Patents Assigned to Methanol Casale S.A.
  • Patent number: 6926873
    Abstract: A reactor, in particular for exothermic reactions, of the type including: a shell (2) of substantially cylindrical shape, at least one catalytic bed (3) in the shell, including a perforated cylindrical outer side wall (4), which forms a free space (8) with the shell, and an inner side wall (5) coaxial to the previous one, a heat exchanger (13) in the bed (3), the heat exchanger (13) being formed by a plurality of tubes (15) in the form of a spiral, a coil or alike in fluid communication with feed and discharge collectors (14, 16) for a cooling fluid.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: August 9, 2005
    Assignee: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Patent number: 6916453
    Abstract: A reactor (1) for carrying out exothermic or endothermic heterogeneous reactions comprising an outer shell (2) of substantially cylindrical shape and at least a heat exchanger (9) embedded in a catalytic layer (10) supported in said shell (2), is characterized in that the heat exchanger (9) is a plate (14) heat exchanger.
    Type: Grant
    Filed: May 10, 2001
    Date of Patent: July 12, 2005
    Assignee: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Publication number: 20050095184
    Abstract: A method for carrying out chemical reactions in so-called pseudo-isothermal conditions and in a predetermined reaction environment, for example a catalytic bed, comprises the step of arranging in the reaction environment at least one heat exchanger crossed by an operating fluid along a main direction.
    Type: Application
    Filed: October 29, 2004
    Publication date: May 5, 2005
    Applicant: Methanol Casale S.A.
    Inventor: Giuseppe Guarino
  • Publication number: 20040184976
    Abstract: A horizontal chemical reactor comprises at least one catalytic bed (5a-5d) arranged horizontally in the reactor and comprising a lower gas-permeable wall (6) for gas outlet, and a holding element (2) of the at least one catalytic bed.
    Type: Application
    Filed: March 19, 2004
    Publication date: September 23, 2004
    Applicant: Methanol Casale S.A.
    Inventors: Giorgio Pagani, Enrico Rizzi, Umberto Zardi
  • Publication number: 20040091403
    Abstract: Method for carrying out in continuous, under so-called pseudo-isothermal conditions and in a predetermined reaction environment, such as a catalytic bed, a selected chemical reaction, comprising the steps of providing in the reaction environment at least one tubular heat exchanger fed with a first flow of a heat exchange operating fluid at a respective predetermined inlet temperature, the fluid passing through the at least one tubular heat exchanger according to a respective inlet/outlet path, which method also provides the step of feeding into the at least one tubular heat exchanger and at one or more intermediate positions of said path, a second flow of operating fluid having a respective predetermined inlet temperature.
    Type: Application
    Filed: August 27, 2003
    Publication date: May 13, 2004
    Applicant: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Publication number: 20040071606
    Abstract: A heat exchange unit for axial and radial pseudo-isothermal reactors which comprise a substantially cylindrical shell (2) closed at the opposite ends by base plates (3, 4), a reaction zone (6) containing a catalytic bed and at least one heat exchanger (11) of the type with a plate having a variable section along the direction of the flow of operating heat exchange fluid
    Type: Application
    Filed: April 4, 2003
    Publication date: April 15, 2004
    Applicant: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Publication number: 20020117294
    Abstract: Method for carrying out in continuous, under so-called pseudo-isothermal conditions and in a predetermined reaction environment, such as a catalytic bed, a selected chemical reaction, comprising the steps of providing in the reaction environment at least one heat exchanger fed with a first flow of a heat exchange operating fluid at a respective predetermined inlet temperature, the fluid passing through at least one heat exchanger according to a respective inlet/outlet path, which method also provides feeding into at least one heat exchanger and at one or more intermediate positions of said path, a second flow of operating fluid having a respective predetermined inlet temperature.
    Type: Application
    Filed: February 26, 2002
    Publication date: August 29, 2002
    Applicant: METHANOL CASALE S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Publication number: 20020088613
    Abstract: Heat exchange unit for pseudo-isothermal reactors including a substantially cylindrical shell (2) closed at its opposite ends by respective bottoms (3, 4), at least one thereof is provided with at least one manhole opening (5) of predetermined dimensions, a reaction zone (6) inside the shell (2) in order to contain a catalytic bed, comprising at least two modular and assembly heat exchangers (11), having predetermined cross dimensions smaller than those of the manhole opening (5), each heat exchanger (11) comprising at least one heat exchange element (12).
