Abstract: Disclosed are silicon and carbon containing film forming compositions comprising a polycarbosilazane polymer or oligomer formulation that consists of silazane-bridged carbosilane monomers, the carbosilane containing at least two —SiH2— moieties, either as terminal groups (—SiH3R) or embedded in a carbosilane cyclic compound, wherein R is H, a C1-C6 linear, branched, or cyclic alkyl- group, a C1-C6 linear, branched, or cyclic alkenyl- group, or combination thereof. Also disclosed are methods of forming a silicon and carbon containing film comprising forming a solution comprising a polycarbosilazane polymer or oligomer formulation and contacting the solution with the substrate via a spin-on coating, spray coating, dip coating, or slit coating technique to form the silicon and carbon containing film.

Abstract: A device for refuelling containers with pressurized gas, comprising a pressurized gas source, a transfer circuit intended to be removably connected to a container, the device comprising a refrigeration system for cooling the gas flowing from the gas source prior to its entering into the container, the refrigeration system comprising a refrigerant cooling loop circuit comprising, arranged in series, a compressor, a condenser section, an expansion valve and an evaporator section, the refrigeration system comprising a cold source in heat exchange with the condenser section and a heat exchanger located in the transfer circuit, the device comprising an electronic controller connected to the expansion valve and configured for controlling cooling power produced by the refrigeration system via the control of the opening of the expansion valve, the device comprising a differential temperature sensor system measuring the difference between the temperature of the refrigerant in the refrigerant cooling loop circuit at th

Abstract: Method for filling a liquefied gas tank with pressurized liquefied gas from a source of liquefied gas using a filling apparatus comprising a transfer circuit that is provided with first and second pipes, each connecting between the source via respective first ends and the tank via respective second ends, third and fourth pipes each connecting between the first and second pipes, and a set of valves controlling flows of fluid in the pipes. The tank is depressurized and at least part of the circuit is cooled by transferring pressurized vaporization gas from the tank to the first end of the second pipes via the second end of the second pipe, the third pipe, the first pipe, and the fourth pipe.

Abstract: Plant and method for liquefying a flow of gas, comprising a cooling circuit which is provided with an upstream end which is intended to be connected to a source of pressurised gas to be liquified and a downstream end which is intended to be connected to a user member, the plant comprising, between the upstream and downstream ends, a set of members which are intended to liquefy the gas and comprise at least one exchanger for cooling the gas, and at least one expansion turbine which is mounted on a rotary axle which is supported by at least one bearing of the gas-static type, the cooling circuit comprising a pressurised gas injection conduit having an upstream end which is intended to receive pressurised gas supplied by the source and a downstream end which is connected to the bearing in order to provide support to the rotary axle, the plant comprising a conduit for recovering the gas which has been used in the bearing, the conduit for recovering the gas comprising an upstream end which is connected to the bear

Abstract: A hydrogen refilling station for filling tanks of fuel cell electric vehicles includes a liquid hydrogen tank that feeds liquid hydrogen to an upstream end of a filling circuit that also includes a heat exchanger. The heat exchanger exchanges heat between the liquid hydrogen and heat transfer fluid flows to thereby cool the heat transfer fluid and vaporize the liquid hydrogen to provide a supply of high pressure hydrogen gas for filling hydrogen-fueled vehicle tanks at a downstream end of the circuit. Because the liquid hydrogen is surrounded by the heat transfer fluid inside the heat exchanger, little if any fogging occurs.

Abstract: A process for the production of a hydrogen gas stream having a CO content of less than 1 ppm having a production cycle comprising two phases: phase 1 includes a) purifying a synthesis gas in a PSA unit, b) recovering a hydrogen gas stream comprising a CO content of greater than 1 ppm, c) purifying the gas stream by adsorption in a TSA unit, and recovery a hydrogen gas stream exhibiting a CO content of less than 1 ppm, and phase 2 includes e) purifying the synthesis gas in a PSA unit, f) recovering a hydrogen gas stream having a CO content of less than 1 ppm, where throughout steps e) and f), the TSA unit is bypassed by the hydrogen gas stream and is regenerated.

Abstract: The invention relates to a gas scrubbing process for purifying crude synthesis gas with methanol as a physical absorption medium, wherein an acid gas comprising at least hydrogen sulfide (H2S) is produced. The acid gas is produced in a hot regenerator arranged downstream of an absorption apparatus and subsequently separated from gaseous methanol in an acid gas separator by cooling and condensation. The acid gas separator has a condensation region and an absorption region, wherein both regions are separated from one another by a gas-permeable tray. This has the result that impurities such as hydrogen cyanide and/or ammonia outgassing from a first acid gas substream are not reabsorbed in the condensation region of the acid gas separator, thus avoiding an accumulation of impurities in the hot regenerator or other parts of the gas scrubbing plant. The invention further relates to an acid gas separator and to the use of the acid gas separator according to the invention in a process according to the invention.

Abstract: Method and plant for generation of synthesis gas, comprising the steps of air fractionation to give oxygen, nitrogen and tail gas, gasification of a hydrocarbonaceous fuel to give crude synthesis gas and cleaning of the crude synthesis gas by removal of acid gas by means of cryogenic absorption, wherein the absorbent is cooled by means of a compression coolant circuit and the cooling water used is cooled by evaporative cooling by means of the tail gas obtained in the air fractionation.

Abstract: Cryogenic fluid storage tank comprising a pipe for drawing off vaporized gas, which pipe is connected to a first casing and comprises a vaporizer and at least one control valve, a first filling pipe connected to the lower portion of the first casing, a second pipe for filling a downstream end connected to the upper portion of the first casing, a distribution valve assembly configured to enable distribution of the fluid from the fluid source in the filling pipes, a pressurization pipe connected to the lower end of the first casing and a second end connected to the upper portion of the first casing and at least one control valve and a heater, the tank further comprising an air vent regulator, the valve assembly for distribution in the filling circuit, the valve for controlling the pressurization pipe, the valve for controlling the drawing-off circuit and the air vent regulator being integrated into the same valve module, which shares at least one valve element.

Abstract: Disclosed is a method for forming Si-containing films, such as SiN film, by PEALD using trisilylamine (TSA) at ultralow temperature, such as a temperature below 250° C.

Abstract: Refrigeration device intended to extract heat from at least one member by heat exchange with a working fluid circulating in the working circuit comprising in series: a fluid compression mechanism a fluid cooling mechanism, preferably isobaric or substantially isobaric, a fluid expansion mechanism, and a fluid heating mechanism, in which device the compression mechanism is of the centrifugal compression type and consists of two compression stages arranged in series in the circuit, the device comprising two respective electric drive motors driving the two compression stages, the expansion mechanism consisting of a turbine coupled to the motor of one of the compression stages, the turbine of the expansion mechanism being coupled to the drive motor of the first compression stage.

Abstract: Low-temperature refrigeration device arranged in a frame and comprising a working circuit forming a loop and containing a working fluid, the working circuit forming a cycle comprising in series: a compression mechanism, a cooling mechanism, an expansion mechanism and a heating mechanism, the device comprising a refrigeration heat exchanger intended to extract heat from at least one member by exchanging heat with the working fluid, the mechanisms for cooling and reheating the working fluid comprising a common heat exchanger in which the working fluid transits in counter-flow in two separate transit portions of the working circuit, the compression mechanism comprising at least two compressors and at least one motor for driving the compressors, the working fluid expansion mechanism comprising at least one rotary turbine, the device comprising at least one drive motor comprising a drive shaft, one end of which drives a compressor and the other end of which is coupled to a turbine, the motor being attached to the

Abstract: Disclosed is a low-temperature refrigeration device which is arranged in a frame and comprises a working circuit that forms a loop and contains a working fluid, the working circuit forming a cycle comprising, connected in series: a compression mechanism, a cooling mechanism, an expansion mechanism and a heating mechanism, wherein the mechanisms for cooling and heating the working fluid comprise a common heat exchanger in which the working fluid flows in opposite directions in two separate transit portions of the working circuit, the device further comprising a refrigeration heat exchanger for extracting heat from at least one member by exchanging heat with the working fluid flowing in the working circuit, the compression mechanism comprising two separate compressors, the mechanism for cooling the working fluid comprising two cooling heat exchangers which are arranged respectively at the outlet of the two compressors and ensure heat exchange between the working fluid and a cooling fluid, wherein the frame exte

