Patents Assigned to L'Air Liquide Societe Anonyme Pour L'Etude Et L
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Patent number: 11634325Abstract: The invention relates to an absorber column and to the use thereof for separation of unwanted, especially acidic, gas constituents, for example carbon dioxide and hydrogen sulfide, from a crude synthesis gas by absorption with an absorbent, especially under low load states of the absorber column in relation to the synthesis gas velocity. According to the invention, a defined concentration of carbon dioxide in the clean synthesis gas is established by mixing at least a portion of the absorbent regenerated by flash regeneration with the absorbent regenerated by means of hot regeneration prior to the recycling thereof into the absorber column.Type: GrantFiled: December 10, 2018Date of Patent: April 25, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Alfred Gubrinski, Sandra Jensen, Sharon Corbet
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Publication number: 20230119575Abstract: Facility and method for hydrogen refrigeration, comprising a hydrogen circuit to be cooled, comprising:—a first and a second set of heat exchanger(s) arranged in series for exchanging heat with the hydrogen circuit to be cooled;—a first cooling device for exchanging heat with the first set of heat exchanger(s) comprising a refrigerator that operates a refrigeration cycle of a first cycle gas;—a second cooling device for exchanging heat with the second set of heat exchanger(s) comprising a refrigerator that operates a refrigeration cycle of a second cycle gas having a molar mass of less than 3 g/mol, the refrigerator of the second cooling device comprising, arranged in series in a cycle circuit: at least one centrifugal compressor, a cooling member, an expansion member and a member for reheating the second expanded cycle gas;—a system for mixing at least one additional component having a molar mass greater than 50 g/mol with the second cycle gas before it enters the at least one centrifugal compressor and a meType: ApplicationFiled: March 3, 2021Publication date: April 20, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Patrick LE BOT, Marine ANDRICH, Nicolas KOFMAN
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Patent number: 11629050Abstract: A method for decreasing the SFFC of a steam reforming plant, including establishing a base operating mode. Then modifying the base operating mode by introducing the shift gas stream into a solvent based, non-cryogenic separator prior to introduction into the pressure swing adsorption and introducing the compressed hydrogen depleted off-gas stream in a membrane separation unit, wherein the membrane is configured to produce the hydrogen enriched permeate stream at a suitable pressure to allow the hydrogen enriched permeate stream to be combined with carbon dioxide lean shift gas stream, prior to introduction into the pressure swing adsorption unit without requiring additional compression. Thereby establishing a modified operating mode. Wherein said pressure swing adsorption unit has a modified overall hydrogen recovery. Wherein said modified operating mode has a modified hydrogen production, a modified hydrogen production unit firing duty, a modified SCO2e, and a modified SFFC.Type: GrantFiled: July 16, 2021Date of Patent: April 18, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Pierre-Philippe Guerif, Joseph T. Stroffolino, IV, Alain Guillard
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Patent number: 11629111Abstract: Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example two-stage, heterogeneously catalyzed methanol synthesis, wherein the methanol product formed in every synthesis stage is separated by condensation and the remaining residual gas is supplied to the downstream synthesis stage or after separation of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention after each synthesis stage the residual gas streams have separated from them a respective purge stream, from which, using one or more hydrogen recovery apparatuses, hydrogen is separated and recycled to the first synthesis stage. The ratio of the individual purge streams and their total molar flow may optionally be varied to allow better control of the reaction in the individual synthesis stages and to allow reaction to the advancing deactivation of the catalysts present therein.Type: GrantFiled: December 13, 2021Date of Patent: April 18, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Veronika Gronemann, Karin Huder
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Patent number: 11629051Abstract: A method for decreasing the SFFC of a steam reforming plant, including establishing a base operating mode. Then modifying the base operating mode by introducing the shift gas stream into a solvent based, non-cryogenic separator prior to introduction into the pressure swing adsorption and introducing the compressed hydrogen depleted off-gas stream in a membrane separation unit, wherein the membrane is configured to produce the hydrogen enriched permeate stream at a suitable pressure to allow the hydrogen enriched permeate stream to be combined with carbon dioxide lean shift gas stream, prior to introduction into the pressure swing adsorption unit without requiring additional compression. Thereby establishing a modified operating mode. Wherein said pressure swing adsorption unit has a modified overall hydrogen recovery. Wherein said modified operating mode has a modified hydrogen production, a modified hydrogen production unit firing duty, a modified SCO2e, and a modified SFFC.Type: GrantFiled: July 16, 2021Date of Patent: April 18, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Pierre-Philippe Guerif, Joseph T. Stroffolino, IV, Alain Guillard
