Patents Assigned to Mitsubishi Gas Chemical Co. Inc.
  • Patent number: 5202127
    Abstract: An insect-proofing agent comprising 1,3,5-trioxane as an active ingredient is disclosed. This insect-proofing agent has a high insect-proofing action and gives no irritating odor, and the insect-proofing agent is not toxic to human bodies and has a high safety. Furthermore, this insect-proofing agent causes no discoloration in metallic substance such as silver thread, gold threads and spangles used for clothing decoration. This insect-proofing agent is effectively applied in the form of a solid preparation, an aqueous solution or an organic solvent solution.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: April 13, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Mutsuhiko Takeda, Minoru Kakuda, Masafumi Shimpo
  • Patent number: 5182363
    Abstract: Disclosed is a process for producing powder aggregate particle of high molecular weight polycarbonate resin which comprises adding a poor solvent to a solution containing 3 to 8% by weight of high molecular weight polycarbonate resin having a viscosity average molecular weight of at least 70,000 in a solvent in a ratio of the poor solvent to the solution of the polycarbonate resin of 0.2 to 0.6 by volume, continuously pouring the resulting mixture into water heated to a higher temperature than a boiling point of a solvent of the solution of the polycarbonate resin, thereby suspending the mixture in the warm water, distilling out the solvent and the poor solvent from the mixture, thereby obtaining a slurry of the polycarbonate resin and water in the following ratio by volume:Solvent/polycarbonate resin.ltoreq.0.55Solvent/poor solvent.ltoreq.0.7,and recycling at least a portion of the slurry to a wet-process pulverizer, while further distilling out the solvent and the poor solvent from the slurry.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: January 26, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Toshiaki Asoh, Tatsuhide Hosomi
  • Patent number: 5180518
    Abstract: The present invention relates to novel oxygen absorbent comprising as main ingredients a 1,2-glycol, glycerine or sugar alcohol with the oxygen absorbent materials.
    Type: Grant
    Filed: April 18, 1990
    Date of Patent: January 19, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Yasuo Sugihara, Toshio Komatsu, Takashi Kashiba, Hidetoshi Hatakeyama, Teruo Takeuchi
  • Patent number: 5179152
    Abstract: A fiber-reinforced resin composition having surface smoothness, which comprises(1) 100 parts by weight of a thermoplastic resin composition comprising an aromatic polycarbonate resin and a thermoplastic polyester resin in a weight ratio of from 10/90 to 90/10,(2) from 50 to 100 parts by weight of glass fiber sheet chips having an almost rectangular shape, each side having a length of from 1 to 30 mm, the glass fiber sheet chips being obtained by forming E-glass fibers having an average fiber diameter of 2 .mu.m or less which have been surface-treated with a silane coupling agent, into a sheet by a paper making process and then cutting the resulting sheet, and(3) from 0 to 40 parts by weight of a thermoplastic elastomeric polymer,and an exterior automotive part showing excellent image clarity, obtained by shaping the fiber-reinforced resin composition.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: January 12, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Goro Shimaoka, Makoto Mizutani, Isamu Mio, Kunitoshi Mimura
  • Patent number: 5160358
    Abstract: A process for easily producing a silica glass plate having an internal refractive index distribution suitable for a planar optical waveguide involves carrying out the following steps.(a) A porous silica gel plate produced by a sol-gel method is kept in a reactor, the pressure of which is reduced to a substantially vacuum state.(b) Germanium tetrachloride gas is introduced into the reactor at a partial pressure appropriate to establish an absorption equilibrium between a desired concentration of germanium tetrachloride in said porous silica gel plate and a partial pressure of germanium tetrachloride introduced.(c) The partial pressure of germanium tetrachloride in step (b) is reduced so as to desorb germanium tetrachloride from the surface of the porous silica gel plate.(d) The porous silica gel plate having a described concentration distribution is brought into contact with water within or outside the reactor so as to fix the distribution.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: November 3, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Osamu Kondo, Masukazu Hirata, Mitsuzo Arii
  • Patent number: 5157902
    Abstract: An oxygen-absorber accommodation parcel in which an air-impermeable material is superimposed on and peelably bonded to an air-permeable face of an air-permeable accommodation parcel which accommodates an oxygen-absorber compound. In the case of strip-formed continuous parcels in which accommodation parcels are connected side-by-side in one direction, a strip-formed air-impermeable material is bonded to the continuous parcels. During use, the air-impermeable material is peeled and removed from the strip-formed continuous parcels and, immediately thereafter, the strip-formed continuous parcels from which the air-impermeable material has been removed is cut along each connecting seal portion into individual oxygen-absorber accommodation parcels.
