Patents Assigned to L'Air Liquide, Societe Anonyme Pour L'Etude
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Patent number: 11959702Abstract: An air separation device can include: a first compressor and a second compressor for compressing feed air; a first refrigerator and a second refrigerator for cooling the feed air; a pre-purification unit for pre-purifying the feed air; a flow rate measuring unit for measuring the flow rate of the feed air; a main heat exchanger for subjecting the feed air to heat exchange; a purification portion into which the feed air led out from the main heat exchanger is fed, and which separates and purifies product nitrogen and/or product oxygen from the feed air; and a compressor control unit for controlling the feed quantity of the feed air in accordance with an increase or decrease in the production quantity of product nitrogen and/or product oxygen.Type: GrantFiled: March 4, 2021Date of Patent: April 16, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Takuya Kaneda, Tsuyoshi Sugitani
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Publication number: 20240116009Abstract: Composite hollow fiber gas separation membranes with improved permeance and separation layer adhesion are manufactured by providing dipping a hollow fiber membrane substrate in a pre-coat layer coating composition followed by drying to thereby provide a pre-coated substrate and dipping the pre-coated substrate in a separation layer coating composition followed by drying to thereby provide the composite hollow fiber gas separation membranes. The pre-coating composition includes a first polymer dissolved in a first solvent and the separation layer composition includes a second polymer dissolved in a second solvent. The first and second polymers are the same or different, each of the first and second polymers is at least 1 wt % soluble in a same third solvent, the first and second solvents are the same or different, the first and third solvents are the same or different, and the second and third solvent are the same or different.Type: ApplicationFiled: October 10, 2022Publication date: April 11, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Junyi LIU, Sudhir KULKARNI, Raja SWAIDAN, Megha SHARMA
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Publication number: 20240117911Abstract: Self-closing emergency release and coupling device for the transport of cryogenic fluid comprising two pipes extending in a longitudinal direction and each comprising, at a connection end, a valve mechanism configured to automatically close the pipe when the connection ends are separated and to open the pipe when the connection ends are coupled, the device further comprising a tube arranged around each pipe and defining a vacuum space for thermally insulating the pipeline, the device is characterized in that it further comprises a chamber disposed around the valve mechanism and delimited by a wall assembly located between the outer tube and the transport pipe, the volume of the insulation chamber being independent of the vacuum space between the outer tube and the transport pipe.Type: ApplicationFiled: January 17, 2022Publication date: April 11, 2024Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Gaetan COLEIRO, Yan PENNEC
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Publication number: 20240118024Abstract: Disclosed is a device for refrigerating or liquefying a fluid such as natural gas or hydrogen, comprising a circuit for fluid that is to be cooled and has an upstream end for connection to a source of gaseous fluid and a downstream end for connection to a member for collecting the cooled or liquefied fluid, the device comprising a heat exchanger assembly in heat exchange with the circuit of fluid to be cooled, the device comprising a refrigerator in heat exchange with at least a portion of the heat exchanger assembly, the refrigerator being of the type that has a cycle for refrigerating a cycle gas containing at least one of: helium, hydrogen, nitrogen or neon; said refrigerator comprising, arranged in series in a cycle circuit: a mechanism for compressing the cycle gas, at least one member for coding the cycle gas, a mechanism for expanding the cycle gas, and at least one member for reheating the expanded cycle gas, wherein the compression mechanism comprises a plurality of compression stages in series compoType: ApplicationFiled: January 18, 2022Publication date: April 11, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Mathieu ROIG, Remi NICOLAS, Fabien DURAND, Guillaume DELAUTRE
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Publication number: 20240117285Abstract: Raw biogas from an anaerobic digester is fed to a membrane separation unit that produces methane rich biomethane and a CO2 rich permeate that is recycled to the anaerobic digester where it is mixed with the digestate.Type: ApplicationFiled: October 6, 2022Publication date: April 11, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Sudhir KULKARNI, Min Ho MAENG, Shu FANG
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Publication number: 20240118025Abstract: Disclosed is a device for refrigerating or liquefying a fluid such as natural gas or hydrogen, comprising a fluid circuit that is to be cooled and has an upstream end for connection to a source of gaseous fluid as well as a downstream end for connection to a member for collecting the cooled or liquefied fluid, the device comprising a heat exchanger assembly in heat exchange with the fluid circuit to be cooled, the device comprising a refrigerator in heat exchange with at least a portion of the exchanger assembly, the refrigerator being of the type that has a cycle for refrigerating a cycle gas containing at least one of: helium, hydrogen, nitrogen or neon; said refrigerator comprising in series in a cycle circuit: a mechanism for compressing the cycle gas, at least one member for cooling the cycle gas, a mechanism for expanding the cycle gas, and at least one member for reheating the expanded cycle gas, wherein the compression mechanism comprises a plurality of compression stages in series composed of a centrType: ApplicationFiled: January 18, 2022Publication date: April 11, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Mathieu ROIG, Remi NICOLAS, Fabien DURAND, Guillaume DELAUTRE