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Patent number: 11629918Abstract: The invention relates to a heat exchanger for vaporizing a coolant fluid by heat exchange with a calorigenic fluid, said exchanger comprising several parallel plates defining a plurality of passages between them which are suitable for the coolant fluid or calorigenic fluid to flow, a first wave and a second wave extending between two successive plates so as to define a plurality of channels within the same passage, said first and second waves comprising two adjacent edges, at least one assembly member extending from one edge to the other so as to connect the waves to one another. According to the invention, the assembly member is forcibly engaged in at least one part of a channel of the first wave on one hand, and in at least one part of a channel of the second wave on the other hand.Type: GrantFiled: April 12, 2018Date of Patent: April 18, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Guillaume Cardon, Frederic Crayssac, Philippe Grigoletto, Natacha Haik-Beraud, Frederic Rousseau, Marc Wagner
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Patent number: 11628392Abstract: An absorption column including at least one external heat exchange circuit for cooling or heating the absorption liquid, including one or more serially connected heat exchangers, wherein the junction of the pipeline for withdrawal of the absorption liquid from the column is disposed above the junction of the pipeline into the first heat exchanger in the flow direction, wherein the pipeline also includes a dumped bed.Type: GrantFiled: August 2, 2018Date of Patent: April 18, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaideInventors: Sophia Schmidt, Dorit Rappold, Christian Frey, Sharon Corbet, Alfred Gubrinski
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Patent number: 11624479Abstract: A quantity of gas is introduced into a gas reservoir via a filling station provided with a filling line. The quantity is measured. A signal is generated indicating a corrected quantity of transferred gas. The signal is obtained by adding a predetermined, positive or negative, corrective amount to the measured quantity of gas transferred.Type: GrantFiled: March 29, 2018Date of Patent: April 11, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Thibaut Francois, Marcus Buck
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Patent number: 11624035Abstract: The invention relates to a gas scrubbing process and plant for purifying raw synthesis gas by physical absorption in methanol. A raw synthesis gas stream which includes hydrogen and carbon monoxide as desired constituents and water and acid gases as undesired constituents is admixed with methanol and subsequently cooled below the freezing point of water. According to the invention a liquid phase including methanol and water is separated from the cooled raw synthesis gas stream. Acid gases are removed from the remaining gaseous phase by physical absorption in methanol at elevated pressure. Separating the water from the raw synthesis gas stream before the absorption of the acid gases prevents larger amounts of water passing into the methanol circuit of the gas scrubbing process. This achieves savings in resources and certain plant parts may be smaller than is customary.Type: GrantFiled: May 19, 2021Date of Patent: April 11, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Ganesh Arumugam, Dorit Rappold, Sharon Corbet, Robert Szabo
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Patent number: 11624464Abstract: A device for supplying pressurized fluid, comprising a first valve) and a second valve accommodating internal circuits, the first valve and the second valve including respective coupling members that form a quick-connection system for removably connecting the second valve to the first valve, the internal circuits including a set of one or more control valves the device including at least one manually actuable mobile control member for controlling the set of one or more control valves, between a first, rest position, in which the flow of fluid towards the outlet is prevented, and a second, active position, in which the flow of fluid towards the outlet is allowed, the quick-connection system including a connection piece for connecting the second valve to the first valve between a first position.Type: GrantFiled: May 20, 2020Date of Patent: April 11, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Antoine Frenal, Guillaume Casaert, Valérie Nille, Sébastien Gorry, René Fogen, Morgan Lamiable
