Abstract: A primer assembly is provided for use in vertical boreholes wherein the primer charge is initiated by means of electric blasting caps, the electric caps, in turn, being initiated electromagnetically. A covered, cup-shaped primer assembly contains a toroid transformer element and connected electric blasting cap in detonating relationship with a primer explosive charge. The assembly is arranged to receive therethrough a looped wire conductor which conductor passes freely through the toroid transformer. When an energy source is coupled to the looped conductor, a magnetic flux is induced in the toroid transformer which sets off the cap and primer charge. The assembly may be passed freely or slid along the looped conductor to any location in the borehole. The assembly permits the use of electric time-delay, deck-charge blasting without the usual hazards associated with normal electric cap blasting.

Abstract: A polyethylene shipping bag having an internal nylon barrier coating which permits packaging of materials which normally migrate through polyethylene. The coating is flexographically applied from a nylon solution in a lower aliphatic alcohol with up to 15% water to a polyethylene film which has been previously treated to make it receptive to printing ink. The bag may be single ply or double ply and may have a filling valve.

Abstract: A thermoplastic film package containing a blasting explosive is provided having utility in secondary blasting operations. The package comprises superimposed film panels joined along their periphery to form a bag and having closeable neck-like openings at opposite ends of the bag. The package lends itself to fabrication from flat film or sheet by heat-sealing techniques and may be filled with explosives on continuous packaging apparatus.

Abstract: A two-component emulsion explosive composition is provided consisting of a continuous oil/fuel phase and a discontinuous aqueous oxidizer salt phase and, as an emulsifier, a dimer acid glyceride wherein the dimer acid has a carbon atom chain length of C18-C60. The composition demonstrates superior properties of long period storage stability and sensitivity.

Abstract: A method and apparatus is provided for cartridging viscous explosives mixtures, such as emulsion explosives, in convolutely wound paper tubes. The method comprises winding a section of paper film on a rotating hollow mandrel, closing one end of the wound paper tube, injecting the explosives mixture through the hollow mandrel into the paper tube upon the mandrel, removing the filled tube from the mandrel and closing the tube open end. The method replaces higher cost plastic chub packages with low cost paper and allows the efficient and economic production of sensitive small-diameter cartridges wherein the occluded air or gas is not dissipated during cartridging.

Abstract: A semi-automatic, semi-continuous method is provided for the manufacture of cast explosive boosters. The method makes us of a mold assembly which is transported through filling, cooling and disassembly stations in a substantially continuous manner with little or no manual intervention. The method is adaptable to the manufacture of sheath/core or multiple layer boosters employing two explosives of different sensitivities. The method results in reduced operating costs and improved safety.

Abstract: An improvement is provided in the operation of a long vertical shaft bioreactor in the treatment of waste which comprises circulating waste liquor and oxygenating gas through the bioreactor in which the uppermost portion of the shaft (the surface basin) is under supra-atmospheric pressure. The use of a pressurized surface basin subjects the waste to improved oxidizing conditions in a critical zone of the bioreactor and results in more effective biodegradation of the waste. By precise control of surface basin pressure, adequate levels of oxygen in the waste are maintained for biodegradation purposes while unwanted gas, such as carbon dioxide and nitrogen, are disengaged. The pressure on the surface of the waste in the basin is controlled so as to ensure that the concentration of oxygen in the waste is subsaturated and retained while the unwanted gas concentration is super saturated and becomes disengaged.

Abstract: A water-in-oil emulsion explosive composition is provided wherein the continuous carbonaceous oil or fuel phase comprises an unrefined or partly refined petroleum product, for example, slackwax. The resulting explosive composition exhibits properties of strength, detonation velocity and stability comparable and in some cases superior to similar compositions containing refined petroleum fuels.

Abstract: A composite electrode made up by stacking a multiplicity of alternate anode plates and cathode plates the adjacent surfaces of which are insulated from each other by a thin film of an insulating material such as fluon, kynar, PVC, etc. With this composite electrode, a K value of 0.100 to 0.150 can be easily achieved in the electrolytic production of chlorates and hypochlorites.

Abstract: A process for making calcium hypochlorite from caustic soda calcium hydroxide and chlorine by feeding to a stirred reactor an aqueous solution of the total required amount of caustic soda and an aqueous suspension of up to 80% by weight of the total required amount of calcium hydroxide, passing chlorine through the mixture until a redox potential of 650 to 800 mV is reached and while continuing chlorination adding the remaining of the calcium hydroxide at such rate with respect to chlorine that redox potential gradually increases to between 850 and 950 mV. This process prevents thickening and caking which are a recognized problem with conventional batch processes.

Abstract: An improved nitrogen gas generating pyrotechnic composition is provided which consist of a stoichiometric mixture of an alkali metal azide or alkaline earth metal axide fuel and an oxidant consisting of a mixture of at least two metal oxides selected from the oxides of iron, silicon, manganese, tantalum, niobium and tin. The mixed metal oxides provide a synergistic effect and result in a composition having improved ignition delay time, burn rate and gas pressure as well as a reduction in toxic by-products and dust.

Abstract: An improved method and apparatus is provided for the treatment of sewage waste in a long vertical shaft bioreactor wherein waste sewage is caused to circulate under air injected oxidizing conditions around a loop comprising adjacent riser and downcomer chambers connected at their upper and lower ends. The improved method comprises the steps of introducing influent waste at depth into the riser chamber at a point higher in the riser than the point of air injection and withdrawing treated effluent from the riser at a point lower in the riser than the point of air injection. A separation chamber may also be operatively connected to the riser chamber to recover sludge for return to the bioreactor. The method provides an improvement in oxygen uptake rate and reduces the anoxic zone in the reactor thus providing additional capacity for BOD.sub.5 removal.

Abstract: A process for the continuous preparation of a slurry of calcium hypochlorite wherein a solution of sodium hydroxide is fed to one end of an elongated tubular reaction and a calcium hydroxide slurry and chlorine are introduced through a number of injection sites along the length of the reactor. The redox potential of the reaction mixture at any injection site must not be inferior to that at the immediately preceding site and must be in the range 900 to 950 mV at the exit end of the reactor. The process permits easy control of the reaction temperature and of the viscosity of the reaction mixture.

Abstract: A heat exchanger having a disc and doughnut baffle configuration, in which the tubes are laid out in a set of concentric rings. Each ring of a set contains the same number of tubes as each other ring of the set, and the tubes in each ring are spaced uniformly apart. Each tube in each ring is located circumferentially midway between the two adjacent tubes of each neighboring ring and is separated from each of the two adjacent tubes in each adjacent ring by a ligament distance h. The distance h is held constant for all tubes in the set, by varying the radial spacing between rings, and the distance between any two adjacent tubes in any ring of the set is made greater than or equal to 2 h. The ligament gaps h which are constant therefore determine the minimum flow area between adjacent rings, and therefore the mass flow velocity through the tube bundle is constant.

Abstract: A water-in-oil explosive composition based on colloidal dispersions is provided. Unlike conventional emulsion explosive compositions, the microemulsion composition of the invention displays exceptional long term storage stability retaining sensitivity to propagation even in small diameter charges. The composition is also tolerant to doping with further fuel and energy enhancing ingredients. The microemulsion-producing component of the composition comprises a combination of at least one conventional water-in-oil emulsifier and at least one amphiphatic synthetic polymeric emulsifier selected from graft, block or branch polymers.

Abstract: In a blow-molded, cylindrical plastic container for explosives adapted for end-to-end coupling with like containers, an improvement is provided in the sealing of the container at the exposed explosives end. The improvement comprises a section of reduced diameter in the portion of the container immediately beyond the point of connection of a like container. The section of reduced diameter is adapted to receive therein a resilient plastic, disc-like sealing member in fluid-tight engagement. The seal prevents contamination of the explosive yet yields upon the pressure exerted by an adjacent, connected container.

Abstract: In a long vertical shaft bioreactor for the treatment of degradable wastes in a circulating loop, a process is provided for separating and treating the slowly biodegradable components of the waste. The process comprises the steps of aerating and oxidizing the waste liquor in the reactor to produce an effluent and a foam which foam contains the slowly biodegradable components, which have not been degraded in the oxidizing step, separating and collecting the foam, collapsing the foam and subjecting the collapsed foam to further aeration/oxidation treatment to produce a treated effluent. The thus further treated effluent is returned to the bioreactor for reprocessing.

Abstract: An explosive booster is provided for the detonation of insensitive blasting agents. The booster contains TNT as the sole explosive ingredient, is sensitive to blasting cap initiation yet remains insensitive to impact initiation. The booster comprises an elongate structure having a gradually increasing density from end to end, only the less dense end being cap sensitive. Reduced density is accomplished by the incorporation of voids or pockets, by means of, for example, glass microspheres. Particulate sodium nitrate and vermiculite are included as density enhancers.

Abstract: An improved gland seal is provided for an extrusion, chub container packaging apparatus. The seal comprises a rigid ring sealing element adapted to swivel upon a ball-like holder attached to the end of the filling horn. The sealing element may be simply positioned to compensate for variations in casing diameters and is not subject to expansion caused by pressure pulses during packaging. Package breakage and malformation is reduced and a uniform product is provided.

Abstract: An improved method of gassing an aqueous slurry explosive composition with an inorganic nitrite gassing agent is provided. The method makes use of a thiocyanate ion-containing material in the composition as a gassing accelerator. The presence of the thiocyanate ion produces improved rate and quantity of gas generation even under low temperature where gas generation is normally retarded.