Patents Assigned to Mitsui Toatsu Chemicals
  • Patent number: 4484003
    Abstract: .beta.-Chloroalanine is prepared by reacting in an aqueous medium an aziridine-2-carboxylate with hydrogen chloride in an amount of 2.0-5.0 moles per mole of the aziridine-2-carboxyalte and causing the thus-formed .beta.-chloroalanine to selectively crystallize out from the liquid reaction mixture. Since the solution recovered after the isolation of the crystallized .beta.-chloroalanine still contains .beta.-chloroalanine and by-produced .alpha.-chloro-.beta.-alanine dissolved therein, they may be converted into an aziridine-2-carboxylate by treating them with a base to recirculate it for reuse.
    Type: Grant
    Filed: December 29, 1982
    Date of Patent: November 20, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masaharu Ohoka, Toshio Katoh, Ryuichi Mita, Nobuyuki Kawashima, Chojiro Higuchi, Nobuhiro Kawashima, Akihiro Yamaguchi, Shousuke Nagai, Takao Takano
  • Patent number: 4482742
    Abstract: 3,3'-diamino diphenylsulfones are prepared by catalytically reducing and dehalogenating, in the presence of a reduction catalyst and a dehydrohalogenation agent, a diphenylsulfone compound of the general formula ##STR1## in which X is a halogen atom and Y is hydrogen or a halogen atom.
    Type: Grant
    Filed: April 12, 1983
    Date of Patent: November 13, 1984
    Assignee: Mitsui Toatsu Chemicals Inc.
    Inventors: Keizaburo Yamaguchi, Kenichi Sugimoto, Yoshimitsu Tanabe
  • Patent number: 4481131
    Abstract: An electroconductive polyolefin composition comprising (1) 100 parts by weight of a polyolefin resin, (2) 10 to 60 parts by weight of carbon black, (3) 0.1 to 6 parts by weight of sulfur and (4) at least 0.1 part by weight of one or two specified accelerators, and optionally containing 5 to 60 parts by weight of atactic polypropylene.
    Type: Grant
    Filed: February 11, 1982
    Date of Patent: November 6, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoichi Kawai, Yoshihisa Gotoh, Masami Maki, Sachio Yokote, Katsumi Sekiguchi, Katsuyoshi Sasagawa, Masao Imai
  • Patent number: 4481175
    Abstract: A calcium-phosphorus apatite is obtained by reacting a calcium compound with a phosphorus compound under reflux in a reaction medium consisting mainly of an organic solvent and water.
    Type: Grant
    Filed: October 21, 1983
    Date of Patent: November 6, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shinji Iino, Akihiko Nakamura, Kensaku Maruyama, Kohji Nakamura
  • Patent number: 4480002
    Abstract: Dyestuff-containing microscopic capsule suspension for record materials, containing in microscopic capsules a lactone family dyestuff represented by the general formula (I): ##STR1## wherein a, b, c and d are each a carbon atom or either one or two atoms of said a, b, c and d are nitrogen atoms and the remaining atoms are carbon atoms, said a, b, c and d may have one or two substituent groups, adjacent a-b, b-c or c-d bond may form another ring, X and Y represent individually a benzene, naphthalene or aromatic heterocyclic ring which may include one or more substituent groups, and X and Y may be the same or different and may be coupled together to form a ring; and a metal ion sequestering agent in the capsules or a liquid medium in which the capsules are suspended.
    Type: Grant
    Filed: November 30, 1981
    Date of Patent: October 30, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Makoto Asano, Kiyoharu Hasegawa, Hiroyuki Akahori, Michihiro Tsujimoto
  • Patent number: 4480065
    Abstract: A polypropylene-base resin composition which comprises:(a) 80-60 wt. % of a crystalline ethylenepropylene block copolymer having an ethylene content of 11-30 wt. % and specific physical data;(b) 5-35 wt. % of an ethylene-propylene copolymer rubber having a propylene content of 20-50 wt. % and a specific Mooney viscosity;(c) 5-35 wt. % of an ethylene-propylene-a specific diene terpolymer having a propylene content of 20-50 wt. % and a specific Mooney viscosity; and(d) 2-5 wt. %, based on the total weight of the above resin components (a), (b) and (c), of an inorganic filler having a particle size of 3 .mu.m or smaller.The composition has excellent paintability and high stiffness, impact resistance and molding fluidity.
    Type: Grant
    Filed: May 17, 1983
    Date of Patent: October 30, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoichi Kawai, Yoshihisa Gotoh, Masami Maki, Akio Yoshihara, Minoru Hoshino, Katsumi Sekiguchi
  • Patent number: 4476310
    Abstract: A process for the preparation of indoles which comprises reacting aniline or a derivative thereof with a 1,2-glycol in the presence of a catalyst comprising silver supported on a carrier having a specific surface area of not less than 10 m.sup.2 /g.
