Abstract: Provided is a process for measuring the amount of impurities in a gas sample filling a laser absorption spectroscopy analysis cell. The process includes calculating the value of a characteristic representative of the absorbance of the gas sample, from a measurement of the gas sample at a single given pressure, and quantifying the impurities on the basis of a predetermined law for the variation of the characteristic as a function of the amount of impurities. The characteristic is the ratio of the difference between the luminous intensity (Iana) of a light beam transmitted through the gas and the luminous intensity (Iref) of the incident beam to the luminous intensity (Iref) of the incident beam. The impurities are quantified on the basis of a value of the coefficient of proportionality between the amount of impurities and the characteristic, determined on the basis of a table of variation of the characteristic as a function of pressure, for a given amount of impurities.
Type:
Grant
Filed:
October 12, 1999
Date of Patent:
January 29, 2002
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Inventors:
Mélanie Bartolomey, Jean-Marc Girard, Patrick Mauvais, James McAndrew
Abstract: The invention relates to a process for the manufacture of improved active charcoal exhibiting a high resistance to sulphur-comprising products, such as H2S, COS and mercaptans; to the improved active charcoal thus obtained; and to a process for the purification of a gas stream comprising sulphur-comprising compounds. The gas to be treated is air, nitrogen, hydrogen produced by reforming or cracking of alcohols, of ammonia or of hydrocarbons, natural gas, combustion gas or fermentation gas.
Type:
Application
Filed:
March 7, 2001
Publication date:
January 24, 2002
Applicant:
L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
Abstract: Process for welding one or more metal workpieces to be joined together by producing at least one welded joint between the edges to be welded of the said metal workpiece or workpieces, the said welded joint being obtained by using at least one laser beam and at least one electric arc, in which process, during welding of the joint, at least one part of the welding zone comprising at least one part of said welded joint is shielded during the operation with at least one shielding atmosphere formed by a gas mixture consisting of argon and/or helium with a content greater than or equal to 70% by volume; and at least one additional compound chosen from H2, O2, CO2 and N2 with a content of 0 to 30% by volume.
Type:
Application
Filed:
May 31, 2001
Publication date:
January 24, 2002
Applicant:
L'Air Liquid, Societe Anonyme Pour L'Etude et L'Explooitation des Procedes Georges
Inventors:
Francis Briand, Christian Bonnet, Philippe Lefebvre
Abstract: In an air separation apparatus comprising at least two columns (104, 105) and optionally a mixing column (107), a liquid containing between 22 and 70 mol % oxygen is vaporized in a reboiler/condenser (109) against a stream of air (86) which condenses therein at least partially. The stream of at least partially condensed air is sent to at least one column (104, 105, 107) of the column system.
Type:
Grant
Filed:
June 22, 2000
Date of Patent:
January 22, 2002
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Abstract: Air is distilled in a single column installed on a boat, and from here an oxygen-enriched liquid flow is drawn off. This flow is pressurized by a pump and vaporized by heat exchange with air or nitrogen. The oxygen is used for the partial oxidation of a flow contained hydrocarbons, for example natural gas.
Type:
Grant
Filed:
May 10, 2000
Date of Patent:
January 22, 2002
Assignees:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes
Georges Claude
Abstract: A liquid distributor includes a principal container with a perforated bottom, as well as transport members to transmit, by gravity, the liquid from at least one opening in the perforated bottom, to a supply point not in vertical alignment with this opening.
Type:
Grant
Filed:
November 17, 1998
Date of Patent:
January 15, 2002
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Abstract: Process for separating nitrogen from a gas mixture containing nitrogen and at least one gas which is less polar than nitrogen, and employing a differential gas adsorption technique, called PSA process, using an adsorbent of zeolite type, according to which the PSA process is used at a temperature of at least 40° C. by employing as adsorbent a zeolite whose nitrogen adsorption isotherm at 20° C.
