Patents Assigned to L'Air Liquide, Societe Anonyme Pour L'Etude
  • Publication number: 20240011706
    Abstract: In a method for regulating a device for separating air by cryogenic distillation, during the change from a low-flow mode to a high-flow mode, two flow rates of reflux sent to the low-pressure column of a double column are increased more rapidly than the flow rate of gaseous air sent to the medium-pressure column of the double column in order to ensure the stability of the oxygen content in the argon bulge of the low-pressure column during the mode change.
    Type: Application
    Filed: July 5, 2023
    Publication date: January 11, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: John PACHON MORALES, Jean-Francois RAUCH, Jean-Pierre TRANIER
  • Publication number: 20240011704
    Abstract: A device for separating air by cryogenic distillation, comprising a first module containing a main air compressor, a second module, a third module containing a purification unit, a fourth module containing a heat exchanger and a system of columns comprising at least one distillation column that is or is not contained in the fifth module, the second module containing a connection for connecting the compressor of the first module to the purification unit of the third module in order to send compressed air from the compressor to the purification unit and also containing a connection for connecting the purification unit to the heat exchanger of the fourth module in order to send purified air in the purification unit to the heat exchanger.
    Type: Application
    Filed: December 2, 2021
    Publication date: January 11, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventor: Benoit DAVIDIAN
  • Patent number: 11865491
    Abstract: The invention relates to a method for managing a PSA unit having at least N adsorbers arranged in pairs, where each pair is designed to be able to be selectively isolated, a control device, and a plurality of interfaces for accessing the instrumentation of each adsorber. When a first pair is fluidically isolated, the first pair having a first and a second adsorber, the isolating of a third adsorber includes setting the control device to control N-4 adsorbers, fluidically isolating a second pair having the third and a fourth adsorber, isolating one of the first and second adsorbers and the third adsorber, configuring the interfaces so as to swap over the instrumentation of the other of the first and second adsorbers and the instrumentation of the fourth adsorber, placing the first and second pairs in fluidic communication, and setting the control device to control N-2 adsorbers.
    Type: Grant
    Filed: June 10, 2021
    Date of Patent: January 9, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Jan Matthyssen, Pascal Meerman, Luc Nelis
  • Publication number: 20240003617
    Abstract: The invention relates to an installation for liquefying hydrogen, comprising a circuit for hydrogen to be cooled, a set of heat exchanger(s) in heat exchange with the circuit, a cooling system comprising a refrigerator with a cycle of refrigeration of a first cycle gas comprising helium and/or hydrogen, the circuit comprising at least one catalysis section so as to ensure conversion of the ortho-hydrogen into para-hydrogen, the circuit further comprising a first bypass portion bypassing at least one catalysis section, the downstream end of the circuit comprising two parallel branches that are not combined and are supplied respectively with the hydrogen that has passed through the first bypass portion and hydrogen that has passed through the catalysis section so as to provide two distinct hydrogen streams that have different relative proportions of ortho-hydrogen and para-hydrogen.
    Type: Application
    Filed: June 29, 2023
    Publication date: January 4, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventor: Plays THIBAULT
  • Patent number: 11857911
    Abstract: A unit for purifying a gas mixture by adsorption, including at least one adsorber having at least one cluster of N identical adsorbent modules operating in parallel, where N?2, each cluster of N adsorbent modules includes a common inlet manifold having a straight inlet duct of axis Xe supplying N inlet nozzles Tei, where i ranges from 1 to N, respectively connected to the inlets Ei, where i ranges from 1 to N, of the N modules of the cluster, a common outlet manifold having a straight outlet duct of axis Xs collecting the flow leaving the N outlet nozzles Tsi, where i ranges from 1 to N, respectively connected to the outlets Si, where i ranges from 1, of the N modules of the cluster.
    Type: Grant
    Filed: February 27, 2019
    Date of Patent: January 2, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christian Monereau, Benjamin Morineau, Guillaume Rodrigues
  • Patent number: 11857912
    Abstract: A process for producing a purified gas stream having impurities, using a production unit for producing a gas stream and a storage reservoir. The process includes producing a first gas stream by means of the production unit. Storing at least a portion of the first gas stream in the storage reservoir. Extracting, from the storage reservoir, a second gas stream corresponding to at least one portion of the first stream polluted by the impurities. Purifying the second gas stream by transfer of at least one portion of the impurities contained in the second gas stream into the first gas stream. And recovery of the purified gas stream at the output of the purification.
    Type: Grant
    Filed: March 7, 2019
    Date of Patent: January 2, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christian Monereau, David Frimat, Vincent Gueret, Pierre Petit
  • Patent number: 11859283
    Abstract: Methods for forming an Indium-containing film by a vapor deposition method using a heteroalkylcyclopentadienyl Indium (I) precursor having a general formula: In[R1R2R3R4CpL1] or In[CpL1L2y] wherein Cp represents a cyclopentadienyl ligand; R1 to R4 are each independently H, C1-C4 linear, branched or cyclic alkyls; L1 and L2 are each independently a substituent bonded to the Cp ligand and consisting of an alkyl chain containing at least one heteroatom, such as Si, Ge, Sn, N, P, B, Al, Ga, In, O, S, Se, Te, F, Cl, Br, I; and y=1-4. Examplary heteroalkylcyclopentadienyl Indium (I) precursors include In(Cp(CH2)3NMe2) or In(CpPiPr2).