    Type: Grant
    Filed: June 9, 1982
    Date of Patent: October 9, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadatoshi Honda, Fujio Matsuda, Tadamitsu Kiyoura, Kazuhiro Terada
  • Patent number: 4476335
    Abstract: In a process for the preparation of mononitrochlorobenzene by nitration of chlorobenzene using a mixed acid of nitric acid and phosphoric acid, the nitration reaction is carried out by using a molar ratio of nitric acid to chlorobenzene of not more than equimol in the presence of a concentrated phosphoric acid as the phosphoric acid component at temperatures of 50.degree.-120.degree. C. while maintaining the concentration of phosphoric acid to 72.4 weight % as P.sub.2 O.sub.5 or more during the reaction.
    Type: Grant
    Filed: November 30, 1982
    Date of Patent: October 9, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shinji Takenaka, Takeshi Nishida, Joshiro Kanemoto
  • Patent number: 4474969
    Abstract: Preparation process of indole from aniline and ethylene glycol. Upon preparing indole by reacting aniline and ethylene glycol in a gas phase and in the presence of a catalyst, ethylene glycol is charged in portions to a multiplicity of catalyst stages formed by dividing a catalyst bed and connected in series. This divided supply of ethylene glycol permits the suppresing of the decomposition of ethylene glycol, even if the molar ratio of feed aniline to total feed ethylene glycol is small. The above process permits making the yield of indole large and reducing the amount of unreacted aniline to be separated and recovered from the reaction effluent.
    Type: Grant
    Filed: April 22, 1983
    Date of Patent: October 2, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tadatoshi Honda, Kazuhiro Terada
  • Patent number: 4473486
    Abstract: A composition for nematic liquid crystal color display elements, said composition comprising at least one anthraquinonic dye represented by the following formula ##STR1## wherein X and Y are identical or different and represent --NH.sub.2 or --OH; Z represents halogen, --OR, --NHR, ##STR2## --CONHR.sub.2 or --COOR.sub.2, in which R represents an alkyl group having 1 to 15 carbon atoms or a lower alkyl group optionally substituted by --OH, ##STR3## R.sub.1 represents hydrogen, halogen, --OH, --OCH.sub.3, an alkyl group having 1 to 15 carbon atoms, or a methoxy group optionally substituted by ##STR4## and R.sub.2 is a phenyl group, an alkyl group having 2 to 5 carbon atoms or a cyclohexyl group; and n is an integer of 1 or 2 provided that when X is --NH.sub.2 and Y is --OH, and when X and Y are both --OH, n is an integer of 1, and when n represents an integer of 2, the two Z's may be identical or different dissolved in at least one nematic liquid crystal.
    Type: Grant
    Filed: August 4, 1982
    Date of Patent: September 25, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Ryoichi Morinaka, Ryoichi Tukahara, Tsutomu Nishizawa, Tuneo Hidaka
  • Patent number: 4473698
    Abstract: A process for the preparation of indole and derivatives thereof wherein an aniline is reacted with a 1,2-glycol in the vapor phase, the liquid phase or a mixed vapor-liquid phase. A salt of a metal of group IIa of the periodic table, a salt of iron, a salt of cobalt and/or a salt of nickel are used as the catalyst for this reaction. The present invention makes it possible to prepare indole and derivatives thereof in a single step by using inexpensive compounds as the starting materials.
    Type: Grant
    Filed: April 22, 1981
    Date of Patent: September 25, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Fujio Matsuda, Takazo Kato, Tadatoshi Honda
  • Patent number: 4473577
    Abstract: Disclosed are 2-thiazol derivatives having the general formula ##STR1## where R.sub.1 and R.sub.2 independently represent lower alkyl radicals having 1 to 4 carbon atoms and X represents a lower alkyl radical, a lower alkoxy radical, a lower alkoxycarbonyl radical, a halogenoalkoxy radical, a radical of the formula ##STR2## or a radical of the formula ##STR3## Also disclosed are a process for preparing the derivatives and pharmaceutical compositions having immunomodulatory activity which comprise the derivatives as the active ingredient.
    Type: Grant
    Filed: October 22, 1982
    Date of Patent: September 25, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Isao Sakano, Tatsuro Yokoyama, Kajiya Seitaro, Yutaka Okazaki, Hiroshi Tokuda, Hiroshi Kawazura, Mikio Kumakura, Takuo Nakano, Akira Awaya
  • Patent number: 4469506
    Abstract: Disclosed herein is a process for producing ferromagnetic iron powder, which process comprises adding and mixing boron oxide or a borate with .alpha.-FeOOH or .alpha.-Fe.sub.2 O.sub.3 without dissolving the former, heating the thus-obtained mixture to 350.degree. C. or higher in a non-reducing atmosphere and then reducing the thus-heated mixture.
    Type: Grant
    Filed: January 24, 1983
    Date of Patent: September 4, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Haruo Sekiguchi, Kimiteru Tagawa, Kazushi Ohshima, Nobuhiro Fukuda
  • Patent number: 4469507
    Abstract: Disclosed herein is a process for producing ferromagnetic iron powder, which process comprises adding and mixing zinc borate with .alpha.-FeOOH or .alpha.-Fe.sub.2 O.sub.3 without dissolving the former, heating the thus-obtained mixture to 350.degree. C. or higher in a non-reducing atmosphere and then reducing the thus-heated mixture.
    Type: Grant
    Filed: January 24, 1983
    Date of Patent: September 4, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Haruo Sekiguchi, Kazufuyu Sudoh, Sadao Kobayashi, Nobuhiro Fukuda
  • Patent number: 4468257
    Abstract: Method of adding water and a hydroxide of an alkali metal or alkaline earth metal to a washing solvent such as an alkylamide and/or alkylsulfoxide when washing and removing high molecular substances stuck on the interior of a production apparatus or molding machine for an aromatic vinyl-acrylonitrile copolymer. A method for regenerating and recovering the washing solvent used for the above-mentioned washing and removal by means of an evaporator and distillation tower.
    Type: Grant
    Filed: June 18, 1982
    Date of Patent: August 28, 1984
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masahiro Kaneko, Tadashi Asanuma, Nobutaka Uchikawa, Ichiro Fujio, Tetsunosuke Shiomura
  • Patent number: 4465856
    Abstract: In a conventional process for the purification of crude methacrylamide by the recrystallization from an aqueous medium, pH of the aqueous methacrylamide solution is controlled to a value in alkaline range of at least 8 and then methacrylamide is crystallized out. As the alkali used for the pH control, there have been used alkali metal and alkaline earth metal carbonates and hydroxides. Methacrylamide to be recrystallized is crude methacrylamide obtained by neutralizing methacrylamide sulfate obtained from acetone cyanhydrin and sulfuric acid with ammonia in the presence of water.
    Type: Grant
    Filed: January 19, 1982
    Date of Patent: August 14, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masato Horiuchi, Yoshinori Hatazaki, Kouji Terada
  • Patent number: 4464539
    Abstract: A process for producing an .alpha.,.beta.-unsaturated carboxylic acid or esters thereof which comprises bringing an .alpha.-hydroxycarboxylic acid amide into contact with a solid acid catalyst independently or along with water, or along with water and an aliphatic alcohol, or along with an aliphatic alcohol.
    Type: Grant
    Filed: April 6, 1983
    Date of Patent: August 7, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masao Hashimoto, Tadatoshi Honda
  • Patent number: 4460278
    Abstract: Disclosed is a continuous bulk polymerization reactor comprising a cylindrical reaction vessel elongated in the direction of the reacting fluid and a shaft installed within the reaction vessel. A plurality of flow of double helical-ribbon agitators are attached to the shaft in such a way that they face in the same direction, and a plurality of baffles having a relative open area of 5 to 40% based on the cross-sectional area of the internal space of the reaction vessel, are disposed between any adjacent ones of the agitators. Thus the formation of stagnant fluid pockets is avoided and excellent piston flow properties are achieved.
    Type: Grant
    Filed: January 7, 1982
    Date of Patent: July 17, 1984
    Assignees: Toyo Engineering Corporation, Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tetsuyuki Matsubara, Norifumi Ito, Yuzuru Ishida, Mune Iwamoto, Tetsuo Maeda
  • Patent number: 4459234
    Abstract: A novel process for producing anthraquinone in good yields is provided which comprises reacting phthalic anhydride with benzene in a single step in the vapor phase in the presence of a catalyst comprising titanium oxide and/or tin oxide.
    Type: Grant
    Filed: May 30, 1980
    Date of Patent: July 10, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Motoo Kawamata, Shiro Fujikake
  • Patent number: 4459218
    Abstract: As dichroic dyes for use in a liquid color display device, compounds of formula (I) ##STR1## such as 4'-octylphenyl perylene-3,9-dicarboxylate are provided. These compounds have various characteristic properties. For example, (1) they have a sufficient coloring ability in small amounts; (2) they have a high dichroic ratio and show a high contrast by application and non-application of voltage; (3) they have sufficient compatibility with liquid crystals; (4) they have excellent durability, are stable, and do not reduce the performance of a display device even in long-term use.
    Type: Grant
    Filed: May 21, 1982
    Date of Patent: July 10, 1984
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yasuyuki Yamada, Tadaaki Tanaka, Ryoichi Tukahara, Tsutomu Nishizawa