Patents Assigned to L'Exploitation Des
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Patent number: 11578284Abstract: A process and a plant for purifying a crude gas stream containing sulfur components and hydrocarbons by gas scrubbing using a scrubbing medium which is selective for sulfur components in an absorption column. Heavy hydrocarbons and heavy mercaptans are removed from the crude gas in a lower section of the absorption column and the resulting, loaded scrubbing medium stream is fed separately from the other loaded scrubbing medium streams to a hot regeneration column. A vapor stream enriched in water, hydrocarbons and sulfur components is obtained as overhead product from the hot regeneration column and this stream is cooled to below its dew point and is separated in a gas-liquid-liquid phase separation apparatus. The resulting, organic liquid phase contains heavy hydrocarbons and heavy mercaptans and can thus be discharged from the process or the plant, as a result of which accumulation thereof in the scrubbing medium is prevented.Type: GrantFiled: June 29, 2021Date of Patent: February 14, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Alfred Gubrinski, Dorit Rappold, Michael Wilken, Matthias Linicus
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Patent number: 11577967Abstract: A process of conditioning tungsten pentachloride to form specific crystalline phases are disclosed. The specific crystalline phases permit stable vapor pressures over extended periods of time during vapor deposition and etching processes.Type: GrantFiled: December 16, 2020Date of Patent: February 14, 2023Assignee: L'Air Liquide Société ANonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Feng Li, Sonia Plaza, Jean-Marc Girard, Nicolas Blasco, Yumin Liu
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Patent number: 11578916Abstract: A method and a device for producing an air product based on cryogenic rectification; after being cooled by a main heat exchanger, raw material air and nitrogen compressed by means of a compressor are sent to a rectification system for low temperature separation. In the rectification system, products such as oxygen and nitrogen are obtained by means of low temperature separation, and oxygen-enriched liquid air is obtained at or near the bottom of a rectification tower. The oxygen-enriched liquid air or liquid-state air in the rectification system is sent out after being raised to a target pressure by means of a low temperature liquid air pump; air products of various pressures can be produced by means of selecting low temperature liquid air pumps with different lifts or by connecting in series different amounts of low temperature liquid air pumps.Type: GrantFiled: December 29, 2017Date of Patent: February 14, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georqes ClaudeInventors: Bowei Zhao, Alain Briglia, Fengjie Xue
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Publication number: 20230032906Abstract: Apparatus for supplying oxygen to a vehicle user, comprising a source of pressurized respiratory gas containing oxygen-enriched air, a flow-regulating and/or pressure-regulating unit, and at least one mask provided for supplying gas to the respiratory tract of said user, the regulating unit comprising at least one inlet connected to the source and at least one outlet connected to the mask, the regulating unit being configured to regulate the flow and/or the pressure of the respiratory gas supplied to the mask according to the respiratory demand of the user, the apparatus comprising at least one sensor measuring the pressure and/or the flow of respiratory gas delivered by the regulating unit to the mask, and an electronic data storage and processing unit configured to receive the measurements from the at least one sensor and to calculate, from these measurements, the frequency of the gas flows supplied to the mask and corresponding to the respiratory frequency of the user, to compare this calculated frequencyType: ApplicationFiled: December 9, 2020Publication date: February 2, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Michel CAZENAVE, Loic VILLARD
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Patent number: 11566841Abstract: A method for producing liquid nitrogen using a residual gas stream derived from a flue gas of a power plant is provided. The residual gas stream is purified in a front-end purification unit to remove freezable components and then the purified stream is compressed. Following compression, the stream can be divided into a first portion and a second portion, wherein the first portion is cooled and sent to a distillation column, wherein oxygen and argon are separated, thereby leaving an essentially pure gaseous nitrogen stream. The gaseous nitrogen stream can then be liquefied using refrigeration provided by expanding the second portion of the purified stream. In a preferred embodiment, the second portion is expanded in two turbines, and the gaseous nitrogen is compressed in a cold nitrogen booster, which is powered by one of the two turbines. In an additional embodiment, after warming, the expanded second portion of the purified stream can be used to regenerate the front-end purification unit.Type: GrantFiled: November 27, 2019Date of Patent: January 31, 2023Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Michael A Turney
