Patents Assigned to Methanol Casale S.A.
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Publication number: 20130171041Abstract: An isothermal chemical reactor (1) is described comprising a plate (30) heat exchange unit (12), immersed in a catalytic bed (7) and destined to heat or cool the reagents in order to maintain the reaction temperature in a predetermined range; said plates (30) are formed by two flat walls (31, 32) and longitudinal spacers (33), with obtainment of parallel channels (34) for the circulation of a heat exchange fluid.Type: ApplicationFiled: February 22, 2013Publication date: July 4, 2013Applicant: Methanol Casale S.A.Inventor: Methanol Casale S.A.
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Patent number: 8460614Abstract: An isothermal chemical reactor (1) comprising an array of radially arranged plate-like heat exchange elements (11) inside a reaction space, each element comprising feeding and collecting ducts and a bundle of parallel tubes (15) defining channels (12) for a heat exchange medium, the tubes (15) having an elongated cross section and being disposed with a variable orientation relative to the radial direction of the reactor, so that inner tubes near the axis of the reactor have the cross-section major axis aligned with said radial direction, and outer tubes have the same axis perpendicular to the radial direction. The preferred structure of a plate-like heat exchange element is also disclosed.Type: GrantFiled: August 12, 2009Date of Patent: June 11, 2013Assignee: Methanol Casale S.A.Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo, Luca Redaelli
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Patent number: 8404188Abstract: Plate heat exchange unit (12) for isothermal or pseudo-isothermal chemical reactors, for the heat exchange between a fluid circulating inside the plates and an outer flow of reactant gases, wherein the walls (14, 15), of the plates (13) have notches (14s, 15s) surrounded by suitable joining lines (105), obtaining openings (104) passing through the plates (13) themselves, the plates resulting substantially permeable in the transversal direction to the reactant gases.Type: GrantFiled: June 30, 2008Date of Patent: March 26, 2013Assignee: Methanol Casale S.A.Inventors: Agostino Barbieri, Nicola Sorlini
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Patent number: 8307696Abstract: The present invention concerns an isothermal reactor (1) comprising a pressure vessel (2) closed at the opposite ends by respective bottoms (3, 4), a reaction zone (9) in said pressure vessel (2) in which at least one catalytic basket (10) is positioned, and at least one heat exchange unit (13) embedded in said at least one catalytic basket (10), each heat exchange unit (13) comprising a plurality of heat exchangers (14) each having an inner chamber intended to be crossed by an operating heat exchange fluid, the reactor being characterized in that it comprises means (17, 18) for picking up samples of operating heat exchange fluid from groups (16) of pre-established exchangers in each heat exchange unit (13), so as to ascertain the possible existence of damaged exchangers (14) in said groups (16) of exchangers through analysis of respective samples of operating heat exchange fluid.Type: GrantFiled: April 27, 2007Date of Patent: November 13, 2012Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Patent number: 8302672Abstract: Plate type heat exchanger (20,120) for a isothermal chemical reactor (60), of the type comprising a substantially box-shaped flattened body (22), defining an internal chamber (24) and equipped with an inlet connection (28) and an outlet connection (29) for a first flow of a heat exchanger operative fluid into and from said chamber (24), at least one supplying-distributing device (26, 126) of a second fluid flow, associated with said body (22) and in fluid communication with the internal chamber (24) thereof, in order to regulate the temperature of said operative fluid, said at least one supplying-distributing device (26,126) being supported inside said internal chamber (24) and in fluid communication therewith.Type: GrantFiled: October 31, 2006Date of Patent: November 6, 2012Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo, Luca Zanichelli
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Publication number: 20120148456Abstract: Isothermal vertical reactor (1) for a chemical reaction, comprising a shell (2) with internal gas-permeable walls (16, 18) defining an inlet distribution chamber (17) and a product collecting chamber (19), an open-top catalytic bed between said gas-permeable walls, and a tube heat exchanger (5) embedded in said catalytic bed, the tube heat exchanger (5) comprising a bundle of U-tubes, where an inlet (14) is disposed to direct a fresh charge in an upper chamber (21) over the catalytic bed and the U-shaped top portion of the tube bundle; a portion (F1) of the fresh charge passes through the catalytic bed with a mixed axial-transversal flow, and another portion (F2) of the fresh charge enters the inlet gas-distribution chamber (17) and passes through the catalytic bed with a substantially transversal flow.Type: ApplicationFiled: August 6, 2010Publication date: June 14, 2012Applicant: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Publication number: 20120039762Abstract: A tube isothermal chemical reactor (1), comprising a vessel (2) with a central axis (A-A), and an annular tube heat exchanger (40) embedded in a catalytic reaction space, the exchanger (40) comprising a plurality of concentric ranks (10, 11) of tube packs (10a), each of said tube packs comprising parallel tubes (30), a respective heat-exchange fluid feeder (20) and a respective heat-exchange fluid collector (21).Type: ApplicationFiled: March 25, 2010Publication date: February 16, 2012Applicant: Methanol Casale S.A.Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo, Fabiano Montini
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Publication number: 20120017508Abstract: A methanation section for producing substitute natural gas (SNG) by reacting a fresh syngas, the methanation section comprising adiabatic reactors connected in series, with heat removal and reacted gas-recirculation, wherein the fresh syngas is fed in parallel to said adiabatic reactors. In a preferred embodiment the reacted gas is recirculated to the first reactor and further dilution of the fresh gas at the inlet of the first and second reactor is achieved by steam addition.Type: ApplicationFiled: September 15, 2011Publication date: January 26, 2012Applicant: Methanol Casale S.A.Inventors: Ermanno Filippi, Francesco Baratto
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Publication number: 20110313064Abstract: A process for producing methanol, where a hydrocarbon feedstock (1) is reformed and a make-up syngas is reacted in a synthesis loop, obtaining crude methanol which is further treated to obtain high-grade methanol, and where the carbon dioxide dissolved in the crude methanol is recycled to the reforming section in order to adjust the stoichiometric number of the make-up syngas. In a preferred embodiment, a flash gas (9) separated from the crude methanol (8) and light ends (10) coming from distillation are recycled to a compressor (106) and fed to a primary reformer (100); further carbon dioxide can be recycled from the flue gas (11).Type: ApplicationFiled: March 8, 2010Publication date: December 22, 2011Applicant: Methanol Casale S.A.Inventors: Sergio Panza, Giovanni Luigi Capetti
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Patent number: 8071059Abstract: A chemical reactor for catalytic reactions, comprises a substantially cylindrical shell (2) closed at the opposite ends by respective covers (3 and 4), at least one reaction zone (7, 8) in which a respective catalytic bed (9, 10) and a plurality of heat exchangers (25) placed in said at least one reaction zone (7, 8) are supported.Type: GrantFiled: December 30, 2009Date of Patent: December 6, 2011Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Patent number: 8039519Abstract: A process for producing substitute natural gas (SNG) comprising the steps of reacting a fresh syngas (11) into a methanation section (10) comprising adiabatic reactors (101-104) connected in series, with heat removal and reacted gas-recirculation, wherein the fresh syngas is fed in parallel to said adiabatic reactors. In a preferred embodiment the reacted gas is recirculated to the first reactor (101) and further dilution of the fresh gas at the inlet of the first and second reactor is achieved by steam addition.Type: GrantFiled: March 31, 2009Date of Patent: October 18, 2011Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Francesco Baratto
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Patent number: 8007734Abstract: The present invention concerns an isothermal reactor (1) for carrying out exothermal or endothermal heterogeneous reactions comprising: —a substantially cylindrical outer shell (2) with longitudinal axis (X), —at least one catalytic bed (6) extending in the shell (2) and comprising opposite perforated side walls (7, 8) respectively for the inlet of a gaseous flow of reactants and for the outlet of a gaseous flow comprising reaction products, and —a heat exchange unit (12) immersed in said at least one catalytic bed (6) and crossed by a heat exchange fluid, characterized in that said heat exchange unit (12) comprises at least one succession of heat exchangers (13) arranged substantially parallel to each other and substantially parallel to the direction in which said at least one catalytic bed (6) is crossed by said gaseous flow of reactants.Type: GrantFiled: August 20, 2007Date of Patent: August 30, 2011Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Patent number: 7998427Abstract: A method for carrying out chemical reactions in so-called pseudo-isothermal conditions and in a predetermined reaction environment, for example a catalytic bed, comprises the step of arranging in the reaction environment at least one heat exchanger crossed by an operating fluid along a main direction.Type: GrantFiled: February 5, 2007Date of Patent: August 16, 2011Assignee: Methanol Casale S.A.Inventor: Giuseppe Guarino
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Publication number: 20110186278Abstract: An isothermal chemical reactor (1) comprising an array of radially arranged plate-like heat exchange elements (11) inside a reaction space, each element comprising feeding and collecting ducts and a bundle of parallel tubes (15) defining channels (12) for a heat exchange medium, the tubes (15) having an elongated cross section and being disposed with a variable orientation relative to the radial direction of the reactor, so that inner tubes near the axis of the reactor have the cross-section major axis aligned with said radial direction, and outer tubes have the same axis perpendicular to the radial direction. The preferred structure of a plate-like heat exchange element is also disclosed.Type: ApplicationFiled: August 12, 2009Publication date: August 4, 2011Applicant: Methanol Casale S.A.Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo, Luca Redaelli
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Patent number: 7981271Abstract: Pseudo-isothermal radial chemical reactor for catalytic reactions, comprising a substantially cylindrical shell closed at the opposite ends by respective base plates, comprising a reaction zone in which a respective catalytic bed is supported and a plurality of heat exchangers placed in said reaction zone.Type: GrantFiled: January 15, 2004Date of Patent: July 19, 2011Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Patent number: 7941921Abstract: A method for the production of heat exchangers (10, 110, 210) of the so-called plate type, comprising the operative steps of: —juxtaposing a couple of substantially identical metal plates (12, 14), —fixing together said juxtaposed plates (12, 14) to one another by means of welding performed at respective perimetric sides (13a, 13b, 13c, 13d), —further fixing together said juxtaposed plates to each other by means of a plurality of welding tracts (22), arranged in at least two alignments, parallel and adjacent to a couple of opposite perimetric sides (13a, 13c) of the plates themselves (12, 14), and at a pre-established spaced relationship from said sides, —introducing a fluid under pressure between said juxtaposed metal plates (12, 14), to form a hollow, substantially box-shaped body (17), in which an internal chamber (16) and two substantially tubular passages (16a, 16b), formed between said couple of opposite perimetric sides (13a, 13c) and the respective adjacent alignments of the welding tracts (22), are dType: GrantFiled: October 31, 2006Date of Patent: May 17, 2011Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Publication number: 20110052457Abstract: A chemical isothermal reactor (1) with internal plate heat exchanger (10) having heat-exchange radial plates (11), and radial ducts (14, 15) parallel to sides (13i, 13s) of the plates (11) for distributing and collecting a heat exchange fluid, said radial ducts having a portion with a smaller cross section near the inner converging ends (14c, 15c).Type: ApplicationFiled: February 13, 2009Publication date: March 3, 2011Applicant: Methanol Casale S.A.Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo
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Publication number: 20100303682Abstract: An isothermal chemical reactor (1) is described comprising a plate (30) heat exchange unit (12), immersed in a catalytic bed (7) and destined to heat or cool the reagents in order to maintain the reaction temperature in a predetermined range; said plates (30) are formed by two flat walls (31, 32) and longitudinal spacers (33), with obtainment of parallel channels (34) for the circulation of a heat exchange fluid.Type: ApplicationFiled: November 6, 2008Publication date: December 2, 2010Applicant: Methanol Casale S.A.Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo
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Publication number: 20100284869Abstract: System for supporting a plate heat exchanger (10, 100, 200) inside an isothermal chemical reactor (1), comprising a circumferential ring structure (40) fixed at least to top radial sides (19s) of the plates (11), said structure being formed as a single or double ring.Type: ApplicationFiled: November 20, 2008Publication date: November 11, 2010Applicant: Methanol Casale S.A.Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo
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Patent number: 7807115Abstract: A chemical reactor for catalytic reactions, comprises a substantially cylindrical shell (2) closed at the opposite ends by respective covers (3 and 4), at least one reaction zone (7, 8) in which a respective catalytic bed (9, 10) and a plurality of heat exchangers (25) placed in said at least one reaction zone (7, 8) are supported.Type: GrantFiled: April 27, 2004Date of Patent: October 5, 2010Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo