Abstract: .beta.-Chloroalanine is prepared by reacting in an aqueous medium an aziridine-2-carboxylate with hydrogen chloride in an amount of 2.0-5.0 moles per mole of the aziridine-2-carboxyalte and causing the thus-formed .beta.-chloroalanine to selectively crystallize out from the liquid reaction mixture. Since the solution recovered after the isolation of the crystallized .beta.-chloroalanine still contains .beta.-chloroalanine and by-produced .alpha.-chloro-.beta.-alanine dissolved therein, they may be converted into an aziridine-2-carboxylate by treating them with a base to recirculate it for reuse.
Abstract: 3,3'-diamino diphenylsulfones are prepared by catalytically reducing and dehalogenating, in the presence of a reduction catalyst and a dehydrohalogenation agent, a diphenylsulfone compound of the general formula ##STR1## in which X is a halogen atom and Y is hydrogen or a halogen atom.
Abstract: An electroconductive polyolefin composition comprising (1) 100 parts by weight of a polyolefin resin, (2) 10 to 60 parts by weight of carbon black, (3) 0.1 to 6 parts by weight of sulfur and (4) at least 0.1 part by weight of one or two specified accelerators, and optionally containing 5 to 60 parts by weight of atactic polypropylene.
Abstract: A calcium-phosphorus apatite is obtained by reacting a calcium compound with a phosphorus compound under reflux in a reaction medium consisting mainly of an organic solvent and water.
Abstract: Dyestuff-containing microscopic capsule suspension for record materials, containing in microscopic capsules a lactone family dyestuff represented by the general formula (I): ##STR1## wherein a, b, c and d are each a carbon atom or either one or two atoms of said a, b, c and d are nitrogen atoms and the remaining atoms are carbon atoms, said a, b, c and d may have one or two substituent groups, adjacent a-b, b-c or c-d bond may form another ring, X and Y represent individually a benzene, naphthalene or aromatic heterocyclic ring which may include one or more substituent groups, and X and Y may be the same or different and may be coupled together to form a ring; and a metal ion sequestering agent in the capsules or a liquid medium in which the capsules are suspended.
Abstract: A polypropylene-base resin composition which comprises:(a) 80-60 wt. % of a crystalline ethylenepropylene block copolymer having an ethylene content of 11-30 wt. % and specific physical data;(b) 5-35 wt. % of an ethylene-propylene copolymer rubber having a propylene content of 20-50 wt. % and a specific Mooney viscosity;(c) 5-35 wt. % of an ethylene-propylene-a specific diene terpolymer having a propylene content of 20-50 wt. % and a specific Mooney viscosity; and(d) 2-5 wt. %, based on the total weight of the above resin components (a), (b) and (c), of an inorganic filler having a particle size of 3 .mu.m or smaller.The composition has excellent paintability and high stiffness, impact resistance and molding fluidity.
Abstract: A process for the preparation of indoles which comprises reacting aniline or a derivative thereof with a 1,2-glycol in the presence of a catalyst comprising silver supported on a carrier having a specific surface area of not less than 10 m.sup.2 /g.
Abstract: In a process for the preparation of mononitrochlorobenzene by nitration of chlorobenzene using a mixed acid of nitric acid and phosphoric acid, the nitration reaction is carried out by using a molar ratio of nitric acid to chlorobenzene of not more than equimol in the presence of a concentrated phosphoric acid as the phosphoric acid component at temperatures of 50.degree.-120.degree. C. while maintaining the concentration of phosphoric acid to 72.4 weight % as P.sub.2 O.sub.5 or more during the reaction.
Abstract: Preparation process of indole from aniline and ethylene glycol. Upon preparing indole by reacting aniline and ethylene glycol in a gas phase and in the presence of a catalyst, ethylene glycol is charged in portions to a multiplicity of catalyst stages formed by dividing a catalyst bed and connected in series. This divided supply of ethylene glycol permits the suppresing of the decomposition of ethylene glycol, even if the molar ratio of feed aniline to total feed ethylene glycol is small. The above process permits making the yield of indole large and reducing the amount of unreacted aniline to be separated and recovered from the reaction effluent.
Abstract: A composition for nematic liquid crystal color display elements, said composition comprising at least one anthraquinonic dye represented by the following formula ##STR1## wherein X and Y are identical or different and represent --NH.sub.2 or --OH; Z represents halogen, --OR, --NHR, ##STR2## --CONHR.sub.2 or --COOR.sub.2, in which R represents an alkyl group having 1 to 15 carbon atoms or a lower alkyl group optionally substituted by --OH, ##STR3## R.sub.1 represents hydrogen, halogen, --OH, --OCH.sub.3, an alkyl group having 1 to 15 carbon atoms, or a methoxy group optionally substituted by ##STR4## and R.sub.2 is a phenyl group, an alkyl group having 2 to 5 carbon atoms or a cyclohexyl group; and n is an integer of 1 or 2 provided that when X is --NH.sub.2 and Y is --OH, and when X and Y are both --OH, n is an integer of 1, and when n represents an integer of 2, the two Z's may be identical or different dissolved in at least one nematic liquid crystal.
Abstract: A process for the preparation of indole and derivatives thereof wherein an aniline is reacted with a 1,2-glycol in the vapor phase, the liquid phase or a mixed vapor-liquid phase. A salt of a metal of group IIa of the periodic table, a salt of iron, a salt of cobalt and/or a salt of nickel are used as the catalyst for this reaction. The present invention makes it possible to prepare indole and derivatives thereof in a single step by using inexpensive compounds as the starting materials.
Abstract: Disclosed are 2-thiazol derivatives having the general formula ##STR1## where R.sub.1 and R.sub.2 independently represent lower alkyl radicals having 1 to 4 carbon atoms and X represents a lower alkyl radical, a lower alkoxy radical, a lower alkoxycarbonyl radical, a halogenoalkoxy radical, a radical of the formula ##STR2## or a radical of the formula ##STR3## Also disclosed are a process for preparing the derivatives and pharmaceutical compositions having immunomodulatory activity which comprise the derivatives as the active ingredient.
Abstract: Disclosed herein is a process for producing ferromagnetic iron powder, which process comprises adding and mixing boron oxide or a borate with .alpha.-FeOOH or .alpha.-Fe.sub.2 O.sub.3 without dissolving the former, heating the thus-obtained mixture to 350.degree. C. or higher in a non-reducing atmosphere and then reducing the thus-heated mixture.
Abstract: Disclosed herein is a process for producing ferromagnetic iron powder, which process comprises adding and mixing zinc borate with .alpha.-FeOOH or .alpha.-Fe.sub.2 O.sub.3 without dissolving the former, heating the thus-obtained mixture to 350.degree. C. or higher in a non-reducing atmosphere and then reducing the thus-heated mixture.
Abstract: Method of adding water and a hydroxide of an alkali metal or alkaline earth metal to a washing solvent such as an alkylamide and/or alkylsulfoxide when washing and removing high molecular substances stuck on the interior of a production apparatus or molding machine for an aromatic vinyl-acrylonitrile copolymer. A method for regenerating and recovering the washing solvent used for the above-mentioned washing and removal by means of an evaporator and distillation tower.
Abstract: In a conventional process for the purification of crude methacrylamide by the recrystallization from an aqueous medium, pH of the aqueous methacrylamide solution is controlled to a value in alkaline range of at least 8 and then methacrylamide is crystallized out. As the alkali used for the pH control, there have been used alkali metal and alkaline earth metal carbonates and hydroxides. Methacrylamide to be recrystallized is crude methacrylamide obtained by neutralizing methacrylamide sulfate obtained from acetone cyanhydrin and sulfuric acid with ammonia in the presence of water.
Abstract: A process for producing an .alpha.,.beta.-unsaturated carboxylic acid or esters thereof which comprises bringing an .alpha.-hydroxycarboxylic acid amide into contact with a solid acid catalyst independently or along with water, or along with water and an aliphatic alcohol, or along with an aliphatic alcohol.
Abstract: Disclosed is a continuous bulk polymerization reactor comprising a cylindrical reaction vessel elongated in the direction of the reacting fluid and a shaft installed within the reaction vessel. A plurality of flow of double helical-ribbon agitators are attached to the shaft in such a way that they face in the same direction, and a plurality of baffles having a relative open area of 5 to 40% based on the cross-sectional area of the internal space of the reaction vessel, are disposed between any adjacent ones of the agitators. Thus the formation of stagnant fluid pockets is avoided and excellent piston flow properties are achieved.
Abstract: A novel process for producing anthraquinone in good yields is provided which comprises reacting phthalic anhydride with benzene in a single step in the vapor phase in the presence of a catalyst comprising titanium oxide and/or tin oxide.
Abstract: As dichroic dyes for use in a liquid color display device, compounds of formula (I) ##STR1## such as 4'-octylphenyl perylene-3,9-dicarboxylate are provided. These compounds have various characteristic properties. For example, (1) they have a sufficient coloring ability in small amounts; (2) they have a high dichroic ratio and show a high contrast by application and non-application of voltage; (3) they have sufficient compatibility with liquid crystals; (4) they have excellent durability, are stable, and do not reduce the performance of a display device even in long-term use.