Abstract: In a method for supplying nitrogen to a combustion chamber, gaseous nitrogen (9) is drawn off from an air separation unit (7) at a first pressure, the nitrogen is compressed in at least two stages (C1, C2) of a nitrogen compressor and sent to a combustion chamber (25) at a second pressure, which is the output pressure of the last stage (C3) of the nitrogen compressor, between two stages of the nitrogen compressor the nitrogen is humidified by direct contact in passing through a contactor (17) supplied at its top with water, and the humidified nitrogen is compressed in at least one stage of the nitrogen compressor and sent to the combustion chamber.
Type:
Grant
Filed:
November 23, 2012
Date of Patent:
May 9, 2017
Assignee:
L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Inventors:
Richard Dubettier-Grenier, Sylvain Gerard, Loïc Joly
Abstract: A weather shelter for providing protection during assembly of a column at a remote manufacturing yard is provided. The weather shelter can include a frame mounted to a hanging platform, and extending upwards from the hanging platform, the hanging platform supported by the column; and a protective covering mounted on the frame having a side covering and a top covering, the protective covering configured to provide an inner atmosphere within the protective covering protected from external elements when the protective covering is secured to the column.
Type:
Grant
Filed:
May 22, 2014
Date of Patent:
May 2, 2017
Assignee:
L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Abstract: Disclosed are methods of depositing silicon-containing films on one or more substrates via vapor deposition processes using penta-substituted disilanes, such as pentahalodisilane or pentakis(dimethylamino)disilane.
Type:
Grant
Filed:
December 28, 2015
Date of Patent:
April 25, 2017
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: Group 4 transition metal-containing film forming compositions are disclosed. The Group 4 transition metal-containing film forming compositions comprise Group 4 transition metal precursors having the formula L2-M-C5R4-[(ER2)2—NR]—, wherein M is Ti, Zr, or Hf bonded in an ?5 bonding mode to the Cp group; each E is independently C, Si, B or P; each R is independently a hydrogen or a C1-C4 hydrocarbon group; and each L is independently a ?1 anionic ligand selected from the group consisting of NR?2, OR?, Cp, amidinate, ?-diketonate, or keto-iminate, wherein R? is a H or a C1-C4 hydrocarbon group and adjacent R's may be joined to form a hydrocarbyl ring; provided that at least one R on the Cp is C1 to C4. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.
Type:
Application
Filed:
December 30, 2016
Publication date:
April 20, 2017
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: Group 4 transition metal-containing film forming compositions are disclosed. The Group 4 transition metal-containing film forming compositions comprise Group 4 transition metal precursors having the formula L2—M-C5R4-[(CER2)m-(CER2)n—O]-, wherein M is Ti, Zr, or Hf bonded in an ?5 bonding mode to the cyclopentadienyl group; each E is independently C, Si, B or P; m and n is independently 0, 1 or 2; m+n>1; each R is independently a hydrogen or a C1—C4 hydrocarbon group; each L is independently a -1 anionic ligand selected from the group consisting of NR?2, OR?, Cp, amidinate, ?-diketonate or keto-iminate, wherein R? is H or a C1—C4 hydrocarbon group; and adjacent R?s may be joined to form a hydrocarbyl ring. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on the substrates via vapor deposition processes.
Type:
Application
Filed:
December 30, 2016
Publication date:
April 20, 2017
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Wontae NOH, Daehyeon KIM, Satoko GATINEAU, Jean-Marc GIRARD
Abstract: Group 4 transition metal-containing film forming compositions comprising Group 4 transition metal precursors having the formula: wherein M is Ti, Zr, or Hf; each E is independently C, Si, B or P; m and n is independently 0, 1 or 2; m+n>1; o and p is independently 0, 1 or 2; o+p>1; each R is independently hydrogen or or a C1-C4 hydrocarbon group; each L is independently a?1 anionic ligand selected from the group consisting of NR?2, OR?, Cp, amidinate, ?-diketonate or keto-iminate, wherein R? is a H or a C1-C4 hydrocarbon group; and each L? is independently NR? or O, wherein R? is a H or a C1-C4 hydrocarbon group. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.
Type:
Application
Filed:
December 30, 2016
Publication date:
April 20, 2017
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: Group 4 transition metal-containing film forming compositions are disclosed comprising Group 4 transition metal precursors having the formula: wherein M is Ti, Zr, or Hf; each A is independently N, Si, B or P; each E is independently C, Si, B or P; m and n is independently 0, 1 or 2; m+n>1; each R is independently a H or a C1-C4 hydrocarbon group; each L is independently a ?1 anionic ligand selected from the group consisting of NR?2, OR?, Cp, amidinate, ?-diketonate, or keto-iminate, wherein R? is a H or a C1-C4 hydrocarbon group; and L? is NR? or O, wherein R? is a H or a C1-C4 hydrocarbon group. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.
Type:
Application
Filed:
December 30, 2016
Publication date:
April 20, 2017
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: A method for separating a feed gas, containing nitrogen and carbon monoxide as main components, in a distillation column: the feed gas is cooled in a heat exchanger; at least a portion of the feed gas, or at least a portion of a gas derived from the feed gas, is sent to a reboiler of the distillation column so as to condense the gas while producing a liquid, and optionally a gas; at least a portion of the liquid is sent to the distillation column; a nitrogen gas-rich flow is extracted from the distillation column; a carbon monoxide-rich flow is extracted from the distillation column, heated in the heat exchanger, and compressed so as to provide a carbon monoxide-rich material at production pressure.
Type:
Grant
Filed:
November 4, 2010
Date of Patent:
April 18, 2017
Assignee:
L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Inventors:
Arthur Darde, Antoine Hernandez, Bernard Saulnier
Abstract: A process for producing short-chain olefins by conversion of oxygenates in a multi-stage fixed-bed reactor, in which the individual stages for reaction zones are covered with beds of a granular, form-selective zeolite catalyst and the feed mixture containing oxygenates is added distributed over the reaction stages. An increase of the availability of the fixed-bed reactor for the olefin production with the same or an increased yield of short-chain olefins is achieved in that one or more reaction zones are charged with a distinctly reduced mass flow of the feed mixture containing oxygenates, wherein the reduced mass flow fraction is distributed over other reaction zones.
Type:
Grant
Filed:
May 6, 2013
Date of Patent:
April 18, 2017
Assignee:
L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Inventors:
Thomas Renner, Frank Castillo-Welter, Stephane Haag, Martin Gorny, Theis Ohlhaver, Roberta Olindo
Abstract: The invention relates to a nozzle for laser cutting comprising a nozzle body (1) comprising an axial housing (5) and a first outlet orifice (11) situated in the region of the front face (1a) of the nozzle body (1), a mobile element (2) arranged in the axial housing (5) of the nozzle body (1), comprising a skirt-forming front part (2a) and comprising a second outlet orifice (12), said mobile element (2) being able to be moved in a translational movement inside the axial housing (5) toward the first outlet orifice (11) under the effect of a gas pressure applied to the mobile element (2) until such time as the skirt-forming front part (2a) of the mobile element (2) projects out from the axial housing (5) through the first outlet orifice (11), and an elastic element (8) arranged in the axial housing (5), between the nozzle body (1) and the mobile element (2), applying an elastic return force to the mobile element (2).
Type:
Grant
Filed:
February 13, 2013
Date of Patent:
April 11, 2017
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: Process for laser welding at least one metal workpiece (1) by a laser beam (3), the workpiece having a surface coating (2) containing aluminum, characterized in that the laser beam (3) is combined with at least one electric arc (4) so as to melt the metal and actually weld the workpiece(s).
Type:
Grant
Filed:
July 12, 2007
Date of Patent:
April 11, 2017
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Inventors:
Francis Briand, Olivier Dubet, Corinne Chovet
Abstract: A process for producing dry synthetic natural gas (SNG, Synthetic Natural Gas) from solid or liquid, carbonaceous fuel, substantially consisting of the following process steps: a) gasification of a solid or liquid, carbonaceous fuel to a raw synthesis gas b) cooling of the gas, separation of solids and the gas condensate c) raw gas conversion d) washing of the gas with methanol for separating hydrogen sulfide, carbon dioxide and moisture, wherein the methanol is circulated via a regeneration plant, e) methanation, f) condensation of moisture by means of cooling and/or cold water, g) further drying of the gas by condensation at low temperature by adding methanol to avoid the formation of ice.
Type:
Grant
Filed:
October 25, 2013
Date of Patent:
April 4, 2017
Assignee:
L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDE
Inventors:
Manfred Meyer, Stefan Walter, Ute Herrlett
Abstract: The invention relates to a nozzle for laser cutting, comprising a nozzle body (1) comprising a first axial housing (5), a movable element (2) formed from an electrically insulating material and comprising a second axial housing (4), said movable element (2) being arranged in the first axial housing (5), and an elastic element (8) arranged in the first axial housing (5) between the nozzle body (1) and the movable element (2). According to the invention, the nozzle furthermore comprises an insert (3) comprising an axial passage (18) and a front portion (3a) forming a skirt that protrudes out of the second axial housing (4), said insert (3) being arranged in the second axial housing (4) of the movable element (2) and formed from an electrically conductive material. Associated laser head and apparatus. Laser cutting process employing such a nozzle.
Type:
Grant
Filed:
October 23, 2013
Date of Patent:
April 4, 2017
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: The invention relates to a device for the transfer of water and heat between a first and a second air flow. The inventive device consists of a stack of at least two transfer sub-assemblies having a lamellar configuration, each sub-assembly comprising a two-layer transfer structure with hydrophilic porous materials (3, 4), which is disposed between a first structure for the distribution of the first air flow (1) and a second structure for the distribution of the second air flow (2).
Type:
Grant
Filed:
September 9, 2004
Date of Patent:
April 4, 2017
Assignee:
L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Inventors:
Guillaume Roberge, Pierre Charlat, Thierry Novet
Abstract: Process for treating a catalytic reactor comprising a catalyst bed that includes the successive steps of passivating the catalytic reactor leading to the production of an oxidation layer at the surface of the active sites of the catalyst bed, opening the reactor, and skimming at least one portion of the catalyst bed.
Type:
Grant
Filed:
March 5, 2014
Date of Patent:
March 28, 2017
Assignee:
L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Inventors:
Daniel Gary, Raphael Faure, Olivier Debellemaniere, Angelo Vaccari, Giuseppe Brenna