Type:
Grant
Filed:
September 27, 1996
Date of Patent:
January 8, 2002
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Abstract: This device comprises a closed heating chamber (36) extending through the wall (3, 4, 5) of the tank and connected to this wall, a feed pipe (22) suitable for feeding the heating chamber (36) with a heating fluid having a temperature above the temperature of the cryogenic fluid, and an exhaust pipe (23) intended for discharging the heating fluid, each of the pipes intended for discharging the heating fluid, each of the pipes (22, 23) passing through an outer wall (20) of the heating chamber (36). The device is particularly useful in the delivery of ultrapure helium.
Type:
Grant
Filed:
June 8, 2000
Date of Patent:
January 8, 2002
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Abstract: Installation for analyzing the level of at least one element, from at least two initial gas sources (S1, S2, . . . ) in a sampling procedure, using at least one analyzer (A1, A2, . . . ) capable of analyzing the element, including:
at least two sources (S1, S2, . . . ) of initial gases to be analyzed;
at least two tapping lines (Lp1, Lp2, . . . ), each line being connected in its upstream part to one of the initial gas sources, and in its downstream part to a respective flow-directing component (V1, V2. . . );
at least two discharge lines (LE1, LE2, . . . ), each discharge line being connected in its upstream part to one of the directing components and in its downstream part to a discharge or to a storage point (E1, E2, . . . );
at least two secondary lines (Ls1, Ls2, . . .
Type:
Grant
Filed:
June 8, 1999
Date of Patent:
December 25, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des procedes Georges Claude
Abstract: Provided is a process for the manufacture of technical glass. The process includes, heating a glass bath with at least one flame, wherein the at least one flame is a non-hard flame which is blue in color and includes substantially no reducing species.
Type:
Grant
Filed:
December 4, 1997
Date of Patent:
December 25, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Inventors:
Pierre Bodelin, Patrick Recourt, Takashi Oguro, Kazuyoshi Nakano, Toshi Takaha, Hiroyuki Tanaka
Abstract: A PSA, especially VSA, plant for separating a gas stream, operating in a production cycle and comprising at least one adsorber, preferably two or three adsorbers, and several valves having long and heterogeneous operating times. More specifically, the average operating time (&mgr;) of the valves is such that: 0.5 s<&mgr;<2 s and the operating time (&Dgr;t) of each of the valves is such that: &mgr;−x<&Dgr;t<&mgr;+x, with 0.1 s<x<0.5 s. The invention also relates to the use of such a PSA plant for producing a gas stream rich in oxygen, in nitrogen or in hydrogen, particularly a stream comprising more than 80% oxygen, which is then sent to an oxygen-consuming plant chosen from a combustion furnace, a paper-pulp manufacturing unit and a water treatment unit.
Type:
Grant
Filed:
November 8, 1999
Date of Patent:
December 25, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Abstract: The treatment of a food product is carried out using ozonized water in at least two containers, each container possibly being associated with a set value of the dissolved-ozone content that it is desirable to maintain therein, by ozonizing a stream of water so as to obtain a dissolved-ozone content of the stream of ozonized water greater than or equal to the highest of the set values of the dissolved-ozone content which are associated with each of said containers, and the dissolved-ozone content in each of the solution containers is analyzed in order to compare the result of each of the analyses with the associated set value and to carry out a feedback operation, where appropriate, depending on the result of each comparison, on the control of the flow of ozonized water injected into the container in question, so as to reestablish the dissolved-ozone content of this solution container at its associated set value.
Type:
Grant
Filed:
September 3, 1999
Date of Patent:
December 11, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Abstract: Provided is a novel method of and system for recovering and recirculating a deuterium-containing gas. According to the inventive method, a deuterium-containing feed gas is introduced into a chamber. An exhaust gas containing deuterium is removed from the chamber. The deuterium concentration of the exhaust gas is adjusted to a predetermined value, thereby producing a concentration-adjusted gas stream. Finally, the concentration-adjusted gas stream is introduced into the chamber as the deuterium-containing feed gas. The invention makes the use of deuterium, for example, in the mass production of semiconductor devices, commercially feasible.
