Patents Assigned to Kunming University of Science and Technology
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Patent number: 10960391Abstract: The present invention discloses a method and system of recovering elemental sulfur and regenerating the catalyst for a sulfur-deposited catalyst, including immersing the sulfur-deposited catalyst in the ammonium sulfide solution, the leaching reaction under normal pressure and temperature, replacing the ammonium sulfide solution and immersing again for extraction for the same time; collecting the leachate of the two steps, conducting gas stripping of the elemental sulfur by adopting the high-temperature nitrogen gas, condensing the tail gas of gas stripping, subjecting to a purification treatment and then discharging, with the liquor condensate being the ammonium sulfide solution. Finally, the solid in the leachate is filtered, washed and dried after the gas stripping to obtain the elemental sulfur; and the washing and drying of catalysts that has been subjected to the two times of immersion and extraction obtain the regenerated catalysts.Type: GrantFiled: November 26, 2019Date of Patent: March 30, 2021Assignee: KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Ping Ning, Qiulin Zhang, Tengxiang Zhang, Yaqing Zhang, Huimin Wang
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Patent number: 10843131Abstract: The present invention relates to a system and method for desulfurization and denitrification integrated treatment and recycling of flue gas by using red mud, and belongs to the recycling and environmental protection technology field. The system includes a desulfurization spray tower, an ozone generator, a denitration spray tower, a slurry mixing tank, a slurry storage tank, a vacuum filter, an ammonia water neutralization tank, an aluminum hydroxide precipitation tank, an ammonia water tank, an aluminum hydroxide storage tank, a filter press, an ammonia distillation tower, a dephlegmator, a cooler, a concentrated ammonia water storage tank, a gypsum precipitation tank, and an anaerobic biochemical pool. In the present invention, red mud slurry is used for desulfurization and denitrification treatment of flue gas to remove SO2 and NO in the flue gas, so that SO2 and NO in the flue gas reach an emission standard.Type: GrantFiled: December 6, 2019Date of Patent: November 24, 2020Assignees: Kunming University of Science and Technology, Pingxiang Huaxing Environmental Protection Engineering Technology Co., Ltd.Inventors: Ping Ning, Liangtao Yin, Qiulin Zhang, Lijuan Jia, Zaifei Yin, Bo Li, Shaoming Li, Bin Li
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Patent number: 10814273Abstract: The invention discloses a method for simultaneously removing SO2 and NOx in flue gas: uniformly mixing a water-soluble ruthenium salt with ammonia water to obtain an aqueous solution of a ruthenium-amine complex; subjecting the flue gas and the aqueous solution of the ruthenium-amine complex to a countercurrent contact reaction under the temperature of 5-60° C., pH of 7.5-12 to obtain a solution A and purified gas; discharging the solution A of the step (2) into a crystallization tank to crystallize and separate an ammonium salt to obtain a solution B, returning the solution B to replace the aqueous solution of the ruthenium-amine complex. The invention utilizes the ruthenium-amine complex having a strong capability of complexing with NO as well as residual oxygen in the flue gas to carry out liquid phase catalytic oxidation to convert the NOx into ammonium nitrate, and the removal efficiency of the NOx and the SO2 is high.Type: GrantFiled: October 15, 2019Date of Patent: October 27, 2020Assignee: Kunming University of Science and TechnologyInventors: Yingjie Li, Senlin Tian, Jianhong Huang, Xuewei Hu, Ping Ning
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Publication number: 20200323051Abstract: The present invention provides a microwave-based high-throughput material processing device with a concentric rotary chassis. The device includes a microwave source generator, a microwave reaction chamber, and a temperature acquisition device. The microwave reaction chamber is provided with a rotary table, a thermal insulation barrel and a crucible die. The thermal insulation barrel is disposed on the rotary table, and the crucible die is disposed in the thermal insulation barrel. The crucible die is provided with a plurality of first grooves, and the first grooves are evenly distributed on a first circumference. A plurality of first fixing holes are disposed on a top of the thermal insulation barrel, and the first fixing holes are disposed corresponding to the first grooves. A first acquisition hole is disposed on the top of the microwave reaction chamber, and the first acquisition hole is located right above the first circumference.Type: ApplicationFiled: April 3, 2020Publication date: October 8, 2020Applicant: Kunming University of Science and TechnologyInventors: Lei Xu, Jinhui Peng, Shenghui Guo, Libo Zhang, Zhaohui Han, Yi Xia, Shaohua Ju, Shanju Zheng, Shiwei Li, Zemin Wang, Zhang Xu