    Type: Grant
    Filed: July 28, 2020
    Date of Patent: January 2, 2024
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Antoine Bruneau, Takashi Ono, Christian Dussarrat
  • Patent number: 11850537
    Abstract: The present invention relates to an insertion device for inserting at least one packing section for a gas/liquid separation column into a cylindrical casing, comprising a base provided with retaining means which are configured to grip a packing section and which are arranged uniformly around a main axis, characterized in that the insertion device comprises at least two fastening means secured to the base, said fastening means being configured to fasten the insertion device to the casing. The invention also covers an insertion system for inserting at least one packing section into a cylindrical casing, comprising such an insertion device, and a method for inserting at least one packing section into a cylindrical casing that is implemented by such an insertion system.
    Type: Grant
    Filed: February 7, 2023
    Date of Patent: December 26, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Cyrille Babinet, Eric Gallopin, Gilles Lebain
  • Patent number: 11852408
    Abstract: In a method for separating air by cryogenic distillation using a column system consisting of a higher pressure column operating at a first pressure and a lower pressure column operating at a second pressure, a first air flow constituting between 75% and 98% of the air sent to the column system compressed to a third pressure above the first pressure, is sent to the higher pressure column, a second air flow constituting between 5% and 25% of the air sent to the column system is compressed to a fourth pressure above the second pressure but lower than the third pressure, is sent to the lower pressure column, a third column separates an argon-enriched flow and the air sent to the lower pressure column constitutes between 10% and 25% of the total air sent to the column system.
    Type: Grant
    Filed: May 5, 2021
    Date of Patent: December 26, 2023
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Jean-Pierre Tranier, Richard Dubettier-Grenier, Maxime Rozieres
  • Publication number: 20230408193
    Abstract: Apparatus for separating air comprising a device for breaking up a jet of cryogenic liquid in a gas flow, comprising a supply pipeline for the cryogenic liquid having an inside diameter greater than or equal to 10 mm, and a gas pipe of circular section, with a diameter d, the gas pipe comprising a portion having a reduction in diameter by a ratio of 20 to 50% at the point of injection of liquid and over a distance y wherein: y=n×d and wherein the supply pipeline penetrates the gas pipe such that its end is in the portion of the pipe having the reduction in diameter and n is between 7 and 9.
    Type: Application
    Filed: May 23, 2023
    Publication date: December 21, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: John PACHON MORALES, Mikael WATTIAU, Bernard LABEGORRE, Lian-Ming SUN
  • Publication number: 20230408189
    Abstract: Plant and method for producing hydrogen at cryogenic temperature, in particular liquefied hydrogen, comprising: an electrolyzer having an oxygen outlet and a hydrogen outlet; a hydrogen circuit to be cooled, comprising an upstream end connected to the hydrogen outlet and a downstream end to be connected to a member for collecting cooled and/or liquefied hydrogen, the plant also comprising a set of heat exchanger(s) in heat exchange with the hydrogen circuit to be cooled, the plant further comprising at least one cooling device in heat exchange with at least a portion of the set of heat exchanger(s), the hydrogen circuit to be cooled comprising a system for expanding the hydrogen stream and at least one hydrogen compressor upstream of the hydrogen stream expansion system, the hydrogen stream expansion system comprising at least one expansion turbine, wherein said at least one expansion turbine and said at least one compressor are coupled to the same rotating shaft to transfer expansion work from the pressurize
    Type: Application
    Filed: October 20, 2021
    Publication date: December 21, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Pierre CRESPI, Pierre BARJHOUX
  • Patent number: 11845040
    Abstract: Method and installation for treating a CO2- and H2O-containing flue gas generated by an industrial process unit before CCUS, whereby the flue gas evacuated from the unit is subjected to cooling to a temperature T2 between 100 and 600° C., whereby the cooled flue gas is pretreated in one or more particle removal and/or gas cleaning and/or drying stages and the temperature of the cooled flue gas is further reduced to a temperature T3<T2, before a first part of pretreated flue gas is subjected to CCUS, a second part of the pretreated flue gas being recycled at temperature T3 as a cooling agent and mixed with the flue gas during the controlled cooling thereof, partially or fully purified CO2 from the CCUS may be recycled at temperature T4<T2 may be recycled as a cooling agent and mixed with the flue gas during the controlled cooling.
    Type: Grant
    Filed: January 12, 2022
    Date of Patent: December 19, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Fabrice Del Corso, Jean Caudal, Xavier Paubel
  • Publication number: 20230398496
    Abstract: A hollow fiber membrane bundle useful for manufacturing a wide variety of hollow fiber membrane modules having different flow configurations includes hollow fiber membranes arranged around a porous support tube, a cured resin tubesheet formed at first end of the bundle, and either a cured resin nub or a cured resin tubesheet formed at a second end of the bundle. The bore(s) of the hollow fiber membranes are open at a face of the tubesheet adjacent the first end of the bundle. The tubesheet has an annular structure that encapsulates the hollow fiber membranes and the porous support tube at the first end of the bundle but which does not completely block a bore of the porous support tube, wherein the collection tube has a plurality of orifices formed therein at least at positions adjacent the nub.
