yukio Nezu
  • Patent number: 4070377
    Abstract: A process for producing a mono- or di-alkali metal salt or alkaline earth metal salt of L-ascorbic acid-2-sulfate which comprises reacting L-ascorbic acid in which the 5 and 6 positions are protected by a ketone or aldehyde, with dimethyl formamide-sulfur trioxide complex, and neutralizing the product with an alkali metal hydroxide or an alkaline earth metal hydroxide, and removing said protecting aldehyde or ketone at 5-and 6-positions.
    Type: Grant
    Filed: August 3, 1976
    Date of Patent: January 24, 1978
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Eiichi Hayashi, Kiyoshi Takita, Hironari Sugiyama, Yukio Nezu
  • Patent number: 4032663
    Abstract: Complex enzymes which can lyse the cell wall of a variety of microorganisms such as bacteria, fungi, yeast, Basidiomycetes and chlorella are produced and recovered from cultivation of Pellicularia sasakii or Pellicularia filamentosa.
    Type: Grant
    Filed: April 9, 1976
    Date of Patent: June 28, 1977
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Reisuke Kobayashi, Hironari Sato, Kiyoshi Takita, Nobuo Toyama
  • Patent number: 4028091
    Abstract: A herbicidal composition comprises a bipyridylium salt and a thiocarbamate having the formula ##STR1## wherein R and R.sub.1 each represent a lower alkyl group which in combination with each other can form a heterocyclic ring with the N atom; R.sub.2 represents ##STR2## AND X represents a halogen atom or a lower alkyl group; and n represents 0, 1 or 2.
    Type: Grant
    Filed: September 2, 1975
    Date of Patent: June 7, 1977
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Kazuo Jikihara, Shinichi Iori, Ichiro Kimura, Kyoichi Adachi
  • Patent number: 4022605
    Abstract: A halocyanoacetamide compound having the formula: ##STR1## wherein X is a halogen such as Cl, F, Br and I; Y represents a halogen such as chlorine, fluorine, bromine and iodine or hydrogen atom; andR represents a hydrogen atom or a lower alkyl group containing from 1 to 8 carbon atoms, is stabilized with an organic carboxylic acid or a diol.
    Type: Grant
    Filed: June 25, 1975
    Date of Patent: May 10, 1977
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Kazumi Konya, Yoshihiro Konagai, Makoto Muto, Hironari Sato, Yoshio Takahashi
  • Patent number: 3985804
    Abstract: An agricultural germicide having the formula ##SPC1##Wherein R represents C.sub.1.sub.-12 alkyl, alkenyl, alkynyl, benzyl or chlorobenzyl.
    Type: Grant
    Filed: August 15, 1975
    Date of Patent: October 12, 1976
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Isao Chiyomaru, Seigo Kawada, Kiyoshi Takita
  • Patent number: 3978091
    Abstract: 2,4-Dimethyl-3-carboxanilido- or naphthyl amido-furan of the formula ##SPC1##Involving the reaction of ##SPC2##Or ##SPC3##Wherein X represents a halogen atom, an alkyl group, hydroxyl group, an alkoxyl group, an alkenyloxy group, trifluoromethyl group, phenyl group, cyano group, acetyl group, a metal substituted hydroxy group or a combination thereof are useful as agricultural germicides, fungicides, insecticides and nematodicides.
    Type: Grant
    Filed: February 27, 1974
    Date of Patent: August 31, 1976
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Shigeru Tsuchiya, Yoshitaka Suda, Isao Chiyomaru, Seigo Kawada, Kiyoshi Takita
  • Patent number: 3978228
    Abstract: Noxious fungi on plants are controlled by applying thereto compounds having the general formula ##EQU1## wherein X and X' are halogen atoms, R is hydrogen atom or methyl group and R' is alkyl, haloalkyl, phenyl group or phenyl group substituted with at least one of halogen atom, alkyl group, alkoxy group and nitro group.
    Type: Grant
    Filed: March 24, 1975
    Date of Patent: August 31, 1976
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Eiichi Yoshinaga, Shigeki Wakamori, Gosaburo Dowke, Kiyoshi Takita
  • Patent number: 3969189
    Abstract: Complex enzymes which can lyse the cell wall of a variety of microorganisms such as bacteria, fungi, yeast, Basidiomycetes and chlorella are produced and recovered from cultivation of Pellicularia sasakii or Pellicularia filamentosa.
    Type: Grant
    Filed: November 8, 1974
    Date of Patent: July 13, 1976
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Reisuke Kobayashi, Hironari Sato, Kiyoshi Takita, Nobuo Toyama
  • Patent number: 3962457
    Abstract: Parasitic mites are eliminated from plants by a method which comprises applying an effective amount of S-.beta.-naphthylmethyl-N,N-dimethylthiolcarbamate to said plants.
    Type: Grant
    Filed: January 24, 1975
    Date of Patent: June 8, 1976
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Shigeki Wakamori, Haruki Ogawa, Masayoshi Yamaguchi, Seigo Kanamori
  • Patent number: 3961049
    Abstract: Novel thioureidobenzene compounds having the general formula ##EQU1## wherein R and R' are lower alkyl groups and X is oxygen or sulfur atom is prepared by reacting a compound having the general formula ##EQU2## wherein Y is chlorine or bromine, with a compound having the general formula ##EQU3## wherein M is ammonium or an alkali metal. These compounds have high miticidal and fungicidal activity.
    Type: Grant
    Filed: January 10, 1975
    Date of Patent: June 1, 1976
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Tetsuo Horii, Isao Chiyomaru, Seigo Kawada, Kiyoshi Takita
  • Patent number: 3937840
    Abstract: An agricultural germicide having the formula ##SPC1##Wherein R represents C.sub.1-12 alkyl, alkenyl, alkynyl, benzyl or chlorobenzyl.
    Type: Grant
    Filed: July 17, 1974
    Date of Patent: February 10, 1976
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Isao Chiyomaru, Seigo Kawada, Kiyoshi Takita
  • Patent number: RE29826
    Abstract: A halocyanoacetamide compound having the formula: ##STR1## wherein X is a halogen such as Cl, F, Br and I; Y represents a halogen such as chlorine, fluorine, bromine and iodine or hydrogen atom; andR represents a hydrogen atom or a lower alkyl group containing from 1 to 8 carbon atoms, is stabilized with an organic carboxylic acid or a diol.
    Type: Grant
    Filed: October 5, 1977
    Date of Patent: November 7, 1978
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Kazumi Konya, Yoshihiro Konagai, Makoto Muto, Hironari Sato, Yoshio Takahashi