Patents Assigned to L'Air Liquide Societe Anonyme Pour L'Etude Et L
  • Patent number: 11794400
    Abstract: A method for manufacturing a composite pressurized-fluid vessel including winding a first polyolefin resin-based tape thereby forming a first layer of the vessel, depositing an intermediate second layer on the first layer, consisting of a material having variable permeability properties depending on the temperature and permeability below a pre-determined temperature threshold and non-permeability above the temperature threshold, winding a second resin-based tape on the intermediate second layer thereby forming a third layer, and cooling the intermediate second layer to a temperature below the temperature threshold while the first and third layers are each kept at a temperature above the melting temperature of their resin. Wherein the tape forming the third layer is based on a different resin from the first layer and during the step of depositing the intermediate second layer.
    Type: Grant
    Filed: November 2, 2020
    Date of Patent: October 24, 2023
    Assignee: L'Air Liquide, Société, Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Philippe Papin
  • Publication number: 20230332299
    Abstract: The invention relates to an electrolysis device and method for producing molecular hydrogen, the device comprising a negative electrode compartment for reducing H2O into H2 and a positive electrode compartment comprising circulating supercapacitive particles in contact with a conductive substrate. Such a device or method advantageously comprises a power supply provided by one or more photovoltaic cells.
    Type: Application
    Filed: June 29, 2021
    Publication date: October 19, 2023
    Applicants: Centre national de la recherche scientifique, INSTITUT PHOTOVOLTAÏQUE D'ILE DE FRANCE (IPVF), L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, ELECTRICITE DE FRANCE, TotalEnergies OneTech
    Inventor: David AYME-PERROT
  • Patent number: 11784041
    Abstract: The disclosed lanthanide precursor compounds include a cyclopentadienyl ligand having at least one aliphatic group as a substituent and at least one bidentate ligand. These precursors are suitable for depositing lanthanide containing films.
    Type: Grant
    Filed: February 8, 2022
    Date of Patent: October 10, 2023
    Assignees: L'Air Liquide, Sociéte Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.
    Inventors: Daehyeon Kim, Junhyun Song, Wontae Noh, Venkateswara R. Pallem
  • Patent number: 11780730
    Abstract: A reformer tube for producing synthesis gas by steam reforming of hydrocarbon-containing input gases is proposed where an outer shell tube is divided by means of a separating tray into the reaction chamber and an exit chamber, a dumped bed of a steam-reforming-active, solid catalyst is arranged in the reaction chamber, at least one heat exchanger tube is arranged inside the reaction chamber and inside the dumped catalyst bed whose entry end is in fluid connection with the catalyst bed and whose exit end is in fluid connection with the exit chamber, wherein gas-contacted parts of the reformer tube, in particular the at least one heat exchanger tube, are fabricated from a nickel-based alloy and coated on their inside with an aluminum diffusion layer.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: October 10, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Dieter Ulber, Sebastien Doublet, Pascal Del-Gallo, Laurent Prost
  • Patent number: 11781082
    Abstract: The invention relates to a process and a plant for removing thiols from synthesis gas. Thiols and optionally thiophene and carbon disulfide are absorbed in a dedicated absorption stage with methanol as physical absorption medium. Methanol laden with at least thiols is freed of thiols in a stripping stage with methanol vapours as stripping gas and the methanol vapours-containing thiols are freed of methanol in a scrubbing stage. The process according to the invention minimizes methanol losses and the amounts of coolant required for the process.
    Type: Grant
    Filed: December 8, 2021
    Date of Patent: October 10, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Sophia Schmidt, Matthias Linicus, Hincal Leichner
  • Patent number: 11780859
    Abstract: Compounds and method of preparation of Si—X and Ge—X compounds (X?N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X?N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films.
