Patents Assigned to Mitsubishi Chemical Industries Ltd.
  • Patent number: 4585591
    Abstract: This is disclosed novel intermediates, i.e. 17.beta.-ethynylsteroids, which are useful for the preparation of corticoids such as hydrocortisone and prednisolone, and a process for preparing the same.
    Type: Grant
    Filed: November 25, 1981
    Date of Patent: April 29, 1986
    Assignee: Mitsubishi Chemical Industries, Ltd.
    Inventors: Issei Nitta, Shinichiro Fujimori, Toshio Haruyama, Shinya Inoue
  • Patent number: 4585766
    Abstract: Novel 6-oxygenated corticoid 17.alpha.-carbonates are disclosed. These compounds have strong topical anti-inflammatory activity which are accompanied by extremely weak systemic adverse reaction. The present compounds are useful for the treatment of acute and chronic eczema, eczema seborrhoicorum, contact dermatitis, atopic dermatitis, asthma, etc.
    Type: Grant
    Filed: August 28, 1984
    Date of Patent: April 29, 1986
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Issei Nitta, Kenichiro Nakao, Motoyoshi Miyake, Akira Maruyama, Junko Takashima
  • Patent number: 4582662
    Abstract: A process for producing a carbon fiber from pitch material, which comprises melt spinning pitch material through spinning nozzles to form precursory pitch fibers and oiling the precursory pitch fibers, followed by infusible treatment and carbonization and optionally by graphitization, characterized in that an oiling agent composed essentially of a silicone oil is applied to the precursory pitch fibers prior to or during the oiling operation.
    Type: Grant
    Filed: May 22, 1984
    Date of Patent: April 15, 1986
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Shinichiro Koga, Taizo Okajima, Shigeya Yamaguchi, Eisaku Kakikura
  • Patent number: 4577385
    Abstract: A method and apparatus for observing and/or repairing damages on a wall of a coke oven or combustion chamber is disclosed. The damages on the wall are detected by positioning a heat resisting lance which includes an optical system for observing an image on the wall and conduit having a nozzle for spraying repairing materials onto damaged areas on the wall in the inside of the coke oven and moving the lance horizontally and vertically within the coke oven along its wall while observing the image on the wall at an outside of the coke oven through the optical system. When the damages are detected, the damages are repaired by spraying the repairing material onto the damaged area on the wall from the nozzle.
    Type: Grant
    Filed: May 20, 1983
    Date of Patent: March 25, 1986
    Assignee: Mitsubishi Chemical Industries, Ltd.
    Inventors: Yoshihiro Omae, Kunio Ishikawa, Takahisa Fukao, Katsushige Yoshida
  • Patent number: 4576966
    Abstract: 2-(4-Methylaminobutoxy)diphenylmethane or pharmaceutically acceptable salts thereof have been found to be useful as a pharmaceutical composition for improvement and/or treatment of mental symptoms caused by an organic disorder in the brain.
    Type: Grant
    Filed: August 3, 1984
    Date of Patent: March 18, 1986
    Assignees: Eisai Co., Ltd., Mitsubishi Chemical Industries Ltd.
    Inventors: Shizuo Kuriyama, Mikio Saitoh
  • Patent number: 4574012
    Abstract: A calcium silicate shaped product comprises heat-resistant particles having a radiation energy absorptivity of at least 20% throughout the entire range of the wavelength of from about 2 to about 5.mu., as measured by a 0.1 wt. % KBr disc method.
    Type: Grant
    Filed: December 28, 1982
    Date of Patent: March 4, 1986
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Yasuo Oguri, Mitsuru Awata, Noriyuki Ariyama
  • Patent number: 4562211
    Abstract: 2-Substituted-1-(omega-aminoalkoxy)benzenes are prepared and found useful as pharmaceutical agents, particularly as antidepressants.
    Type: Grant
    Filed: November 16, 1979
    Date of Patent: December 31, 1985
    Assignee: Mitsubishi Chemical Industries, Ltd.
    Inventors: Ryoji Kikumoto, Akihiro Tobe, Shinji Tonomura, Hidenobu Ikoma
  • Patent number: 4560807
    Abstract: A process for producing dimethyl ether useful as a propellant by dehydrating methanol and recovering dimethyl ether from the dehydrated product by distillation, which comprises(A) a reaction step wherein the dehydration reaction of methanol is conducted in a vapor phase under pressure of from 2 to 50 kg/cm.sup.2 G in the presence of a solid acid catalyst,(B) a first distillation step wherein the reaction mixture formed by the above reaction step is cooled and introduced into a pressurized distillation column under pressure of at least 5 kg/cm.sup.
    Type: Grant
    Filed: April 27, 1984
    Date of Patent: December 24, 1985
    Assignee: Mitsubishi Chemical Industries, Ltd.
