Patents Assigned to Mitsubishi Kasei Corporation
  • Patent number: 5245078
    Abstract: A process for separating an organic acid or acids from an organic acid-containing solution obtained by a fermentation method in which glucose is used as starting material, which comprises contacting said organic acid-containing solution to a cation exchange resin to have the organic acid or acids adsorbed on the cation exchange resin, then contacting the cation exchange resin to an eluent to have the organic acid or acids desorbed, and then separating from the eluate a solution containing the organic acid or acids, wherein said organic acid-containing solution is contacted to the cation exchange resin under such a condition that the pH or the organic acid-containing solution is maintained at a pH level lower than pKa where Ka is the ionization constant of the organic acid or acids or the primary ionization constant in a case of a polybasic acid or acids, and the pH of the eluate is maintained at the above pH level.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: September 14, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Toshihiro Maeda, Isao Nakazawa
  • Patent number: 5245085
    Abstract: Acyclic terpene compounds useful as intermediates for producing sarcophytol A which have an anti-carcinogenic promoter activity and anti-tumor activity, which compounds are shown by the general formula (I): ##STR1##
    Type: Grant
    Filed: October 15, 1992
    Date of Patent: September 14, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hisao Takayanagi, Yasunori Kitano, Yasuhiro Morinaka
  • Patent number: 5243768
    Abstract: A hydrophilic drying liquid such as isopropyl alcohol is evaporated and supplied to an object to be dried such as an electronic component. As the drying liquid is condensed on the surface of the object and flows down together with water adhering to the object, the object is dried. Water contained in the condensate is removed by means of a membrane-type separator disposed in the liquid or vapor of the drying liquid. A rise in the water concentration in the drying liquid is prevented so as to maintain high drying efficiency.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: September 14, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Takahisa Fukao, Masaaki Mita, Seiji Sudoh, Katashi Shioda
  • Patent number: 5238771
    Abstract: There are disclosed a photosensitive composition which comprises:(1) an o-naphtoquinonediazide compound;(2) an alkali soluble resin; and(3) any one selected from the groups consisting of:(a) an ester compound of a polyoxyalkylene sorbitol fatty acid and/or an ether compound of the fatty acid,(b) an alkylene oxide adduct of castor oil, hardened castor oil, lanolin alcohol, beeswax, phytosterol or phytostanol, and(c) at least one activator selected from the group consisting of polyoxypropylene alkyl ethers, polyoxypropylene alkylphenyl ethers and polyoxypropylene alkyl esters;.and a photosensitive lithographic printing plate which comprises a support; and a photosensitive layer formed by applying the above photosensitive composition.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: August 24, 1993
    Assignees: Konica Corporation, Mitsubishi Kasei Corporation
    Inventors: Kiyoshi Goto, Hideyuki Nakai, Hiroshi Tomiyasu, Yoshiko Kobayashi
  • Patent number: 5237746
    Abstract: A method for preparing a drum comprising a cylindrical aluminum substrate coated with an electrophotographic photoreceptor having reduced streak defects which comprises forming the cylindrical aluminum substrate by the porthole method using a mold having ceramic surfaces.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: August 24, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Motohisa Aoki, Yasuo Soyama, Katsuji Sakata
  • Patent number: 5239108
    Abstract: A process for producing an aliphatic or alicyclic aldehyde is disclosed, which process comprises the step of hydrogenating an aliphatic or alicyclic carboxylic acid or a derivative thereof with molecular hydrogen in the presence of a catalyst, wherein the catalyst is a zirconium oxide catalyst which contains chromium as an essential component, has a weakly basic site amount of more than 0.03 mmol/g as determined by a temperature programmed desorption method using carbon dioxide as an adsorbate in which the amount of carbon dioxide desorbed in the temperature range of from 100.degree. to 250.degree. C. is measured, and has pores having a radius of from 20 to 500 .ANG. in an amount of not less than 0.1 cc/g and pores having a radius of from 1,000 to 50,000 .ANG. in an amount of not less than 0.05 cc/g as measured with a mercury porosimeter. Aldehydes can be obtained directly from aliphatic or alicyclic carboxylic acids or derivatives thereof in high yield.
    Type: Grant
    Filed: October 20, 1992
    Date of Patent: August 24, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Toshiharu Yokoyama, Naoko Matsuyama, Takao Maki
  • Patent number: 5239045
    Abstract: A copolyester comprising a dicarboxylic acid component comprising (a) 80 to 99.5 mol % of terephthalic acid or an ester forming derivative thereof and (b) 0.5 to 4.5 mol % of a phenylenedioxy diacetic acid or an ester forming derivatives thereof and a diol component is described. Hollow containers and stretched film produced from the copolyester are further described. The copolyester has a high transparency, superior gas barrier property, mechanical strength, water resistance and heat resistance. In addition, since the copolyester has a low oligomer content, it scarcely contaminates a mold used in molding process, which leads to a high productivity. The molded article produced from the copolyester can be used widely as packaging materials including various films, sheets and containers. Moreover, since a molded article having superior properties is obtained form the copolyester alone, it is possible to manufacture various packaging materials without using a complicated apparatus and complicated process.
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: August 24, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Takuji Hirahara, Katsuji Tanaka, Kazuyoshi Mino
  • Patent number: 5236768
    Abstract: A thermal transfer recording sheet comprising a base film, a heat transferable ink layer formed on one side of the base film and a heat resistant lubricating layer formed on the other side of the base film, wherein the heat resistant lubricating layer contains a modified silicone oil having a viscosity of not lower than 600 cst, an average modified amount of which is not more than 1,500 g per mol of a modifying group.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: August 17, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Toshio Fujii, Yutaka Kawai, Yoshio Shimizu
  • Patent number: 5235113
    Abstract: A hydroformylation process for preparing a hydroformylated product by reacting an olefinic compound with hydrogen and carbon monoxide in the presence of a Group VIII metal catalyst, in the reaction of which there is present a phosphite compound having the formula (I), ##STR1## wherein R.sup.1 and R.sup.2 are respectively an aromatic hydrocarbon groups which may be the same or different and the aromatic hydrocarbon group has at least a hydrocarbon group on a carbon atom adjacent to a carbon atom bonded with an oxygen atom as a substituent; A.sup.1 is an n-valent organic group having an aliphatic hydrocarbon group, a cycloaliphatic hydrocarbon group or an aromatic hydrocarbon group bonded with an adjacent oxygen atom, which may respectively have a substituent; n is an integer of from 2 to 4; and the respective ##STR2## group may be the same or different.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: August 10, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Keiichi Sato, Yuji Kawaragi, Masaki Takai, Tooru Ookoshi
  • Patent number: 5234948
    Abstract: Optically active alkylenedioxybenzene derivatives of the formula: ##STR1## wherein m is an integer of 2-5, and n is an integer of 1-3, and acid addition salts thereof. A pharmaceutical composition containing a compound (I) or racemate, and a method of treating anxiety in a warm-blooded animal by administering the above compound (I) to said animal are also provided.
    Type: Grant
    Filed: August 18, 1992
    Date of Patent: August 10, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Heitaro Iwata, Akemichi Baba, Toshio Matsuda, Mitsuo Egawa, Akihiro Tobe, Kenichi Saito
  • Patent number: 5233575
    Abstract: A magneto-optical recording medium capable of overwriting which comprises a substrate, a magneto-optical recording layer provided on the substrate, a recording auxiliary layer provided on the substrate, a recording auxiliary layer provided on the magneto-optical recording layer and a heat sink layer provided on the side of the recording auxiliary layer.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: August 3, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Kenichi Uchino, Toshifumi Kawano
  • Patent number: 5231214
    Abstract: A process for producing a nitrile, which comprises subjecting an alkane and ammonia in the gaseous state to catalytic oxidation in the presence of an oxide of the formula:Mo.sub.a V.sub.b Te.sub.c Nb.sub.d X.sub.x O.sub.n ( 1)wherein X is at least one element selected from the group consisting of Mg, Ca, Sr, Ba, Al, Ga, Tl, In, Ti, Zr, Hf, Ta, Cr, Mn, W, Fe, Ru, Co, Rh, Ni, Pd, Pt, Zn, Sn, Pb, As, Sb, Bi, La and Ce,when a=1,b=0.01 to 1.0,c=0.01 to 1.0,d=0 to 1.0, andx=0.0005 to 1.0,and n is a number such that the total valency of the metal elements is satisfied.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: July 27, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Takashi Ushikubo, Kazunori Oshima, Tiaki Umezawa, Ken-ichi Kiyono
  • Patent number: 5231173
    Abstract: A metal chelate compound of a dis-azo compound represented by the following formula (I) with a metal: ##STR1## (wherein A is a residue forming a heterocyclic ring together with the carbon atom and the nitrogen atom to which it is bonded, X is a residue forming an aromatic group together with the two carbon atoms to which it is bonded, and D is an aromatic residue which may have a substituent, or a heterocyclic amine residue which may have a substituent, and Y is a group having active hydrogen) and an optical recording medium having a recording layer provided on a substrate so that information can be written in and/or read out by a laser, wherein the recording layer contains a metal chelate compound of the dis-azo compound represented by the above formula (I), with a metal.
    Type: Grant
    Filed: January 14, 1992
    Date of Patent: July 27, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Tetsuo Murayama, Shuichi Maeda, Satoru Imamura, Masako Takeuchi, Takumi Nagao
  • Patent number: 5229489
    Abstract: Peptide derivatives of the following general formula (I): Seq. ID Nos. 1-6. ##STR1## wherein AAA is deletion or Ser, BBB is deletion or Glu, CCC is deletion, Ile, Phe, Leu, cyclohexylalanine, D-alle or Lys substituted at the .epsilon.-position by C.sub.6 -C.sub.18 alkylcarbonyl group, DDD is Gly or Gln, EEE is Leu, Nle or Phe, FFF is Met, Leu or Nle, GGG is Ala, Ser, Leu, Asn, Asp or Gln, HHH is Leu, Glu or Lys, III is His, Lys or Arg, JJJ is His, Lys or Arg, Xaa is Ala modified at the carboxy terminal with an amino group, provided that CCC and DDD may independently be modified at the amino terminal by C.sub.2 -C.sub.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: July 20, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Tatsuhiko Kanmera, Akihisa Mori, Yoshihide Nakao, Toshihiko Minegishi
  • Patent number: 5229202
    Abstract: A carbon fiber having its surface coated with a copolymer composed of a diamine compound, a dicarboxylic acid compound and a glycidyl polyalkylene oxide derivative of the following formula (I), wherein the copolymer contains said polyalkylene oxide derivative in an amount of from 10 to 50% by weight as in the monomer composition: ##STR1## wherein R.sup.1 is H or an alkyl group having not more than 20 carbon atoms, R.sup.2 is H or CH.sub.3, and n is an integer of from 1 to 40.
    Type: Grant
    Filed: May 20, 1991
    Date of Patent: July 20, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Shigeki Tomono, Yoshihiro Sakamoto, Yasushi Omata, Manabu Fujiya
  • Patent number: 5227532
    Abstract: A method for producing an aldehyde, which comprises reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a Group VIII metal compound and an organic phosphite compound to produce a corresponding aldehyde, wherein an organic phosphite compound of the formula (I):P(OR.sub.1)(OR.sub.2)(OR.sub.3) (I)wherein each of R.sub.1 and R.sub.2 which may be the same or different, is a 2-naphthyl group which may have a substituent, provided that at least one of R.sub.1 and R.sub.2 is a substituted 2-naphthyl group of the formula (II): ##STR1## wherein R.sub.4 is a C.sub.1-30 organic group, and each of R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 which may be the same or different, is a hydrogen atom or an organic group, and R.sub.3 is 1 a 2-naphthyl group which may have a substituent, 2 a phenyl group which may have a substituent, or 3 an alkyl group which may have a substituent, is used as said organic phosphite compound.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: July 13, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Keiichi Sato, Masaki Takai, Yuji Kawaragi, Tooru Ookoshi
  • Patent number: 5227510
    Abstract: A method for producing a carbonic acid ester, which comprises reacting an aliphatic alcohol with carbon monoxide and oxygen in the presence of 1 a platinum group metal or its salt, 2 metal copper, a copper salt or a copper complex, 3 at least one member selected from the group consisting of alkali metal salts and alkaline earth metal salts, and 4 a 2-hydroxypyridine.
    Type: Grant
    Filed: July 24, 1992
    Date of Patent: July 13, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Eiichi Watanabe, Kenji Murayama, Kazutaka Ida, Keisuke Wada, Yukio Kasori
  • Patent number: 5227482
    Abstract: A method for preparing a lactam, which comprises subjecting a cycloalkanone oxime to a Beckmann rearrangement reaction in a gas phase in the presence of a carrier-supported catalyst containing tantalum, wherein the carrier-supported catalyst is the one prepared by contacting an organic compound containing tantalum to a silica carrier having pores with pore diameters of from to 150,000 .ANG. wherein the pore volume of pores with pore diameters of from 40 to 2,000 .ANG. is at least 80% of the total pore volume of pores with pore diameters of from 40 to 150,000 .ANG..
    Type: Grant
    Filed: April 17, 1992
    Date of Patent: July 13, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventor: Takashi Ushikubo
  • Patent number: 5227451
    Abstract: A urethane prepolymer useful for preparing paints, coating agents, adhesives, etc., is obtained by reacting a di-isocyanate with a tetra-functional polyol prepared by reacting erythritol with an alkylene oxide or lactone.
    Type: Grant
    Filed: April 7, 1992
    Date of Patent: July 13, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yukio Tsuge, Hisaharu Hotta, Haluo Iizuka
  • Patent number: 5225309
    Abstract: Disclosed is a light-sensitive litho printing plate comprising:a support, a light-sensitive layer and a silicone rubber layer provided thereon,wherein said light-sensitive layer contains a substance,whereby said substance forms a color during developing or after developing.
    Type: Grant
    Filed: March 19, 1992
    Date of Patent: July 6, 1993
    Assignees: Konica Corporation, Mitsubishi Kasei Corporation
    Inventors: Norihito Suzuki, Kiyoshi Goto, Hiroshi Tomiyasu, Kazuo Noguchi, Akeo Kasakura