    Type: Application
    Filed: January 4, 2002
    Publication date: July 11, 2002
    Applicant: METHANOL CASALE S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Publication number: 20020085969
    Abstract: An isothermal reactor for carrying out heterogeneous exothermic or endothermic reactions, comprises within a catalytic bed (3) housed in an appropriate outer shell (2), at least one tube (13) for the passage of a cooling or heating fluid which advantageously extends with a cone shaped helicoidal.
    Type: Application
    Filed: December 13, 2001
    Publication date: July 4, 2002
    Applicant: METHANOL CASALE S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Publication number: 20020018740
    Abstract: A reactor (1) for carrying out exothermic or endothermic heterogeneous reactions comprising an outer shell (2) of substantially cylindrical shape and at least a heat exchanger (9) embedded in a catalytic layer (10) supported in said shell (2), is characterized in that the heat exchanger (9) is a plate (14) heat exchanger.
    Type: Application
    Filed: May 10, 2001
    Publication date: February 14, 2002
    Applicant: METHANOL CASALE S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Patent number: 6333014
    Abstract: A process for ammonia and methanol co-production in a plant comprising a secondary reformer section, a high-temperature CO conversion section and a low-temperature CO conversion section, arranged in series, and an ammonia synthesis section, is distinguished by the fact that the unreacted gas flow coming from a methanol synthesis section, before being fed to the low-temperature CO conversion section, is advantageously saturated with a liquid flow comprising H2O appropriately heated by indirect heat exchange with a gaseous flow coming from the secondary reformer section.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: December 25, 2001
    Assignee: Methanol Casale S.A.
    Inventor: Ermanno Filippi
  • Patent number: 6290920
    Abstract: The present invention relates generally an apparatus for uniformly mixing gaseous flows at different temperatures. In particular, a preferred embodiment of the present invention relates to a heterogeneous exothermic synthesis reactor including a plurality of superimposed catalytic beds wherein at least one of the beds is provided with a gas permeable wall for outlet of a hot gas flow. In this embodiment, a baffle extends below and parallel to the gas permeable wall, thereby defining an air space to collect the hot gas flow. An annular opening is provided for outlet of the hot gas flow from the air space defined between the baffle and a side wall supporting the beds associated with the reactor and a perforated distributor for cooling a gas flow supported below said baffle at a predetermined distance from the annular opening.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: September 18, 2001
    Assignee: Methanol Casale S.A.
    Inventors: Umberto Zardi, Giorgio Pagani
  • Patent number: 6106793
    Abstract: A process for ammonia and methanol co-production in a plant comprising a first primary reforming section (11) and a secondary reforming section (12) arranged in series, an ammonia synthesis section (13) and a methanol synthesis section (22), is distinguished by the fact that ammonia and methanol are produced in independent synthesis processes where the heat required for the reforming reaction in the methanol process is advantageously obtained by utilizing the high heat content present in the gas flow coming from the secondary reforming section (12) of the ammonia process.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: August 22, 2000
    Assignee: Methanol Casale S.A.
    Inventors: Marco Badano, Franco Fabbri, Ermanno Filippi
  • Patent number: 5951953
    Abstract: The present invention relates to method for mixing gaseous flows at different temperatures. In particular, the present invention relates to heterogeneous exothermic synthesis reactors of the type including a plurality of superimposed catalytic beds wherein at least one of the beds is provided with a gas permeable wall for outlet of a hot gas flow. This method includes the steps of supplying gaseous reagents to at least one bed; reacting the gaseous reagents in that bed; and collecting a hot reaction gas flow leaving the gas permeable wall in an air space defined between the bed and a baffle extending below and parallel thereto. Further steps require directing the hot gas flow in the air space radially outward to an annular opening of constant thickness defined between the baffle and a side wall supporting the bed, wherein the ratio of the width of the annular opening and the thickness of the air space being between 0.2 and 1.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: September 14, 1999
    Assignee: Methanol Casale S.A.
    Inventors: Umberto Zardi, Giorgio Pagani
  • Patent number: 5756048
    Abstract: A method for in-situ modernization of a reactor for carrying out heterogeneous exothermic synthesis reactions, in particular of the so-called lozenge type including an external shell (2), calls for prearrangement within the shell (2) of a plurality of superimposed catalyst beds (12, 13, 14) supported at a pre-set distance by means of support elements (22, 23, 24) rested on or fixed to, e.g. by welding, a plurality of annular shoulders (8a, 8b, 8c) pre-existing in the reactor.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: May 26, 1998
    Assignee: Methanol Casale, S.A.
    Inventors: Umberto Zardi, Giorgio Pagani