    Type: Grant
    Filed: May 28, 1991
    Date of Patent: October 27, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventor: Hidetoshi Hatakeyama
  • Patent number: 5134097
    Abstract: A sintered silicon nitride-silicon carbide composite material is provided comprising a matrix phase of silicon nitride and silicon carbide where silicon carbide grains having an average diameter of not more than 1 .mu.m are present at grain boundaries of silicon nitride grains and silicon carbide grains having a diameter of several nanometers to several hundred nanometers, typically not more than about 0.5 micrometers, are dispersed within the silicon nitride grains and a dispersion phase where (a) silicon carbide grains having an average diameter of 2 to 50 .mu.m and/or (b) silicon carbide whiskers having a short axis of 0.05 to 10 .mu.m and an aspect ratio of 5 to 300 are dispersed in the matrix phase. A process for the production of the composite material is also provided.
    Type: Grant
    Filed: November 4, 1991
    Date of Patent: July 28, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Koichi Niihara, Kansei Izaki, Takamasa Kawakami
  • Patent number: 5128304
    Abstract: A method of alkylating phenols which comprises reacting phenols having a hydrogen atom in at least one of the ortho-positions with regard to the hydroxyl group with an alcohol in a gaseous phase under heat in the presence of a catalyst comprising iron oxide, silica, chromium oxide, germanium oxide and an alkali metal compound. The catalyst exhibits a long catalytic activity duration and decreases frequency of regeneration and replacement of catalysts.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: July 7, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventor: Muneo Ito
  • Patent number: 5115081
    Abstract: A process for producing a dichloroformate of a tetrahalogenated bisphenol by an interfacial process in a high yield and a high content and a process for producing an aromatic copolycarbonate oligomer by a solution process using the resulting dichloroformate monomer are disclosed. The first process comprises adding a catalyst for chloroformate formation to a tetrahalogenated bisphenol in an amount of from 1.times.10.sup.-4 to 1.times.10.sup.-1 mol per mol of the bisphenol and consecutively adding a halogenated carbonyl to effect reaction while controlling the pH of the reaction system between 10 and 12 by consecutive addition of a basic inorganic compound to the reaction system. The copolycarbonate oligomer obtained using the dichloroformate monomer has high alternating regularity.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: May 19, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventor: Mituhiko Masumoto
  • Patent number: 5106462
    Abstract: Process for producing a copper plated resin article by forming a uniform copper coating having excellent adhesive strength on a fiber-reinforced or unreinforced thermoplastic or thermosetting resin article having a heat deformation temperature higher than 165.degree. C. The resin article is heated along with a source of copper formate under a reduced pressure or in a non-oxidative atmosphere to a temperature in the range above 165.degree. C. but lower than the heat deformation temperature of the resin article. The process makes it possible to produce a resin article having formed thereon a copper layer having an excellent adhesive strength by a very simple manner, and the resin article thus obtained can be used in various industrial fields.
    Type: Grant
    Filed: November 7, 1989
    Date of Patent: April 21, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Takamasa Kawakami, Rieko Nakano, Kazuhiro Ando, Ryuji Fujiura
  • Patent number: 5095049
    Abstract: A process for producing a low-particle-content transparent thermoplastic resin solution, which comprises centrifuging a solution of a transparent thermoplastic resin containing free water to separate it into a resin solution phase, an aqueous phase and an intermediate layer, and separating the resin solution phase from the aqueous phase and the intermediate layer. By this process, the number of particles having a size of at least 0.5 .mu.m in the resin solution can be decreased to 10,000 or less, preferably substantially zero, per gram of the transparent thermoplastic resin.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: March 10, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Kenji Maeda, Toshikazu Umemura, Yuki Ohtani, Takeaki Megumi
  • Patent number: 5094686
    Abstract: A process for producing a copper fine powder, which comprises thermally decomposing anhydrous copper formate in a solid phase in a non-oxidizing atmosphere at a temperature in the range of from 150.degree. to 300.degree. C., thereby yielding a copper fine powder having a primary particle diameter of from 0.2 to 1 .mu.m, a specific surface area of from 5 to 0.5 m.sup.2 /g and small agglomerating properties, said anhydrous copper formate being an anhydrous copper formate powder 90 wt % or more of which undergoes thermal decomposition within a temperature range of from 160.degree. to 200.degree. C. when the anhydrous copper formate powder is heated in a nitrogen or hydrogen gas atmosphere at a heating rate of 3.degree. C./min.
    Type: Grant
    Filed: September 11, 1990
    Date of Patent: March 10, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Takamasa Kawakami, Satoru Makinose, Kazuhiro Ando, Rieko Nakano
  • Patent number: 5094846
    Abstract: By incorporating a liquid or solid silicone or paraffin into 1,3,5-trioxane, agglomeration of trioxane particles and adhesion of the trioxane to a machine wall or the like can be prevented. The silicone or paraffin is used in an amount of 0.003 to 1% by weight.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: March 10, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Mutsuhiko Takeda, Minoru Kakuda, Masafumi Shimpo, Kiyoshi Yoshida
  • Patent number: 5084290
    Abstract: A method and an apparatus for applying a freshness keeping agent to a food packaging body arranged to comprise: a step in which a hot-melt adhesive agent is, at a predetermined interval, dripped on to the inner surface of a wrapping film which is being continuously supplied; a step in which an elongated train consisting of a plurality of freshness keeping agent bags successively connected in a direction and continuously supplied is cut into individual freshness keeping agent bags; a step in which each freshness keeping agent bag is conveyed to the wrapping film through a chute; and a step in which either side of each freshness keeping agent bag and the inner surface of the wrapping film are joined to each other under pressure at a portion to which the hot-melt adhesive agent is applied.
    Type: Grant
    Filed: July 12, 1990
    Date of Patent: January 28, 1992
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Yoshikazu Morita, Yuichi Fujii
  • Patent number: 5071870
    Abstract: Disclosed is a composition comprising trioxane and an assistant aiding in the insect-proofing action of trioxane or controlling its vapor pressure.
    Type: Grant
    Filed: April 26, 1989
    Date of Patent: December 10, 1991
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Mutsuhiko Takeda, Minoru Kakuda, Kiyoshi Yoshida, Toshie Takahashi, Masafumi Shimpo
  • Patent number: 5058978
    Abstract: A main optical waveguide portion and/or branching optical waveguide portions of the optical waveguide is tapered in such a way so as to expand towards the output side for reducing a coupling loss due to mismatching of numerical apertures N.A. between optical fibers and the optical waveguide, wherein the light entering the optical waveguide at an angle determined by the numerical aperture N.A. of the optical fiber gradually reduces its angle of incidence to an interface of the core and cladding as it passes by a portion where the taper is provided and when the light reaches the output side of the optical fiber, the numerical aperture N.A. thereof is effectively reduced to a value which is lower than the numerical aperture N.A. determined by a difference of refractive-indices in the optical waveguide. By making the numerical aperture N.A.
    Type: Grant
    Filed: October 22, 1990
    Date of Patent: October 22, 1991
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Osamu Kondoh, Mitsuzo Arii, Tohru Nakajima, Yasunari Kawabata
  • Patent number: 5059727
    Abstract: A method of alkylating phenols which comprises reacting phenols having a hydrogen atom in at least one of the ortho-positions with regard to the hydroxyl group with an alcohol in a gaseous phase under heat in the presence of a catalyst comprising iron oxide, silica, chromium oxide, germanium oxide and an alkali metal compound. The catalyst exhibits a long catalytic activity duration and decreases frequency of regeneration and replacement of catalysts.
    Type: Grant
    Filed: August 21, 1990
    Date of Patent: October 22, 1991
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventor: Muneo Ito
  • Patent number: 5051309
    Abstract: An anti-dazzling polycarbonate polarizing plate is formed with a polarizing thin layer composed of a polymeric film having a dichroic substance adsorbed on and oriented in the polymeric film, and a polycarbonate sheet having a retardation value of at least 2000 nm bonded to one or both surfaces of the polarizing thin layer.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: September 24, 1991
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Takao Kawaki, Ryozo Kawai, Katsushige Hayashi, Masaki Nagata
  • Patent number: 5034447
    Abstract: A sliding resin composition comprising an aromatic polycarbonate resin composition (A) and zinc oxide whiskers (B) in an amount of from 1 to 40% by weight based on the total weight of the sliding resin composition. The sliding resin composition is suitably used in fields where a sliding property is required, such as a lens frame (lens tube) for cameras, gears and cams for OA machines and apparatus, etc.
    Type: Grant
    Filed: November 16, 1990
    Date of Patent: July 23, 1991
    Assignees: Mitsubishi Gas Chemical Co., Inc., Matsushita Electric Industrial Co., Ltd.
    Inventors: Toshiaki Izumida, Koujiro Matsuo, Jun Yagi, Sangoro Ichii, Naoto Obayashi
  • Patent number: 5028640
    Abstract: An aromatic polycarbonate resin composition for molding, comprising (a) an aromatic polycarbonate resin, (a) carbon fibers sized with an aromatic polycarbonate resin, and (c) an organic compound having at least two oxazoline rings per molecule is dislosed. The composition has excellent extrusion workability, mold deposit-preventing property and mechanical strength, and can be used as a molding material in the field of precision machines such as cameras, VTR's and facsimiles.
    Type: Grant
    Filed: November 28, 1989
    Date of Patent: July 2, 1991
    Assignee: Mitsubishi Gas Chemical Co. Inc.
    Inventors: Goro Shimaoka, Kenji Kouno