Type:
Grant
Filed:
February 6, 1998
Date of Patent:
December 11, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Inventors:
Daniel Gary, Jean-Marc Girard, Jean-Christophe Rostaing, Jean-Marie Friedt
Abstract: A PSA, especially VSA, process for separating a stream of gas, such as air, containing at least one first compound, such as nitrogen, which is preferentially adsorbed on at least one adsorbent and at least one second compound, such as oxygen, which is adsorbed less preferentially on the adsorbent than the first compound. The adsorbent comprises at least particles of a zeolite having a Si/Al ratio of less than or equal to 5 and chosen from zeolites of X or A type, the zeolite having a kinetics coefficient (ak) and an intrinsic strength (&agr;), with: ak>0.5 s−1 and 0.10<&agr;<2. The invention also relates to an adsorbent for the non-cryogenic separation of gases, especially the gases from air and from syngas.
Type:
Grant
Filed:
March 27, 2000
Date of Patent:
December 11, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Abstract: Process for partial oxidation in a Claus furnace of at least one gas stream having hydrogen sulphide, and including the steps of: (a) injecting at least one gas stream including hydrogen sulphide and at least one oxygen-enriched gas stream into the Claus furnace, wherein each of the streams is injected at a speed of injection which is substantially parallel, and (b) controlling the speed of injection of the gas stream including hydrogen sulphide and the speed of injection of the oxygen-enriched gas stream such that the speeds have a ratio between 0.8 and 1.2.
Type:
Grant
Filed:
February 16, 2000
Date of Patent:
December 11, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
Inventors:
Ebrahim Djavdan, Jacques Koening, Jean-François Nicolas, Vincent Queudot, Olivier Charon
Abstract: In a separation apparatus, a stream of liquid partially vaporizes in a heat exchanger before being sent to a phase separator. The liquid stream from the phase separator is divided into a first portion which is taken off and a second portion which is mixed with the liquid to be vaporized.
Type:
Grant
Filed:
November 6, 2000
Date of Patent:
November 27, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'etude et l'Exploitation
des Procedes Georges Claude
Abstract: A synthesis gas obtained by steam reforming is sent to a pressure swing adsorption unit (2) which separates a CO/H2 mixture, as a production gas, from the other constituents. The CO/H2 mixture is sent to a unit (3) for at least partially purifying CO, for example a permeation unit, which produces under pressure the CO with high purity or an H2/CO mixture with an adjusted CO content, containing very little impurities.
Type:
Grant
Filed:
January 4, 2000
Date of Patent:
November 27, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour L'Exploitation des
Procedes Georges Claude
Abstract: The device (1) for controlling an installation (2) comprising means (9,10,11,12,13, for monitoring and/or commanding the operation of the installation (2), and a central data processing unit (14) adapted to communicate with the means for monitoring and/or commanding (9,10,11,12,13) for reading, sending and/or processing the data concerning the operation of the installation. The central unit (14) comprises memory means (16) for storing at least one parameterized task acting on said data concerning the operation of the installation, memory means storing at least one table, each table being associated with a parameterized task and comprising values of parameters of the considered task, for executing the latter, and, connected to each memory means (16,17), means (15) for executing said parameterized tasks by using said values stored in said table or tables when executing said parameterized tasks.
Type:
Grant
Filed:
June 26, 1998
Date of Patent:
November 20, 2001
Assignee:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes George Claude
Inventors:
Laurent Ferenczi, Patrick Bacot, Bertrand Oresve
Abstract: In a process for production of oxygen enriched fluid and argon enriched fluid by cryogenic distillation of air, a feed stream (1) containing nitrogen, oxygen and argon is sent to a main column system wherein it is separated by cryogenic distillation, an argon containing gaseous stream (33) is removed from a column (103) of the main column system, said column operating at a pressure of at least 2 bar abs., and the argon containing gaseous stream is at least partially condensed, at least part of the at least partially condensed argon containing gaseous stream is sent to an intermediate point of an argon column (104) and an argon enriched product stream (80) is removed from the top of the argon column and a first oxygen enriched product stream (36) is removed from the bottom of the argon columnn.
Type:
Grant
Filed:
August 11, 2000
Date of Patent:
November 20, 2001
Assignee:
L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude