Abstract: A process and equipment for treating natural gas produced by a well that has recently been stimulated, and that contains an undesirably high concentration of the fracturing gas used to stimulate the well. The process involves treating the gas by membrane separation, and provides for control of treatment parameters to compensate for the changing concentration of fracturing gas in the produced gas, as well as changes in gas flow rate.
Abstract: A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes a set of tubes, each containing gas-separation membranes, arranged within a housing. The housing contains a tube sheet that divides the space within the housing into two gas-tight spaces. A permeate collection system within the housing gathers permeate gas from the tubes for discharge from the housing.
Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.
Type:
Grant
Filed:
May 6, 2004
Date of Patent:
November 7, 2006
Assignee:
Membrane Technology & Research, Inc.
Inventors:
Johannes G Wijmans, Alvin Ng, Anurag P Mairal
Abstract: A process and apparatus for treating oily wastewater, such as bilge water or ballast water, generated on a ship. The process uses a combination of a centrifugal separation step and a membrane separation step, such as an ultrafiltration step. The membrane separation step uses a dense, non-porous filtration membrane. The process is able to remove both emulsified oil and dissolved oil from the wastewater to low levels.
Type:
Grant
Filed:
October 24, 2002
Date of Patent:
March 28, 2006
Assignee:
Membrane Technology and Research, Inc.
Inventors:
Anurag P. Mairal, Alvin Ng, Johannes G. Wijmans, Ingo Pinnau, Jennifer H. Ly
Abstract: A process for regenerating a facilitated-transport membrane, such as a gas separation membrane, that contains an ionic complexing agent, and that has lost performance as a result of reduction of at least some of the ions to a less charged or uncharged form. The process involves exposing the membrane to an oxidizing agent, such as hydrogen peroxide. The invention also includes membranes that have been regenerated in this way, and their use, particularly for separating light olefins from light paraffins by membrane gas separation.
Abstract: A process for separating a component from a low molecular weight organic mixture by pervaporation. The process uses fluorinated membranes and is particularly useful for treating mixtures containing light organic components, such as methane, propylene or n-butane.
Type:
Application
Filed:
August 31, 2005
Publication date:
January 5, 2006
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Andre Da Costa, Ramin Daniels, Ankur Jariwala
Abstract: An inorganic membrane suitable for ultrafiltration or nanofiltration, and methods for making and using the membrane. The membrane has a organic polymer deposited on the feed surface, but is not able to perform separations by solution-diffusion.
Type:
Application
Filed:
June 29, 2004
Publication date:
December 29, 2005
Applicant:
Membrane Technology and Research Inc.
Inventors:
Anurag Mairal, Jennifer Ly, Alvin Ng, Ingo Pinnau
Abstract: Processes for recovering helium from reject gas streams of various types that arise during natural gas processing. The processes include a membrane gas separation step. The reject gas stream is treated in the membrane separation step to yield a helium-enriched permeate stream and a helium-depleted residue stream. The permeate stream is sent for further helium separation or purification in the gas plant or at another facility or sold as crude helium. The residue stream is discharged from the process to a vent line, fuel line, purge line or the like.
Abstract: A process for treating mixtures of organic components, including azeotropic mixtures. The process includes a gas- or liquid-phase membrane separation step in conjunction with a dephlegmation step to treat at least a portion of the permeate vapor from the pervaporation step. The process yields a membrane residue stream, a stream enriched in the more volatile component as the overhead stream from the dephlegmator and a condensate stream enriched in the less volatile component as a bottoms stream from the dephlegmator. Any of these may be the principal product of the process.
Type:
Grant
Filed:
June 11, 2003
Date of Patent:
May 31, 2005
Assignee:
Membrane Technology and Research, Inc.
Inventors:
Johannes G. Wijmans, Richard W. Baker, Anurag P. Mairal
Abstract: A membrane-based process for separating mixtures of target gases if the gas mixture also contains C3+ hydrocarbon vapors. The process uses gas-separation membranes having a base membrane and a coating layer. The base membrane incorporates a selective layer made from a polymer selective between the light gases to be separated. The coating layer comprises a fluorinated polymer capable of protecting the base membrane from C3+ hydrocarbon vapors and liquids.
