Patents Assigned to L'Exploitation Des
  • Patent number: 9878279
    Abstract: Entrained metal hydride particle are removed from a flow of hydrogen from a Mg-based hydride storage unit using not only a particle filter but improvements for reducing or eliminating drastic changes in flow. In addition to or alternative to removal of entrained metal hydride particles, methane produced by reaction of hydrogen with steel in a metal hydride system preferably operated above 350° C. is removed downstream of the Mg-based hydride storage unit using an adsorption cartridge, preferably containing activated carbon.
    Type: Grant
    Filed: April 30, 2016
    Date of Patent: January 30, 2018
    Assignee: L'AIR LIQUIDE SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Pascal Tessier, Philippe Coignet, Benjamin Jurcik, Ryan Adelman
  • Patent number: 9874469
    Abstract: The invention relates to a device including: at least one fluid-using apparatus; at least one movable tank capable of and intended for providing at least the fluid and connected, via pipes, to the fluid using apparatus, the movable tank containing, at the outset, a given initial amount of the gas; and a means for assessing amounts of the fluid that are used by the fluid using apparatus from the movable tank, the assessment means being rigidly connected to the fluid-using apparatus.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: January 23, 2018
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Patrick Bacot, Franck-Stephane Durtschi, Xavier Vigor
  • Patent number: 9874312
    Abstract: The invention relates to a gas distribution assembly comprising a gas container (20), such as a gas cylinder, a valve unit fixed to the gas container (20) and a protective cap (1, 2, 3, 4) arranged around the said valve unit, the protective cap (1, 2, 3, 4) comprising an opening (9) in which a rotary control member (5) is housed. The opening (9) is bordered by a protruding brim (7) jutting out from the external surface of the body (2) of the protective cap (1, 2, 3, 4). The protruding brim (7) comprises a cutout (8) forming a reading window so that marks or markings (11) corresponding to gas flow-rate values can be read.
    Type: Grant
    Filed: March 9, 2015
    Date of Patent: January 23, 2018
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Air Liquide Santé (International)
    Inventors: Antoine Frenal, Damien Germani, Renaud Ligonesche, Beatriz Lopez, Philippe Rudnianyn, Chiara Tarantello, Catherine Vivier
  • Patent number: 9868753
    Abstract: Disclosed are Germanium- and Zirconium-containing precursors having one of the following formulae: wherein each R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 is independently selected from H; a C1-C5 linear, branched, or cyclic alkyl group; and a C1-C5 linear, branched, or cyclic fluoroalkyl groups. Also disclosed are methods of synthesizing the disclosed precursors and using the same to deposit Zirconium-containing films on substrates via vapor deposition processes.
    Type: Grant
    Filed: October 19, 2016
    Date of Patent: January 16, 2018
    Assignee: L'Air Liquide, Société Anonyme our l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Clément Lansalot-Matras, Julien Lieffrig, Hana Ishii, Christian Dussarrat
  • Patent number: 9868173
    Abstract: The invention relates to an arc welding method that implements an arc welding torch provided with an electrode, in which a central gas flow is supplied so as to contact the electrode and an annular gas flow is supplied on the periphery of said first gas flow. The central gas flow contains only argon and hydrogen (H2), the hydrogen content being 2 to 8 vol %. The sheath gas flow only contains argon and 1.8 to 3 vol % of carbon dioxide (CO2) or 0.9 to 1.5 vol % of oxygen (O2). The method is used for welding parts made of steel, in particular stainless steel or carbon steel, as well as steel coated with zinc or aluminium or any other material for preventing the corrosion of said steel.
    Type: Grant
    Filed: February 3, 2010
    Date of Patent: January 16, 2018
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Sébastien Gadrey, Jean-Pierre Planckaert
  • Patent number: 9868101
    Abstract: An exhaust system for a steam reformer comprises at least one longitudinal collecting tube, wherein along the longitudinal axis of the longitudinal collecting tube ports for connection to catalyst tubes are provided, which in the connected condition are aligned parallel to each other and vertically to the longitudinal collecting tube, a transverse collector which is connected to the at least one longitudinal collecting tube and has a longitudinal axis which extends vertically to the at least one longitudinal collecting tube and vertically to the catalyst tubes, wherein the longitudinal collecting tube is formed as hot exhaust system and the transverse collector is formed as cold exhaust system. The transverse collector is arranged on a side of the longitudinal collecting tube facing away from the ports centrally to the longitudinal collecting tube.
    Type: Grant
    Filed: July 31, 2013
    Date of Patent: January 16, 2018
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Antonio Coscia, Lukas Spies
  • Patent number: 9862632
    Abstract: The invention relates to a unit and method for melting in a furnace comprising a combustion-heated melting chamber, in which the air is heated by means of heat exchange with the fumes generated by combustion. The heated air is used in a gas turbine in order to generate electrical and/or mechanical energy. In addition, the effluent from the gas turbine is used to pre-heat the combustion oxygen and/or gaseous fuel upstream of the melting chamber.
    Type: Grant
    Filed: December 5, 2013
    Date of Patent: January 9, 2018
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Benoit Davidian, Youssef Joumani, Jocelyn Le Dirach, Jean-Pierre Tranier
  • Patent number: 9863655
    Abstract: The invention relates to a device for storing articles in a controlled atmosphere, comprising: at least one storage module capable of receiving the articles to be stored; a storage module provided with at least one shelf for positioning the articles, the storage module having a substantially parallelepiped shape, and having two substantially vertical and opposite walls between which the shelves extend, wherein the device is characterized in that shutters are provided, each shutter being positioned opposite one of the shelves, and between one of the two walls and the shelf in question, so as to prevent the gas from flowing vertically at the location of a shutter, and to allow the gas to flow only transversely along the shelf associated with the shutter in question.
    Type: Grant
    Filed: July 18, 2011
    Date of Patent: January 9, 2018
    Assignee: L'Air Liquide, Société Anonyme l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Vincent Maherault, Robert Briend, Marc Leturmy
  • Publication number: 20180001269
    Abstract: Metallopolyimide precursor fibers for aging-resistant carbon molecular sieve hollow fiber membranes having enhanced selectivity include transition metal cations complexed with electronegative regions of a polyimide. CMS membranes are made by pyrolyzing the metallopolyimide precursor fibers. The cations are introduced by including, in the spin dope composition used to extrude the fibers, either a salt of the transition metal and an inorganic anion or a transition metal/organic ligand complex.
    Type: Application
    Filed: June 30, 2016
    Publication date: January 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Raja SWAIDAN, David J. HASSE, Madhava R. KOSURI, Canghai MA, Robert A. GAGLIANO, Henri CHEVREL
  • Publication number: 20180003435
    Abstract: An apparatus for the production of air gases with variable liquid production by the cryogenic separation of air can include a cold box having a heat exchanger, and a system of columns; a pressure monitoring device; and a controller. The cold box can be configured to receive a purified and compressed air stream under conditions effective for cryogenically separating the air stream to form an air gas product. The apparatus may also include means for transferring the air gas product from the cold box to an air gas pipeline. The pressure monitoring device is configured to monitor the pipeline pressure, and the controller is configured to adjust the product pressure of the air gas product coming out of the cold box based upon the pipeline pressure and to further adjust liquid production from the cold box based on the adjusted product pressure.
    Type: Application
    Filed: December 19, 2016
    Publication date: January 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Paul KONG, Minh PHAM-HUY, Wendy YIP
  • Publication number: 20180003437
    Abstract: A method for the production of air gases with variable liquid production by the cryogenic separation of air can include the steps of sending a purified and compressed air stream to a cold box under conditions effective for cryogenically separating the air stream into an oxygen product and nitrogen using a system of columns, wherein the purified and compressed air stream is at a feed pressure when entering the system of columns; withdrawing the oxygen product at a product pressure; delivering the oxygen product at a delivery pressure to an oxygen pipeline, wherein the oxygen pipeline has a pipeline pressure; wherein during the second mode of operation, the method can include monitoring the pipeline pressure; reducing the difference between the pipeline pressure and the delivery pressure; and adjusting liquid production from the cold box. By operating the method in a dynamic fashion, additional liquid production can be realized in instances in which the pipeline pressure deviates from its highest value.
    Type: Application
    Filed: December 19, 2016
    Publication date: January 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Paul Kong, Minh Pham-Huy, Wendy Yip
  • Publication number: 20180001271
    Abstract: Metallopolyimide precursor fibers for aging-resistant carbon molecular sieve hollow fiber membranes having enhanced selectivity include transition metal cations complexed with electronegative regions of a polyimide. CMS membranes are made by pyrolyzing the metallopolyimide precursor fibers. The cations are introduced by including, in the spin dope composition used to extrude the fibers, either a salt of the transition metal and an inorganic anion or a transition metal/organic ligand complex.
    Type: Application
    Filed: June 30, 2016
    Publication date: January 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Raja SWAIDAN, David J. HASSE, Madhava R. KOSURI, Canghai MA, Robert A. GAGLIANO, Henri CHEVREL
  • Publication number: 20180003433
    Abstract: A method for the production of air gases by the cryogenic separation of air can include the steps of sending a purified and compressed air stream to a cold box under conditions effective for cryogenically separating the air stream into an oxygen product and nitrogen using a system of columns, wherein the purified and compressed air stream is at a feed pressure when entering the system of columns; withdrawing the oxygen product at a product pressure; delivering the oxygen product at a delivery pressure to an oxygen pipeline, wherein the oxygen pipeline has a pipeline pressure; wherein during the second mode of operation, the method can include monitoring the pipeline pressure; and reducing the difference between the pipeline pressure and the delivery pressure. By operating the method in a dynamic fashion, a power savings can be realized in instances in which the pipeline pressure deviates from its highest value.
    Type: Application
    Filed: December 19, 2016
    Publication date: January 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Paul KONG, Minh PHAM-HUY, Wendy YIP
  • Publication number: 20180001270
    Abstract: Metallopolyimide precursor fibers for aging-resistant carbon molecular sieve hollow fiber membranes having enhanced selectivity include transition metal cations complexed with electronegative regions of a polyimide. CMS membranes are made by pyrolyzing the metallopolyimide precursor fibers. The cations are introduced by including, in the bore fluid used to extrude the fibers, either a salt of the transition metal and an inorganic anion or a transition metal/organic ligand complex.
    Type: Application
    Filed: June 30, 2016
    Publication date: January 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Raja SWAIDAN, David J. HASSE, Madhava R. KOSURI, Canghai MA, Robert A. GAGLIANO, Henri CHEVREL, Dean W. KRATZER
  • Publication number: 20180003432
    Abstract: An apparatus for the production of air gases by the cryogenic separation of air can include a cold box having a heat exchanger, and a system of columns; a pressure monitoring device; and a controller. The cold box can be configured to receive a purified and compressed air stream under conditions effective for cryogenically separating the air stream to form an air gas product. The apparatus may also include means for transferring the air gas product from the cold box to an air gas pipeline. The pressure monitoring device is configured to monitor the pipeline pressure, and the controller is configured to determine whether to operate in a power savings mode or a variable liquid production mode. By operating the apparatus in a dynamic fashion, a power savings and/or additional high value cryogenic liquids can be realized in instances in which the pipeline pressure deviates from its highest value.
    Type: Application
    Filed: June 29, 2017
    Publication date: January 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Paul KONG, Minh PHAM-HUY, Wendy YIP
  • Patent number: 9856269
    Abstract: A method for producing a highly pure PMDA comprises at least the following steps: (1) a step of preparing a raw material solution by dissolving a raw material of a pyromellitic dianhydride in an acetic acid solvent, (2) a step of preparing a precursor pyromellitic dianhydride by recrystallizing the pyromellitic dianhydride in the prepared raw material solution and separating the acetic acid solvent, (3) a step of performing a degassing treatment on the precursor pyromellitic dianhydride by stirring the precursor pyromellitic dianhydride in a fluidized state while heating under reduced-pressure conditions, and (4) a step of taking out the pyromellitic dianhydride subjected to the degassing treatment.
    Type: Grant
    Filed: September 1, 2014
    Date of Patent: January 2, 2018
    Assignee: L'Air Liquide, SociétéAnonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Kohei Tarutani, Takashi Kameoka, Tomoko Yanagita, Ryohei Matsui
  • Patent number: 9851142
    Abstract: In a method for separating at least one lighter impurity of a gaseous mixture containing at least 30% mol of carbon dioxide, a liquid (101) enriched with carbon dioxide is drawn off into a vat of a distillation column (25), at least part (27) of the liquid enriched with carbon dioxide is vaporized and then heated to a first temperature higher than the boiling temperature thereof in the exchanger and leaves the exchanger at the hot end thereof, and at least part of the vaporized and heated liquid is sent from the hot end of the exchanger at the first temperature, without being cooled in the exchanger and without having been compressed, to the lower part of the distillation column, where it participates in the distillation while enriching itself.
    Type: Grant
    Filed: September 24, 2013
    Date of Patent: December 26, 2017
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Arthur Darde, Mathieu Leclerc
  • Patent number: 9851102
    Abstract: A plurality of independently flow rate-controlled flows of oxidant may be preheated at a heat exchanger (or both oxidant and fuel at separate heat exchangers) by heat exchange with a hot shell-side (heat transfer) fluid. The separate flows of hot oxidant are directed to associated separate burners where they combust with flows of fuel to produce hot combustion gases. The hot combustion gases are used to preheat the hot shell-side fluid at a recuperator or regenerator.
    Type: Grant
    Filed: July 31, 2013
    Date of Patent: December 26, 2017
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Taekyu Kang, James J. F. McAndrew, Youssef Joumani, Remi Pierre Tsiava
  • Publication number: 20170362122
    Abstract: Method of operating a long direct-fired inclined counterflow rotary kiln for the thermal treatment of material and counterflow rotary kiln adapted for same, whereby material to be treated is introduced into the kiln at the inlet end and treated material is evacuated from the kiln at the outlet end, whereby a main combustion zone extends inside the kiln over a distance of ¼ to ? of the internal length Lint of the kiln, whereby a supplementary combustion zone in which supplementary combustion takes place with an oxygen-rich oxidant extends inside the kiln over a distance from the inlet end of at most ¼ of the internal length Lint, and whereby no combustion takes place in a heat exchange zone located between the main combustion zone and the supplementary combustion zone.
    Type: Application
    Filed: December 24, 2015
    Publication date: December 21, 2017
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Bernard LABEGORRE, Carlo RENNA, Remi TSIAVA, Sergio FERNANDES
  • Patent number: 9844753
    Abstract: A plant for purifying a gas stream comprising at least 0.02% by volume of water, CO2 and NOx, comprising an adsorber characterized by: a cavity (1); an adsorbent (2) included in the cavity (1); an outer casing (3) made of carbon steel; an inner casing (4) made of stainless steel making a space having a width of between 10 and 100 mm between said inner casing and the outer casing, said space being at equal pressure with the cavity.
    Type: Grant
    Filed: June 3, 2013
    Date of Patent: December 19, 2017
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christophe Szamlewski, Christian Monereau, Samuel Amy, Mathieu Leclerc, Thierry Gesbert