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Publication number: 20200299207Abstract: The present invention discloses a method for ammonium-enhanced flue gas desulfurization (FGD) by using red mud slurry. The method specifically includes: crushing red mud, sieving the crushed red mud, slurrying the red mud, conducting aeration treatment, adding an ammonium salt and/or ammonia, and conducting natural sedimentation to obtain pretreated red mud slurry and pretreated red mud liquor; adding an ammonium salt and/or ammonia to the slurry, adding water and conducting uniform mixing, conducting pre-FGD, conducting deep desulfurization on treated flue gas by using the pretreated red mud liquor, and directly discharging desulfurized flue gas; and charging the pretreated red mud slurry and the pretreated red mud liquor obtained after the treatment to a replacement tank below, adding lime milk to the replacement tank, conducting stirring and natural sedimentation, conducting soilization on subnatant thick red mud slurry, and refluxing the supernatant to a red mud aeration tank.Type: ApplicationFiled: March 17, 2020Publication date: September 24, 2020Applicant: Kunming University of Science and TechnologyInventors: Ping NING, Senlin TIAN, Jianhong HUANG, Qin ZHANG, Xuewei HU, Bin LI
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Publication number: 20200299145Abstract: The present invention discloses a method for aluminum-enhanced dealkalization of red mud and separation and recovery of aluminum and iron. The method includes: dissolving red mud in water, introducing excessive SO2, introducing O2 for aeration, and refluxing part of alkaline leachate after filtering; when pH of a red mud mixture decreases to below 3, washing and filtering the red mud mixture, adding NaOH to acidic leachate to adjust its pH to a strongly alkaline level, aging and filtering the leachate, treating filter residue to recover Fe2O3, and refluxing part of alkaline leachate after filtering to the red mud mixture; and adjusting pH of the remaining alkaline leachate after filtering to a weakly acidic level, and conducting filtering to recover aluminum.Type: ApplicationFiled: March 17, 2020Publication date: September 24, 2020Applicant: Kunming University of Science and TechnologyInventors: Ping NING, Senlin TIAN, Jianhong HUANG, Yunjian CHEN, Xuewei HU, Yingjie LI
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Patent number: 10730010Abstract: The invention is a device and method for purifying sulfur dioxide and nitrogen oxide in flue gas with an electrolysis-chemical advanced oxidation enhanced ammonia method. The device includes a thermal activation reactor, ammonium hydroxide storage tank, absorption tower, electrolytic bath and crystallization separator. The method takes raw material part of an ammonium sulfate solution that is a reaction product of ammonia and sulfur oxide in flue gas, and an ammonium persulfate solution prepared by electrolysis of an electrolytic bath as an oxidant to enhance the efficiency of purifying sulfur dioxide and nitrogen oxide in the flue gas with an ammonia method. A thermal activation reactor activates an ammonium persulfate containing solution to generate a strong oxidizing SO4.?, so that NOx and SO2 in the flue gas may be more efficiently converted into a product having higher solubleness for enhanced removal of sulfur dioxide and nitrogen oxide in the flue gas.Type: GrantFiled: July 18, 2019Date of Patent: August 4, 2020Assignee: Kunming University of Science and TechnologyInventors: Senlin Tian, Yuxin Song, Jianhong Huang, Xuewei Hu, Yingjie Li, Ping Ning
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Patent number: 10731266Abstract: The present disclosure provides a composite anode unit, comprising: a metal core rod; a metal layer coated on the metal core, wherein the metal layer is lead or lead alloy; a conductive ceramic layer coated on the metal layer, wherein the conductive ceramic layer comprises ?-PbO2—Al2O3 composite oxide; an active ceramic layer is coated on the conductive ceramic layer, wherein the active ceramic layer comprises ?-MnO2—Ti4O7 composite oxide. Methods for preparing the composite anode unit and an anode plate made from the composite anode unit are also provided.Type: GrantFiled: December 18, 2017Date of Patent: August 4, 2020Assignees: KUNMING HENDERA SCIENCE AND TECHNOLOGY CO., LTD., KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY, JINNING HENDERA SCIENCE AND TECHNOLOGY CO., LTD.Inventors: Zhongcheng Guo, Hui Huang, Buming Chen, Xuelong Li, Panlong Zhu, Jin Dong, Mingxi Pan, Feng Huang, Taixiang Huang, Ning Tan, Chutao Huang