Abstract: An apparatus for producing product nitrogen gas and product argon, comprising: a first rectification column into which raw air is introduced; a second rectification column from which product nitrogen gas is drawn; a third rectification column from which product argon gas is drawn; and a first condenser configured to perform heat exchange between a gas accumulated in a column top portion of the first rectification column, and a liquid accumulated in a column bottom portion of the second rectification column, wherein an intermediate portion gas containing nitrogen is drawn from an intermediate portion of the second rectification column and merged with a condenser gas drawn from the first condenser. The merged gases are expanded and cooled by means of an expansion turbine whereby the cold thereof is utilized.

Abstract: A liquefied fuel cryogenic tank has an inner jacket delimiting a fluid storage volume and an outer jacket disposed around the inner jacket with a vacuum thermal insulation gap therebetween. A withdrawal circuit has an assembly of one or more valves and a withdrawal line that has a first heating heat exchanger located outside the inner jacket and a second heating heat exchanger located inside the inner jacket. Fluid flows through the withdrawal line via the first heat exchanger and then the second heat exchanger or via the first heat exchanger without entering the second heat exchanger.

Abstract: An adsorbent bed, including at least one elementary composite structure that includes adsorbent particles in a polymer matrix, wherein the adsorbent bed has a bed packing, ?bed, defined as a volume occupied by the at least one elementary composite structure Vecs divided by a volume of the adsorbent bed Vbed where ?bed is greater than 0.60.

Abstract: The invention provides a method for on-site monitoring of the quality of the gases delivered to a consumer site, the monitoring being carried out during the delivery, in order to declare the delivery compliant or non-compliant with specifications, being characterized in that, during the delivery, a monitoring of the gas(es) delivered is carried out by the thermal conductivity technique.

Abstract: A method of natural gas treatment including introducing a natural gas containing stream into a dryer unit, thereby producing a treated natural gas containing stream. Introducing the treated natural gas containing stream into a nitrogen rejection unit, thereby producing a further treated natural gas stream as a nitrogen rejection unit product. Splitting the nitrogen rejection unit product into at least two portions, introducing the first portion of the further treated natural gas stream into a reformer unit as first part of feed, and introducing a second portion of the further treated natural gas stream into the dryer unit as a regeneration stream, thereby producing a regeneration waste stream. Introducing at least a portion of the regeneration waste stream into the reformer unit as second part of feed.

Abstract: A method of providing electrical energy to a dewar containing a cryogenic liquid including introducing an insulated heat pipe, with a distal end and a proximal end, into a cryogenic dewar comprising an exterior surface. And providing a Seebeck module, with a cold junction and a hot junction. The distal end is in thermodynamic contact with a cryogenic fluid and the proximal is thermodynamically connected to the cold junction. The hot junction is thermodynamically connected to the exterior surface of the dewar, thereby producing an electrical flow in the Seebeck module. A level probe may be calibrated by taking a first capacitance reading with the dewar full, and a second capacitance reading when the cryogenic liquid level is within a calibration gap. The level probe is calibrated by utilizing the first capacitance reading and the second capacitance reading.

Abstract: Process and plant for membrane permeation treatment of a carbon dioxide and methane-containing biogas stream in which the biogas stream is compressed with a compressor and the compressed biogas stream is fed to a membrane separation unit comprising first and second modules each containing at least one membrane selective for carbon dioxide over methane. The first module separates the compressed biogas stream into a first, second, and third methane-deficient permeates (in comparison to the biogas stream) and a first methane-enriched retentate (in comparison to the biogas stream). The first permeate being richer in methane than the second or third permeates. The second module separates the first permeate into a fourth methane-deficient permeate and a second methane-enriched retentate. The second and third retentates are recycled back to an inlet of the compressor.