Abstract: Disclosed are Group 6 film forming compositions comprising Group 6 transition metal-containing precursors selected from the group consisting of: M(=O)(NR2)4 Formula I, M(=O)2(NR2)2 Formula II, and M(=NR)2(OR)2 Formula III, wherein M is Mo or W and each R is independently H, a C1 to C6 alkyl group, or SiR?3, wherein R? is H or a C1 to C6 alkyl group. Also disclosed are methods of synthesizing and using the disclosed compositions to deposit Group 6 transition metal-containing films on substrates via vapor deposition processes.

Abstract: A process and a plant for the continuous conversion of a hydrocarbonaceous feed gas into a synthesis gas comprising carbon monoxide and hydrogen, wherein the H2/CO molar ratio of the product gases can be varied within a wide range. This is achieved in that at least a part of a methane-rich gas obtained during the fractionation of the raw synthesis gas is admixed to the feed gas mixture, and that in the alternative at least a part of the H2 product gas and/or a fraction of a hydrogen-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to lower the H2/CO ratio, or at least a part of the CO product gas and/or a fraction of a carbon monoxide-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to increase the H2/CO ratio.

Abstract: The invention relates to a liquefied-fluid storage tank including a storage wall the inner surface of which defines a storage volume for liquefied fluid, the tank including an exchanger for cooling the fluid contained in the tank in particular to condense vapors of said fluid. The invention is characterized in that the cooling exchanger includes a body of metal, in particular aluminum, in which at least one pipe of a coolant circuit is integrated in order to cool said body and in that the body is in contact with and attached to the outer surface of the storage wall.

Abstract: The invention relates to a fiberglass material manufacture method and facility, were in molten glass is converted into fiberglass material via the steps of spinning, drawing, sizing, and collecting, followed by a step of producing a resulting fiberglass material that is then subjected to thermal desizing. The fumes from the melting furnace are used to preheat a combustion reagent from the melting furnace in two steps: a first step in which air is heated via heat exchange with the fumes, and a second step in which the combustion reagent is preheated via heat exchange with the hot air, the air then being used in the step of desizing the fiberglass material.

Abstract: One or more polymeric hollow fiber membranes are pyrolyzed to form one or more hollow fiber CMS membranes by directing a flow of pyrolysis gas through a polymeric membrane cartridge (including a porous center tube around which one or more green, polymeric, hollow fiber membranes is arranged) or a bundle of polymeric membranes (including a plurality of green, polymeric hollow fiber membranes oriented so that their ends are disposed with ends of the bundle) in a direction perpendicular to a length direction of the cartridge or bundle in order to sweep away off-gases that are formed during pyrolysis.

Abstract: The invention relates to a station and method for filling a tank with a fuel gas. Said station includes at least one fuel gas source store and a gas transfer system having a first upstream end connected to the source store(s) and a second downstream end that is in fluid communication with the tank. The gas transfer system includes at least one control valve, characterized in that the at least one source store includes a rigid outer wall and a flexible sealing wall that is arranged inside the space defined by the rigid outer wall. The flexible wall defines a storage space for the fuel gas. The first upstream end of the system is connected to the storage space defined by the flexible wall.

Abstract: A method for filling or withdrawing from a pressurized gas tank. The tank having a wall having a cylindrical overall shape with dimensions and thermophysical properties that are given and known. The method including the regulation of the flow rate of the introduced or withdrawn gas, and/or of the temperature of the introduced gas, to avoid a situation in which the tank reaches a given high temperature threshold or a given low temperature threshold. The method including a step of estimating, by calculating in real time, at least one tank temperature from: the average temperature of the tank wall, the maximum temperature reached by the tank wall, the minimum temperature reached by the tank wall, and in that the flowrate of gas or the temperature of the gas is regulated depending on the calculated tank temperature.

Abstract: The invention relates to a facility for producing liquid helium from a source gas mixture substantially comprising nitrogen and helium. The facility includes a cryogenic purifier including a system for separating the nitrogen from the source gas mixture with a view to producing helium at a temperature lower than the temperature of the source gas. The facility also includes a helium liquefier that subjects the helium to a work cycle including, in series: compressing the helium, cooling and decompressing the compressed helium, and reheating the cooled, decompressed helium. The facility includes a helium transfer pipe connecting an outlet of the purifier to an inlet of the liquefier in order to transfer helium produced by the purifier into the work cycle of the liquefier. The facility is characterized in that the cryogenic purifier includes a decompression system that includes an inlet to be connected to a source of pressurized nitrogen gas.

Abstract: A plant for producing an argon-rich stream from a mixture formed by a purge fluid from a plant for producing ammonia comprises at least two methane scrubbing columns upstream of a methane separation column and, downstream therefrom, a nitrogen/argon separation column.

Abstract: An exhaust system for a steam reformer comprises at least one longitudinal collecting tube, wherein along the longitudinal axis of the longitudinal collecting tube ports for connection to catalyst tubes are provided, which in the connected condition are aligned parallel to each other and vertically to the longitudinal collecting tube, a transverse collector which is connected to the at least one longitudinal collecting tube and has a longitudinal axis which extends vertically to the at least one longitudinal collecting tube and vertically to the catalyst tubes, wherein the longitudinal collecting tube is formed as hot exhaust system and the transverse collector is formed as cold exhaust system. The transverse collector is arranged on a side of the longitudinal collecting tube facing away from the ports centrally to the longitudinal collecting tube.

Abstract: A method for filling tanks with pressurized gas via a filling station comprising several storage containers and a fluid circuit for transferring the gas from the containers to the tanks, the circuit comprising a first end to which the containers are linked in parallel and a second end provided with a transfer line intended to be connected to the tank(s) to be filled, the circuit comprising, arranged in series between the first end and the second end, a first isolation valve, a flow or pressure regulation member, and a second isolation valve, the method comprising filling a first tank, characterized in that, on completion of the filling of the first tank and before filling a second tank, the first and second isolation valves are closed to trap a supply of pressurized gas in the circuit between said two valves and in that the supply of gas is used to refill at least one of the containers.

Abstract: Exchanger having a tube and fin bundle and comprising: a duct (4) through which a cryogenic fluid can flow between a fluid inlet (1) into the exchanger and a fluid outlet (2) from the exchanger; and a system of flat, continuous and parallel fins (3) through which said duct passes inside the exchanger, it being possible for air (12) to circulate within the exchanger by passing through channels delimited by the space between the duct and the parallel fins. The exchanger is characterized in that it comprises at least two independent ducts (10a, 10b) for the circulation of cryogenic fluid within the exchanger.

Abstract: The invention relates to a stack of cells of a fuel cell comprising an anode plate and a cathode plate, at a first one of the two ends thereof, the stack ending in a first anode or cathode end plate, respectively, arranged on the cathode or anode plate, respectively, of the last cell of the stack, said first end plate defining a circuit for the cooling fluid of the last cell and said first end plate being an anode or cathode plate, respectively, identical to the anode and cathode plates, respectively, of the cells but missing the opening for dispensing reagent. It is thus possible to simplify the development and the assembly of a stack of cells of a fuel cell with proton-exchange membrane while ensuring a good seal and satisfactory cooling at the end of the stack.

Abstract: The method for the production of nitrogen can include the steps of a) providing a waste nitrogen gas stream at a first pressure called low pressure, wherein the waste nitrogen gas originates from a low pressure column of a cryogenic air separation unit; b)compressing the waste nitrogen gas stream to a second pressure in a waste nitrogen compressor to produce a pressurized nitrogen stream; and c) introducing the pressurized nitrogen stream to a nitrogen generator under conditions effective for producing a purified nitrogen product, wherein the purified nitrogen product has a higher concentration of nitrogen as compared to the pressurized nitrogen stream.

Abstract: An apparatus for the production of air gases by the cryogenic separation of air can include a cold box having a heat exchanger, and a system of columns; a pressure monitoring device; and a controller. The cold box can be configured to receive a purified and compressed air stream under conditions effective for cryogenically separating the air stream to form an air gas product. The apparatus may also include means for transferring the air gas product from the cold box to an air gas pipeline. The pressure monitoring device is configured to monitor the pipeline pressure, and the controller is configured to adjust the product pressure of the air gas product coming out of the cold box based upon the pipeline pressure.

Abstract: The present invention relates to a plant for removing C6-C11 hydrocarbons from methanol, comprising at least one reactor for the conversion of carbon monoxide and hydrogen to a crude methanol containing hydrocarbons, a distillation column with a head and a sump for the purification of the methanol, and at least one conduit for guiding the crude methanol from the at least one reactor into the distillation column. At its head, the distillation column includes a feed conduit for feeding in water.

Abstract: A process for the stepwise separation of accompanying gases from a raw synthesis gas stream by a liquid absorbent countercurrently guided through all process steps and circulated via regeneration plants, wherein either the accompanying gases H2S, COS and CO2 are separated in a common absorption step or, in one of the selective absorption steps chiefly H2S and COS are separated and in the next step in flow direction of the gas chiefly CO2 is separated, and in the last step a separation of accompanying gas residues (fine wash) is effected, wherein before the separation of H2S and COS an absorption step chiefly for the separation of aromatics and subsequently an absorption step chiefly for the separation of methyl mercaptan is carried out.

Abstract: In a method for compressing a gas that is to be separated in a low-temperature CO2 separation unit using at least one partial condensation step and/or at least one distillation step, the gas that is to be separated has a variable composition and/or variable flow rate, the gas that is to be separated is compressed in a compressor to produce a compressed gas and the inlet pressure of the gas that is to be separated, entering the compressor, is modified according to the CO2 content and/or the flow rate of the gas that is to be separated so as to reduce the variations in volumetric flow rate of the gas that is to be separated entering the compressor.

Abstract: The invention relates to a method for membrane permeation of a gas flow including methane and carbon dioxide, wherein said gas flow is cooled to a temperature of 0° C. to ?60° C. before being fed into a membrane separation unit.

Abstract: A method and apparatus for the production of air gases by the cryogenic separation of air with front end purification and air compression can include using an available compressed dry gas such as nitrogen, oxygen, stored purified air, or synthetic air to repressurize the adsorber without diverting any of the purified air just exiting the currently on-line adsorber or changing the flow rate of the main air compressor or air sent to the cold box. This enables the main air compressor (MAC) to operate at a relatively constant flow rate while also sending a relatively constant air flow to the cold box during this repressurization step, thereby reducing the risks of process upsets and minimizing capital expenditures related to the MAC and other warm-end equipments.