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Publication number: 20200179872Abstract: The present invention relates to a system and method for desulfurization and denitrification integrated treatment and recycling of flue gas by using red mud, and belongs to the recycling and environmental protection technology field. The system includes a desulfurization spray tower, an ozone generator, a denitration spray tower, a slurry mixing tank, a slurry storage tank, a vacuum filter, an ammonia water neutralization tank, an aluminum hydroxide precipitation tank, an ammonia water tank, an aluminum hydroxide storage tank, a filter press, an ammonia distillation tower, a dephlegmator, a cooler, a concentrated ammonia water storage tank, a gypsum precipitation tank, and an anaerobic biochemical pool. In the present invention, red mud slurry is used for desulfurization and denitrification treatment of flue gas to remove SO2 and NO in the flue gas, so that SO2 and NO in the flue gas reach an emission standard.Type: ApplicationFiled: December 6, 2019Publication date: June 11, 2020Applicants: KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY, PINGXIANG HUAXING ENVIRONMENTAL PROTECTION ENGINEERING TECHNOLOGY CO., LTD.Inventors: Ping NING, Liangtao YIN, Qiulin ZHANG, Lijuan JIA, Zaifei YIN, Bo LI, Shaoming LI, Bin LI
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Publication number: 20200171433Abstract: The present invention discloses a method and device for purifying CO from a flue gas and coupling-suppressing white fog, where the flue gas is introduced into a ceramic honeycomb carrier coated with a CO catalyst, sufficient O2 in the flue gas is utilized to generate CO2 from a low concentration of CO through catalytic oxidation, so as to achieve the purpose of purifying CO, and the flue gas is heated up by the heat released from the catalytic oxidation reaction to more than 110° C. and then discharged into the air, which meets the temperature requirement of coupling-suppressing white fog; the device includes a CO concentration sensor, a temperature sensor, a CO catalytic oxidation layer, an oxidation reaction tower, a desulfurized sintering flue gas, a packing layer I, a packing layer II, a chimney, and a solenoid valve II.Type: ApplicationFiled: December 3, 2019Publication date: June 4, 2020Applicants: KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY, PINGXIANG HUAXING ENVIRONMENTAL PROTECTION ENGINEERING TECHNOLOGY CO., LTD.Inventors: Ping NING, Qiulin ZHANG, Guangcheng WEI, Dehua ZHANG, Jing WANG, Xin LIU, Huimin WANG, Bo LI, Shaoming LI, Bin LI
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Publication number: 20200129923Abstract: The invention discloses a method for simultaneously removing SO2 and NOx in flue gas: uniformly mixing a water-soluble ruthenium salt with ammonia water to obtain an aqueous solution of a ruthenium-amine complex; subjecting the flue gas and the aqueous solution of the ruthenium-amine complex to a countercurrent contact reaction under the temperature of 5-60° C., pH of 7.5-12 to obtain a solution A and purified gas; discharging the solution A of the step (2) into a crystallization tank to crystallize and separate an ammonium salt to obtain a solution B, returning the solution B to replace the aqueous solution of the ruthenium-amine complex. The invention utilizes the ruthenium-amine complex having a strong capability of complexing with NO as well as residual oxygen in the flue gas to carry out liquid phase catalytic oxidation to convert the NOx into ammonium nitrate, the removal efficiency of the NOx and the SO2 is high.Type: ApplicationFiled: October 15, 2019Publication date: April 30, 2020Applicant: Kunming University of Science and TechnologyInventors: Yingjie Li, Senlin Tian, Jianhong Huang, Xuewei Hu, Ping Ning
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Patent number: 10632396Abstract: The present disclosure discloses a microwave flash evaporation process and apparatus and uses thereof. A microwave flash evaporation process, wherein the process makes integration of those technologies for liquid spraying, liquid droplet flash evaporation, microwave enhancement, vacuum steam discharge, and simulation and optimization of multi-mode resonant cavity, wherein through the coupling effect of the microwave, by means of one stage microwave flash evaporation, the effect normally achieved by multi-effect evaporation and flash evaporation is obtained and a liquid droplet micro-system with microwave energy transfer in situ is formed so as to prevent a circulation pump and a steam heat exchange system from being corroded under high temperature and high pressure, and prevent scaling on a heat exchanger, and improve evaporation efficiency.Type: GrantFiled: April 19, 2016Date of Patent: April 28, 2020Assignee: KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Shaohua Ju, Jinhui Peng, Zhanyong Guo, Hua Chen, Jun Sun, Shenghui Guo, Chao Liu, Lei Xu, Linqing Dai, Lihua Zhang, Shihong Tian
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Publication number: 20200114405Abstract: The present disclosure relates to a method for thermal desorption treatment of organic-contaminated soil. The method includes: subjecting thermal desorption flue gas with a temperature of 120-700° C. and the organic-contaminated soil to a countercurrent contact reaction for 5-30 min to obtain desorption waste gas comprising an organic pollutant and thermally desorbed soil; drying biomass to a water content of ?12%, and crushing to a length of ?20 cm to obtain a biomass segment; uniformly mixing the thermally desorbed soil with the biomass segment to obtain a mixture A, carrying out low-temperature pyrolytic carbonization of the biomass in the mixture A at a temperature of 250-450° C., heating the soil to obtain remedied soil including organic carbon and pyrolysis gas from the low-temperature pyrolytic carbonization. The disclosure mixes the thermally desorbed soil with the biomass for pyrolytic carbonization, greatly improving the content of an organic matter, recovering a soil function.Type: ApplicationFiled: October 7, 2019Publication date: April 16, 2020Applicant: Kunming University of Science and TechnologyInventors: Senlin TIAN, Qun ZHAO, Yingjie LI, Jianhong HUANG, Xuewei HU, Xiaolong CHAI, Yan CAO, Yingxue GENG, Linzhen XU, Linfeng ZHANG, Yina TU
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Patent number: 9999847Abstract: The invention involves a vibrating inclined plate box settlement separator, which is used for the liquid-solid separation, particularly applicable to high-efficiency settling concentration and separation of solid particles from liquid or water. The separator consists of an upper box and a lower tapered hopper. The upper box and the lower tapered hopper are connected securely to each other and sealed. The upper box is a rectangular or square steel-structured box with two supporting platforms on both of its sides, on which several spring assemblies are installed. The inclined plate box modules which can independently vibrate are installed on the spring assemblies. The feed box is placed on top of or inside the upper box. An overflow collect chute is welded on the side of the box frame opposite to the feed box.Type: GrantFiled: June 5, 2013Date of Patent: June 19, 2018Assignee: KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGYInventor: Xinglong Zhou
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Publication number: 20160008746Abstract: The invention involves a vibrating inclined plate box settlement separator, which is used for the liquid-solid separation, particularly applicable to high-efficiency settling concentration and separation of solid particles from liquid or water. The separator consists of an upper box and a lower tapered hopper. The upper box and the lower tapered hopper are connected securely to each other and sealed. The upper box is a rectangular or square steel-structured box with two supporting platforms on both of its sides, on which several spring assemblies are installed. The inclined plate box modules which can independently vibrate are installed on the spring assemblies, The feed box is placed on top of or inside the upper box. An overflow collect chute is welded on the side of the box frame opposite to the feed box.Type: ApplicationFiled: June 5, 2013Publication date: January 14, 2016Applicants: KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGYInventor: Xinglong ZHOU
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Publication number: 20150041722Abstract: Disclosed is a process for purifying tail gases from an ore-smelting electrical furnace by catalytic oxidization, which comprises: impregnating a catalyst carrier in an impregnating solution, then aging, calcinating, and finally drying, so as to prepare a catalyst of high efficiency; then washing the tail gases from an ore-smelting electrical furnace with an aqueous alkali-containing solution, pre-heating the alkali-washed tail gas; and adjusting the oxygen volume content in the tail gases, charging the tail gases at a certain speed, purifying the gases by a catalytic oxidization fixed bed containing the catalyst of high efficiency, cooling the purified gas, so as to obtain the feed gases for C1 chemistry.Type: ApplicationFiled: March 12, 2012Publication date: February 12, 2015Applicant: Kunming University of Science and TechnologyInventors: Ping Ning, Xueqian Wang, Xiangyu Wang, Senlin Tian, Xiaolong Tang, Huaping Gao, Honghong Yi