Abstract: This distributor comprises: a peripheral crown; a series of vertical partitions fixedly mounted on the crown at both ends thereof and extending parallel to one another; sealingly closing means bounding, between the vertical partitions, alternate spaces for collecting gas and liquid; means enabling the upward evacuation of the gas contained in the spaces for collecting gas; and a perforated bottom disposed at the base of each liquid collecting space and sealingly connected to the or each adjacent vertical partition and to the crown. Application to air distillation columns.
Type:
Grant
Filed:
December 12, 1990
Date of Patent:
July 21, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Jean-Francois Alleaume, Patrice Andre, Christian Barbe, Maurice Bosquain, Jean-Yves Lehman, Pierre Jeannot, Francois Darchis
Abstract: Fresh fruit and vegetables are preserved under refrigerated temperatures generally between 0.degree. C. and 20.degree. C. by placing the fruits and vegetables in a gaseous atmosphere initially containing an effective amount of nitrogen monoxide or argon in the range of 10-100%, with optionally up to 50% oxygen, any remainder being composed of an inert gas. The fruits and vegetables may be maintained continuously in such atmosphere or in stages interspersed by placing the vegetable products in a different atmosphere.
Type:
Grant
Filed:
July 16, 1990
Date of Patent:
July 7, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The device comprises an assembly intended to be mounted on a closure valve of a high pressure container and comprises a manual control device operating a distribution valve in which the upstream end communicates with the closure valve, a pressure reducer and a safety device against over pressures between the distribution valve and an outlet for connection to a user circuit, as well as a manometer which measures the pressure upstream of the distribution valve. A pusher-rod operates the valve of the closure valve in response to a movement of the distribution valve.
Type:
Grant
Filed:
July 9, 1991
Date of Patent:
July 7, 1992
Assignees:
L'Air Liquide, Societe Anonyme pour L'Etude et L'Exploitation des Procedes Georges Claude, L
Inventors:
Gerard Campion, Alain Demeulemeester, Eric Fortuit
Abstract: Process for producing an atmosphere for the manufacture of high performance composite parts, of the type wherein the atmosphere is used in an autoclave above a superposition of cutouts with fibrous structure impregnated with a thermosetting organic material disposed between a lower mold and an upper sealing covering member, the space between the covering member and the mold being under vacuum. The atmosphere is nitrogen gas prepared from raw nitrogen by separation from air through permeation or adsorption, incorporating a residual content of oxygen between 0.5% and 6%, with a low content of water vapor. Application for example to the manufacture of secondary and primary structures in aeronautical and space construction.
Type:
Grant
Filed:
February 12, 1990
Date of Patent:
June 16, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The present invention relates to a multilayer protective coating for a substrate and a process for protecting a substrate by the deposition of a continuous, transparent, amorphous, inorganic coating essentially comprising silicon, carbon, nitrogen, oxygen and hydrogen by means of a plasma. The invention also concerns the application of the coatings according to the invention in the protection of substrates and in particular against electrostatic charges.
Type:
Grant
Filed:
May 11, 1989
Date of Patent:
May 26, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Jean-Marie Gauthier, Francois Coeuret, Claude Bonet
Abstract: A thermal decomposition trap includes a trap main body (21) having an inlet port (26) for supplying a gas to be thermally decomposed and an outlet port (27) for exhausting the gas, and a heater (23, 25) for heating the gas supplied in the trap main body (21). An oil trap (28) containing an oil and having an oil discharge port (29) and a valve (V3) connected thereto is formed on a bottom portion of the trap main body (21). Particles generated by thermal decomposition of the gas are precipitated in the oil in the oil trap (28). The oil containing the particles is easily discharged in a short time period by opening the valve (V3) mounted on the oil discharge port (29). An oil-free auxiliary pump is arranged between a reaction chamber and the thermal decomposition trap, whereby a mass flow rate of exhaust from rate in the reaction chamber is not reduced regardless of the arrangement of the thermal decomposition trap.
Type:
Grant
Filed:
February 9, 1990
Date of Patent:
May 19, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The present invention concerns a cutting head made of a cutting nozzle (2) with cutting oxygen duct (6) having radial ribs (11), the assembly being force fitted in a sheath (3) thus forming ducts of oxycombustible mixture (32). This nozzle which produces an improved heat dissipation can be made of reduced dimensions.
Type:
Grant
Filed:
May 9, 1990
Date of Patent:
May 19, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Michel Arnout, Didier Lasnier, Richard Soula
Abstract: The holding container comprises an inner casing and an outer casing of the same or different materials and a cryogenic liquid withdrawing pipe including an inner portion having a section advantageously in the form of adjacent spiral turns, which is kept in resilient contact, typically by means of a spring spacer against the inner face of the other casing, thus enabling to provide heat exchange contact between the section of the first part of the pipe and the outer casing notwithstanding the nature of the materials constituting the pipe and the outer casing. Application for example to self-pressurizable holding containers.
Type:
Grant
Filed:
November 7, 1990
Date of Patent:
May 12, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The object of the invention is a catalytic composition comprising titanium and phosphorus and resulting from the contacting of at least one titanate with at least one quaternary "onium" salt of an acid selected from the group consisting of phosphoric acid and the phosphonic acids of formula R.sup.7 H.sub.2 PO.sub.3 in which R.sup.7 is a hydrocarbon group having 1 to 38 atoms of carbon and the "onium" remainder is a remainder of formula (R.sup.8 R.sup.9 R.sup.10 R.sup.11 M).sup.+ in which M is an element from the group VA of the periodic table of elements, preferably nitrogen or phosphorous, and R.sup.8, R.sup.9, R.sup.10 and R.sup.11, identical or different, represent each an atom of hydrogen or a hydrocarbon group having 1 to 38 atoms of carbon.This catalytic composition is utilizable for producing asters and polyesters from epoxides and carboxylic acid anhydrides.
Type:
Grant
Filed:
October 16, 1990
Date of Patent:
April 14, 1992
Assignees:
Institut Francais du Petrol, L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Elf France
Inventors:
Jacques Garapon, Isabelle Muller, Remi Touet, Catherine Huet, Bernard Damin
Abstract: Process for protecting a transparent optical substrate which is polymeric and has a vitreous transformation temperature and is selected from the group consisting of polycarbonate, polymethylmethacrylate, polystyrene acrylonitrile, crystalline polystyrene, polyimide, polyester, polyamide, polyvinyl chloride and glass, by deposition of an inorganic continous and transparent film consisting essentially of silicon, carbon, nitrogen, oxygen and hydrogen of the formula Si C.sub.x N.sub.y O.sub.z H.sub.t, in whichx is between 0 and 5y is between 0.3 and 0.8z is between 1.3 and 2.5t is between 0.5 and 1.2.A surface of the substrate is exposed to a plasma at a temperature below the temperature of vitreous transition of the substrate in the presence of precursors of Si, C, N, O and H is gaseous form, the precursor gas of the silicon being selected from the group consisting of SiH.sub.4, Si.sub.2 H.sub.6 and Si.sub.3 H.sub.
Type:
Grant
Filed:
June 7, 1990
Date of Patent:
March 3, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Claude Bonet, Francois Coeuret, Sylvie Nowak, Jean-Marie Gauthier
Abstract: Process for the gas treatment of a product in a confined treatment zone by a flow of an inert gas, such as nitrogen, wherein a gas flow which originates from a gas treatment containing a high proportion of nitrogen, becomes loaded with impurities such as: oxygen, and/or carbon dioxide, and/or water, and wherein the flow of gas which originates from the treatment undergoes at least substantially in part, a removal of the impurities in a separator of the adsorption or permeation type before being recycled as treatment gas, with addition of a compensating gas flow predominantly containing nitrogen. Application for example to the deoxygenation of liquids, in particular nutritious liquids, to the providing of inert conditions in ovens or storage enclosures for products such as electronic pieces, or in chambers used for preserving nutritious products in an atmosphere which is substantially free from oxygen.
Type:
Grant
Filed:
August 10, 1990
Date of Patent:
February 25, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: A thin copper film is formed by CVD, by (a) forming a gas stream containing a copper halide, followed by introducing said gas stream into a CVD reaction chamber having a heated catalytic metal filament arranged herein, (b) introducing hydrogen gas into the CVD reaction chamber for activation of said hydrogen gas by the heated catalytic metal filament, and (c) carrying out the reaction between the copper halide contained in the gas stream introduced in step (a) and the hydrogen activated in step (b) near the surface of a substrate arranged within the CVD reaction chamber so as to deposit a thin copper film of copper on the substrate surface.