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Publication number: 20230107973Abstract: Dilution refrigeration device and method comprising a loop working circuit containing a working fluid comprising a mixture of helium-3 (3He) and helium-4 (4He), the working circuit comprising, arranged in series and fluidically connected via a first set of pipes, a mixing chamber, an evaporator and transfer member, the first set of pipes being configured to transfer the working fluid from an outlet of the mixing chamber to an inlet of the evaporator and from an outlet of the evaporator to an inlet of the transfer member, the working circuit comprising a second set of pipes connecting an outlet of the transfer member to an inlet of the mixing chamber, the working circuit comprising at least a first heat-exchange portion for exchange of heat between at least part of the first set of pipes and the second set of pipes, the first heat-exchange portion being situated between the evaporator and the mixing chamber, the device further comprising at least one cooling member in a heat-exchange relationship with the workType: ApplicationFiled: February 3, 2021Publication date: April 6, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Simon CRISPEL, Alain RAVEX
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Patent number: 11619443Abstract: A method and apparatus for the production of air gases by the cryogenic separation of air with front end purification and air compression can include using an available compressed dry gas such as nitrogen, oxygen, stored purified air, or synthetic air to repressurize the adsorber without diverting any of the purified air just exiting the currently on-line adsorber or changing the flow rate of the main air compressor or air sent to the cold box. This enables the main air compressor (MAC) to operate at a relatively constant flow rate while also sending a relatively constant air flow to the cold box during this repressurization step, thereby reducing the risks of process upsets and minimizing capital expenditures related to the MAC and other warm-end equipments.Type: GrantFiled: December 15, 2020Date of Patent: April 4, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Kong, Minh Pham-Huy, Wendy Yip
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Publication number: 20230085780Abstract: The invention relates to a fluid compression apparatus having a plurality of compression stages, comprising a first compression chamber, a second compression chamber, an intake system communicating with the first compression chamber which is configured to allow fluid to be compressed into said first compression chamber, a transfer system configured to allow in an open position the transfer of fluid from the first compression chamber to the second compression chamber, a mobile piston for ensuring the compression of the fluid in the first and second compression chambers.Type: ApplicationFiled: October 21, 2020Publication date: March 23, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Cyril BENISTAND-HECTOR, Guillaume PETITPAS
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Patent number: 11608294Abstract: Method and installation for calcining cement raw meal in a calciner whereby fuel and a calciner oxidant having an oxygen content of at least 30% vol are introduced into the calciner so as to generate either an oxidant-lean zone or a fuel-lean zone in the calciner located between the lowermost fuel inlet level and the lowermost oxidant inlet level of the calciner, between 50% and 100% by weight of the raw meal being supplied to the calciner upstream of and/or within the oxidant-lean, respectively the fuel-lean zone.Type: GrantFiled: March 20, 2020Date of Patent: March 21, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Faustine Panier, Xavier Paubel, Carlo Renna, Michel Gimenez, Colin Paxton, Henrik Wassard, Morten Drivsholm, Remi Tsiava
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Publication number: 20230080231Abstract: The invention relates to a fluid compression apparatus comprising a housing having a compression chamber, an intake system communicating with the compression chamber which is configured to allow fluid to be compressed into said compression chamber, and a mobile piston for ensuring the compression of the fluid in the compression chamber. The apparatus further comprises a discharge port which is configured to allow the exit of compressed fluid from the compression chamber, the compression chamber being defined by a portion of the body of the piston and a fixed wall of the apparatus, the piston being translationally mobile along a longitudinal direction. The invention is characterized in that the piston has a tubular portion mounted around a fixed central guide, a first terminal end of the central guide forming the fixed wall delimiting a part of the compression chamber.Type: ApplicationFiled: October 21, 2020Publication date: March 16, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Cyril BENISTAND-HECTOR, Guillaume PETITPAS
