Patents Assigned to Loctite (R&D) Limited
-
Publication number: 20080035597Abstract: The present invention provides a child-resistant closure for a container. The closure comprises a dispensing nozzle, a cap for the dispensing nozzle, inter-engaging formations and a resiliently deformable element. The inter-engaging formations provided on the closure hold the cap to the nozzle in an interengaged assembly thereof. The resiliently deformable element biases the cap and the nozzle apart. The inter-engaging formations comprise a retaining slot for receiving a retainer and a retainer for engagement with the retaining slot. The retaining slot, retainer and resiliently deformable element are arranged so that the cap and the nozzle are retained interengaged in the interengaged assembly by bias from the resiliently deformable element. The release of the interengaging formations is achieved by applying sufficient pressure axially to the assembly to overcome the bias of the resiliently deformable element, and sufficient turning force to move the retainer out through the opening of the retaining slot.Type: ApplicationFiled: August 10, 2007Publication date: February 14, 2008Applicant: Loctite (R&D) LimitedInventor: Gary Leonard
-
Patent number: 7267886Abstract: Quaternary boron salts are used as initiators of polymerisation in adhesive compositions for bonding low surface energy substrates such as polyolefins. The quaternary boron salts are of the formula I wherein R1 is C1–C10 alkyl, R2, R3 and R4, which may be the same or different, are, C1–C10 alkyl or C3–C10 cycloalkyl, phenyl, or phenyl-substituted C1–C10 alkyl or C3–C10 cycloalkyl, provided that any two of R1–R4 may optionally be part of a carbocyclic ring, and M+ is a metal ion or a quaternary ammonium ion. Particular examples of initiator compounds include sodium tetraethyl borate and lithium tetraethyl borate, lithium phenyl triethyl borate and tetraethylammonium phenyl triethyl borate.Type: GrantFiled: December 3, 2004Date of Patent: September 11, 2007Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Gerry Coughlan
-
Patent number: 7189463Abstract: Quaternary boron salts are used as initiators of polymerisation in adhesive compositions for bonding low surface energy substrates such as polyolefins. The quaternary boron salts are of the formula I wherein R1 is C1–C10 alkyl, R2, R3 and R4, which may be the same or different, are, C1–C10 alkyl or C3–C10 cycloalkyl, phenyl, or phenyl-substituted C1–C10 alkyl or C3–C10 cycloalkyl, provided that any two of R1–R4 may optionally be part of a carbocyclic ring, and M+ is a metal ion or a quaternary ammonium ion. Particular examples of initiator compounds include sodium tetraethyl borate and lithium tetraethyl borate, lithium phenyl triethyl borate and tetramethylammonium phenyl triethyl borate.Type: GrantFiled: October 23, 2001Date of Patent: March 13, 2007Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Gerry Coughlan
-
Patent number: 7168707Abstract: A material for sealing threaded pipe joints includes a multifilament yarn ready-coated with a joint sealing composition. The material is packaged in a dispenser from which the coated yarn may be supplied for direct application to a threaded area of a pipe.Type: GrantFiled: September 10, 2003Date of Patent: January 30, 2007Assignee: Loctite (R&D) LimitedInventors: Tadgh Eisirt Casey, Francis Richard Martin, Ellen Patricia Cullen, Philip Malcolm Regan
-
Patent number: 7108920Abstract: This invention relates to thermosetting resin compositions useful for mounting onto a circuit board semiconductor devices, such as chip size or chip scale packages (“CSPs”), ball grid arrays (“BGAs”), land grid arrays (“LGAs”), and the like, each of which having a semiconductor chip, such as large scale integration (“LSI”), on a carrier substrate, as well as compounds useful in such compositions. The compositions include compounds having a thermally cleavable linkage, and include an episulfide group within the compound. The compositions of this invention are reworkable when subjected to appropriate conditions.Type: GrantFiled: September 15, 2000Date of Patent: September 19, 2006Assignees: Henkel Corporation, Loctite (R&D) LimitedInventors: Lawrence N. Crane, Mark M. Konarski, Brendan J. Kneafsey, Afranio Torres-Filho, Z. Andrew Szczepaniak
-
Patent number: 7098279Abstract: This invention relates to (meth)acrylate based polymerizable compositions and adhesive systems prepared therefrom, which include an initiator system comprising a complex of an organoborane with a complexing agent, an aziridine-containing compound, and a carrier material with which the initiator system is unreactive and which renders the composition having a flash point above 140° F. The inventive compositions desirably have a flash point above 200° F., for each of the parts of the adhesive system. To achieve the physical properties of the inventive compositions and adhesive systems, it is desirable for the carrier material to have such flash points; however, provided that in their entirety the inventive compositions and adhesive systems have such flash points, it is not necessary for the carrier material itself to have such flash points. The inventive compositions and adhesive systems also include a package for controlling the rate of cure and indicating the extent of cure.Type: GrantFiled: April 21, 2003Date of Patent: August 29, 2006Assignees: Loctite (R&D) Limited, Henkel CorporationInventors: Eerik Maandi, Brendan J. Kneafsey
-
Patent number: 6995227Abstract: An activator composition for the accelerated hardening of cyanoacrylate adhesives, wherein the activator comprises a member selected from the group consisting of: aromatic heterocyclic compounds having at least one N hetero atom in the ring(s) such as pyridines, quinolines and pyrimidines and substituted on the ring(s) with at least one electron-withdrawing group which decreases the base strength of the substituted compound compared to the corresponding unsubstituted compound, mixtures of any of the foregoing with each other, and/or with N,N-dimethyl-p-toluidine, and mixtures of any of the foregoing and/or N,N-dimethyl-p-toluidine with an organic compound containing the structural element, —N?C—S—S—, such as dibenzothiazyl disulfide. 6,6?dithiodinicotinic acid, 2,2?-dipyridyl disulfide, and bis(4-t-butyl-1-isopropyl-2-imidazolyl)disulfide. An activator composition may comprise a solution of one or more activators in a solvent mixture which comprises a volatile hydrocarbon and a cyclic ketone.Type: GrantFiled: May 11, 2001Date of Patent: February 7, 2006Assignee: Loctite R&D LimitedInventors: Bernard Ryan, Hanns Roland Misiak, James A. Houlihan, Gerard R. McCann
-
Patent number: 6977025Abstract: The invention provides a method of forming a monolayer of substantive particles including the steps of applying to a substrate a curable composition having substantive particles contained therein, the substantive particles having a particle size on at least one dimension thereof of at least 1 micrometer and being in two or more groups of different sizes; exposing the substantive particle-containing curable composition to a source of energy suitable for effecting polymerization of the curable composition for a sufficient time to effect polymerization of a layer of the curable composition having a thickness of no more than 50% of the height of the largest substantive particles; and optionally, removing uncured curable composition. The invention also provides a method of forming a monolayer of substantive particles in a non-random array where the curable composition comprises a ferrofluid composition.Type: GrantFiled: March 17, 2003Date of Patent: December 20, 2005Assignee: Loctite (R&D) LimitedInventors: Ciaran Bernard McArdle, Rory Brian Barnes
-
Patent number: 6939932Abstract: Use of an initiator system comprising: a combination of an organoborane and a polyaziridine, in a ratio of aziridine groups to boron atoms of greater than 1.3:1, as an initiator of polymerisation in an adhesive composition for bonding a low surface energy substrate; provided that the initiator system does not contain more than a trace amount of a complex of organoborane with a complexing agent selected from: an amine other than a polyaziridine; a complexing agent comprising at least one hydroxide; a complexing agent comprising at least one alkoxide; or amidine complexing agent.Type: GrantFiled: April 21, 2003Date of Patent: September 6, 2005Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Gerry Coughlan
-
Patent number: 6918984Abstract: The present invention is directed to a photocurable composition for use as an encapsulant, for underfill or attachment adhesives, capable of curing at wavelengths greater than 290 nm. Reaction products of these photocurable compositions have a low level of extractable halide ion, such as less than 100 ppm. In use, the photocurable composition may be applied, for instance, over the wire bonds that electrically connect a semiconductor device to a substrate to maintain a fixed positional relationship and protect the integrity of the electrical connection from vibrational and shock disturbances, as well as from interference from environmental contaminants.Type: GrantFiled: June 24, 2002Date of Patent: July 19, 2005Assignee: Loctite (R&D) LimitedInventors: Helen M. Murray, Jonathan P. Wigham, John E. Cahill, Aisling Lakes, Matthew J. Holloway, Eadaoin D. Ledwidge, Mary B. Ward
-
Patent number: 6874665Abstract: The invention is a nozzle assembly (3, 20) with a re-useable break off cap (20) for dispensing a product from a container (1). On a dispensing end (5) of the nozzle (3) a break-off cap (20) is integrally formed thereon and closes off the dispensing end (5) of the nozzle (3). The break-off cap (20) is removable by breaking a frangible connection (22) between the nozzle (3) and the break-off cap (20). Removing the break-off cap opens the dispensing end (5) of the nozzle (3) thereby allowing product to be dispensed through the nozzle (3). The break-off cap (20) removed from the nozzle (3) can then be re-engaged with the nozzle (3) to close off the dispensing end (5) thereby preventing further product from being dispensed. The cap can be attached to or removed from the nozzle (3) as often as a user requires. The invention also includes packaging which includes a tray (111) or pouch into which the nozzle assembly (3, 20) and container (1) can be inserted.Type: GrantFiled: June 7, 2001Date of Patent: April 5, 2005Assignee: Loctite (R&D) LimitedInventors: Michael A. Doherty, Peter C. Rushe
-
Patent number: 6872762Abstract: This invention relates to curable epoxy-based compositions for use in the field of microelectronics, such as those having an epoxy compound which has two or more epoxy groups per molecule, optionally a polythiol compound which has two or more thiol groups per molecule, a latent hardener, and at least one solid organic acid which is substantially insoluble in a mixture of the foregoing components at room temperature. The solid organic acid may be selected from the group consisting of: aliphatic, cycloaliphatic and aromatic carboxylic acids and derivatives thereof, aliphatic, cycloaliphatic, and aromatic quinones and derivatives thereof, phenols and derivatives thereof and enolisable aliphatic, cycloaliphatic and aromatic compounds and derivatives thereof. The solid organic acid should have a pKa of less than or equal to about 12.0, desirably less than or equal to about 10, and often less than or equal to about 9.0, such as less than or equal to about 7.5.Type: GrantFiled: July 3, 2003Date of Patent: March 29, 2005Assignee: Loctite (R&D) LimitedInventors: Barry N. Burns, Harry Woolfson, Paul Malone, Jonathan Wigham
-
Patent number: 6867271Abstract: This invention relates to (meth)acrylate based polymerizable compositions and multipart adhesive systems prepared therefrom, which include an aziridine-containing compound in a carrier material with which the aziridine-containing compound is unreactive. The inventive composition demonstrates a flash point above 140° F., desirably above 200° F., for each of the parts of the adhesive system. To achieve the physical properties of the inventive compositions and adhesive systems, it is desirable for the carrier material to have such flash points; however, provided that in their entirety the inventive compositions and adhesive systems have such flash points, it is not necessary for the carrier material itself to have such flash points. The inventive compositions and adhesive systems also include a package for controlling the rate of cure and indicating the extent of cure.Type: GrantFiled: May 14, 2003Date of Patent: March 15, 2005Assignees: Henkel Corporation, Loctite (R&D) LimitedInventors: Eerik Maandi, Brendan J. Kneafsey
-
Patent number: 6852193Abstract: A composition including at least one anaerobically polymerizable compound; and at least one condensation product of an aldehyde and or ketone/with a polyol. The invention also provides a composition as described above which is in the form of a soft solid, for example, in the form of a stick. A two-part composition is provided, comprising a first part containing at least one polymerizable compound; and a second part containing at least one curing component for polymerizing the composition, wherein at least one of the first or second parts additionally comprises at least one gelling or solidifying agent. A kit is provided comprising the composition according to the invention which includes at least one primer component and at least one carrier solvent for the primer component, and a second composition which includes at least one anaerobically polymerizable compound and at least one condensation product of an aldehyde and or ketone/with a polyol.Type: GrantFiled: May 30, 2001Date of Patent: February 8, 2005Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, John Guthrie, Gerard Coughlan
-
Patent number: 6844080Abstract: Metal alkyl borohydrides are used as initiators of polymerisation, particularly in adhesive compositions for bonding a wide range of substrates including low surface energy substrates such as polyolefins. As described, the metal alkyl borohydrides are of the formula I or II. wherein R1 is C1-C10 alkyl, R2 and R3, which may be the same or different, are H, D, C1-C10 alkyl or C3-C10 cycloalkyl, phenyl, or phenyl-substituted C1-C10 alkyl or C3-C10 cycloalkyl, provided that any two of R1-R3 may optionally be part of a carbocyclic ring, and M+ is a metal ion. In particular, alkali metal trialkyl borohydrides are used, the alkali metal salt being selected from: Lithium triethylborohydride, Sodium triethylborohydride, Potassium triethylborohydride, Lithium tri-sec-butylborohydride, Sodium tri-sec-butylborohydride, Potassium tri-sec-butylborohydride, and Lithium triethylborodeuteride. Other exemplified compounds which are less effective on low surface energy substrates include Lithium 9-borabicyclo [3.3.Type: GrantFiled: October 23, 2001Date of Patent: January 18, 2005Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Gerry Coughlan
-
Patent number: 6835789Abstract: This invention relates to cyanoacrylate-containing compositions that include, in addition to the cyanoacrylate component, certain accelerators to improve fixture speeds on certain substrates.Type: GrantFiled: June 18, 2003Date of Patent: December 28, 2004Assignee: Loctite (R&D) LimitedInventors: Brendan J. Kneafsey, Ruth A. Kelly, Fergal W. Tierney, David P. Birkett, Hanns R. Misiak, Kieran Mulcahy, Harry J. Woolfson
-
Patent number: D558587Type: GrantFiled: December 2, 2005Date of Patent: January 1, 2008Assignee: Loctite (R&D) LimitedInventors: David J. Gibson, Geoffrey F. Seymour
-
Patent number: D561599Type: GrantFiled: December 2, 2005Date of Patent: February 12, 2008Assignee: Loctite (R&D) LimitedInventors: David J. Gibson, Geoffrey F. Seymour
-
Patent number: D563798Type: GrantFiled: December 2, 2005Date of Patent: March 11, 2008Assignee: Loctite (R&D) LimitedInventors: David J. Gibson, Geoffrey F. Seymour
-
Patent number: D568405Type: GrantFiled: August 4, 2006Date of Patent: May 6, 2008Assignee: Loctite (R&D) LimitedInventor: Patrick Kealy