Type:
Grant
Filed:
October 11, 1990
Date of Patent:
February 25, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Pierre Claverie, Masao Kimura, Juichi Arai, Pierre Jalby
Abstract: Process for preparing disilane, wherein a raw gas including monosilane, disilane, trisilane and impurities such as phosphine, hydrogen sulfide, arsine, disiloxane and higher siloxanes, undergoes a step of separation by distillation for the substantial elimination of the other compounds of silicon, except disiloxane, and the substantial elimination of phosphine, hydrogen sulfide and arsine impurities, wherein a final purification of the disilane takes place by selective adsorption on molecular sieves, in which one is a sieve of type 3 A and which is used for the elimination of the siloxanes and hydrogen sulfide and the other is a sieve of type 4 A for the elimination of phosphine and arsine.
Type:
Grant
Filed:
September 24, 1990
Date of Patent:
February 18, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The invention relates to the treatment of a liquid with a gas. A gas injector, for example oxygen, is surrounded with a sheath to carry a flow of a liquid under treatment (for example lead) which is taken up and circulated by the pump. The end of the injector is thereby protected by moving away the bubbles of oxygen. Application for example in the refining of metals, for example non ferrous metals, food liquids, paper pulps and the production of sulfur.
Type:
Grant
Filed:
April 11, 1990
Date of Patent:
February 11, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l Exploitation des Procedes Georges Claude
Abstract: The pressure reducer body includes oppositely disposed bores for mounting inlet and outlet connecting devices, and the outer end of another bore defining a high pressure chamber in which the regulating valve is mounted, is adapted to receive a connecting device for a high pressure manometer defining a rest for a spring of a regulating valve which includes an annular truncated lining in which is force fittingly engaged a connecting rod between the regulating valve and the piston bounding the low pressure chamber. Applications to various pressure reducer arrangements for industrial use.
Type:
Grant
Filed:
February 5, 1991
Date of Patent:
February 11, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Didier Lasnier, Bruno Beaco, Daniel Sakreiter
Abstract: A light component of the compressed mixture is separated by permeation. The remaining heavy fraction is condensed with water, sub-cooled and expanded. The light component, cooled at the same temperature, is added to the sub-cooled condensate, and the whole is vaporized under low pressure to produce the required refrigeration.
Type:
Grant
Filed:
October 1, 1990
Date of Patent:
February 11, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: A device for trapping gaseous compounds of refractory metals includes at least a vertically disposed elongated enclosure (1) in the form of a hollow cylindrical member (2), sealingly closed in its upper part via a cover (4), and having a hollow bottom (5) in its lower part. The enclosure is lined in the major part of the height of the member with a heat conductive lining (10) leaving within itself free vertical spaces from top to bottom; The enclosure includes a gas inlet opening (8) below the lower portion of the lining, a gas outlet opening (11) above the lining, a heater and heat insulation.
Type:
Grant
Filed:
November 28, 1988
Date of Patent:
January 28, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: To meet the requirement of a variable demand of gaseous oxygen, a constant flow of liquid oxygen is sent from the double distillation column into a container, and a variable flow of liquid oxygen is withdrawn therefrom, which is thereafter vaporized in a heat exchanger by condensation of a corresponding flow of incoming air. The liquefied air is stored in a second container, from which a constant flow of liquefied air is sent into the double column.
Type:
Grant
Filed:
September 18, 1990
Date of Patent:
January 21, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The invention concerns the production of ceramic-metal multilayer components comrising effecting, after making up in the crude state, in particular by metallization and stacking of pre-cut raw ceramic bands, a simultaneous firing operation, termed cofiring, on the components under an atmosphere based on hydrogen or nitrogen or a mixture of hydrogen and nitrogen, having a regulated water vapor content at a temperature of first of all between 800.degree. C. and 1800.degree. C., and more precisely either at a moderately high temperature plateau between 800.degree. C. and 1300.degree. C. for certain ceramic materials such as codierite and metallic materials such as copper and nickel, or at a temperature plateau between about 1400.degree. C. and 1800.degree. C.
Type:
Grant
Filed:
February 22, 1990
Date of Patent:
January 21, 1992
Assignee:
L'Air Liquide, Societe Anonyme pour L'Etude et L'Exploitation des Procedes Georges Claude
Inventors:
Frederic Rotman, Yannick Rancon, Philippe Queille, Michel Olivier
Abstract: The support for the electrode has at its end a cavity at the bottom of which there is an emissive insert made of zirconium of hafnium. A portion of the support end around the insert has at least a portion of an electroconductive material axially projecting with respect to the insert. Application to plasma cutting torches ignition by short-circuit.
Type:
Grant
Filed:
July 13, 1990
Date of Patent:
January 21, 1992
Assignee:
L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude