Patents Assigned to Mitsubishi Polyester Film GmbH
  • Patent number: 7238417
    Abstract: The invention relates to a polyester film with a thickness of from about 4 to about 23 ?m, which comprises, alongside polyethylene terephthalate as main constituent, from about 2 to about 20% by weight of polyethylene naphthalate (based on the weight of the film), and has fewer than 30 pinholes per 100 m2. The invention further relates to a process for producing these films, and to the use of the films in packaging composites.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: July 3, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Ursula Murschall, Thorsten Kiehne, Gottfried Hilkert, Bart Janssens
  • Patent number: 7238428
    Abstract: Biaxially oriented polyester films which have a polyester-containing base layer (B) which additionally comprises poly(m-xyleneadipamide) and at least one overlayer (A), and whose average roughness is preferably from 10 to 100 nm and whose gloss is greater than 100, feature improved optical properties and very good barrier properties, especially toward passage of oxygen, and are therefore suitable as packaging materials for foods or other consumable items.
    Type: Grant
    Filed: January 15, 2004
    Date of Patent: July 3, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Matthias Konrad, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 7229696
    Abstract: The invention relates to an at least two-layer polyester film with a total thickness of from about 5 to about 200 ?m which comprises polyethylene terephthalate and from about 2 to about 20% by weight—based on the weight of the entire film—of polyethylene naphthalate, and also at least one functional outer layer.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: June 12, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Ursula Murschall, Franz Hora, Guenther Crass, Herbert Peiffer, Bodo Kuhmann
  • Patent number: 7229581
    Abstract: Invention relates to a process for producing a single-layer or multilayer film by extrusion or coextrusion, biaxial orientation, and heat setting based on crystallizable thermoplastics whose principal constituent is a crystallizable thermoplastic having a standard viscosity SV (DCA) of from 600 to 1000. The thermoplastic is mixed prior to extrusion or coextrusion with 50% by weight (based on the total weight of all thermoplastics) of a secondary thermoplastic having a standard viscosity SV (DCA) of more than 900 to 1500, the standard viscosity SV (DCA) of the two thermoplastics differing by at least 100 units. The secondary thermoplastic is a byproduct or waste product from the production of PET plastic bottles or originates from recycled PET bottles.
    Type: Grant
    Filed: November 5, 2003
    Date of Patent: June 12, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ulrich Kern, Ursula Murschall, Holger Kliesch
  • Patent number: 7229697
    Abstract: The invention relates to a hydrolysis-stable polyester film comprising a polyester, whose thickness is preferably in the range from 0.4 to 500 ?m. The film comprises polyester and at least one hydrolysis stabilizer and is distinguished by its low hydrolysis rate. The invention furthermore relates to a process for the production of the film and its use.
    Type: Grant
    Filed: September 8, 2005
    Date of Patent: June 12, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Bodo Kuhmann, Thorsten Kiehne, Ingo Fischer, Gottfried Hilkert
  • Patent number: 7223459
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least CPET, the heatsealable and peelable top layer (A) consisting of a) 80–98 % by weight of polyester and b) 2–10 % by weight of inorganic and/or organic particles having an average diameter d50 of from 2.5 to 12.0 ?m (based on the mass of the top layer (A)), wherein c) the polyester is composed of 12–89 mol % of units derived from at least one aromatic dicarboxylic acid and 11–88 mol % of units derived from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, d) the ratio of particle diameter d50 and layer thickness dA of the top layer (A) being greater than/equal to 1.0 and e) the layer thickness of the top layer (A) dA being from 2.3 to 10.0 ?m. The invention further relates to a process for producing the film and to its use.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: May 29, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
  • Patent number: 7211306
    Abstract: Coextruded, biaxially oriented polyester films which have a base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) includes a) from 80 to 98% by weight of polyester and b) from 2 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 3 to 12 ?m, and where c) the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and d) the ratio calculated from the particle size d50 of the particles and the layer thickness dA of the outer layer (A) is greater than or equal to 1.5, and the shrinkage of the films, at least in one direction, is more than 5%. The films of the invention are especially suitable, owing to their property of self-venting, as a lid film for APET/CPET or CPET trays.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: May 1, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
  • Patent number: 7205040
    Abstract: Coextruded, biaxially oriented polyester films which have a base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) comprises from 80 to 99% by weight of polyester and from 1 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 2.5 to 12 ?m, and where the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and the ratio calculated from the particle size d50 of the particles and the layer thickness dA of the outer layer (A) is ?1, and the base layer (B) comprises poly(-xyleneadipamide). The films of the invention are suitable, owing to their increased oxygen barrier, as a packaging material for foods and other consumable goods or as a lid film for APET/CPET or CPET trays.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: April 17, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
  • Patent number: 7189452
    Abstract: Biaxially oriented polyester films formed from a crystallizable polyester having increased diethylene glycol content and/or increased polyethylene glycol content, and/or increased isophthalic acid content, preferably polyethylene terephthalate. The films of the invention further include at least one IR-reflective pigment and one UV stabilizer. The inventive films feature adjustable mattness, diffuse scattering power for visible light, high light transmittance and IR reflectance and good thermoformability, and are suitable for thermally protective coatings or thermally protective packaging.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: March 13, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Ursula Murschall, Holger Kliesch
  • Patent number: 7189451
    Abstract: Multilayer, biaxially oriented polyester films which include as a constituent of the base layer B, a crystallizable polyester with increased diethylehe glycol content and/or increased polyethylene glycol content, and/or increased isophthalic acid content, preferably polyethylene terephthalate. The outer layers of the inventive films advantageously include at least one IR-reflective pigment and one UV stabilizer. The inventive films advantageously feature adjustable mattness, diffuse scattering power for visible light, high light transmittance, IR reflectance, and good thermoformability, and are suitable for thermally protective coatings or thermally protective packaging.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: March 13, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Ursula Murschall, Holger Kliesch
  • Patent number: 7186455
    Abstract: The invention relates to a white, biaxially oriented film which comprises a crystallizable thermoplastic as main componet and is characterized by further comprising at least one UV-stabilizer, at least one white pigment and at least one flame-proofing agent, which is soluble in the thermoplastic and introduced directly, during the film production, by masterbatch technology, whereby the masterbatch is pre-conditioned by gradual heating under reduced pressure and with stirring.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: March 6, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Andreas Stopp, Guenther Crass, Ulrich Kern
  • Patent number: 7186452
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least the APET side of an APET/CPET tray, the heatsealable and peelable top layer (A) consisting of a) 50–95% by weight of polyester and b) 5–40% by weight of a polyester-incompatible polymer (=anti-PET polymer) based on the mass of the top layer (A), wherein c) the polyester is composed of 20–95 mol % of units derived from at least one aromatic dicarboxylic acid and 5–80 mol % of units derived from at least one aliphatic dicarboxylic acid, and d) the layer thickness dA is from 1.3 to 3.0 ?m. The invention further relates to a process for producing the film and to its use.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: March 6, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Bodo Kuhmann, Harald Mueller
  • Patent number: 7182997
    Abstract: The invention relates to an opaque, white film with a thickness of from 10 to 500 ?m whose principal constituent is a crystallizable thermoplastic. The film comprises at least barium sulfate and at least one optical brightener. The barium sulfate and/or the optical brightener are incorporated directly into the crystallizable thermoplastic or are fed as a masterbatch during film production. At least one surface of the film bears a functional coating with a thickness of from 5 to 100 nm, in order to confer on the film surface an additional function such as sealability, printability, metallizability, sterilizability, antistatic properties, aroma barrier properties or improved adhesion to materials which would not adhere to the film surface without the coating, for example photographic emulsions.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: February 27, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Klaus Oberlaender
  • Patent number: 7157132
    Abstract: Biaxially oriented, co-extruded polyester films comprising a base layer consisting of at least 90 wt. % thermoplastic polyester, preferably polyethylene terephthalate (PET), at least one sealable outer layer and a second non-sealable outer layer and, optionally, other intermediate layers, in addition to at least one flame-retardant agent, preferably organic phosphorous compounds. The inventive films are characterized by low inflammability, high UV stability, no embrittlement when subjected to thermal stress and a surface which is devoid of troublesome opacity. They are suitable for a multiplicity of uses both indoors and outside. The outer layers contain anti-blocking agents such as silicic acid having an average particle diameter of preferably less than 50 nm and/or 2 ?m. Preferably, the sealable outer layer consists of a copolyester which is made of ethylene terephthalate and ethylene isophthalate units.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: January 2, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass, Herbert Peiffer