    Inventors: Nobuyuki Murai, Kazuya Nakamichi, Masayuki Otake, Takashi Ushikubo
  • Patent number: 4560623
    Abstract: A specular product of bronze-like tone particularly suitable for use as a decorative material. The specular product uses, as a substrate, a composite board comprising a synthetic resin sheet and metal sheets laminated thereon, and includes a nickel deposit plated on the metal sheet and a specular film of Sn-Ni alloy electroplated on the nickel deposit using a specific electroplating bath.
    Type: Grant
    Filed: May 8, 1984
    Date of Patent: December 24, 1985
    Assignee: Mitsubishi Chemical Industries, Ltd.
    Inventors: Yoshitaka Iwata, Ken Matsuda
  • Patent number: 4560682
    Abstract: The present invention provides a novel organophosphoric acid ester represented by the following formula, a process for its production and a pesticidal composition containing this ester as an active ingredient: ##STR1## where R.sup.1 is an alkyl group, R.sup.2 is an alkyl group or a thioalkyl group, each of R.sup.3, R.sup.4 and R.sup.5 is a hydrogen atom, a halogen atom, an alkylthio group, a nitro group, a cyano group, an alkyl group, an alkylsulfinyl group, an alkylsulfonyl group or a trifluoromethyl group, and X is an oxygen atom or a sulfur atom.
    Type: Grant
    Filed: December 7, 1984
    Date of Patent: December 24, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Ohta Hiroki, Oda Masatsugu, Kato Jun
  • Patent number: 4546172
    Abstract: A process for producing polycarbonate resin particles from a methylene chloride solution of a polycarbonate resin obtained by the polycondensation of a dihydroxydiaryl compound and phosgene, which comprises continuously supplying the methylene chloride solution of the polycarbonate resin to a particle-forming vessel, heating it while maintaining it in a suspended state in water to evaporate methylene chloride and to form an aqueous slurry containing polycarbonate resin particles, subjecting at least a part of the resulting aqueous slurry withdrawn from the particle-forming vessel and containing the polycarbonate resin particles to wet pulverization treatment and recycling at least a part of the treated polycarbonate resin particles to the particle-forming vessel.
    Type: Grant
    Filed: January 5, 1984
    Date of Patent: October 8, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Katsuhisa Kohyama, Akira Matsuno, Kenji Tsuruhara
  • Patent number: 4543365
    Abstract: A method for increasing the porosity of a cross-linked copolymer composed essentially of at least one monovinyl aromatic compound selected from the group consisting of styrene, vinyl toluene and ethyl vinyl benzene, at least one polyvinyl aromatic compound selected from the group consisting of divinyl benzene, trivinyl benzene, divinyl toluene and divinyl xylene, and an aliphatic vinyl compound, wherein the proportion of the polyvinyl aromatic compound relative to the total vinyl compounds is from 8 to 80% by weight, and the proportion of the aliphatic vinyl compound relative to the total vinyl compounds is from 0 to 20% by weight, which method comprises treating particles of said copolymer with a Lewis acid catalyst in an amount of from 0.05 to 1 part by weight relative to 1 part by weight of the copolymer particles, in the presence of an organic solvent.
    Type: Grant
    Filed: January 24, 1985
    Date of Patent: September 24, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Takaharu Itagaki, Tsuyoshi Ito, Kiyoto Ando, Hiromi Teshima
  • Patent number: 4541914
    Abstract: A process for converting coal, comprising, subjecting a slurry composed essentially of coal, a hydrocarbon solvent and a hydrogenation catalyst to primary hydrogenation to liquify the coal, separating the ash content of said coal from the reaction product thereby obtaining a liquified product, subjecting at least a portion of the liquified product to secondary hydrogenation in the presence of a hydrogenation catalyst thereby converting the liquified product to light oil product, the secondary hydrogenation step being a point of supply of hydrogenation catalyst to the coal conversion system, separating the hydrogenation catalyst from the reaction product of the secondary hydrogenation step, and returning said separated hydrogenation catalyst to the primary hydrogenation step where it is used as the catalyst for primary hydrogenation of said slurry.
    Type: Grant
    Filed: April 12, 1983
    Date of Patent: September 17, 1985
    Assignees: Mitsubishi Chemical Industries Ltd., Kabushiki Kaisha Kobe Seikosho, Idemitsu Kosan Company Limited, Asia Oil Company Limited, Nippon Brown Coal Liquefaction Co., Ltd.
    Inventors: Nobuyoshi Hirokoh, Yoichi Kageyama, Yukio Nakako, Tetsuo Matsumura
  • Patent number: 4542070
    Abstract: A polyurethane elastomer and a metal are strongly adhered by using (1) a composition containing a polyepoxy compound and a polyamine compound and (2) a composition containing an isocyanate compound having a concentration of isocyanate group of 15-50% by weight. An adhered composite article thus obtained has excellent water resistance and heat resistance.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: September 17, 1985
    Assignees: Mitsubishi Chemical Industries Ltd., Ihara Chemical Industry Co., Ltd.