Type:
Grant
Filed:
July 2, 2003
Date of Patent:
May 24, 2005
Assignee:
Membrane Technology and Research, Inc.
Inventors:
Ingo Pinnau, Zhenjie He, Rolande J. Blanc
Abstract: A reverse osmosis membrane, and methods for making and using the membrane. The membrane has a continuous, defect-free, non-porous, hydrophilic coating that reduces the susceptibility to fouling.
Type:
Application
Filed:
October 9, 2003
Publication date:
April 14, 2005
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Ingo Pinnau, Jennifer Ly, Richard Baker
Abstract: A membrane process for treating zein solutions to increase the zein concentration in the solution. The process uses a non-porous membrane that preferentially permeates the solvent and rejects the zein. Optionally, the process can be operated as a diafiltration process to yield a concentrate of high zein purity.
Type:
Grant
Filed:
May 14, 2003
Date of Patent:
January 25, 2005
Assignee:
Membrane Technology and Research, Inc.
Inventors:
Anurag P. Mairal, Alvin Ng, Johannes G. Wijmans
Abstract: A membrane process for treating zein solutions to increase the zein concentration in the solution. The process uses a non-porous membrane that preferentially permeates the solvent and rejects the zein. Optionally, the process can be operated as a diafiltration process to yield a concentrate of high zein purity.
Type:
Application
Filed:
May 14, 2003
Publication date:
November 18, 2004
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Anurag P. Mairal, Alvin Ng, Johannes G. Wijmans
Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.
Type:
Application
Filed:
May 6, 2004
Publication date:
October 21, 2004
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.
Type:
Grant
Filed:
October 25, 2002
Date of Patent:
September 14, 2004
Assignee:
Membrane Technology and Research, Inc.
Inventors:
Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
Abstract: A process for separating a component from a low molecular weight organic mixture by pervaporation. The process uses fluorinated membranes and is particularly useful for treating mixtures containing light organic components, such as methane, propylene or n-butane.
Type:
Application
Filed:
March 7, 2003
Publication date:
September 9, 2004
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Andre R. Da Costa, Ramin Daniels, Ankur D. Jariwala
Abstract: A process for treating liquids containing organic compounds and water. The process includes a pervaporation step in conjunction with a dephlegmation step to treat at least a portion of the permeate vapor from the pervaporation step. The process yields a membrane residue stream, a stream enriched in the more volatile component (usually the organic) as the overhead stream from the dephlegmator and a condensate stream enriched in the less volatile component (usually the water) as a bottoms stream from the dephlegmator. Any of these may be the principal product of the process. The membrane separation step may also be performed in the vapor phase, or by membrane distillation.
Type:
Grant
Filed:
June 12, 2002
Date of Patent:
June 29, 2004
Assignees:
Membrane Technology and Research, Inc., The United States of America as represented by the
Environmental Protection Agency
Inventors:
Leland M. Vane, Anurag P. Mairal, Alvin Ng, Franklin R. Alvarez, Richard W. Baker
Abstract: A process and apparatus for treating oily wastewater, such as bilge water or ballast water, generated on a ship. The process uses a combination of a centrifugal separation step and a membrane separation step, such as an ultrafiltration step. The membrane separation step uses a dense, non-porous filtration membrane. The process is able to remove both emulsified oil and dissolved oil from the wastewater to low levels.
Type:
Application
Filed:
October 24, 2002
Publication date:
April 29, 2004
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Anurag P. Mairal, Alvin Ng, Johannes G. Wijmans, Ingo Pinnau, Jennifer H. Ly
Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.
Type:
Application
Filed:
October 25, 2002
Publication date:
April 29, 2004
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
Abstract: A membrane-based process for separating mixtures of target gases if the gas mixture also contains C3+ hydrocarbon vapors. The process uses gas-separation membranes having a base membrane and a coating layer. The base membrane incorporates a selective layer made from a polymer selective between the light gases to be separated. The coating layer comprises a fluorinated polymer capable of protecting the base membrane from C3+ hydrocarbon vapors and liquids.
Type:
Application
Filed:
July 2, 2003
Publication date:
March 18, 2004
Applicant:
Membrane Technology and Research, Inc.
Inventors:
Ingo Pinnau, Zhenjie He, Rolande J. Blanc