Patents Assigned to L'Exploitation Des
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Patent number: 9086015Abstract: An integrated oxy-combustion turboexpander process including producing an enriched carbon dioxide product stream, by combusting a compressed synthetic air stream, including an oxygen-enriched stream and a carbon dioxide recycle stream, with a fuel stream and expanding the combustion stream thereby producing the carbon dioxide recycle stream and an enriched carbon dioxide product stream; producing an essentially pure carbon dioxide product stream, by processing the enriched carbon dioxide product stream into a deoxo methane combustor.Type: GrantFiled: April 19, 2012Date of Patent: July 21, 2015Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Craig LaForce, Bhadra S. Grover
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Patent number: 9085823Abstract: A method for forming a tantalum-containing layer on a substrate, the method comprising at least the steps of: a) providing a vapor comprising at least one precursor compound of the formula Cp(R1)mTa(NR22)2(?NR3) (I): wherein: R1 is an organic ligand, each one independently selected in the group consisting of H, linear or branched hydrocarbyl radical comprising from 1 to 6 carbon atoms; R2 is an organic ligand, each one independently selected in the group consisting of H, linear or branched hydrocarbyl radical comprising from 1 to 6 carbon atoms; R3 is an organic ligand selected in the group consisting of H, linear or branched hydrocarbyl radical comprising from 1 to 6 carbon atoms; b) reacting the vapor comprising the at least one compound of formula (I) with the substrate, according to an atomic layer deposition process, to form a layer of a tantalum-containing complex on at least one surface of said substrate.Type: GrantFiled: July 15, 2009Date of Patent: July 21, 2015Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Nicolas Blasco, Anthony Correia-Anacleto, Audrey Pinchart, Andreas Zauner, Ziyun Wang
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Patent number: 9074766Abstract: The invention relates to a method for heating a material in a zone heated by combustion of a fuel with an oxidant by means of a oxyburner comprising an injector arranged within a block defining a chamber with a confinement index Iconf=(S/S?)×(L/L?)×(1/(1+a/100))=0.10; the fuel being injected into the burner chamber with a rate IF and the oxidant being injected into the burner chamber at a rate Iox such that 0.7=IF=3.6 et 0.3=Iox=5.1, provided that when Iox>3.8 then IF=3.3.Type: GrantFiled: November 21, 2008Date of Patent: July 7, 2015Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Robert Kalcevic, Jacky Laurent, Bertrand Leroux, Remi Tsiava
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Patent number: 9073952Abstract: Si(OEt)2[CH2—Si(OEt)3]2 compounds are synthesized by reacting a Grignard reagent having the formula Si(OEt)3(CH2MgCl) with a quenching agent having the formula Si(OEt)2Cl2.Type: GrantFiled: April 27, 2012Date of Patent: July 7, 2015Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc., Air Liquide Electronics U.S. LPInventors: Zhiwen Wan, Ziyun Wang, Ashutosh Misra, Jean-Marc Girard, Andrey V. Korolev
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Patent number: 9067173Abstract: The invention relates to a method for treating a gas stream comprising combustion fumes containing CO2 in an initial proportion, water vapor, one or more volatile acid compounds, and one or more additional impurities selected from among oxygen, nitrogen and argon, comprising the steps of: i) compressing the gas stream to a final pressure of 1 bar to 74 bar absolute; ii) cooling the gas stream to a temperature of around ?10° C. to around ?130° C. and eliminating at least one additional impurity; and iii) recovering a CO2-enriched gas stream containing a final proportion of CO2 greater than the initial proportion of CO2 in the stream to be treated. In addition, the method comprises, prior to step i), a step of pre-drying the stream for removing therefrom at least a portion of the water vapor which it contains.Type: GrantFiled: February 25, 2011Date of Patent: June 30, 2015Assignee: L'Air Liquide SociétéAnonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Bruno Alban, Philippe Arpentinier, Alain Briglia, Serge Moreau, Fabrice Del Corso, Benoit Davidian
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Patent number: 9068154Abstract: A method for removing dissolved oxygen from a plant product such as grapes or the like and for maintaining it in a controlled atmosphere when it is placed in mechanical means for harvesting, transport and storage, said means comprising a collection tank which receives the plant product which is present in a solid and a liquid state in this tank, said removal and controlled atmosphere being provided by using an inert gas, said tank having a lower portion or first part and a second upper part or portion into which the product is introduced when being placed in the tank. Provision is made for the use of said inert gas in an initial solid state, its subsequent sublimation and the interaction of the gas in gaseous state thus produced with said product inside the tank.Type: GrantFiled: March 2, 2010Date of Patent: June 30, 2015Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Maurizio Frati
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Patent number: 9067785Abstract: An integrated reforming and power generation process is provided. This process employs a steam methane reformer to provide a hot process gas stream and a flue gas stream, utilizes the hot process gas stream to provide heat to produce a total steam stream comprising a process steam stream and an excess steam stream, and utilizes the flue gas stream to provide heat to at least a pre-reformer mixture stream, a reformer feed stream, the process steam stream and a pre-reformer steam stream The flue gas stream also provides heat to an integrated power generation process, and the excess steam stream is less than 15% of the total steam stream.Type: GrantFiled: October 1, 2013Date of Patent: June 30, 2015Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Bruce Eng, Rahul Khandelwal
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Patent number: 9061240Abstract: The invention relates to an on-site medical gas production plant (100) comprising a unit (50) for purifying gas, such as air, a first vessel (A) for storing purified gas, and a main gas line (10) fluidically connecting the gas purification unit (50) to the said first storage vessel (A). It furthermore comprises a three-way solenoid valve (VA) arranged on the main gas line (10) upstream of the first storage vessel (A), and furthermore connected to the atmosphere (at 12) via a vent line (11), as well as an operating device (4) which controls at least the three-way solenoid valve (VA), and at least a first gas analysis device (D1) of which a first measurement line (29) is fluidically connected (at 28) to the main line (10), upstream of the three-way solenoid valve (VA), and which is electrically connected to the said operating device (4).Type: GrantFiled: February 13, 2013Date of Patent: June 23, 2015Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Vincent Sommier, Peter Neu, Hartmut Franken, Karsten Bongers, Kais Maamar
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Patent number: 9062908Abstract: System for the operation and management of a fleet of refrigerated autonomous containers for transporting perishable goods, comprising: containers provided with a passive tag comprising identification information and with an active tag comprising a temperature probe and a recorder connected to said probe and capable of recording the measured temperature values; a gun or means for injecting a refrigerant into the container, which means is provided with a device capable of reading the passive tag of the container, so as to be cognizant of the identification number of the passive tag; and a data acquisition and processing unit capable of carrying out the following operations: receiving said identification information from said device and linking this identification number of the passive tag with the number of the active tag in the container; calculating, as a function of data associated with the logistic travel of the container and physical data of a refrigerant, an amount of liquefied gas to be injected into thType: GrantFiled: January 15, 2007Date of Patent: June 23, 2015Assignee: L'Air Liquide Société Anonyme pour l'Ètude Et l'Exploitation des Procedes Georges ClaudeInventors: Jochen Weidlich, Dominique Jouvaud, Michel Kostelitz, Serge Morel-Jean
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Patent number: 9062996Abstract: Disclosed are methods and apparatuses for supplying a liquid and controlling its level inside of a container. In particular, the liquid inside of the container may be a liquid material suitable for use in a chemical vapor deposition process, wherein the liquid is controlled and supplied in a manner which minimizes the introduction of impurities.Type: GrantFiled: January 27, 2010Date of Patent: June 23, 2015Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Toshiyuki Nakagawa, Takamitsu Shigemoto, Yoshio Uetake, Masahiro Kimoto, Tetsuro Shigeno, Masaaki Muro, Naoyuki Nakamoto
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Publication number: 20150168057Abstract: A process for producing a liquid nitrogen product through the cryogenic separation of air in a nitrogen production plant is provided. The nitrogen production plant can include a main air compressor; a heat exchanger; an air separation unit having a single column, a top condenser, and a bottom reboiler; a recycle compressor; at least one turbine-booster having a booster and a turbine; a liquid/gas separator; and a subcooler. The reboiler can be driven by gaseous nitrogen withdrawn from the recycle compressor, preferably at a first stage discharge of the recycle compressor. Additionally, the single column can be partly refluxed with liquid nitrogen split-off from a Joule-Thompson stream.Type: ApplicationFiled: December 17, 2013Publication date: June 18, 2015Applicant: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Paul MUSICUS
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Publication number: 20150168056Abstract: A method is provided for production of gaseous oxygen at moderate pressures by splitting a main air feed into at least three separate streams, with the first stream being fed to a heat exchanger and then a column system for rectification; the second stream being further compressed in a warm booster, partially cooled in the heat exchanger, expanded in a turbine coupled to the warm booster and then fed to the column system; the third stream being expanded in a warm expander before being introduced to the heat exchanger and introduced to the column system. In certain embodiments, substantially all of the main air feed is eventually introduced to the column system for rectification, resulting in reduced sizing of a main air compressor and improved product recoveries.Type: ApplicationFiled: December 17, 2013Publication date: June 18, 2015Applicant: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Paul MUSICUS
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Patent number: 9052063Abstract: A container for storing compressed gas includes a plurality of aligned glass capillaries extending into a tubesheet. Each of the capillaries has an open end flush with a front face of the tubesheet. An end cap having a gas outlet connectable to a compressed gas valve or conduit is fitted to the tubesheet in gas-tight fashion to form a high pressure space defined by inner surfaces of the capillaries, the front face of the tubesheet, and inner surfaces of the end cap.Type: GrantFiled: December 31, 2012Date of Patent: June 9, 2015Assignees: L'Air Liquide Société Anonyme Pour L'Étude, Et L'Exploitation Des Procedes Georges Claude C.En Ltd.Inventors: Pascal Tessier, Tao Li, Edgar S. Sanders, Jr., David P. Edwards, Francoise Barbier
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Publication number: 20150151266Abstract: An apparatus for decreasing steam methane reformer (SMR) tube temperature is provided. The apparatus can include an SMR furnace, a monitoring system in communication with the SMR furnace and a water source in fluid communication with the SMR furnace. The SMR furnace includes a plurality of SMR tubes disposed within the SMR furnace. The monitoring system is configured to monitor the temperature of at least a plurality of SMR tubes and compare the temperature against a first predetermined value, and the water source is configured to introduce water to an SMR tube that has a temperature above the first predetermined value, such that the temperature of the SMR tube is reduced.Type: ApplicationFiled: December 4, 2013Publication date: June 4, 2015Applicant: L'Aire Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Taekyu KANG, Rong FAN, Pavol PRANDA, Hwanho KIM, Robert A. GAGLIANO
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Patent number: 9046219Abstract: The invention relates to a method for controlling a homogeneous batch (1) of pressurized fluid cylinders (2) during at least part of the use cycle of said cylinders. According to the invention, each of the cylinders (2) is provided with a valve (3) having an electronic device (4) including at least one sensor (14) for measuring the pressure (P) inside the cylinder (2), a system (44) for storing/acquiring and processing data and an electromagnetic wave transmitter (34), for example using radio frequency, designed for the remote transmission of at least one of the following items of information: the identity of the cylinder (2) and the pressure (P) measured inside said cylinder.Type: GrantFiled: March 27, 2008Date of Patent: June 2, 2015Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Christian Bleys, Fabrice Pin, Philippe Deck