  • Patent number: 7147925
    Abstract: The invention relates to a single- or multilayer, white, biaxially oriented polyester film. Films of the invention are formed from thermoplastic polyester and are coated on at least one side with a water-soluble adhesion-promoting layer that includes a hydrolyzed amino-functional silane. The invention further relates to the use of the film and to a process for its production.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: December 12, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 7144615
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable with respect to at least CPET. The heatsealable and peelable top layer (A) consists of a) 70–97% by weight of polyester and b) 3–20% by weight of a polyester-incompatible polymer (=anti-PET polymer) based on the mass of the top layer (A), wherein c) the polyester is composed of 20–95 mol % of units derived from at least one aromatic dicarboxylic acid and 5–80 mol % of units derived from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, and d) the layer thickness of the top layer (A) dA is from 1.7 to 6.0 ?m. The invention further relates to a process for producing the film and to its use.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: December 5, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert, Matthias Konrad, Cynthia Bennett, Paul Broemmel
  • Patent number: 7141293
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least APET, the heatsealable and peelable top layer (A) consisting of a) 60–97% by weight of polyester and b) 3–30% by weight of a polyester-incompatible polymer (=anti-PET polymer), based on the mass of the top layer (A), wherein c) the polyester being composed of 25–95 mol % of units which derive from at least one aromatic dicarboxylic acid and 5–75 mol % of units which derive from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, and d) the layer thickness of the top layer (A) dA being from 0.7 to 2.5 ?m.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: November 28, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
  • Patent number: 7141307
    Abstract: Polyester films which comprise not only thermoplastic polyester, e.g. polyethylene terephthalate, but also from 5 to 45% by weight of poly(m-xyleneadipamide) and optionally from 0.02 to 1% by weight of fillers, and which have, on at least one surface, an adhesion-promoting layer comprised of a hydrolyzed amino-functional silane. The films of the invention are produced by a sequential stretching process, and feature improved mechanical properties, such as a modulus of elasticity greater than 3500 N/mm2 in both orientation directions, high gloss, low haze, and very good barrier properties with respect to oxygen transmission. Films of the invention are therefore a suitable packaging material for foods and other consumable items, and as starting material for production of laminates via extrusion coating.
    Type: Grant
    Filed: June 14, 2005
    Date of Patent: November 28, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Oliver Klein, Herbert Peiffer, Matthias Konrad
  • Patent number: 7138176
    Abstract: The present invention relates to a transparent, low-flammability, UV-resistant, oriented film made from a crystallizable thermoplastic and having a thickness of from 5 to 300 ?m. The film comprises at least one UV stabilizer and at least one flame retardant, and at least the flame retardant, and preferably also the UV stabilizer, is fed directly as a masterbatch to the crystallizable thermoplastic during production of the film. The film may have one or more layers, and the UV stabilizer may have been selected from the group consisting of the 2-hydroxybenzophenones, the 2-hydroxybenzotriazoles, the organonickel compounds, the salicylic esters, the cinnamic ester derivatives, the resorcinol monobenzoates, the oxanilides, the hydroxybenzoic esters, the sterically hindered amines and triazines, and the flame retardant may be an organic phosphorus compound, in particular an organic phosphorus compound soluble in polyethylene terephthalate.
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: November 21, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Andreas Stopp
  • Patent number: 7128968
    Abstract: Biaxially oriented polyester films which have at least one polyester-containing base layer (B) and at least one matt overlayer (A), the overlayer (A) comprising particles, preferably SiO2, which have a median diameter of from 2 to 10 ?m and have a SPAN98 of ?2, and the overlayer (A) comprising a polyester which has isophthalic acid units, feature in particular low opacity, high transparency, low gloss of the overlayer (A) and high processing reliability, and are therefore suitable as flexible packaging films even for use on high-speed packaging machinery.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: October 31, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Matthias Konrad, Herbert Peiffer, Gottfried Hilkert