    Inventors: Masaaki Ohtani, Takao Harada, Yoshijiro Oyaizu, Tatsuhiko Kobayashi
  • Patent number: 4541859
    Abstract: A method for reducing the phytotoxicity of agricultural machine oil in its application to an agricultural or horticultural plant to exterminate noxious insects and acarines, characterized in that, prior to or at the same time as the application of the machine oil, a sucrose fatty acid ester is applied to the agricultural or horticultural plant in an amount of from 0.1 to 50 parts by weight per 100 parts by weight of the machine oil, in the form of an aqueous solution containing from 0.001 to 1 wt/v % of the ester.
    Type: Grant
    Filed: December 22, 1983
    Date of Patent: September 17, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Takashi Tozawa, Masahiro Endo, Yukio Eiraku
  • Patent number: 4536209
    Abstract: .DELTA.'-Tetrahydrophthalimides having a substituted oxy group at 3-position and, if necessary, a halogen atom at 4-position and/or at 2-position of phenyl group as N-substituent have excellent herbicidal activity and are useful as selective herbicides.
    Type: Grant
    Filed: October 5, 1981
    Date of Patent: August 20, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Tetsuo Jikihara, Masatsugu Oda, Bunji Natsume, Hisao Watanabe, Seiichi Suzuki
  • Patent number: 4534953
    Abstract: A process for preparing solid titanium trichloride useful for the polymerization of an .alpha.-olefin, which comprises precipitating violet-colored fine solid particles of titanium trichloride at a temperature of not higher than 150.degree. C. from a liquid of titanium trichloride liquefied in the presence of an ether, characterized in that after the amount of the precipitated violet-colored fine solid particles of titanium trichloride reaches at least 80% based on the total amount of titanium trichloride in the system, titanium tetrachloride is added in an amount within a molar ratio of from 0.2 to 10 based on the total amount of titanium trichloride in the system, followed by aging at a temperature of from 60.degree. to 120.degree. C.
    Type: Grant
    Filed: June 29, 1983
    Date of Patent: August 13, 1985
    Assignee: Mitsubishi Chemical Industries, Ltd.
    Inventors: Nobuaki Goko, Yumito Uehara
  • Patent number: 4528403
    Abstract: A hydroformylation process which comprises hydroformylating an olefinic compound by reacting it with water gas in a catalyst solution containing rhodium and an oxide of an organic trivalent phosphorus compound; adding an organic trivalent phosphorus compound to the reaction mixture, followed by distillation to separate a distillate containing the hydroformylation product from a high-boiling residue containing rhodium; oxidizing the high-boiling residue at the same time as or subsequent to the distillation, to convert the organic trivalent phosphorus compound to its oxide; and recycling the oxidized residue to the hydroformylation reaction zone.
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: July 9, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Kazuo Tano, Keiichi Sato, Toru Okoshi
  • Patent number: 4525554
    Abstract: In a process for polymerizing an olefin in the presence of a catalyst system combining an organoaluminum compound with a hydrocarbon insoluble solid catalytic component prepared by treating a hydrocarbon solution containing a magnesium compound, and a titanium compound with an aluminum halide having the formulaAlR.sub.l.sup.1 X.sub.3-l.sup.1(R.sup.1 represents an alkyl, aryl or cycloalkyl group and X.sup.1 represents a halogen atom, and l is 1.ltoreq.l.ltoreq.2),an improvement characterized in that the magnesium compound is a compound having the formulaMg(OR.sup.2).sub.m X.sub.2-m.sup.2(R.sup.2 represents an alkyl, aryl or cycloalkyl group; X.sup.2 represents a halogen atom; and m is 1 or 2) and the titanium compound is a compound having the formulaTi(OR.sup.3).sub.n X.sub.4-n.sup.3(R.sup.3 represents an alkyl, aryl or cycloalkyl group; X.sup.3 represents a halogen atom; n is 1, 2 or 3).
    Type: Grant
    Filed: March 4, 1981
    Date of Patent: June 25, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Toru Tanaka, Kazutoshi Iwatani, Nobuo Enokido, Atsushi Murakami, Yukio Yamaguchi
  • Patent number: 4520208
    Abstract: An aromatic polyester comprising two structural units represented by the following formulas A and B in a molar ratio of the structural unit A to the structural unit B being from 70:30 to 90:10 or four structural units represented by the following formulas A, B, C and D in a molar ratio of the total of the structural units A and C to the total of the structural units B and D being from 10:90 to 95:5 and the total of the structural units C and D being less than 50 molar %, and having a reduced viscosity .eta.sp/C of from 0.6 to 4 dl/g as measured at 30.degree. C. at a concentration of 1.
    Type: Grant
    Filed: June 17, 1983
    Date of Patent: May 28, 1985
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Masahiro Hayashi, Seiichi Nozawa, Takashi Oikawa