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Patent number: 9044704Abstract: The present invention is a method of integrating oxygen production with blast furnace operation. A heated air stream is introduced to an ion transfer membrane separator, producing a permeate and a retentate. The permeate and the motive stream are introduced into an ejector jet pump producing an oxygen enriched stream. The oxygen enriched stream is introduced into blast furnace. In another embodiment of the present invention, the permeate and a steam motive stream are introduced into an ejector jet pump. Heated air inlet stream is introduced into a cascading series of ion transfer membrane separators, producing a series of permeate streams and a series of retentate streams wherein each retentate stream acts as the input stream for the subsequent ion transfer membrane separator. Thereby producing a series of oxygen enriched streams which are combined and introduced into blast furnace.Type: GrantFiled: June 21, 2012Date of Patent: June 2, 2015Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Bhadra S. Grover, Kenneth Kaiser, Michael Garry Keith Grant, Wei Huang
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Patent number: 9046264Abstract: Methods and apparatus for controlling the operation of a burner used for heating liquid glass feeders of a glass furnace. A burner is supplied with a fuel and oxygen. An additional gas is injected so that the sum of the oxygen flow, the fuel flow and the additional gas flow is greater than a minimum cooling flow for the burner.Type: GrantFiled: October 15, 2008Date of Patent: June 2, 2015Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges ClaudeInventors: Son-Ha Giang, Luc Jarry, Gerard Le Gouefflec, Dominique Robillard
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Patent number: 9040372Abstract: Disclosed are methods for forming a metal-containing layer on a substrate. The methods include providing a vapor and at least one reaction gas and reacting the vapor and the reaction gas with the substrate by a deposition process. The vapor may be selected from the group consisting of (Cp)V(?NtBu)(NEt2)2; (Cp)V(?NtBu)(NMe2)2; (Cp)V(?NtBu)(NEtMe)2; (Cp)V(?NiPr)(NEt2)2; (Cp)V(?NiPr)(NMe2)2; (Cp)V(?NiPr)(NEtMe)2; (Cp)V(?NC5H11)(NEt2)2; (Cp)V(?NC5H11)(NMe2)2; (Cp)V(?NC5H11)(NEtMe)2; (Cp)Nb(?NtBu)(NEt2)2; (Cp)Nb(?NtBu)(NMe2)2; (Cp)Nb(?NtBu)(NEtMe)2; (Cp)Nb(?NiPr)(NEt2)2; (Cp)Nb(?NiPr)(NMe2)2; (Cp)Nb(?NiPr)(NEtMe)2; (Cp)Nb(?NC5H11)(NEt2)2; (Cp)Nb(?NC5H11)(NMe2)2; and (Cp)Nb(?NC5H11)(NEtMe)2.Type: GrantFiled: May 7, 2013Date of Patent: May 26, 2015Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés GeorgesInventors: Nicolas Blasco, Antony Correia-Anacleto, Audrey Pinchart, Andreas Zauner
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Publication number: 20150141469Abstract: A kit for the production of an antimicrobial foam includes: a) a liquid composition which includes a1)one or more bispyridinium alkane and a2)one or more surfactants selected from non-ionic surfactants, amphoteric surfactants and cation-active surfactants, wherein the composition is formulated so that a foam can be produced therefrom, and b) a device for producing the foam from the composition. By using the bispyridinium alkanes the foam stability of liquid and surfactant-containing compositions is increased.Type: ApplicationFiled: November 18, 2014Publication date: May 21, 2015Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGInventors: Petra KOLDITZ, Sabine BEHRENDS, Anja BEHRENDT, Andreas DETTMANN, Thomas SPUIDA
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Publication number: 20150139862Abstract: A structured adsorbent sheet, is provided including a nano-adsorbent powder, and a binder material, wherein the nano-adsorbent powder is combined with the binder material to form an adsorbent material, and a porous electrical heating substrate, wherein the adsorbent material is applied to the porous electrical heating substrate thereby forming a structured adsorbent sheet. A structured adsorbent module is provided, including a plurality of stacked structured adsorbent sheets, configured to produce a plurality of fluid passages, wherein the plurality of fluid passages have a cross-sectional shape in the direction of a fluid stream. The structured adsorbent module may have a cross-sectional shape that is trapezoidal, rectangle, square, triangular or sinusoidal.Type: ApplicationFiled: November 20, 2013Publication date: May 21, 2015Applicant: L'Air Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Yudong CHEN, Christian MONEREAU, Edgar S. SANDERS, JR., Pascal TESSIER