    Type: Grant
    Filed: February 4, 2022
    Date of Patent: October 10, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Antonio Sanchez, Gennadiy Itov, Peng Zhang, Matthew Stephens, Manish Khandelwal
  • Patent number: 11773483
    Abstract: A cabinet for a solid material container comprises a main body having a top wall, a side wall, and a bottom wall; an entry/exit portion which is attached to a portion of the main body, for putting in and taking out the solid material container; an exhaust duct attached to a portion of the main body; a heating portion for heating the solid material container; a temperature measuring portion for measuring a temperature of the solid material container, or of the heating portion; and a cooling blower for blowing cooling air toward the solid material container.
    Type: Grant
    Filed: May 13, 2020
    Date of Patent: October 3, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Terumasa Koura
  • Publication number: 20230304731
    Abstract: Certain embodiments of the invention relate to a facility for refrigerating a fluid to a cryogenic temperature, comprising a circuit for the fluid to be refrigerated, comprising an upstream end connected to a source and a downstream end connected to a refrigerated and/or liquefied fluid collection member, the facility comprising at least one exchanger for precooling the fluid leaving the upstream end, the precooling exchanger exchanging heat with a precooling circuit composed of a flow of vaporization gas from a user, the facility further comprising a heat exchanger assembly for cooling by heat exchange with the circuit of fluid to be cooled downstream of the precooling exchanger, the facility comprising a device for cooling by heat exchange with at least a part of the cooling heat exchanger assembly, said cooling device comprising a first refrigerator with a refrigeration cycle of a cycle gas in a working circuit, the cycle gas preferably comprising hydrogen and/or helium, the working circuit of the first re
    Type: Application
    Filed: June 28, 2021
    Publication date: September 28, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Pierre BARJHOUX, Golo ZICK
  • Publication number: 20230296314
    Abstract: An air separation apparatus is provided, including an air separation unit including a low-pressure column, a mixing column, and a pure nitrogen column, wherein the low-pressure column has a first nominal diameter, the pure nitrogen column has a second nominal diameter which is smaller than the first nominal diameter, wherein the mixing column has an open cylindrical shape, with the inner diameter nominally greater than the second nominal diameter, with the pure nitrogen column located within the mixing column interior.
    Type: Application
    Filed: July 22, 2020
    Publication date: September 21, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alain BRIGLIA, Bowei ZHAO, Fengjie XUE
  • Patent number: 11761585
    Abstract: Device and method for filling pressurized gas tanks, comprising a fluid transfer circuit comprising an upstream end provided with a plurality of pressurized fluid sources and a downstream end comprising at least two distribution terminals each intended to be connected to separate tanks to be filled, each source comprising a first fluid outlet connected to a first respective outlet valve, each first outlet valve being connected to each of the at least two distribution terminals via parallel transfer ducts, each of the transfer ducts comprising at least one respective isolation valve, each of the distribution terminals being fluidly connected to each first outlet valve of a source via a first direct fluid path passing through a single transfer duct and via at least one second indirect alternative fluid path successively passing through a plurality of transfer ducts.
    Type: Grant
    Filed: August 3, 2022
    Date of Patent: September 19, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Laurent Allidieres
  • Patent number: 11753298
    Abstract: The invention relates to a process for producing hydrogen from a light hydrocarbon source, in which a synthesis gas is generated by steam methane reforming after desulfurization and optionally pre-reforming of the feedstock. The synthesis gas is enriched with hydrogen by steam conversion of carbon monoxide, and is subsequently purified in a pressure swing adsorption unit to give a pure H2 product and a residual gas mixture containing CH4, CO, H2 and CO2; in accordance with the invention, the conversion step is performed in a cooled reactor in which the heat of the conversion reaction is transferred to a fluid which feeds the burners of the reformer, or to the gas for reforming.
    Type: Grant
    Filed: November 26, 2019
    Date of Patent: September 12, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Marie Basin, Daniel Gary, Jean-Philippe Tadiello
  • Publication number: 20230278003
    Abstract: A packing section intended to be installed in a casing so as to form a gas/liquid separation column comprises a block for treating a fluid that has a generally cylindrical shape extending along a longitudinal direction, the treatment block being formed by a stack of plates for treating the fluid along the longitudinal direction, the treatment block having a first disc-shaped face and a second disc-shaped face that each extend in planes parallel to one another, the treatment block having an external face extending over the perimeter of said treatment block between the first disc-shaped face and the second disc-shaped face, the packing section having at least one element for holding the treatment block that extends at least partially around the external face of the treatment block, the holding element having a portion for holding the treatment plates of the treatment block in position.
    Type: Application
    Filed: March 7, 2023
    Publication date: September 7, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Victor BAITOKARA, Vincent FAUCHER, Ludovic AMANT, Philippe DANEL, Gilles LEBAIN, Cyrille BABINET
  • Publication number: 20230280093
    Abstract: An air separation apparatus comprises: a first rectification column, a first condensing portion, a second rectification column, a third rectification column, a second condensing portion, a fourth rectification column, a third condensing portion, and a recycling pipe for recycling a gas drawn from the third condensing portion to the second rectification column. The air separation apparatus furthermore comprises: a branch pipe branching from the recycling pipe; and a control unit for controlling opening/closing of a valve so that a gas drawn from the third condensing portion is fed to the branch pipe for a predetermined period from the start of driving of the third condensing portion, and for controlling opening/closing of the valve so that the gas drawn from the third condensing portion is fed to the recycling pipe after the predetermined period has elapsed.
    Type: Application
    Filed: March 7, 2023
    Publication date: September 7, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l Exploitation des Procedes Georges Claude
    Inventors: Maxime RANCHOUX, Shinji TOMITA
  • Publication number: 20230278004
    Abstract: A casing intended to be equipped with at least one section of packing for a gas/liquid separation column comprises at least a tubular wall extending along a longitudinal direction between two longitudinal ends and an internal face of which contributes to delimiting a housing for the section of packing, the tubular wall contributing to delimiting, at one of its longitudinal ends, an entry opening, the casing comprising an end wall located at the opposite longitudinal end to the entry opening, the casing comprising at least a first hooping device and at least a second hooping device which are positioned around the tubular wall of the casing in contact with an external face of the tubular wall, the first hooping device comprising at least one zone of connection with a movement system for the moving of the casing, the second hooping device having a longitudinal dimension shorter than a longitudinal dimension of the first hooping device.
    Type: Application
    Filed: January 27, 2023
    Publication date: September 7, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Vincent FAUCHER, Manuel DOS REIS, Vincent MARET, Luis TORBADO, Alain APPEL, Eric BIRET, Laurent LECLERC
  • Patent number: 11745150
    Abstract: An installation for rearing animals includes an injector; a water inlet line and a gas inlet line arriving in the injector; a source of oxygen or a gas mixture including oxygen, capable of delivering oxygen into the gas line; and a water recirculation loop including: a water tank, at atmospheric pressure, to supply the injector with fresh water; a coil capable of receiving water charged with dissolved oxygen from the injector through a pump, wherein the coil creates a water/oxygen contact time; and an overflow valve, to have the water resulting from the coil passed in order to be able to direct the water entirely to the animals' watering or partially to the animals' watering and partially back to the water tank. A method for rearing animals includes boosting water with dissolved oxygen up to saturation for animals' watering.
    Type: Grant
    Filed: November 8, 2018
    Date of Patent: September 5, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Franck Cousin, Dominique Ibarra, Philippe Campo, Pauline Le Dru
  • Patent number: 11746009
    Abstract: The invention relates to a process for the start-up of an autothermal reformer, wherein syngas is produced in the autothermal reformer during start-up through steam reforming. To facilitate autoignition in the autothermal reformer reactor of the autothermal reformer, the reformed syngas is recycled to an upstream section of the autothermal reformer reactor and is mixed with process steam and a hydrocarbon containing process stream. As soon as a minimum hydrogen threshold concentration at the upstream section of the autothermal reformer reactor is reached in the mixed process stream, oxygen is added to the burner of the ATR reactor to obtain autoignition of the mixed process stream. Due to the process of the invention, an external hydrogen source for facilitating autoignition of the mixed stream can be omitted. The invention further relates to a plant configured to carry out the process of the invention.
    Type: Grant
    Filed: December 17, 2020
    Date of Patent: September 5, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Chin Han Lim, Hans Kopetsch, Veronika Gronemann
  • Patent number: 11745280
    Abstract: The invention relates to a method for manufacturing a heat exchanger including stacking a set of plates parallel to one another and to a longitudinal direction so as to define a plurality of passages suitable for the flow in the longitudinal direction of a first fluid to be brought into a heat-exchange relationship with at least a second fluid, said plates being delimited by a pair of longitudinal edges extending in the longitudinal direction and a pair of lateral edges extending in a lateral direction perpendicular to the longitudinal direction, and forming at least one of the plates by superposing at least a first flat product and a second flat product on top of one another, having at least one groove that extends parallel to the plates and leads towards the outside of the stack through at least one opening in a lateral or longitudinal edge.
    Type: Grant
    Filed: May 14, 2021
    Date of Patent: September 5, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Jacopo Seiwert, Marc Wagner, Marie-Adelaide Cremieux, Younes Belmekki
  • Patent number: 11746959
    Abstract: The invention relates to a gas container equipped with a gas distribution valve having an electronic device for measuring gas autonomy. Flow selection means allow a desired gas flow to be selected. The electronic device includes a pressure sensor. Signal processing means allow gas autonomies to be determined on the basis of the pressure signal and of the selectable gas flows. A selection component cooperates with the signal processing means in order to successively display, on data display means and in response to successive digital activations by the user of the selection component, the various selectable flow values and the various corresponding autonomies, with each flow value being simultaneously displayed with a corresponding autonomy.
    Type: Grant
    Filed: January 13, 2021
    Date of Patent: September 5, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Federica Bellingeri, Adrien Campagnac, Alexis Mary
  • Patent number: 11740015
    Abstract: An air separation unit using cryogenic distillation comprises a first column, a second column thermally linked to the first column, a first argon column, a second argon column, means for sending cooled, compressed and purified air to at least the first column, means for sending at least one fluid enriched in nitrogen from the first column to the second column and at least one fluid enriched in oxygen from the first column to the second column, means for sending a gas enriched in argon from the second column to a first end of the first argon column, means for sending gas from a second end of the first argon column to a first end of the second argon column, means for removing argon rich fluid from a second end of the second argon column, a pump, means for removing argon enriched liquid from the first end of the second argon column and sending it to the second end of the first argon column via the pump, the first end of the first argon column being raised above the ground by a first supporting structure, the pum
    Type: Grant
    Filed: January 26, 2018
    Date of Patent: August 29, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Remy Kurtz, Patrice Cavagne, Delphine Vallier
  • Patent number: 11739220
    Abstract: A Si-containing film forming composition comprising a catalyst and/or a polysilane and a N—H free, C-free, and Si-rich perhydropolysilazane having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton and comprising N—H free repeating units having the formula [—N(SiH3)x(SiH2-)y], wherein x=0, 1, or 2 and y=0, 1, or 2 with x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 with x+y=3. Also disclosed are synthesis methods and applications for using the same.
    Type: Grant
    Filed: February 21, 2019
    Date of Patent: August 29, 2023
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.
    Inventors: Antonio Sanchez, Gennadiy Itov, Manish Khandelwal, Cole Ritter, Peng Zhang, Jean-Marc Girard, Zhiwen Wan, Glenn Kuchenbeiser, David Orban, Sean Kerrigan, Reno Pesaresi, Matthew Damien Stephens, Yang Wang, Guillaume Husson, Grigory Nikiforov