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Patent number: 11604024Abstract: A process for liquefying a natural gas feed stream including cooling a feed gas stream to obtain a liquefied natural gas stream; introducing the liquefied natural gas stream into a deazotization column to produce a liquefied natural gas stream and a nitrogen-enriched vapor stream; at least partially condensing at least part of the nitrogen-enriched vapor stream to produce a two-phase stream; introducing the two-phase stream into a phase-separating vessel to produce a first liquid stream and a first nitrogen-enriched gas stream; introducing at least part of the nitrogen-enriched gas stream into a distillation column thereby producing a second nitrogen-enriched stream containing less than 1 mol % of methane and a second liquid stream containing less than 10 mol % of nitrogen; wherein at least part of the liquefied natural gas stream is used to cool the at least part of the nitrogen-enriched vapor stream in said heat exchanger.Type: GrantFiled: December 17, 2018Date of Patent: March 14, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Henri Paradowski, Sébastien Lichtle, Marie Muhr
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Publication number: 20230071844Abstract: The invention relates to a fluid compression apparatus comprising a first and a second compression chamber, an intake system communicating with the first compression chamber, a transfer system communicating with the first and second compression chambers, and a mobile piston for ensuring the compression of the fluid in the first and second compression chambers. The apparatus further comprises a discharge port which communicates with the second compression chamber and is configured to allow the outlet of compressed fluid, wherein the second compression chamber is defined by a part of the body of the piston and a fixed wall of the apparatus, the piston being translationally mobile according to a longitudinal direction, the piston having a tubular portion mounted around a fixed central guide, a terminal end of the central guide forming the fixed wall defining a part of the second compression chamber.Type: ApplicationFiled: October 21, 2020Publication date: March 9, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Cyril BENISTAND-HECTOR, Guillaume PETITPAS
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Patent number: 11598521Abstract: Process for combusting a fuel with an oxidant and burner for the implementation thereof, process wherein at least one stream of the fuel is injected through at least one first perforation, a main flow of oxidant is injected below or above the one or more streams of the fuel through at least one second perforation, an auxiliary flow of the oxidant is introduced into contact with the at least one fuel stream so as to generate an initial flame by an initial partial combustion of the fuel with the auxiliary flow of the oxidant, this initial partial combustion being completed downstream of the initial flame by means of the at least one main stream of the oxidant, the flow rate of the main flow of the oxidant or the ratio between the flow rate of the main flow of the oxidant and the flow rate of the auxiliary flow of the oxidant being adjusted depending on the emission intensity of the initial flame.Type: GrantFiled: March 26, 2020Date of Patent: March 7, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Sarah Juma, Chloe Caumont-Prim, Xavier Paubel, Jean-Baptiste Senechal, Benoit Grand
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Publication number: 20230067726Abstract: A liquid cryogen stored in a liquid cryogen space of a closed insulated cryogenic storage vessel is subcooled by allowing it to enter into a conduit disposed in the liquid cryogen space where it is expanded by a pressure reducer in the conduit, thereby producing a cooled biphasic mixture of the cryogen in liquid and vaporized forms. The cooled biphasic mixture has a temperature lower than that of the liquid cryogen in the liquid cryogen space. Heat is transferred across the conduit from the liquid cryogen in the liquid cryogen space to the cooled biphasic mixture.Type: ApplicationFiled: September 2, 2021Publication date: March 2, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Joshua Light
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Publication number: 20230067385Abstract: The invention relates to a fluid-compression device including a compression chamber comprising a movable piston, the device comprising a first end housing a first end of the compression chamber, the device comprising a second end housing a second end of the compression chamber, the piston being translatable between the first and second ends of the compression chamber, the device comprising a regeneration pipe connecting the first and second ends of the compression chamber and including a regenerator, the device comprising a supply pipe comprising an upstream end intended to be connected to a source of fluid to be compressed and a downstream end opening into the first end of the compression chamber, the supply pipe comprising a valve assembly, the device comprising a pipe for discharging the compressed fluid comprising an upstream end connected to the compression chamber and a downstream end intended to be connected to a receiver of the compressed fluid, the discharge pipe comprising a valve assembly, characteType: ApplicationFiled: December 17, 2020Publication date: March 2, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Yan PENNEC, Rasmey TRY