Patents Assigned to Mitsubishi Chemical Corporation
  • Patent number: 5529885
    Abstract: Disclosed are a negative photosensitive composition comprising an alkali-soluble resin, a photo acid generating system, and a crosslinking agent for the alkali-soluble resin which acts on the resin under acidic conditions, in which the crosslinking agent is a highly-alkylated alkoxymethylmelamine resin having a monomer content of from 5 to 40% by weight, and a method for forming a negative photo-resist pattern using the composition. The resist composition is stable during storage and gives good pattern profiles having high aspect ratios even though the resist film is made thick.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: June 25, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tameichi Ochiai, Ryuichiro Takasaki, Yasuhiro Kameyama, Shichiro Takahashi
  • Patent number: 5530144
    Abstract: A process for producing a precursor of a phosphorus-vanadium oxide catalyst for production of maleic anhydride by vapor phase oxidation of a hydrocarbon having 4 carbon atoms, which comprises reacting phosphoric acid and a pentavalent vanadium compound in an organic solvent capable of reducing at least a portion of the pentavalent vanadium to a valence state of +4, the phosphoric acid being substantially composed of orthophosphoric acid, and a phosphoric acid solution whose concentration is 88 to 96% being used as a source of the phosphoric acid; and a process for producing the catalyst comprising dry-pulverizing the catalyst precursor.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: June 25, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasushi Tsurita, Masayoshi Murayama, Kenji Shima, Masumi Ito
  • Patent number: 5529973
    Abstract: The disclosure describes a thermal transfer recording sheet comprising a base film, a colorant layer provided on one side of said base film and containing a heat-transferable dye, and a heat-resistant lubricating layer provided on the other side of said base film and containing a thermoplastic resin having a glass transition point of not less than 50.degree. C., an amino-modified silicone oil and a carboxy-modified silicone oil.
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: June 25, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hideo Shinohara, Tsutomu Taki, Katsuhiko Kuroda, Takashi Morishima
  • Patent number: 5527875
    Abstract: A process for producing an aromatic polycarbonate having a weight average molecular weight of from 7,000 to 60,000 is disclosed, comprising melt polycondensing an aromatic diol compound (e.g., bisphenol A) and a diaryl carbonate compound (e.g., diphenyl carbonate) in the presence of a combination of (a) an alkali metal compound and (b) a phosphonium hydroxide compound (e.g., tetraethylphosphonium hydroxide) as an interesterification catalyst. The aromatic polycarbonate has improved heat resistance and hue.
    Type: Grant
    Filed: February 9, 1995
    Date of Patent: June 18, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masuzo Yokoyama, Fumio Keitoku, Junji Takano, Masami Hasegawa, Yukiko Tatsukawa
  • Patent number: 5527818
    Abstract: The present invention relates to a sulfamoyl triazole derivative and a fungicide containing same as an effective component, the sulfamoyl triazole derivative being expressed by general formula (I): ##STR1## in which R.sup.1 and R.sup.2 are the same or different lower alkyl groups or an alkylene chain formed by integrating R.sup.1 and R.sup.2 and having 3 to 6 carbon atoms which may be substituted by a lower alkyl group; p is an integer 0 or 1; and A is a substituted aryl group.The fungicide does not damage field and garden plants and it is effective for preventing and curing various disease injury at very small dosages.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: June 18, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Atsushi Goh, Yoshihiro Usui, Yoshimi Tsutsumi, Yoshie Kirio, Yoshihiro Takayama, Seiichiro Yamada, Masako Yamanaka
  • Patent number: 5527963
    Abstract: An improved process for producing N-vinylformamide including the steps of evaporating N-(.alpha.-substituted-ethyl)formamide or ethylidenebisformamide under reduced pressure and thermally decomposing the vapor at 150.degree.-600.degree. C., wherein the improvement comprises performing thermal decomposition by means of a pyrolysis reactor which is made up of two stages, the first being an unpacked tubular reactor constructed such that liquid flows down and the second being a packed tubular reactor, while keeping the vapor temperature at 200.degree.-400.degree. C. at the outlet of the unpacked tubular reactor and the inside temperature of the packed tubular reactor at 200.degree.-600.degree. C.
    Type: Grant
    Filed: October 16, 1994
    Date of Patent: June 18, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shin-ichi Sato, Yasuharu Mori, Toshimitsu Inoue
  • Patent number: 5525558
    Abstract: A process for producing a carbon fiber reinforced carbon composite material, comprising dispersing a short fibrous bundle of carbon fibers which comprises a plurality of single fibers, preparing a sheet in which fibers are in the two-dimensional random orientation, impregnating with a resin or pitch, laminating and molding, and then applying a baking and densifying treatment, a dispersion degree of the bundle of carbon fibers being controlled based on the formula (1) expressing correlation between the dispersion degree of the bundle of carbon fibers and the mechanical strength of the carbon fiber reinforced composite material:Dispersion degree=A-B.times.coefficient of friction (1)wherein A and B are constants determined experimentally, to produce a carbon fiber reinforced carbon composite material having desired mechanical characteristic.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: June 11, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kazuo Niwa, Toshihiro Fukagawa, Nobuyuki Oonishi, Takeo Matsui, Yutaka Kawamata, Hitoshi Seki
  • Patent number: 5521010
    Abstract: A polyethylene for an insulation layer of a power cable, of which the dissipation factor never increases even in a high-temperature, high electric field, and a crosslinked polyethylene insulated power cable which uses this polyethylene so that the high-temperature dielectric breakdown voltage is large enough for high-capacitance transmission. This polyethylene is a low-density polyethylene which is synthesized by high-pressure radical polymerization of ethylene, and has properties including: a melt flow rate of 0.1 to 10 g/10 minutes; a density of 0.915 to 0.935 g/cm.sup.3 ; an absorbance of 0.03 to 1.0 for a ketone-type carbonyl group, having a peak in a position corresponding to a wave-number of 1,725.+-.4 cm.sup.-1 in an infrared absorption spectrum, an absorbance of 1.0 or less for an ester-type carbonyl group, having a peak in a position corresponding to a wave-number of 1,743.+-.4 cm.sup.-1 and absorbances of less than 0.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: May 28, 1996
    Assignees: The Furukawa Electric Co., Ltd., Mitsubishi Chemical Corporation
    Inventors: Toshiya Tanaka, Hitoshi Kimura, Koji Yamamoto, Mitsugu Ishioka, Setsuo Goto
  • Patent number: 5519106
    Abstract: A process for preparing an aromatic polycarbonate resin from an aromatic dihydroxy compound and a carbonate diester by transesterification in the presence of a transesterification catalyst comprising; reacting a purified carbonate diester with an aromatic dihydroxy compound in the presence of a transesterification catalyst to form a polycarbonate prepolymer; said carbonate diester containing benzophenone and benzoate ester derivatives having a molecular weight of less than 1,000, each in an amount of 100 ppm or less, said polycarbonate prepolymer having a viscosity average molecular weight of 5,000 to 20,000 at a temperature of 140.degree. to 280.degree. C., the reaction pressure being from 0.1 Torr to normal pressure; polymerizing said prepolymer at a temperature of 240.degree. to 350.degree. C. in a lateral, bi-axial, self-cleaning reactor to obtain an aromatic polycarbonate resin having a viscosity average molecular weight of 15,000 to 60,000.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: May 21, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masahiro Nukui, Takao Tayama, Takeshi Kashiwagi, Masatoshi Kimura, Hidekazu Shoji
  • Patent number: 5518627
    Abstract: A method for demineralizing water or an aqueous solution, which comprises contacting the water or the aqueous solution to be treated to a strongly basic anion exchanger made of a crosslinked polymer having a constituting unit of the following formula (I): ##STR1## wherein A is a C.sub.1-2 linear alkylene group, B is a C.sub.4-8 linear alkylene group, each of R1, R2 and R3 which may be the same or different, is a C.sub.1-4 alkyl group or a C.sub.2-4 alkanol group, X is a counter ion coordinated on the ammonium group, and the benzene ring D may have an alkyl group or a halogen atom as a substituent.
    Type: Grant
    Filed: March 1, 1995
    Date of Patent: May 21, 1996
    Assignees: Mitsubishi Chemical Corporation, Tohoku Electric Power Co., Inc.
    Inventors: Masao Tomoi, Teruo Onozuka, Manabu Shindo, Hideaki Kiniwa, Hirohisa Kubota, Shintaro Sawada
  • Patent number: 5516350
    Abstract: Synthetic quartz glass powder is produced by (a) hydrolyzing an alkoxysilane to form a gel, (b) finely dividing the gel and then drying, or drying the gel and then finely dividing, and (c) calcining the obtained powder, the powder being maintained under an atmosphere with an oxygen concentration of not less than 30 vol % during at least a part of the calcining period at a temperature of not lower than 1,000.degree. C.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: May 14, 1996
    Assignee: Kimmon Manufacturing Co., Ltd. and Mitsubishi Chemical Corporation
    Inventors: Hajime Onoda, Hiroshi Ota, Kazumi Kimura, Akira Utsunomiya, Masaru Shimoyama
  • Patent number: 5514526
    Abstract: A composition for forming anti-reflection film on resist surface which comprises an aqueous solution of a water soluble fluorine compound, and a pattern formation method which comprises the steps of coating a photoresist composition on a substrate; coating the above-mentioned composition for forming anti-reflection film; exposing the coated film to form a specific pattern; and developing the photoresist, are provided. Since the composition for forming anti-reflection film can be coated on the photoresist in the form of an aqueous solution, not only the anti-reflection film can be formed easily, but also, the film can be removed easily by rinsing with water or alkali development. Therefore, by the pattern formation method according to the present invention, it is possible to form a pattern easily with a high dimensional accuracy.
    Type: Grant
    Filed: February 2, 1994
    Date of Patent: May 7, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Mineo Nishi, Hideo Makishima
  • Patent number: 5514711
    Abstract: Styrene derivatives of the following general formula (I): ##STR1## or pharmaceutically acceptable salts thereof. A pharmaceutical composition useful as anticancer agent, which comprises the above compound as an essential component, is also provided.
    Type: Grant
    Filed: January 5, 1995
    Date of Patent: May 7, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasunori Kitano, Hisao Takayanagi, Koichi Sugawara, Hiroto Hara, Hideo Nakamura, Toshiko Oshino
  • Patent number: 5512645
    Abstract: There is provided a lactam ring-containing polymer comprising: 20 to 100 molar % of a structural unit represented by the general formula (1); 0 to 70 molar % of a structural unit represented by the general formula (2); and 0 to 70 molar % of a structural unit represented by the general formula (3) and/or a structural unit represented by the general formula (4): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom or a methyl group, and X represents COOR.sup.4 and/or CONR.sup.5 R.sup.6 in which R.sup.4, R.sup.5 and R.sup.6 each represents a hydrogen atom or a C1-C4 alkyl.The polymer is excellent in heat resistance and is expected to be used for resin modifiers, polymeric additives for petroleum tertiary recovery, and other various applications.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: April 30, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shigeru Sawayama, Yasuharu Mori, Yukino Nagai
  • Patent number: 5510502
    Abstract: A catalyst component for use in the polymerization of .alpha.-olefins, comprising a compound represented by the following general formula I!: ##STR1## wherein R.sup.1 s represent a hydrogen atom, a C.sub.1-6 hydrocarbon group or a C.sub.1-12 hydrocarbon group containing silicon; each of R.sup.2 and R.sup.3 which forms the condensed ring represents a divalent C.sub.3-20 saturated or unsaturated hydrocarbon group, provided that at least one of R.sup.2 and R.sup.3 forms a ring condensed with the cyclopentadiene which is a seven- to twelve-membered ring having an unsaturated bond inherent in R.sup.2 or R.sup.3 ; Q represents a C.sub.1-20 divalent hydrocarbon group, a silylene group, a silylene group with a C.sub.1-20 hydrocarbon group, a germylene group, or a germylene group with a C.sub.1-20 hydrocarbon group; X and Y represent H, a halogen, a C.sub.1-20 hydrocarbon group, or a C.sub.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: April 23, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toshihiko Sugano, Tomohiko Takahama
  • Patent number: 5508244
    Abstract: Disclosed are a pretreatment process of a zeolite as a catalyst for producing an alcohol by hydration of an olefin, comprising keeping the zeolite in contact with water before the hydration, and a process for producing an alcohol which comprises hydrating an olefin in the presence of a zeolite catalyst obtained by keeping a zeolite as a catalyst in contact with water.
    Type: Grant
    Filed: August 19, 1994
    Date of Patent: April 16, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kouji Watanabe, Yutaka Mori
  • Patent number: 5507865
    Abstract: An aqueous ink comprising at least a water-soluble dye, water, and a basic amino acid, and a method for ink-jet recording which comprises issuing droplets of the aqueous ink from an ejection orifice, and adhering the droplets onto a receiving material.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: April 16, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Naohiro Yoshida, Nobuyoshi Sato
  • Patent number: 5505771
    Abstract: A dental gypsum composition is disclosed, comprising (A) 100 parts by weight of calcined gypsum, (B) from 0.005 to 5.0 parts by weight of an alkali metal tartrate, (C) from 0.1 to 5.0 parts by weight of a sugar alcohol, and (D) from 0.005 to 3.0 parts by weight of a retarder. The composition provides a denture model excellent in surface smoothness, dimensional precision, and mechanical strength even when combined with an impression made of an agar-based material or an alginate-based material.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: April 9, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shoichi Chihara, Kouichi Morita, Noboru Yamaguchi
  • Patent number: 5506782
    Abstract: A coke oven operation management system capable of accomplishing unified management of an operation from receiving of stock coal to production and shipment of coke through management and control processing using a computer. A head office and branch offices of a concern determine basic schedules for production and shipment of coke and receiving of stock coal based on sale and self-consumption depending on a user's demand for coke and incoming information on coal from a colliery for every month and notify a production adjustment and management section of a coke production factory of the basic schedules, request the section of shipment of coke based on the user's demand, and instruct the section to receive coal.
    Type: Grant
    Filed: January 19, 1994
    Date of Patent: April 9, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yoshihiro Omae, Kunio Ishikawa, Yoshifumi Komatsu, Haruo Watanabe, Masaharu Someya, Michio Toyota, Shigenobu Takaki, Kiyohide Nyu, Shigeki Kataoda, Masaki Irie, Yoshio Yoshizumi, Satoru Kimura
  • Patent number: 5506241
    Abstract: A method for preventing fibrin formation in anterior chamber characterized by administering argatroban into the anterior chamber is provided. A phermaceutical preparation for irrigation, eye drop, and drip infusion to effect the said method is also provided.
    Type: Grant
    Filed: September 27, 1994
    Date of Patent: April 9, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tomiya Mano, Jin Shiomura