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Publication number: 20230022033Abstract: A process for the separation of nitrogen from a feed stream containing at least methane and nitrogen, with a methane content between 4 and 12% mol. consists of at least the following steps: separation of the feed stream by means of a rubbery-type membrane to produce a permeate enriched in methane at a pressure greater than 2 bara and a non-permeate which is a nitrogen-enriched residue gas at a pressure greater than 2 bara and processing of the high-pressure residue gas in a cryogenic separation unit to produce a methane rich liquid and a nitrogen-enriched gas wherein the pressure of the membrane permeate is controlled as a function of the nitrogen concentration in the nitrogen-enriched gas.Type: ApplicationFiled: July 16, 2021Publication date: January 26, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Martin RAVENTOS, Paul TERRIEN
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Patent number: 11560308Abstract: Method and plant for generating a synthesis gas which consists mainly of carbon monoxide and hydrogen and has been freed of acid gases, proceeding from a hydrocarbonaceous fuel, and air and steam, wherein low-temperature fractionation separates air into an oxygen stream, a tail gas stream and a nitrogen stream, wherein the tail gas stream and the nitrogen stream are at ambient temperature and the nitrogen stream is at elevated pressure, wherein the hydrocarbonaceous fuel, having been mixed with the oxygen stream and steam at elevated temperature and elevated pressure, is converted to a synthesis gas by a method known to those skilled in the art, and wherein acid gas is subsequently separated therefrom by low-temperature absorption in an absorption column, wherein the nitrogen stream generated in the fractionation of air is passed through and simultaneously cooled in an expansion turbine and then used to cool either the absorbent or the coolant circulating in the coolant circuit of the compression refrigeratioType: GrantFiled: November 20, 2017Date of Patent: January 24, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Lucie Chaubet, Frederic Bonne, Camille Bouet, Holger Schlichting, Marc Wagner
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Patent number: 11560966Abstract: A valve for pressurized fluid, including a body having a front face and a rear face and housing an internal fluid circuit having an upstream end configured to be placed in communication with a reserve of pressurized fluid and a downstream end configured to be placed in communication with a user of fluid, the circuit including a collection of valve shutter(s) including at least one shutoff valve shutter for closing or opening the circuit, the valve comprising a member for manually controlling the collection of valve shutter(s).Type: GrantFiled: August 2, 2018Date of Patent: January 24, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Samuel Vignerol, Antoine Frenal, Denis Muller, Hervé Paoli, Olivier Ondo, Morgan Lamiable, Johan Broechler, Claudio Di Filippo
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Publication number: 20230012928Abstract: Device and method for filling pressurized gas tanks, comprising a pressurized gas source, a transfer pipe connected to a tank to be filled, the transfer pipe comprising a set of valve(s) and a compressor, the device comprising a sensor for detecting the presence of oil in the gas flowing in the transfer pipe downstream of the compressor, the device comprising a bypass pipe connected to the transfer pipe downstream of the compressor and comprising a set of at least two valve(s) in series which are configured to enable, in a first configuration, the gas flowing in the transfer pipe to be extracted in the bypass pipe and, in a second configuration, fluid isolation between the bypass pipe and the transfer pipe, wherein the valve assembly of the transfer pipe defines in the second configuration a closed storage space for the gas extracted and enclosed in the bypass pipe, the closed storage space comprising a pressure relief system for the gas extracted and enclosed in the bypass pipe for lowering the pressure of tType: ApplicationFiled: November 12, 2020Publication date: January 19, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Tom RONY, Thibaut FRANCOIS
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Publication number: 20230019514Abstract: Disclosed is a method for purifying a main gas, in particular helium, from a source gas stream comprising the main gas, a main impurity, in particular nitrogen, and optionally another, secondary impurity, in particular oxygen, the method comprising a step of partial condensation of the gas stream in order to extract therefrom impurities in liquid form, in particular the main impurity, and to produce a gas stream enriched with main gas, characterized in that the method comprises, before the partial condensation step, a step of injecting into the gas stream a compound in which the main impurity of the gas to be treated is soluble and having a saturation vapor pressure lower than the saturation vapor pressure of the main impurity.Type: ApplicationFiled: November 12, 2020Publication date: January 19, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Robin LADOUS, Golo ZICK
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Patent number: 11554955Abstract: The invention relates to a process for the combined production of hydrogen and carbon dioxide from a hydrocarbon mixture, in which the residual gas of a PSA H2 (12) is separated by permeation in order to reduce the hydrocarbon content thereof and the hydrocarbon-purified gas is separated at a low temperature to produce a carbon dioxide-rich liquid (22).Type: GrantFiled: November 8, 2018Date of Patent: January 17, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Jean-Pierre Tranier
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Patent number: 11555158Abstract: The invention relates to a gas scrubbing process and a corresponding plant for removal of acidic gas constituents from crude synthesis gas which make it possible by treatment of shifted and of unshifted crude synthesis gas in the gas scrubbing process and by combination of the thus-obtained partial product streams to produce a plurality of gas products having different compositions. In addition, the invention ensures that the flash gases obtained during decompression of the laden scrubbing medium are utilized materially and/or energetically in advantageous fashion.Type: GrantFiled: May 29, 2019Date of Patent: January 17, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Alfred Gubrinski, Pankaj Puri, Sharon Corbet, Dorit Rappold
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Patent number: 11555556Abstract: A valve for pressurized fluid having a body housing a fluid circuit having an upstream end configured to be placed in communication with a reserve of pressurized fluid and a downstream end configured to be placed in communication with a user of fluid, the circuit including a collection of valve shutter(s) comprising at least one shutoff valve shutter allowing the circuit to be closed or opened, the valve including a mechanism for manually controlling the collection of valve shutter(s), the control mechanism being mounted with the ability to move on the body between a rest position in which the collection of valve shutter(s) is in a position in which the circuit is closed and an active position in which the control mechanism actuates the collection of valve shutter(s) into a position in which the circuit is open to a first bore section.Type: GrantFiled: August 2, 2018Date of Patent: January 17, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Samuel Vignerol, Antoine Frenal, Denis Muller, Hervé Paoli, Morgan Lamiable, Johan Broechler, Claudio Di Filippo
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Publication number: 20230009727Abstract: A method for the liquefaction of hydrogen is provided. The can include the steps of: precooling a hydrogen feed stream in a precooling cold box having a heat exchanger disposed therein to form a cooled hydrogen stream, wherein the heat exchanger is configured to cool down the feed stream within the precooling cold box by indirect heat exchange between the hydrogen feed stream and a precooling refrigerant; and withdrawing the cooled hydrogen stream from the precooling cold box; introducing the cooled hydrogen stream to a plurality of liquefaction cold boxes, wherein the cooled hydrogen stream liquefies within the plurality of liquefaction cold boxes by indirect heat exchange against a liquefaction refrigerant to form a product hydrogen stream in each of the plurality of liquefaction cold boxes, wherein the product hydrogen stream is in liquid form or pseudo-liquid form wherein there are M total precooling cold boxes and N total liquefaction cold boxes, wherein M is less than N.Type: ApplicationFiled: August 25, 2022Publication date: January 12, 2023Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Michael A. TURNEY, Patrick LE BOT, Alain GUILLARD, Bobby Mon-Flan CHAN, Francois FUENTES
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Patent number: 11549747Abstract: A cryogenic air separation apparatus comprises: a heat exchanger, a first rectification column, a first condenser, a second rectification column, a third rectification column, a second condenser, a high-purity oxygen rectification column, a third condenser, a nitrogen compressor, and a compressed recycled gas line L52 for introducing product nitrogen gas compressed by the first nitrogen compressor into a warm end (heat source) of an ultra-high-purity oxygen vaporizer as a compressed recycled gas.Type: GrantFiled: April 3, 2020Date of Patent: January 10, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Geordes ClaudeInventors: Kenji Hirose, Shinji Tomita
