Abstract: The valve assembly for non-returnable packing comprises a valve housing including a main valve and an auxiliary valve the latter being initially kept in opened position through a resilient locking device which is unlocked, at the end of a first filling through a displacement of the main valve beyond its position of normal opening under the action of a long travel filling tap. The auxiliary valve is then forced to rest on its seat by means of a spring with low calibration. Any depression caused by tapping would provoke the opening of the auxiliary valve, while any overpressure resulting from filling would hit the auxiliary valve in a closed position.
Type:
Grant
Filed:
May 29, 1990
Date of Patent:
May 28, 1991
Assignee:
L'Air Liquide, Societe Anonyme Pour L'Etude et L'Exploitation des Procedes Georges Claude
Abstract: The invention concerns glass-metal sealing comprising effecting on a metallic piece, in particular an alloy based on iron and nickel or iron, nickel and cobalt, first of all a decarburization under an atmosphere, at a temperature of between 950.degree. C. and 1,150.degree. C., formed by hydrogen (10 to 99%), water vapor (1 to 8%), with a ratio hydrogen/water vapor higher than five, the possible remainder being nitrogen, then an oxidation under an atmosphere formed by an inert vector gas such as nitrogen, either at a temperature of 600.degree. C. to 800.degree. C. and with a water vapor content of 8% to 2%; or at a temperature of 900.degree. C. to 1,100.degree. C. and with a water vapor content of 4% to 0.5%; then establishing the connection.
Type:
Grant
Filed:
February 22, 1990
Date of Patent:
April 2, 1991
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Frederic Rotman, Yannick Rancon, Philippe Queille, Michel Olivier
Abstract: A closure member (16) of the cooler is controlled by a bulb actuator (18) which defines an auxiliary gas volume (24) located in the cold part of the cooler and connected to a chamber (21) of very much larger volume located in the warm part of the cooler. Application in the cooling of infrared ray detectors.
Type:
Grant
Filed:
March 15, 1990
Date of Patent:
April 2, 1991
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The invention concerns a cutting torch for iron and steel metallurgy which is provided with two oxygen cutting ducts, ending in two housings, for receiving two cutting inserts, or a heating nozzle and a cutting insert. In this manner, there is obtained a torch which may very rapidly be converted into a cutting torch with high heating capacity and single cutting jet, or into a cutting torch with high cutting speed provided with two cutting inserts.
Type:
Grant
Filed:
January 8, 1990
Date of Patent:
March 26, 1991
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Michel Arnout, Didier Lasnier, Eric Dufour
Abstract: In a process for manufacturing fatty alcohols comprising hydrogenating the corresponding fatty acid methyl esters, the hydrogen used for the hydrogenation reaction is regenerated from impure methanol as a by-product of the reaction. The impure methanol recovered from the hydrogenation reactor is conducted to a steam reformer reactor, from whence the regenerated hydrogen is recycled back to the hydrogenation reactor.
Type:
Grant
Filed:
October 12, 1989
Date of Patent:
March 19, 1991
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Rene Dupont, Laurent Ferenczi, Guy Simonet
Abstract: Gas mixture suitable for MAG welding at a high current using a rod filled with non-alloyed or low alloy steels, comprises 20 to 65% argon, 5 to 20% helium, and at least 30% CO.sub.2.
Type:
Grant
Filed:
March 27, 1990
Date of Patent:
March 12, 1991
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Jean-Pierre Schultz, Jean Soler, Daniel Nicoud
Abstract: The invention relates to a process for condensing at least one epoxide on at least one cyclic anhydride of a dicarboxylic acid in the presence of a catalyst consisting of at least one titanium peroxidic complex of the peroxo type of the A form ##STR1## Said process allows to obtain a perfectly alternate polyester.
Type:
Grant
Filed:
December 7, 1989
Date of Patent:
March 5, 1991
Assignees:
Institut Francais du Petrole, L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Elf France
Inventors:
Jacques Garapon, Remi Touet, Catherine Huet, Bernard Damin
Abstract: Process for the heat treatment of low-alloy steels at temperatures higher than 600.degree. C., such as annealing or heating before hardening, etc., said treatment being carried out in a protection atmosphere produced by the injection of nitrogen, hydrocarbon C.sub.x H.sub.y and optionally hydrogen, with a control of the atmosphere. According to the invention, the composition of the residual species CH.sub.4, CO, H.sub.2 O, and the temperature of the gaseous mixture in the furnace are controlled in order to control the carburization and the decarburization of the treated steels.
Type:
Grant
Filed:
August 22, 1990
Date of Patent:
February 12, 1991
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: Process for separating a gaseous mixture by adsorption includes the steps of: (a) a cocurrent isobaric production (f.sub.p1 -f.sub.p2); (b) a pressure equalization between the adsorber undergoing decompression and another adsorber undergoing countercurrent recompression (f.sub.c1 -N.sub.4); (c) a cocurrent partial emptying to a reservoir (f); (d) a final countercurrent decompression (f.sub.a); (e) a countercurrent scavenging by the gas of the reservoir (f.sub.b); (f) a countercurrent partial recompression by at least one pressure equalization (f'.sub.e); (g) a countercurrent final recompression (f'.sub.di -F'.sub.
Type:
Grant
Filed:
September 28, 1989
Date of Patent:
January 1, 1991
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes
Abstract: A process for depositing tungsten silicide films on a silicon substrate by chemical vapor deposition, comprises the steps of producing a silicon sub-fluoride by passing SiF.sub.4 over pieces of silicon heated in a tubular oven about 1200.degree.-1500.degree. K., mixing gaseous WF.sub.6 with the silicon sub-fluoride, and then immediately depositing the tungsten silicide films on said silicon substrate.
Type:
Grant
Filed:
October 17, 1988
Date of Patent:
January 1, 1991
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The process comprises putting the must or wort in contact with a side of a membrane permeable to oxygen and putting the other side of this membrane in contact with a gas containing oxygen under partial pressure higher than the partial pressure in oxygen of the liquid. Application in vinification.
Type:
Grant
Filed:
March 21, 1989
Date of Patent:
December 18, 1990
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: Aromatic aldehydes are produced by oxidation with oxygen of a para-cresol derivative in a solvent, in the presence of a base and a catalytic amount of a cobalt compound. The catalyst is a chelated complex of cobalt with a rigid structure that is slightly oxidizable selected from the group consisting of bis-(4-methylpyridine isoindolinato)cobalt(II) acetate, phthalocyaninatocobalt(II), and sulfophthalocyaninanatocobalt(II). The process is particularly suited to the production of p-hydroxy benzaldehydes.
Type:
Grant
Filed:
December 20, 1988
Date of Patent:
December 18, 1990
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Philippe Campo, Panayotis Cocolios, Paul Dognin, Henry Ledon
Abstract: Oxygen from the bottom of a low pressure column (4) is purified from hydrocarbons in a first auxiliary column (12), and the vapor at the top of this column is distilled in a second auxiliary column (17) heated at the base thereof with air at medium pressure. Ultra-pure oxygen is produced at the bottom of the second auxiliary column. Application in the production of ultra-pure oxygen for the electronic industry.
Type:
Grant
Filed:
January 19, 1990
Date of Patent:
December 18, 1990
Assignee:
l'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The plant comprises a conveyor (1) above which are disposed a device (3) for injecting liquefied gas into the containers and, on the downstream side of the device relative to the direction of travel of the conveyor, a device (4) for closing the containers, and a tunnel (5) for protecting the containers against the surrounding air and extending between the injecting device (3) and the closing device (4). Application in the packing of non-gaseous beverages and organic products in cans or bottles.
Type:
Grant
Filed:
December 14, 1989
Date of Patent:
December 18, 1990
Assignee:
l'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: This PSA cycle comprises two successive pressure equilibration steps in the course of which gas is withdrawn in a cocurrent manner from an adsorber at the beginning of countercurrent decompression and respectively introduced in a countercurrent manner and then in a cocurrent manner in another adsorber at the beginning of recompression. Application in the production of impure oxygen from air of the atmosphere.
Type:
Grant
Filed:
July 5, 1989
Date of Patent:
November 13, 1990
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: An annealing treatment in a continuous furnace in which a flow of dense inert gas is injected in a rising duct and a descending duct, these flows being regulated by the analysis of hydrogen detected by a pressure controller acting on valves to achieve a minimum escape of hydrogen.
Type:
Grant
Filed:
March 14, 1989
Date of Patent:
October 30, 1990
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: A method and apparatus are provided for treating gaseous effluents containing sulfur dioxide. Sulfur dioxide is oxidized by oxygen in a concentrated sulfuric acid medium in the presence of a catalyst comprising electrooxidized salts of Mn+2. The gaseous effluents are converted to directly usable sulfuric acid.
Type:
Grant
Filed:
September 12, 1988
Date of Patent:
July 24, 1990
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Henry Ledon, Jean Louise, Panayotis Cocolios
Abstract: An optical waveguide for infrared light includes a series of metal layers. A thick outer layer of nickel is provided for mechanical stiffness to make the structure self-supporting. Thinner inside layers are also provided of metals such as silver, gold and copper which are good heat conductors. Since nickel has a low thermal conductivity, the waveguide can be damaged due to heat build-up. The layers of good conductors spread the heat efficiently to remove this possibility while the nickel continues to provide the necessary strength. A highly-reflective inert inside layer of gold may also be provided.
Type:
Grant
Filed:
March 17, 1989
Date of Patent:
June 12, 1990
Assignee:
L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes George Claude
Abstract: A process for continuous cooling of an extruded product, wherein the product passes successively in its direction of movement in a tunnel through at least three cooling zones; an upstream zone for cooling by convection in which the gas and the product move countercurrently, a cooling zone by cryogenic fluid spraying on the product, and a downstream stabilization zone in which the gas and the product move concurrently.
Type:
Grant
Filed:
September 21, 1988
Date of Patent:
June 5, 1990
Assignee:
L'air Liquide, Societe Anonyme pour l'etude et l'exploitation des Procedes Georges Claude
Abstract: The microwave torch comprises at least one gas supply conduit (1, 2); a resonant cavity (3) forming around the conduit a sleeve open adjacent to the outlet of the conduit and including a lateral opening (4); a transition coaxial structure perpendicular to the sleeve comprising, on one hand, an outer tube (5) connected to the lateral opening (4) of the sleeve and, on the other hand, an inner element (6) having one end (20) in contact with the conduit and an opposite end which is in contact with the outer surface of a wave guide (8) and carries a transition member (7) disposed in the wave guide; said wave guide supplying microwave energy and having a rectangular section and perpendicular to the coaxial structure (5, 6) being provided with an opening (27) where the outer tube (5) of the coaxial structure is connected; shielding gas supply means in the wave guide and/or the coaxial structure and/or the sleeve; optionally tuning means; and optionally plasma igniting means.
Type:
Grant
Filed:
June 10, 1988
Date of Patent:
May 8, 1990
Assignee:
L'Air Liquide, Societe Anonyme Pour L'Etude et L'exploitation des procedes Georges Claude
Inventors:
Jean-Luc Labat, Lahcen Ougarane, Michel Gastiger