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Patent number: 11953158Abstract: A device and process for refuelling containers comprising a pressurized gas source, a transfer circuit intended to be removably connected to a container, the device comprising a refrigeration system comprising a refrigerant cooling loop circuit comprising, arranged in series, a compressor, a condenser section, an expansion valve and an evaporator section, the refrigeration system comprising a cold source in heat exchange with the condenser section and a heat exchanger located in the transfer circuit, the refrigerant cooling loop circuit comprising a bypass conduit comprising an upstream end connected to the outlet of the compressor and a downstream end connected to the refrigerant cooling loop circuit upstream the compressor inlet, the device further comprising a bypass regulating valve for controlling the flow of refrigerant flowing into the by-pass conduit, the device comprising a pressure sensor for sensing the refrigerant pressure in the cooling loop circuit between the compressor inlet and the heat exchaType: GrantFiled: October 31, 2022Date of Patent: April 9, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Etienne Werlen, Marcus Buck
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Patent number: 11953157Abstract: The invention relates to a method for storing and distributing liquefied hydrogen using a facility that comprises a store of liquid hydrogen at a predetermined storage pressure, a source of hydrogen gas, a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen store, the store comprising a pipe for drawing liquid, comprising one end connected to the liquid hydrogen store and one end intended for being connected to at least one mobile tank, the method comprising a step of liquefying hydrogen gas supplied by the source and a step of transferring the liquefied hydrogen into the store, characterized in that the hydrogen liquefied by the liquefier and transferred into the store has a temperature lower than the bubble temperature of hydrogen at the storage pressure.Type: GrantFiled: September 24, 2019Date of Patent: April 9, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Claude Georges ClaudeInventors: Laurent Allidieres, Renan Luis De Souza Silva
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Patent number: 11952270Abstract: A method and system for purification of helium and CO2 from a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.Type: GrantFiled: October 5, 2021Date of Patent: April 9, 2024Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Air Liquide Advanced Technologies U.S. LLCInventors: Paul Terrien, Pierre-Philippe Guerif, Vincent Follaca, Alain Guillard, Youssef Tazi
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Publication number: 20240110670Abstract: At a liquid cryogen depot, gaseous cryogen from non-completely filled short trailers is used for pressurizing jumbo trailers, from which liquid cryogen is caused to flow into empty trailers through pressure differential.Type: ApplicationFiled: September 29, 2022Publication date: April 4, 2024Applicant: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Joshua LIGHT
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Patent number: 11946594Abstract: Mobile cryogenic tank for transporting cryogenic fluid, notably liquefied hydrogen or helium, comprising an internal shell intended to contain the cryogenic fluid, an external shell arranged around the internal shell and delimiting a space between the two shells, said space containing a thermal insulator, the first shell having a cylindrical overall shape extending along a central longitudinal axis (A), when the tank is in the configuration for transport and use, the central longitudinal axis (A) being oriented horizontally, the tank comprising a set of temperature sensors measuring the temperature of the fluid in the internal shell, characterized in that the set of temperature sensors is situated on the external face of the internal shell and measure the temperature of said shell, the set of temperature sensors comprising a lower sensor positioned at the lower end of the internal shell situated below the central longitudinal axis (A), the set of temperature sensors further comprising a plurality of intermediType: GrantFiled: January 14, 2021Date of Patent: April 2, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Lucien Varrassi, Philippe Cadeau, Thomas Fayer, Stephane Duval
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Patent number: 11946691Abstract: A combined plant for cryogenic separation and liquefaction of methane and carbon dioxide in a biogas stream, including a mixing means, a compressor, a first exchanger, a distillation column, a second exchanger, a separating means, an expanding means, and a separator vessel. Wherein, the mixing means is configured such that the recycle gas is the overhead vapour stream, and the first exchanger and the expanding means are combined.Type: GrantFiled: June 9, 2022Date of Patent: April 2, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation de Procédés Georges ClaudeInventor: Jorge Ernesto Tovar Ramos
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Patent number: 11946692Abstract: A method for separating a mixture containing at least nitrogen and methane by cryogenic distillation in a first column operating in a first pressure and a second column operating at a second pressure lower than the first pressure, the mixture being separated in the first column to form a gas enriched in nitrogen and a liquid enriched in methane, at least a portion of the gas enriched in nitrogen being at least partially condensed in a heat exchanger and returned to the first column, the gas enriched in nitrogen is sent into the heat exchanger by the bottom, ascends in a first series of passages of the exchanger and condenses therein at least partially, the liquid formed descending in these passages of the first series and exiting by the bottom of the exchanger.Type: GrantFiled: April 8, 2022Date of Patent: April 2, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Paul Terrien, Nicolas Chantant, Jean-Marc Peyron
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Patent number: 11946693Abstract: The invention relates to a system for controlling an argon flow rate of a fluid at the outlet of an assembly of at least one distillation column in order to reach a target dioxygen level (SP).Type: GrantFiled: May 22, 2019Date of Patent: April 2, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Marc Bastid
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Patent number: 11946703Abstract: A heat exchanger having a stack of multiple plates which are parallel to one another and to a longitudinal direction, and stacked spaced apart from one another so as to define, between one another, a first series of passages for the flow of at least a first fluid in an overall flow direction parallel to the longitudinal direction, each passage being delimited by closure bars disposed between the plates. A filtering device is arranged in at least one passage of the first series, the filtering device extending for the one part between two adjacent plates defining the passage and for the other part between two of the closure bars delimiting the passage, the filtering device having a metal sheet material chosen from among a metal fabric, a nonwoven of metal fibres, a sintered metal powder or sintered metal fibres, a metal foam, or a microperforated plate.Type: GrantFiled: May 12, 2022Date of Patent: April 2, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Eric Masliah, Arnaud Gueguen, Gilles Lebain, Ludovic Amant
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Publication number: 20240101430Abstract: An apparatus for the separation of a flow containing carbon dioxide by distillation comprising a heat exchange means, a distillation column, means for sending the flow to be cooled in the heat exchange means down to a first intermediate temperature in order to form a liquid flow at a first temperature and at a first pressure, means for dividing the liquid flow in order to form a first fraction and a second fraction, means for expanding the first fraction to the pressure of a distillation column, means for sending the expanded first fraction to an intermediate level of the distillation column, means for exiting the second fraction from the cold end of the heat exchange means after cooling, means for expanding the cooled second fraction to the pressure of the distillation column, means for sending the second fraction to the distillation column and means for the withdrawal, from the bottom of the column, of a liquid flow.Type: ApplicationFiled: January 27, 2022Publication date: March 28, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Michael TRAN, Mathieu LECLERC
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Publication number: 20240102728Abstract: The invention relates to an installation and a process for production of a cryogenic fluid, in particular of liquefied hydrogen, comprising, positioned in at least one cold box, a set of heat exchangers in thermal exchange with the circuit for hydrogen to be cooled, the installation comprising a device for pre-cooling, which is configured to pre-cool the circuit for gas to be cooled to a first determined temperature, and a device for cryogenic cooling which is configured to cool the circuit for gas to be cooled to a second determined temperature, lower than the first temperature, the cycle gas cooling unit and/or the cycle gas heating unit comprise(s) one or more first cycle heat exchangers distinct from the first part of the pre-cooling heat exchangers of the circuit for the gas to be cooled, these first cycle heat exchangers also being cooled by thermal exchange with the pre-cooling fluid circuit of the pre-cooling device.Type: ApplicationFiled: September 26, 2023Publication date: March 28, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Emeline VANDROUX, Florian MARTIN, Ludovic GRANADOS, Jean-Marc BERNHARDT
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Publication number: 20240105967Abstract: The invention relates to a bipolar plate for a fuel cell stack that extends in a vertical plane in the use position, the plate comprising opposed first and second transverse edges, upper and lower longitudinal edges, a central region arranged between the edges, a first opening for a heat transfer fluid inlet, a second opening for heat transfer fluid collection a third opening for an oxidant inlet, a fourth opening for oxidant collection, a fifth opening for the inlet of a fuel, a sixth opening for fuel collection, wherein the first, third and sixth openings are arranged in the first transverse edge and are arranged axially in relation to one another, the second, fourth and fifth openings are arranged in the second transverse edge and are arranged axially in relation to one another, and, in the vertical position of use of the plate: the sixth opening are arranged below the first and third openings, the fourth opening is arranged below the second and fifth openings, and the second opening is arranged above theType: ApplicationFiled: November 17, 2023Publication date: March 28, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Johan ANDRE, Camille BOUVIER, Eric CLAUDE, Nicolas JANNIN, Denis SIRAC, Didier ZAEPFFEL
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Patent number: 11940228Abstract: The present invention discloses a high-temperature fluid transporting pipeline with a heat exchange apparatus installed therein, a suitable heat exchange apparatus and a heat exchange method, wherein heat contained in a high-temperature fluid can be recovered during the transportation thereof. The heat exchange apparatus comprises a heat exchange body inserted into the high-temperature fluid transporting pipeline, and a heat-receiving fluid coil installed therein. The method of heat exchange is that the high-temperature fluid heats an auxiliary fluid in a heat exchange cavity via a heat exchange panel of the heat exchange body in contact therewith, and the heated auxiliary fluid then conducts the heat to a heat-receiving fluid in the heat-receiving fluid coil.Type: GrantFiled: December 17, 2021Date of Patent: March 26, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Yuquan Gu, Peter Van Kampen, KuoHsuan Wang, Aili Zhang, Wenbiao Zhou
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Patent number: 11940149Abstract: An elevated flare system in a synthesis gas production plant for thermal disposal of offgases having at least two different contents of carbon monoxide arising in synthesis gas production and/or synthesis gas treatment.Type: GrantFiled: January 12, 2021Date of Patent: March 26, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Antonio Coscia