Patents Assigned to Mitsubishi Polyester Film GmbH
  • Patent number: 6916548
    Abstract: The invention relates to biaxially orientated, co-extruded polyester films, which have at least one base layer that contains a thermoplastic polyester, preferably polyethylene terephthalate and approx. 2 to 60 wt.-% of a cycloolefin copolymer that is preferably composed of norbornene and ethylene units and which have at least one cover layer that is devoid of a COC and which optionally have additional cover or intermediate layers and can contain conventional additives such as stabilisers and anti-blocking agents. Said films are characterized in particular by a degree of whiteness>70%, an opacity>55% and a gloss, (at least on one side)>100 and are therefore suitable for numerous industrial applications. During the production of the films in accordance with the co-extrusion process, up to 70 wt.-% of reclaimed product can be used, without having a noticeable negative effect on the physical properties of the film.
    Type: Grant
    Filed: May 17, 2001
    Date of Patent: July 12, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Cynthia Bennett, Ulrich Kern, Herbert Peiffer
  • Patent number: 6913817
    Abstract: Biaxially oriented polyester films which have a polyester-containing base layer (B) and a matt overlayer (A), and are characterized by the following features: a) the transverse shrinkage of the film is between 1 and 2.3%, b) the transverse linear expansion of the film during thermo-mechanical analysis is smaller than or equal to 0.2%, c) the matt overlayer comprises particles, preferably SiO2, whose median diameter is from 2 to 10 ?m and whose SPAN98 is smaller than or equal to 2, and d) the matt overlayer (A) comprises a polyester which has from 4 to 30 mol % of isophthalic acid units are notable in particular for low opacity, high transparency and low gloss of the overlayer (A), and are therefore suitable as flexible packaging films and for the purposes of hot lamination.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: July 5, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Oliver Klein, Herbert Peiffer, Matthias Konrad
  • Patent number: 6902818
    Abstract: The invention relates to a transparent, UV-stabilized, single or multi-layered thermoformable film which contains, as a principal constituent, a crystallizable thermoplastic, preferably polyethylene terephthalate, and at least one UV-stabilizer. The inventive films are characterized by having a good stretchability, thermoformability and good optical and mechanical properties. Said films are suitable for outdoor uses just like shaped bodies made of the same.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: June 7, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass
  • Patent number: 6893706
    Abstract: The invention relates to a white, biaxially-oriented and coextruded polyester film which is matt on at least one side with at least one base layer B, which contains a cycloolefin copolymer (COC) in amounts of 4 to 60 wt. %, based on the weight of the base layer, in addition to polyester starting material. The glass transition temperature Tg of the COC lies in the range from 70 to 270° C. Said film has at least one matt outer layer (A), made from polyester and is particularly suitable for use in fast running machines such as winding, metallising, printing or laminating machines.
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: May 17, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Holger Kliesch, Gottfried Hilkert, Bart Janssens
  • Patent number: 6884517
    Abstract: The present invention relates to a high-whiteness, biaxially oriented polyester film with at least a base layer made from polyester. The base layer of the polyester film of the invention also comprises from 2 to 60% by weight of a cycloolefin copolymer (COC), from 0.1 to 25% by weight of a white pigment, and, if desired, from 0 to 5% by weight of an optical brightener, based on the weight of the base layer. The glass transition temperature of the COC here is to be within the range from 70 to 270° C. The film is particularly suitable for packing foods or other consumable items which are sensitive to light and/or to air, or for use in industry, e.g. for producing hot-stamping foils or as a label film, or for image-recording papers, printed sheets, or magnetic recording cards, or for processing on high-speed machinery for winding, metallizing, printing or laminating.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: April 26, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert, Bart Janssens
  • Patent number: 6881470
    Abstract: Biaxially oriented, co-extruded polyester films comprising a base layer consisting of at least 90 wt. % thermoplastic polyester, preferably polyethylene terephthalate (PET), at least one sealable outer layer and a second non-sealable outer layer and, optionally, other intermediate layers, in addition to at least one flame-retardant agent, preferably organic phosphorous compounds. The inventive films are characterized by low inflammability, no embrittlement when subjected to thermal stress and a surface which is devoid of troublesome opacity, and are suitable for a multiplicity of uses both indoors and outside. The outer layers contain anti-blocking agents such as silicic acid having a particle diameter of preferably less than 50 nm and/or more than 2 ?m. Preferably, the sealable outer layer consists of a copolyester which is made of ethylene terephthalate and ethylene isophthalate units.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: April 19, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass, Herbert Peiffer
  • Patent number: 6875803
    Abstract: The invention concerns transparent, flame retardant, thermoformable, UV-stabilized, single layered or multilayered films, containing a cristallizable thermoplastic material, preferably polyethyleneterephthalate, at least one flame retarding agent and a UV stabilizer as main components. Said films are characterized by good stretchability, thermoformability and good optical and mechanical properties, which makes them and the shaped bodies made from said films suitable for both inner and outer applications.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: April 5, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass
  • Patent number: 6872461
    Abstract: The invention relates to a co-extruded, biaxially oriented polyester films containing a flame-retardant agent which can be dissolved in the polyester. The film has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is a polyethylene terephthalate homopolymer, or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or copolymers and component (II) is a polymer containing at least one sulphonate group.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: March 29, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
  • Patent number: 6872460
    Abstract: The invention relates to biaxially oriented, co-extruded polyester films. Said films comprise a base layer which consists of at least 70% by weight of a thermoplastic polyester, preferably polyethylene terephthalate (PET) with a diethylene glycol and/or polyethylene glycol content greater than 1.3% by weight and have at least one matt outer layer and optionally additional intermediate layers. The films also contain at least one UV-absorber, preferably hydroxy benzotriazoles and triazines. The films are characterized by high UV-stability, no embrittlement after exposure to temperature, a matt surface devoid of unwanted clouding and excellent thermoforming properties and are, together with the molded bodies produced therefrom, suitable for numerous interior and exterior applications.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: March 29, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass
  • Patent number: 6872446
    Abstract: The invention relates to a white, biaxially oriented film made from a crystallizable thermoplastic with high whiteness, the thickness of the film being in the range from 10 to 500 ?m. The film comprises at least one rutile-type titanium dioxide as pigment and an optical brightener, with or without other additives, and has at least one additional functionality. The expression “additional functionality” includes UV resistance, yellowing resistance, photooxidative stability, flame retardancy, and sealability. This film may have one or more of the functional properties. All of these films are capable of cost-effective thermoforming, have good orientability, and have very good optical and mechanical properties. The invention further relates to a process for its production.
    Type: Grant
    Filed: February 27, 2002
    Date of Patent: March 29, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Klaus Oberlaender, Thorsten Kiehne
  • Patent number: 6869991
    Abstract: The invention relates to a white film with a thickness in the range of 1 to 500 ?m that contains a crystallizable thermoplast as the main component. The inventive film is further characterized in that it contains at least one UV stabilizer as the light stabilizer and at least one white pigment. The invention further relates to a method for producing said film and the use thereof.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: March 22, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Klaus Oberlaender, Guenther Crass, Ulrich Kern
  • Patent number: 6866920
    Abstract: The invention relates to a transparent, biaxially oriented polyester film with a base layer B which is composed of at least 80% by weight of a thermoplastic polyester, and with at least one outer layer A. Another polymeric layer made from a copolymer crosslinked using an acrylic and/or methacrylic compound, has been applied to that side of the film opposite to the outer layer A. The film has low oxygen transmission and exhibits very good adhesion between the respective layers. The coated film moveover has low coefficient of friction, excellent windability, and excellent antistatic performance. It is particularly suitable for packaging purposes, specifically for packaging foodstuffs or other consumable items. The invention further relates to a process for the production of the film.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: March 15, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Bart Janssens, Herbert Peiffer
  • Patent number: 6863954
    Abstract: Biaxially oriented, coextruded polyester films with a base layer at least 90% by weight of which is composed of a thermoplastic polyester, preferably polyethylene terephthalate (PET), and with at least one sealable outer layer and a second nonsealable outer layer and, if desired, with other intermediate layers, and comprising at least one UV absorber, preferably hydroxybenzotriazoles and triazines, have high UV resistance, do not embrittle when exposed to high temperatures, have a surface without undesirable haze and are suitable for numerous indoor and outdoor applications. The outer layers comprise antiblocking agents, such as silica with an average particle diameter preferably below 50 nm and/or above 2 ?m, and the sealable outer layer is preferably composed of a copolyester which has been built up from ethylene terephthalate units and ethylene isophthalate units.
    Type: Grant
    Filed: May 5, 2003
    Date of Patent: March 8, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Guenther Crass, Ulrich Kern, Ursula Murschall, Andreas Stopp
  • Patent number: 6855758
    Abstract: The invention relates to transparent, biaxially oriented and heat-set films having one or more layers and compris, as main constituent, at least one crystallizable thermoplastic, in particular a polyester, and also comprise at least one hydrolysis stabilizer. The hydrolysis stabilizer is preferably a phenolic compound, an oxazoline, and/or a monomeric or polymeric carbodiimide, where appropriate combined with an organic phosphite. It is preferably added in the form of a masterbatch. The film exhibits low longitudinal and transverse shrinkage. On exposure to moisture and heat it shows practically no embrittlement and retains its ultimate tensile strength. The additional functionality is preferably that the film has been made UV-resistant, or flame-retardant, or on one side or on both sides has been coated, or is sealable, and/or has been corona- or flame-treated.
    Type: Grant
    Filed: June 15, 2001
    Date of Patent: February 15, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Thorsten Kiehne, Harald Hessberger
  • Patent number: 6855395
    Abstract: The invention relates to a biaxially oriented, sealable polyester film with at least one base layer (B), with a sealable outer layer (A) and with another, non-sealable outer layer (C). The sealable outer layer (A) has a minimum sealing temperature (fin) of not more than 110° C. and a seal seam strength (fin) of at least 1.3 N/15 mm of film width. The two outer layers (A) and (C) are characterized by particular features. The film of the invention is particularly suitable for use in flexible packaging, and particularly and specifically for use on systems which operate in a vacuum.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: February 15, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Bart Janssens, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6855435
    Abstract: A transparent film whose thickness is in the range from 1 to 500 ?m and which comprises, as principal constituent, a crystallizable thermoplastic, wherein the film comprises at least one UV stabilizer as light stabilizer and at least one optical brightener, and to the use of the film, and also to a process for its production.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: February 15, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Guenther Crass, Guenter Bewer, Klaus Oberlaender
  • Patent number: 6852387
    Abstract: The invention relates to a one-sided mat, sealable, biaxially oriented polyester film with at least a base layer (B), a sealable cover layer (A) and an additional mat cover layer (C), where the sealable cover layer (A) has a minimum sealing temperature of 120° C. maximum and a seal-seam strength of at least 1.3 N/15 mm film width and where the topographies of the sealable cover layer (A) and the mat shimmering cover layer (C) have certain characteristics. The film according to this invention is suitable for the use as flexible packaging material, especially when used in connection with fast-running packaging machines.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: February 8, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Stefan Bartsch, Gottfried Hilkert
  • Patent number: 6852388
    Abstract: The invention relates to a single- or multilayer, biaxially oriented film based on a crystallizable polyester and comprising at least one primary stabilizer for inhibiting oxidative degradation. The crystallizable polyester comprises from 100 to 10 000 ppm of primary stabilizer in covalently bonded form. The invention further relates to a process for producing the film.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: February 8, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Rainer Kurz, Holger Kliesch, Bodo Kuhmann
  • Patent number: 6849325
    Abstract: The invention relates to a white film with a thickness of from 10 to 500 ?m whose principal constituent is a crystallizable thermoplastic. It also has to comprise at least one titanium dioxide of the rutile type as white pigment and at least one optical brightener. The optical brightener and/or the titanium dioxide are fed as a masterbatch during film production. A white film of this type is particularly suitable for interior decoration, for constructing exhibition stands, for exhibition requisites, for displays, for placards, for labels, in the fitting out of shops or of stores, as a promotional requisite or as a laminating material or for applications associated with food or drink.
    Type: Grant
    Filed: January 23, 2001
    Date of Patent: February 1, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Klaus Oberlaender
  • Patent number: 6841222
    Abstract: The invention relates to a white, sealable, flame-retardant coextruded, biaxially oriented polyester film composed of at least one base layer B and of outer layers A and B applied to the two sides of this base layer. The film also comprises at least one flame retardant and one white pigment. The invention also includes the use of the film and a process for its production.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: January 11, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Klaus Oberlaender, Guenther Crass, Ulrich Kern, Herbert Peiffer