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Patent number: 11552531Abstract: The invention relates to an electrical machine comprising a stator and a rotor that are disposed in a casing comprising a first face provided with ribs and intended to be in contact with a cooling fluid, the machine being provided with a closing structure which is fastened in a leaktight manner to the first face of the casing so as to delimit with the first face of the casing a space forming a circuit for the cooling fluid of the motor, the closing structure being fastened to the first face of the casing by welding and/or brazing and/or crimping and comprising at least one cover, characterized in that the closing structure is fastened to the casing by welding and/or brazing and/or crimping only at said ribs.Type: GrantFiled: August 1, 2018Date of Patent: January 10, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Fabien Durand
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Patent number: 11549182Abstract: Disclosed are Group 6 film forming compositions comprising Group 6 transition metal-containing precursors selected from the group consisting of: M(=O)2(OR)2??Formula I, M(=O)(NR2)4??Formula II, M(=O)2(NR2)2??Formula III, M(=NR)2(OR)2??Formula IV, and M(=O)(OR)4??Formula V, wherein M is Mo or W and each R is independently H, a C1 to C6 alkyl group, or SiR?3, wherein R? is H or a C1 to C6 alkyl group. Also disclosed are methods of synthesizing and using the disclosed compositions to deposit Group 6 transition metal-containing films on substrates via vapor deposition processes.Type: GrantFiled: September 30, 2021Date of Patent: January 10, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Clément Lansalot-Matras, Julien Lieffrig, Christian Dussarrat, Antoine Colas, Jong Min Kim
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Patent number: 11549646Abstract: The invention primarily concerns a facility for storing and cooling a liquefied gas, for example a liquefied natural gas, the facility comprising at least one tank configured to contain the liquefied gas, a closed cooling circuit configured to be supplied with liquefied gas in the liquid state coming from the tank, at least one injection member configured for reinjecting cooled liquefied gas into the tank, the facility being characterized in that it comprises at least one connection line configured to recover a cooled gas from at least one remote container that is separate and independent from the facility.Type: GrantFiled: July 19, 2017Date of Patent: January 10, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Marc Bernhardt, Fabien Durand, Cecile Gondrand, Veronique Grabie
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Patent number: 11550972Abstract: A simulation method for the management of a pipeline network having input and output nodes (S1, S2, C1) and including defining operating states describing operating conditions of the pipeline network, determining, for each operating state STp, a three-dimensional dynamic matrix DMSTp whose each coefficient DMSTp(i,j,tk) corresponds to a pressure variation value from an initial pressure value at a j-th node at a k-th time step tk following a variation, at a i-th node, of a flow rate value, and estimating, for a given node at a given moment, a pressure value on the basis of an operating schedule providing information regarding variations of the flow rate value for each node and evolutions of the operating conditions of the pipeline network until the given moment, the estimation using the operating states and the three-dimensional dynamic matrices.Type: GrantFiled: November 4, 2020Date of Patent: January 10, 2023Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Thierry Roba
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Patent number: 11543837Abstract: The invention can include a device and method for distributing a fluid in an industrial facility that comprises a fluid distribution pipe, a discharge pipe, a distribution valve that is positioned on the distribution pipe and controlling the distribution of fluid between an upstream area and a downstream area, a discharge valve positioned on the discharge pipe, and measuring means for measuring, in real time, a characteristic parameter of the distribution of the fluid within one of the pipes. A module is also included for calculating a sliding threshold value of the characteristic parameter and means configured to control the partial gradual opening or closing of the discharge valve depending on the result of the comparison of said sliding threshold value with an instantaneous value of the characteristic parameter, in order to improve reliability of the industrial facility.Type: GrantFiled: December 17, 2018Date of Patent: January 3, 2023Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Zahra Apert, Francois Demoisy, Alban Pivard