    Type: Application
    Filed: June 9, 2022
    Publication date: December 14, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep K. KARODE, Karl BEERS, Sudhir S. KULKARNI, Tim POLUDNIAK, Fan Z. WORLEY, Ed SANDERS, JR.
  • Publication number: 20230398494
    Abstract: A hollow fiber membrane bundle useful for manufacturing a wide variety of hollow fiber membrane modules having different flow configurations includes hollow fiber membranes arranged around a porous support tube, a cured resin tubesheet formed at first end of the bundle, and either a cured resin nub or a cured resin tubesheet formed at a second end of the bundle. The bore(s) of the hollow fiber membranes are open at a face of the tubesheet adjacent the first end of the bundle. The tubesheet has an annular structure that encapsulates the hollow fiber membranes and the porous support tube at the first end of the bundle but which does not completely block a bore of the porous support tube, wherein the collection tube has a plurality of orifices formed therein at least at positions adjacent the nub.
    Type: Application
    Filed: June 9, 2022
    Publication date: December 14, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep K. KARODE, Karl BEERS, Sudhir S. KULKARNI, Tim POLUDNIAK, Fan Z. WORLEY, Ed SANDERS, JR.
  • Patent number: 11834333
    Abstract: A method of co-producing liquid hydrogen and ammonia, including a hydrogen generator, a nitrogen generator, and a HLU is presented. The method includes pressurizing a hydrogen stream from the hydrogen generator in a hydrogen compressor, dividing the pressurized hydrogen into at least a first portion and a second portion, wherein the first portion includes at least part of the flow of a first refrigeration cycle in the HLU, and the second part comprises at least part of the feed to an ammonia plant. The method also includes pressurizing a nitrogen stream from the nitrogen generator in a HP nitrogen compressor, dividing the pressurized nitrogen stream into at least a first part and a second part, wherein the first part comprises at least part of the flow of a second refrigeration cycle in the HLU, and the second part comprises at least part of the feed to the ammonia plant.
    Type: Grant
    Filed: April 21, 2021
    Date of Patent: December 5, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation Procédés Georges Claude
    Inventors: Michael A. Turney, Alain Guillard, Joseph T. Stroffolino, IV
  • Publication number: 20230382735
    Abstract: A process for recovery of helium from one or more than one helium-containing off-gas streams comprises preconditioning off-gas through a multi-stage preconditioning device, cryogenically separating a helium-enriched gas fraction from the preconditioned off-gas received from the preconditioning device a cryogenic separation device, and purifying the helium-enriched gas fraction received from the cryogenic separation device using a purification device so as to obtain purified helium gas with a higher helium content than the helium-enriched gas.
    Type: Application
    Filed: April 21, 2023
    Publication date: November 30, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude, AIR LIQUIDE ELECTRONICS GmbH
    Inventor: Stefan LINDT
  • Publication number: 20230380430
    Abstract: A method for stunning animals and a respective stunning system is disclosed. Animals are lowered in a cradle into a pit filled with anoxic stunning gas. The cradle is provided with a heat sink, preferably comprising solid carbon dioxide, for cooling the stunning gas in the pit resulting in a density increase of the stunning gas in the pit. This reduces demixing of the stunning gas and rising of components such as nitrogen (N2) usually having a lower density than the air surrounding the stunning system.
    Type: Application
    Filed: May 24, 2023
    Publication date: November 30, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Nadia MAYOUFI OUERGHEMMI, Ansgar RINKLAKE, Marcel BROUNS
  • Patent number: 11828532
    Abstract: A method and apparatus for transferring a first liquid removed from an outlet of a first distillation column to an inlet of a second distillation column is provided. The second distillation column operates at a higher pressure than the first distillation column, and the inlet of the second distillation column is at higher elevation as compared to the outlet of the first distillation column. The method advantageously transfers the first liquid from the outlet to the inlet by mixing with a sufficient amount of a lower density second liquid that results in a mixed liquid having a reduced density as compared to the first liquid.
    Type: Grant
    Filed: December 31, 2020
    Date of Patent: November 28, 2023
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Eric Day
  • Patent number: 11831057
    Abstract: A method of integrating a fuel cell with a steam methane reformer is provided. The system includes at least one fuel cell including an anode and a cathode, and a steam methane reformer including a syngas stream, and a flue gas stream. The method includes introducing at least a portion of the flue gas stream to the cathode, thereby producing a CO2 depleted flue gas stream and introducing a hydrocarbon containing stream to the anode, thereby producing an electrical energy output and a carbon dioxide and hydrogen containing stream from the fuel cell.
    Type: Grant
    Filed: December 18, 2019
    Date of Patent: November 28, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Pierre-Philippe Guerif, Guillaume Rodriges
  • Patent number: D1008422
    Type: Grant
    Filed: September 16, 2020
    Date of Patent: December 19, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Renaud Ligonesche, Olivier Ondo